elements). Make a list of 30 different things in the classroom and then classify them into either elements or compounds. Are there more elements or compounds? How many elements are known to man at this time? How many are metal elements? How many are non-metal elements? 1 When atoms or molecules interact chemically, new substances are formed with new physical and chemical properties.
These interactions are called chemical bonds.
Mg + O MgO Elements compound
The new chemical bond is between the Mg & O in the compound. 2 There are 3 main types of chemical bonds:
Covalent bonds Ionic bonds Metallic bonds
These are collectively called intra- molecular bonds (within molecules) 3 Covalent Bonding Mostly between non-metals. Often diatomic molecules are formed. eg CO 2 , Cl 2 Ionic Bonding Between metals and non-metals. Positive and negative ions are formed. eg NaCl Metallic Bonding Within metals. eg Na, Cu etc 4 The Lewis structures only indicate the valence (outer energy level) electrons for each atom in the molecule. It is also called the electron dot system. Lewis structures do not indicate the valency the unpaired in the outer energy level. 5 In Lewis structures, we show the symbol of the element, surrounded by the valence electrons for that particular element represented as dots/and or crosses.
Two electrons are required to form a bond and atoms react in order to achieve the stable octet (8) structure in which the outer energy level of atoms is now full.
Orbitals are full when they contain 2 electrons each.
A lone pair of (both belonging to 1 atom) does not take part in a chemical reaction, since that orbital is now full. 6 Sometimes it is difficult to see which electrons belong to which atom. The Lewis structure indicates electrons in the outer energy levels as dots & crosses. Here is the Lewis structure for water: O X H H Now draw Lewis structures for: Cl 2 , HCl, CO 2 & NH 3 Bonding pair Lone pair 7 Argon has the following electron structure; Whenever elements combine they either gain, share or lose electrons so that they achieve the stable octet structure. Argon already has this stable octet structure and this is what makes it so un-reactive. Its outer energy level is thus full with 8 . 8 - + 0 E p
Forces of attraction. Forces of repulsion. complete change E D Forming the H2 molecule 9 Sometimes, neither of the combining atoms easily gives up electrons. This usually happens when there are many electrons (4 7) in the outer energy levels. This means that there will need to be a sharing of 1 or more pairs of electrons between the combining atoms in the molecule. This sharing of electron pairs enables each atom to achieve the stable octet structure. It is called the shared electron pair and, if shared equally, it is known as the covalent bond. Covalent bond 10 Consider 2 combining fluorine atoms. Each has 7 in the outer energy level. The only way that each can achieve the octet structure, is for a pair of s to be shared equally between them: + F Atom F Atom F 2 Molecule Covalent bond Each F atom now shares 1 with the other thus each has the octet structure. This is a covalent bond holding the atoms together in the molecule. 11 Now discuss & explain the covalent bonding that occurs in the following molecules: H 2 Cl 2 O 2 N 2 What is the name given to each of these covalent bonds? 12 Atoms of elements have chemical energy and when they react with other elements to form a compound, the compound has less chemical energy than the reacting elements before reaction i.e. there is generally a net energy loss. Sodium reacts with chlorine in a gas jar to form the compound sodium chloride, according to the following: 2Na + Cl 2 2NaCl Very reactive Un-reactive elements with compound with high energy less energy Safe to eat NaCl , but Na & Cl are very poisonous on their own! 13 23 11 Na 35 17 Cl + _ Na has 1 & Cl has 7 in their outer energy levels. In order to achieve the stable octet (8) structure in their outer levels, the Na will lose its to the Cl, thus producing a + and ion respectively. 11 17 10 18 14 When the Na + & Cl - ions are formed, there is a mutual force of attraction between the oppositely charged ions. This force of attraction is called an ionic bond. The ions then form a crystal lattice in which the Na + & Cl - alternate, thus forming a strong crystal. Each Na + & Cl - is bonded to 6 other oppositely charged ions in a 3-dimensional structure as seen on the next slide.
ions Cl - ions N.B. Cl - ions (having gained an ) are larger than the Na + ions (having lost the only in outer energy level). 16 Here the Na + ions are represented by the small purple spheres & the Cl - ions by the larger green spheres. A different way of representing the same NaCl crystal structure. Which are the Na & Cl ions? NaCl crystal lattice 17 When Mg reacts with O 2 and Al reacts with O 2 , ionic bonds are formed. Using what you have just learned about electron transfer, octet structure and ionic bonding, explain what happens in these 2 reactions.
(Hint: they do not combine in a ratio of 1 to 1 - as is the case with NaCl).
Ionic bonds 18 Metals lose to form + ions called cations.
Non-metals gain to form negative ions called anions.
The ions then hold together in the crystal lattice as a result of electrostatic (also called Coulomb forces) of attraction. 19 Metals have a low electronegativity, while non- metals have a high electronegativity.
Electronegativity difference enables us to predict what kind of bond will be formed between 2 atoms.
Low difference means a covalent bond will be formed.
A high difference means an ionic bond will be formed. 20 Ionically bonded substances can conduct electricity when in solution, but covalently bonded substances do not. See if solutions of alcohol, table salt, pure water, tap water, acetone, copper sulphate, sugar and other solutions will conduct electricity, by connecting graphite electrodes (in beaker) to a small light bulb and a 4,5V battery. Those substances that contain ions will conduct electricity and means that there are ionic bonds in the substance. Covalently bonded substances dont conduct electricity. 21 Metals are used to make many substances as a result of their special properties. Metals have few in their outer energy levels and these are only weakly attracted to the nucleus. They () become dislodged from the nucleus and form a negative region in which the remaining + ions are positioned. This is called metallic bonding and gives rise to the properties of metals. 22 Consider copper wire: = dislodged = + Cu ions + + + + + + + + + + + + + + Metallic bonding is set up between the + Cu ions and the dislodged in the wire. 23 Metallic bonding 24 The metal ions are arranged in an orderly manner interspersed amongst the sea of delocalised . 25 Metallic bonding gives rise to the following properties of metals: Metals usually have: High M.P. & B.P. Flexibility Ability to conduct electricity & heat Strength that enables them to be used to make large & small machines. 26