1. Introduction Modern land-based turbine airfoils operate in severe environments with high temperatures and near critical stresses. Highly turbulent combustor exit flows, with significant thermal gradients spew hot combustion products and other airborne particulates at the turbine surfaces for in excess of 20,000 hours before regularly scheduled maintenance [1]. Due to this harsh operating environment turbine surfaces experience significant degradation with service Technical advancements in the design and manufacture of gas path turbomachinery components over the past two decades have only heightened the significance of understanding the effects of owpath degradation on gas turbine operation. For example, surface coatings in both the compressor and turbine, more aggressive airfoil shapes, advanced rotor tip and passage endwall designs, and an increased number of bleeds to feed more intricate film cooling hole geometries are among the technologies that have created an increased urgency for fundamental research into the root causes and effects of degradation. As evidence of this increased emphasis, Figure 1. shows the number of degradation-related journal articles that have been published each year in three of the leading publications for gas turbine research.
Figure 1. Journal and conference articles published in the field of Gas Turbine Roughness, Turbomachinery, Gas Turbines and Power, Propulsion and Power, and Aircraft from 1970 to 2010. [2] The rising trend evidenced in the gure is likely to continue for the foreseeable future as gas turbines continue to command an impressive market share in both the power generation and transportation industries. Wind turbines have had various limitations to their mechanical system reliability owing to tribological problems over the past few decades [3]. Although current turbine designs have addressed and solved a number of the problems plaguing their predecessors, tribological issues still exist. This is evident from the data of Bell (2006), shown in figure 1, which indicate that the number of failures per turbine per year in Denmark and Germany dropped from 1 and 2.5,
Figure 2. Data from Bell (2006) indicate that the number of failures per turbine per year in Denmark (grey circles) and Germany (black triangles) dropped from 1 and 2.5, respectively, in 1994 to 0.5 and 0.8 in 2004 [4] 2. Lubrication Mineral oils are very popular for lubrication. It has several positive features such as easy availability and relatively low cost. On the other hand mineral oils also have several serious defects, such as oxidation and viscosity loss at high temperatures, combustion or explosion in the presence of strong oxidizing agents and solidification at low temperatures. These effects are prohibitive in gas turbine engines where a high temperature lubricant is required, but occasionally very low temperatures must be sustained. [5] To overcome some of the shortcomings of the mineral oils, synthetic lubricants were developed. Synthetic lubricants were originally introduced early this century by countries lacking a reliable supply of mineral oil. These lubricants were expensive and initially did not gain general acceptance. The use of synthetic oils increased gradually, especially in more specialized applications for which mineral oils were inadequate. In other applications such as vacuum pumps and jet engines, low vapour pressure lubricant is needed; in food processing and the pharmaceutical industry low toxicity lubricant is required, etc. In recent years the strongest demand has been for high performance lubricants, especially for applications in the aviation industry with high performance gas turbine engines. Gearing power transmission is a very important mechanism in any machine having rotating components. Snidle et al. presents a brief review of developments in understanding of gear tooth contact lubrication in relation to problems of surface durability and distress [6]. Gear tooth contacts tend to operate under conditions where the lubricating oil film is thin compared to surface roughness.
Figure 3. Gear tooth mesh mechanics (left) and performance of gear of two different surface finish (right) 3. Wear in Gas Turbine 3.1 Erosive Wear Erosive wear is caused by the impact of particles of solid or liquid against the surface of an object. Erosive wear occurs in a wide variety of machinery and typical examples are the damage to gas turbine blades when an aircraft flies through dust clouds, and the wear of pump impellers in mineral slurry processing systems. Figure 3. shows two severely eroded gas turbine blades.
Figure 4. Severely eroded turbine blades Impingement angles play a vital role in erosion mechanics. At zero impingement angle there is negligible wear because the eroding particles do not impact the surface, although even at relatively small impingement angles of about 20, severe wear may occur if the particles are hard and the surface is soft. Wear similar to abrasive wear prevails under these conditions. If the surface is brittle then severe wear by fragmentation of the surface may occur reaching its maximum rate at impact angles close to 90.
Figure 5. Impingement angle of a particle causing erosion of surface. The relationship between the wear rate and impingement angle for ductile and brittle materials is shown in Figure 5.
Figure 6. Schematic representation of the effect of impingement angle on wear rates of ductile and brittle materials. The rate and mechanism of erosive wear are influenced by temperature. The primary effect of temperature is to soften the eroded material and increase wear rates. The effects of temperature on erosion of stainless steel are shown in Figure 5 [7]. It is not until temperatures higher than 600C are reached that the erosion rate shows significant increase.
Figure 7. Effect of temperature on the erosive wear rate of stainless steel In common with other forms of wear, mechanical strength does not guarantee wear resistance and a detailed study of material characteristics is required for wear minimization. The properties of the eroding particle are also significant and are increasingly being recognized as a relevant parameter in the control of this type of wear. New blade coatings and materials are continuously being developed to meet the challenging requirements of modern gas turbine engines.Because of the serious consequences of erosion on gas turbine life and performance, it is necessary to gain a better understanding of the blade surface degradation mechanisms. [8] Turbine vane/blade surface deterioration is strongly dependent on the turbine geometry, blade surface material, and particle characteristics. Hamed et al. conducted simultaneous experiment and computer simulation on turbine blade erosion. Their experimental results for blade and coating material erosion indicate that both erosion rate and surface roughness increase with the eroding particle impact velocities and impingement angles and that larger particles produce higher surface roughness. Table 1 shows the measured surface roughness of the blades that they used for the experiments. Table 1. Roughness parameters for pressure surface roughened blades. [6] Location Ra Rq Rp Rt Suction side, leading edge 5.75 7.30 13.82 44.10 Pressure side, leading edge 3.93 5.72 11.84 36.37 Pressure side, mid chord 3.28 4.51 9.63 31.92 Pressure side, trailing edge 4.04 5.61 12.60 33.24
3.2 Hot Corrosion in Gas Turbine During combustion in the gas turbine, sulfur from the fuel reacts with sodium chloride from ingested air at elevated temperatures to form sodium sulfate. The sodium sulfate then deposites on the hot-section components, such as nozzle guide vanes and rotor blades, resulting in accelerated oxidation (or sulfidation) attack. This is commonly referred as hot corrosion. [9] High-temperature alloys that suffered hot corrosion attack were generally found to exhibit both oxidation and sulfidation.
Figure 8. Scanning electron back scattered image showing thecrosssectionofacorrodedIC-218 nickel aluminide specimen after hot corrosion burner rig testing at 900C Abradable coatings are provided to resist thermal corrosion. Figure 7. shows coated and uncoated turbine blade under high temperature corrosion and a heavily corroded turbine blade.
Figure 9. Coated and uncoated turbine blade under high temperature corrosion (left) heavily corroded turbine blade (right). Due to extreme temperatures on the turbine side of gas turbine engines, brazed or welded metallic structures made from nickel (Ni) based alloys have typically been used to provide gas path sealing. When thermal shock resistant ceramics became available, oxide ceramic, mostly zirconia based high temperature abradable seals for the high pressure turbine stages were developed. Turbine designers need to decide on a case-by-case basis whether metallic or ceramic abradables should be used and whether they can be cut by bare or hard tipped blades [10]. 4. Tribology and Gas Turbine Performance In last two decades, air traffic volume has increased considerably, whereas the total quantity of fuel consumed has remained almost unchanged. The jet engine manufacturers strongly contributed towards this by increasing engine efficiency and power generation. This was achieved by raising the operating temperatures, by the use of efficient aerodynamic design and by the use of lightweight materials. Because all of these are mature technologies, one of the last means to further increase the efficiency is the reduction of the clearance distance between the blade tip and casing. 4.1 Use of Advanced Materials Development in advanced materials, more than anything else, have contributed to the spectacular progress in thrust-to-weight ratio of the aero gas turbine. This has been achieved in the main through the substitution of titanium and nickel alloys for steel (Figure 8.) [11].A modern turbine blade alloy is complex in that it contains up to ten significant alloying elements, but its microstructure is very simple. In the alloy case the block are an intermetallic compound with the approximate composition Ni3(Al,Ta), whereas the cement is a nickel solid solution containing chromium, tungsten and rhenium. Abradables are not restricted to aeroengines. They can be used in most rotating machinery such as stationary gas turbines, turbo compressors, radial compressors, turbo charges, and pumps. The reduction of the blade tip to casing clearance can result in the blades rubbing against the shroud. By coating the shroud with abradables, however, this interaction can be tolerated [12].
Figure 10. Evolution of materials used in aero gas turbine
Figure 11. High temperature strength and hot corrosion trade-off with conventionally cast turbine airfoil alloys [13] Turbine airfoil alloy development typically emphasized high temperature strength and creep resistance at the expense of reduced ductility and resistance to shock, oxidation and hot corrosion. The effects of reduced chromium and increased stress rupture life with a hot corrosion resistance debit are shown in Figure 9. [13]. Yun et al. conducted performance tests in a low-speed, single-stage, axial flow turbine with roughened blades. Figure 10. shows roughened turbine and the performance plot [14]. They concluded that blade surface roughness severely degrades turbine efficiency.
Figure 12. Roughened test turbine (left) and efficiency plots. The study of turbine component roughness and its associated shear drag and convective heat transfer characteristics is important to increasing turbine component lifespan and even increasing overall engine efficiency by characterizing how much turbine surface degradation can cost the engine performance [15]. 5. Conclusion The various roughness mechanisms had very distinct signatures. Air borne contaminants were typically acts as surface spikes while hot corrosion resulted in surface pitting. The surface statistical skewness is a natural delineator between these two roughness forms and may be an important parameter for roughness modeling. Erosion due to the combination of airborne contaminants and corrosion resulted in much more irregular surfaces. Spallation was the most significant form of surface roughness measured, with huge variations in surface character. References [1] J. P. Bons, R. P. Taylor, S. T. McClain and R. B. Rivir, The many faces of turbine surface roughness, Journal of Turbomachinery, 123, pp. 739-748, 2001 [2] Bons, J. P., 2010, "A Review of Surface Roughness Effects in Gas Turbines," J. Turbomach., 132, pp. 021004 (2010), DOI:10.1115/1.3066315 [3] M. N. Kotzalas and G. L. Doll, Tribological advancements for reliable wind turbine performance, Phil. Trans. R. Soc., 368, pp. 4829-4850, 2010 [4] Bell, B. 2006 Wind turbine reliability and service improvements. In 2006 Wind Turbine Reliability Workshop, Albuquerque, NM, 34 October 2006. Albuquerque, NM: Sandia National Laboratories. [5] Gwidon W. Stachowiak and Andrew W. Batchelor, Engineering Tribology Butterworth Heinemann publications [6] R. W. Snidle, H. P. Evans and M. P. Alanou, Gearing lubrication, Tribological Research and Design for Engineering Systems, 41, pp. 575-588, 2003 [7] A. A. Hamed, W. Tabakoff, R. B. Rivir, K. Das, P. Arora, Turbine blade surface deterioration by erosion, AGARD (NATO) 83rd Symposium of Propulsion and Energetics Panel on Turbines, Rotterdam, The Netherlands, 25-28 April 1994 [8] H. Tomizawa and T.E. Fischer, Friction and Wear of Silicon Nitride and Silicon Carbide in Water: Hydrodynamic Lubrication at Low Sliding Speed Obtained by Tribochemical Wear, ASLE Transactions, Vol. 30, 1987, pp. 41-46. [9] Hot Corrosion in Gas Turbine, High Temperature Corrosion and Materials, Application ASM International [10] D. Sporer, S. Wilson, I. Giovannetti, R. Refke and M. Giannozzi, On the potential of metal and ceramic based abradables in turbine seal applications, Proceedings of the thirty-sixth turbomachineryh symposium, Turbomachinery Laboratory, Texas A & M Univeristy, 2007 [11] S. Miller, Advanced materials mean advanced engines, Materials World, 5, pp.446-49, 1996 [12] F. Ghasripoor, R. Schmid and M. Dorfman, Abradable coatings increase gas turbine engine efficiency, Materials World, 5:6, pp.328-30, June 1997 [13] J. W. Fairbanks and R. J. Hecht, The durability and performance of coatings in gas turbine and diesel engines, Material Science and Engineering, 88, pp. 321-330, 1987 [14] Y. I. Yun, I. Y. Park and S. J. Song, Performance degradation due to blade surface roughness in a single stage axial turbine, Journal of Turbomachinery, 127, pp. 137-143, 2005 [15] J. W. Drab, Turbine blade surface roughness effects on shear drag and heat transfer, Thesis, Department of Aeronautical Engineering, Air Force Institute of Technology, Wright- Patterson Air Force Base, Ohio, 2001
Townsend, R._ Winstone, M._ Henderson, M._ Nicholls, J.R._ Partridge, Alan_ Nath, B._ Wood, M._ Viswanathan, R. (Eds.)-Life Assessment of Hot Section Gas Turbine Components - Proceedings of a Conferen