PAPER - 2

INSTRUCTIONS
A. General :
1. This Question Paper contains 45 questions.
2. The question paper CODE is printed on the right hand top corner on this sheet of this booklet.
3. No additional sheets will be provided for rough work.
4. Blank paper, clipboard, log tables, slide rules, calculators, cellular phones, pagers and electronic gadgets
in any form are not allowed.
5. The answer sheet, a machine-gradable Objective Response Sheet (ORS), is provided separately.
6. Do not Tamper / mutilate the ORS or this booklet.
7. Do not break the seals of the question-paper booklet before instructed to do so by the invigilators.
8. Write your Name, Roll No. and Sign in the space provide on the back page of this booklet.
B. Filling the Top-half of the ORS :
Use only Black ball point pen only for filling the ORS. Do not use Gel / Ink / Felt pen as it might smudge the
ORS.
9. Write your Roll no. in the boxes given at the top left corner of your ORS with black ball point pen. Also, darken
the corresponding bubbles with Black ball point pen only. Also fill your roll no on the back side of your ORS
in the space provided (if the ORS is both side printed).
10. Fill your Paper Code as mentioned on the Test Paper and darken the corresponding bubble with Black ball
point pen.
11. If student does not fill his/her roll no. and paper code correctly and properly, then his/her marks will not be
displayed and 5 marks will be deducted (paper wise) from the total.
12. Since it is not possible to erase and correct pen filled bubble, you are advised to be extremely careful while
darken the bubble corresponding to your answer.
13. Neither try to erase / rub / scratch the option nor make the Cross (X) mark on the option once filled. Do not
scribble, smudge, cut, tear, or wrinkle the ORS. Do not put any stray marks or whitener anywhere on the
ORS.
14. If there is any discrepancy between the written data and the bubbled data in your ORS, the bubbled data will
be taken as final.
C. Question paper format and Marking scheme :
15. The question paper consists of 3 parts (Physics, Chemistry & Mathematics). Each part consists of Three
Sections.
16. For each question in SectionI, you will be awarded 4 marks if you darken the bubble corresponding to the
correct choice for the answer and zero mark if no bubbled is darkened. There is no negative marking for
incorrect answer(s) in this section.
17. For each question in SectionII, you will be awarded 2 marks for each row in which you have darkened the
bubble corresponding to the correct answer. Thus, each question in this section carries a maximum of
8 marks. There is no negative marking for incorrect answer(s) in this section.
18. For each question in SectionIII, you will be awarded 4 marks if you darken the bubble(s) corresponding
to the correct choice for the answer and zero mark if no bubbled is darkened. In case of bubbling of
incorrect answer, minus one (1) mark will be awarded.
D
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D
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Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
Date : 22-05-2013 Duration : 3 Hours Max. Marks : 204
TARGET : JEE (ADVANCED)-2013 COURSE : REVISION CLASSES
CODE
0
FULL SYLLABUS TEST-4 (FST-4)-JEE (ADVANCED)
PHYSICS
Space for Rough Work
RESONANCE
P2FST4220513C0-1
PART I : PHYSICS
SECTION - I
Multiple Correct Answers Type
This section contains 5 multiple correct answer(s) type questions. Each question has 4 choices
(A), (B), (C) and (D), out of which ONE OR MORE is/are correct.
1. Two solid isotropic blocks A and B are placed as a shown in the figure. If
block 'B' falls into the liquid, the level of liquid may :
A
(A) decrease
(B) remains same
(C) increase
(D) can't say
2. In a Young's Double Slit experiment, films of thickness t
A
and t
B
and refractive indices !
A
and !
B
are
placed in front of slits A and B respectively. If
A A B B
t t ! # ! , then the central maxima may
(A) not shift (B) shift torwards A (C) shift towards B (D) None of these
3. Choose the correct statements from the following :
(A) Good reflectors are good emitters of thermal raidations
(B) Burns caused by water at 100C are more severe than those caused by steam at 100C.
(C) All bodies emit thermal radiations at all temperatures greater than 0 K.
(D) It is impossible to construct a heat engine of 100% efficiency.
PHYSICS
Space for Rough Work
RESONANCE
P2FST4220513C0-2
4. A particle of mass m and charge q is fastened to one end of a light string
of length ! . The other end of the string is fixed to the point O. The whole
system lies on a frictionless horizontal plane. Initially, the mass is at rest
at A. A uniform electric field in the direction shown is switched on. Then : A
B O
60
E
l (A) the speed of the particle when it reaches B is
m
qEl 2
(B) the speed of the particle when it reaches B is
m
qE l
(C) the tension in the string when particles reaches at B is 2qE
(D) the tension in the string when the particle reaches at B is zero
5. Regarding a nucleus, choose the correct options :
(A) Density of a nucleus is directly proportional to mass number A.
(B) Nucleus radius
3
A $
(C) Nuclear forces are dependent on the nature of nucleons.
(D) Nuclear forces are short range forces.
SECTION - II
Matrix - Match Type
This section contains 2 questions. Each question contains statements given in
two columns, which have to be matched. The statements in Column-I are labelled
A, B, C and D, while the statements in Column-II are labelled p, q, r, s and t. Any
given statement in Column-I can have correct matching with ONE OR MORE
statement(s) in Column-II. The appropriate bubbles corresponding to the answers
to these questions have to be darkened as illustrated in the following example.
If the correct matches are A-p, s and t ; B-q and r; C-p and q; and D-s and t; then the correct darkening of
bubbles will look like the following :
PHYSICS
Space for Rough Work
RESONANCE
P2FST4220513C0-3
6. A source of sound stationary with respect to medium emits sound of frequency f and wavelength %. The
speed of sound with respect to medium is C, speed of medium is V
m
. The observer O
1
receives waves of
frequency f
1
and wavelength %
1
. The observer O
2
receives waves of frequency f
2
and wavelength %
2
. Match
the column given below if V
s
is speed of source with respect to ground.
ColumnI ColumnII
(A) Medium at rest, source at rest, O
1
and O
2
moves (p) %
1
< % < %
2
(B) medium at rest, O
1
, O
2
at rest, source moves (q) f
1
> f > f
2
(C) medium moves, source at rest, O
1
,O
2
at rest (r) %
1
= %
2
= %
(D) medium moves source moves, O
1
, O
2
at rest (s) f
1
< f < f
2
(t) %
1
> % > %
2
PHYSICS
Space for Rough Work
RESONANCE
P2FST4220513C0-4
7. In a hydrogen atom, a
0
= 0.529 , E
1
= 13.6 eV. Some modified situations are given compare the energy
of levels and radius of allowed orbits.
ColumnI ColumnII
(A) An atom consists of positive charge 2e and (p)
2
E
1
or 2E
1
mass m and an electron of mass m revolving around
the centre of mass of the system
(B) An atom consists of positron and an electron (q) 2a
0
or
2
a
0
revolving around the centre of mass of system
(C) An atom consists of a particle of mass double that (r)
9
2
E
1
or
2
9
E
1
of electron and charge same as that of electron revolving
around a heavy nucleus of charge 4e
(D) An atom consists of a nucleus of infinite mass and an (s) a
0
or 8a
0
electron revolving around the nucleus of charge 2e
(t) 4E
1
PHYSICS
Space for Rough Work
RESONANCE
P2FST4220513C0-5
SECTION - III
Integer Answer Type
This section contains 8 questions. The answer to each of the questions is
a single digit integer, ranging from 0 to 9. The appropriate bubble below
the respective question number in the ORS have to be darkened.
8. The figure shows a trolley with a light piston(area = 10 cm
2
)fitted on one end placed on a smooth horizontal
surface .Two moles of a diatomic gas is filled in the trolley. The piston is placed in contact with an ideal
spring which is undeformed.The walls of the trolley and the piston are adiabatic.There is no friction between
the trolley and the piston.Initially the value of
!
is 10 cm. Now the gas is given 20 cal of heat.After some
time it was found that the temperature of the gas was increased by 1.8 K and the piston was at rest with
respect to the trolley and which was then not in contact with the spring .Also the value of
!
is now 14.2 cm.
Neglect the heat capacity of the piston and the cylinder. If the kinectic energy of the trolley (with the piston
and the gas) at this instant is 4.2 p joule, find the value of p. (Take R(gas constant) = 2 cal/moleK and
1 cal = 4.2 J. and P
atm
= 10
5
N/m
2
)
PHYSICS
Space for Rough Work
RESONANCE
P2FST4220513C0-6
9. A converging lens (focal length f) is broken in two equal pieces and placed at 60 cm as shown along
with the object. It is found that real images are formed at the same place and ratio of image heights
is 9 : 1, if the value of f is
&
'
(
)
*
+
,
x
1
22
cm then value of x is :
10. If work done by an ideal diatomic gas in a process from A to B as shown in PV graph is 20 J :
If increase in internal energy of the gas is 50 x, (in joule) then x is :
11. When an object is moved along the principal axis of a thin converging lens of focal length 12 cm, two
images three times the size of object are obtained when object is at x
1
and x
2
distance from the lens. The
ratio of
1
2
x
x
is :
12. The pressure inside the two soap bubbles is 1.01 and 1.02 atmosphere. when they are in air The ratio of
their volumes is : (both have same surface tension)
PHYSICS
Space for Rough Work
RESONANCE
P2FST4220513C0-7
13. An ice cube of edge length 20 cm is floating in a tank of base area 2500 cm
2
partially filled with water. The
displacement of centre of mass of hole system is (in cm), when ice cube melts completely will be:
(-
ice
= 900 kg/m
3
, -
.
= 1000 kg/m
3
, g = 10 m/s
2
)
14. The probability of a radioactive nucleus to survive one mean life is
x e
1
,
, then x is :
15. A particle is moving in a circle of radius 1 cm and with constant speed of 8 cm/s. Centre of the circle
lies on principal axis of a converging lens of focal length 50 cm and at a distance of 75 cm from the
lens. Plane of the circle is perpendicular to principal axis, if speed of image is 2x cm/s then x is :
CHEMISTRY
RESONANCE
P2FST4220513C0-8
PART- II - CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION - I
Multiple Correct Answers Type
This section contains 5 multiple correct answer(s) type questions. Each question has 4 choices (A),
(B), (C) and (D), out of which ONE OR MORE is/are correct.
16. Assume ideal gas behaviour for all the gases considered & neglect vibrational degrees of freedom. Separate
equimolar sample of Ne, O
2
, CO
2
& SO
2
were subjected to a two step process as mentioned. Initially all are
at same state of temperature & pressure.
Step- I ! All undergo reversible adiabatic expansion to attain same final volume, which is double the original
volume thereby causing the decreases in their temperature.
Step- II ! After step-I all are given appropriate amount of heat isochorically to restore the original tempera-
ture.
Mark the correct option (s) :
(A) Due to step-I only, the decrease in temperature will maximum for Ne.
(B) During step-II, heat given will be minimum for SO
2
.
(C) There will be no change in internal energy for any of the gas after both the steps of process are com-
pleted.
(D) The PV graph of O
2
& CO
2
will be same.
17. The equilibrium constant K
p
for the reaction,
SO
2
Cl
2
(g) SO
2
(g) + Cl
2
(g)
is 1.125 atm at temperature T. Select the correct statements for dissociation of pure SO
2
Cl
2
(g) at equilibrium
state at 2 atm equilibrium pressure and temperature T :
(A) degree of dissociation of SO
2
Cl
2
is 0.5
(B) degree of dissociation of SO
2
Cl
2
is 0.6
(C) average molar mass of final equilibrium mixture will be 84.375
(D) average molar mass of final equilibrium mixture will be 75
Space for Rough Work
CHEMISTRY
RESONANCE
P2FST4220513C0-9
Space for Rough Work
18. The standard reduction -potential for the half-cell
NO
3

(aq) + 2H
+
+ e

"! " NO
2
(g) + H
2
O is 0.78 V [Take
F
RT 303 . 2
= 0.06, log 2 = 0.3]
Select correct options :
(A) Reduction potential of half cell in 8 M H
+
(considering other species to be at unit concentation) is 0.888
volt.
(B) Reduction potential of half cell in 8 M H
+
(considering other species to be at unit concentation) is 0.672
volt.
(C) Reduction potential of half cell in a neutral solution (considering other species to be at unit concentation)
is 1.62 volt.
(D) Reduction potential of half cell in a neutral solution (considering other species to be at unit concentation)
is 0.06 volt.
19. The correct statements about the following reaction are
CH CH=C
3
CH
3
H
CH CH
2 3
(P) + (Q) Product/s (R)
Br / CCl
2 4
Br / h
2
(X)
CH
3
monobromination
H / Ni
2
(S)
(A) P and Q have same value of optical rotation with opposite sign
(B) P and Q have different boiling points
(C) R contains two racemic mixture.
(D) S contains a mixture of two diastereomers.
CHEMISTRY
RESONANCE
P2FST4220513C0-10
Space for Rough Work
20. Which of the following are true about the following reaction sequence.
HBr
(PhCOO)
2
HBr
KOH(DMSO)
H O/AgNO
2 3
P
1
P
2
(A) P
2
gives instant turbidity with Lucas reagent
(B) P
1
, P
2
are stereoisomers
(C) P
1
is converted to P
2
on keeping in H
3
O
+
(D) P
1
is more readily oxidised by CrO
3
/H
+
while P
2
is unreactive towards oxidising agents under normal
conditions.
SECTION - II
Matrix - Match Type
This section contains 2 questions. Each question contains statements given in two
columns, which have to be matched. The statements in Column-I are labelled
A, B, C and D, while the statements in Column-II are labelled p, q, r, s and t. Any
given statement in Column-I can have correct matching with ONE OR MORE
statement(s) in Column-II. The appropriate bubbles corresponding to the answers
to these questions have to be darkened as illustrated in the following example.
If the correct matches are A-p, s and t ; B-q and r; C-p and q; and D-s and t; then the correct darkening of
bubbles will look like the following :
21. Column-I Column-II
(A) Number of lone pairs > 2 (p) XeF
5

(B) Planar species (q) XeO

4
(C) All bond angles are equal (r) ClF
3
(D) Non-Polar in nature (s) NH
3
(t) NO
3

CHEMISTRY
RESONANCE
P2FST4220513C0-11
Space for Rough Work
22. Column I Column II
(A)
" " " " " " ! "
OH NH / AgNO
4 3 (p)
(B)
CH
3
CCH=O
O

#
" " " " " ! "
) excess ( NaOH
(q)
(C)
" " " " " " ! "
#
$
/ OH / KMnO
4 (r)
(D)
" " " " " " ! "
2
I / NaOH
(s)
(t)
SECTION - III
Integer Answer Type
This section contains 8 questions. The answer to each of the questions is
a single digit integer, ranging from 0 to 9. The appropriate bubble below the
respective question number in the ORS have to be darkened.
CHEMISTRY
RESONANCE
P2FST4220513C0-12
Space for Rough Work
23. 6.2 g of a sample containing Na
2
CO
3
, NaHCO
3
& non-valatile inert impurity on heating loses 5% of its weight
due to formation of H
2
O and CO
2
as in reaction
2NaHCO
3
"! " Na
2
CO
3
+ H
2
O + CO
2
.
Residue is dissolved in water and formed 100 ml solution and its 10 ml portion requires 4.5 ml of 0.2 M
aqueous solution of BaCl
2
for complete precipitation of carbonates.If number of moles of Na
2
CO
3
in the origi-
nal sample were 'q' then the value of '100 q' is :
24. A mixture of 32 gm of O
2
gas and 16 gm D
2
gas is allowed to effuse through an orifice. If the relative rate of
effusion
%
%
&
'
(
(
)
*
2
2
O
D
r
r
at the start of effusion is expressed as p
2
, then the value of p is :
25. If certain decomposition reaction found to obey equation in term of partial pressure (P) of reactant :
2
2
p
p a +
= b kt, what is order of reaction if a, b and k are constant (t represents time) ?
26. A crystal of formula AB
3
has A ions at the cube corners and B ions at the edge centres. The coordination
numbers of A and B respectively are x and y then sum of x and y is :
27. How many total isomers are possible for square planar complex [Pd(Cl)
2
(SCN)
2
]?
28. How many position isomers of dibromonaphthalene is possible if each ring of naphthalene has one halogen?
29. CH
3
CH=O + CH
3
CH
2
CH=O " " " ! "
#
$
, HO
mixture of aldols
(z) total number of aldols including stereoisomers.
Report your answer as (z 5).
30. The total number of isomeric Bromo-chloro-fluoro-iodopropadienes is ............ .
RESONANCE
P2FST4220513C0-13
MATHEMATICS
PART- III - MATHEMATICS
SECTION - I
Multiple Correct Answer Type
This section contains 5 questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE is/are correct.
31. Which of the following statment(s) is/are True for the function
f(x) = (x 1)
2
(x 2) + 1 defined on [0, 2] ?
(A) Range of f is !
"
#
$
%
&
1 ,
27
23
.
(B) The coordinates of the turning point of the graph of y = f(x) occurs at (1, 1) and
'
(
)
*
+
,
27
23
,
3
5
.
(C) The value of p for which the equation f(x) = p has 3 distinct solutions lies in interval
'
(
)
*
+
,
1 ,
27
23
.
(D) The area enclosed by y = f(x), the lines x = 0 and y = 1 as x varies from 0 to 1 is
12
7
.
32. Let j

a -
!
, k

b -
!
,
i

c -
!
. If
d
!
is a unit vector such that 0 d . a -
!
!
= ] d , c , b [
!
!
!
, then
d
!
(A)
) k

2 j

(
6
1
.
(B)
) k

(
3
1
.
(C)
) k

2 j

(
6
1
.
(D)
) k

(
3
1
.
33. Given f(x) =
/
0
/
1
2
3
4 4
3 x
3 x 3
if
if
e 2
x 10
3 x
2
. The graph of f(x) is
(A) continuous and differentiable at x = 3 (B) continuous but not differentiable at x = 3
(C) differentiable but not continuous at x = 3 (D) niether differentiable nor continuous at x = 3
Space for Rough Work
RESONANCE
P2FST4220513C0-14
MATHEMATICS
Space for Rough Work
34. Consider the sequence a
n
given by a
1
=
2
1
, a
n+1
= a
n
2
+ a
n
, Let S
n
=
1 a
1
1
.
+
1 a
1
2
.
+....+
1 a
1
n
.
then
find the value of [S
2012
], where [.] denotes greatest integer function.
(A) 1 (B) [e/2] (C) [e] (D) [5 1]
35. Two sides of a triangle are parallel to the coordinate axes. If the slopes of the medians through the acute
angles of the triangle are 2 and m, then m can be equal to
(A)
2
1
(B) 2 (C) 4 (D) 8
SECTION - II
Matrix - Match Type
This section contains 2 questions. Each question contains statements given in two
columns, which have to be matched. The statements in Column-I are labelled
A, B, C and D, while the statements in Column-II are labelled p, q, r, s and t. Any
given statement in Column-I can have correct matching with ONE OR MORE
statement(s) in Column-II. The appropriate bubbles corresponding to the answers
to these questions have to be drakened as illustrated in the following example.
If the correct matches are A-p, s and t ; B-q and r; C-p and q; and D-s and t; then the correct darkening of
bubbles will look like the following :
36. Column-I Column-II
(A) If k

m j

n i

17 a
2 2
. -
!
, k

n i

17 b
2
. . -
!
, then number of (p) 1
integral values of m such that
a
!
and
b
!
are perpendicular
(B) If the distance from the orthocentre to the vertex of the (q) 2
triangle, is k times the distance from the circumcentre to
the middle point of the opposite side, then k equals
(C) The remainder when 3
37
is divided by 80 is equal to (r) 3
(D) Number of values of k for which the equations x
3
+ x
2
kx k = 0, (s) 4
x
3
x
2
3x + k = 0 have a common root, is
(t) 5
RESONANCE
P2FST4220513C0-15
MATHEMATICS
Space for Rough Work
37. A variable plane cuts the x-axis, y-axis and z-axis at the points A,B and C respectively such that the volume
of the tetrahedron OABC remains constant equal to 32 cubic unit and O is the origin of the coordinate
system
Column-I Column-II
(A) The locus of the centroid of the tetrahedron is (p) xyz = 24
(B) The locus of the point equidistant from O, A, B and C is (q) (x
2
+ y
2
+ z
2
)
3
= 192xyz
(C) The length of the foot of perpendicular from origin to the (r) xyz = 3
plane is
(D) If PA, PB and PC are mutually perpendicular then the locus (s) (x
2
+ y
2
+ z
2
)
3
= 1536xyz
of P is
(t) xyz = 1
SECTION - III
Integer Answer Type
This section contains 8 questions. The answer to each of the questions is
a single digit integer, ranging from 0 to 9. The appropriate bubble below the
respective question number in the ORS have to be darkened.
38. Suppose f(n) = log
2
(3). log
3
(4). log
4
(5)..........log
n 1
(n) then the sum 6
-
100
2 k
k
) 2 ( f
= 7 , then
1683
7
is equal to
39. If 9 : (5/4, 5/2) and 6
;
-
9
1 n
n
tan
1
= sin9 + cos9 then the value of tan
2
9 is
RESONANCE
P2FST4220513C0-16
MATHEMATICS
Space for Rough Work
40. If the value of
< =
>
5
.
100
0
1 1
] x [tan ] x [cot
dx is 1005 + p cotp, then the value of p is
(where [.] denotes greatest integer function)
41. Let ?, @, A, B : (0, 5) be such that 2cos ? + 6 cos @ + 7 cos A + 9 cos B = 0 and
2 sin ? 6 sin @ + 7 sin A 9sin B = 0 then the value of 7 for which 7 cos (? + B) = 7 cos (@ + A) is
42. Two functions f(x) and g(x) are defined as f(x) =
24 x 10 x
2 x
log
2
10
. C
C
and g(x) = '
(
)
*
+
, C
C
15
3 ] x [ 2
sin
1
where [.] denotes greatest integer function, then the number of even integers for which f(x) + g(x) is defined
is
43. The positive value of 'c' that makes the area bounded by the graph of y = c(1 x
2
) and the x-axis equal to 1,
can be expressed in the form p/q where p,q : N and in their lowest form, then (p + q) equals
44. Suppose a,b,c are such that the curve y = ax
2
+ bx + c is tangent to y = 3x 3 at (1, 0) and is also tangent
to y = x + 1 at (3, 4) then the value of (2a b 4c) equals
45. Let S(x) = 1 + x x
2
x
3
+ x
4
+ x
5
x
6
x
7
+...., where 0 < x < 1. If S(x) =
2
1 2 .
then the value of [x] equals
where [.] denotes greatest integer function.
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