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In 1926, Erwin Schrodinger made a major contribution to the field of quantum mechanics. His electron cloud model shows the electron distribution and probability of finding the electron at a particular instant. Refer to the diagrams below and answer the questions that follow.
In 1926, Erwin Schrodinger made a major contribution to the field of quantum mechanics. His electron cloud model shows the electron distribution and probability of finding the electron at a particular instant. Refer to the diagrams below and answer the questions that follow.
In 1926, Erwin Schrodinger made a major contribution to the field of quantum mechanics. His electron cloud model shows the electron distribution and probability of finding the electron at a particular instant. Refer to the diagrams below and answer the questions that follow.
Electronic Structure of Atoms: The Quantum Numbers
Objectives: 1. Describe the different quantum numbers and its relation to locating electrons. 2. Identify the permissible values of the quantum numbers through various energy levels.
Introduction: In 1926, Erwin Schrodinger made a major contribution to the field of quantum mechanics. He wrote down rather complex mathematical equations to express the wave properties of an electron in an atom. His electron cloud model shows the electron distribution and probability of finding the electron at a particular instant. His model is commonly represented using orbitals within which there is a 90% chance of finding the electron. For instance, a spherical orbital means that the probability of finding the electron is independent of direction.
First Quantum Number, n; Principal Energy Levels The first quantum number, given the symbol n, determines the energy and distance from the nucleus of an electron. Refer to the diagrams below and answer the questions that follow:
Essential Questions: 1. How does each quantum numbers help in locating electrons? 2. How are electrons distributed within an atom?
Questions: 1. In which shell can the electron nearest from the nucleus be found? 2. Which electron shell has the lowest energy? 3. Which electron shell is farthest from the nucleus? 4. What can you say about the energy content of electrons in the fourth electron shell (n=4) to that of the electrons in the first electron shell (n=1)? 5. What is the relationship of the different electron shell to the: (a) amount of energy of the electrons they contain, and (b) distance from the nucleus.
Second Quantum Number, l ; Sublevels or subshells (s, p, d, f) Each principal energy level includes one or more sublevels. The sublevels or subshells are denoted by the quantum number l. It can take on any values starting with zero and going up to the maximum of n-1. Refer to the diagrams below and answer the questions that follow:
Questions: 1. What are the values of l in the second energy level? Third energy level? 2. How are the values of l related to atomic orbitals? 3. What atomic orbital shape do the following values mean? l = 0, l = 1, l = 2, l = 3 4. If an electron has the quantum number of n=4 and l = 2, describe in which electron shell that electron is most likely be found? What is the shape of its orbital at that particular energy level? 5. How many subshells can be found in the third energy level? Fourth energy level? 6. The following are some sublevel designations for the third energy level: 3s 3p 3d Which sublevel designation has the corresponding values, (n=3 l=1)? (n=3 l=2)?
Third Quantum Number, m l ; orientation of orbitals This quantum number determines the direction in space of the electron cloud surrounding the nucleus. Maximum of two electrons can be found in each orbital. For a given value of l, m l can have the following values: from l to l including zero. Refer to the diagrams and answer the questions that follow:
Questions: 1. In how many ways can the s-orbital be oriented in its axis? How about the p-orbitals? 2. Which orbital can be oriented in five different ways? What is the l value for these orbitals 3. What is the maximum number of electrons can be found in 1s orbital? 2p orbitals? 4. What are the values of l for the 3d orbitals? 5. Which of the following set/s of quantum numbers is/are allowable? Why or why not? A= (n=3 l= 2 m l = -2) B= (n=4 l=2 m l = 0)
Fourth Quantum Number, m s ; Electron Spin
The fourth quantum number m s is associated with electron spin. This is not related to the previous quantum numbers and it can have two possible values
m s = +1/2 or m s = -1/2
Electrons that have the same value of m s (i.e. both +1/2 or -1/2) are said to have parallel spins. Hence, electrons have opposing spins when they have different values of m s .
Question:
1. How many electrons are found in 3s subshell? What are the values of its m s ? What can you say about the electron spins?
EXTEND:
Challenge!!!
1. What is the total capacity for electrons of the fourth principal level? 2. How many electrons in an atom can have each of the following quantum number designations? n=2 l=1 m l = 0