Beruflich Dokumente
Kultur Dokumente
)
=
C
/
C
o
HBAP MPAP AP CSTR
0.00
0.20
0.40
0.60
0.80
1.00
1.20
1.40
0.00 0.50 1.00 1.50 2.00 2.50 3.00
= t/HRTt (1.2 l/s)
E
(
)
=
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/
C
o
HBAP MPAP AP CSTR
0.00
0.20
0.40
0.60
0.80
1.00
1.20
1.40
1.60
0.00 0.50 1.00 1.50 2.00 2.50 3.00
= t/HRTt (1.5 l/s)
E
(
)
=
C
/
C
o
HBAP MPAP AP CSTR
0.00
0.50
1.00
1.50
2.00
2.50
3.00
0.00 0.50 1.00 1.50 2.00 2.50 3.00
= t/HRTt (2.0 l/s)
E
(
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=
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o
HBAP MPAP AP CSTR
Seminario Internacional sobre Mtodos Naturales para el Tratamiento de Aguas Residuales
Universidad del Valle/Instituto Cinara Pea, M. R. and Mara, D. D. 71
and outlet being in adjacent (rather than diagonally opposite) corners. Figure 1 also shows a long
tail in the 2
nd
and 3
rd
runs (Q = 1.2 and 1.5 l/s) for the MPAP. However, this pond configuration
dramatically improved its response in the last run (Q = 2.0 l/s) where the RTD curve was very close
to the theoretical RTD for a tank in series model with two mixed reactors in the series (Bailey and
Ollis, 1986). This feature has been observed in high-rate anaerobic reactors (UASBs) by Bolle et al.
(1985) and more recently by Avella (2001).
Figure 3. Effluent concentrations and removal efficiencies of the main parameters
The best removal efficiencies were obtained in the MPAP followed by the HBAP. The removal
efficiencies in the CAP were always lower than those in the modified configurations. The MPAP
was able to remove in average 79% of total COD and 75% of filtered COD at a HRT of 12 h,
whereas the HBAP showed smaller removal efficiencies (67 and 51%) at a HRT of 18 h. The CAP
was not able to handle hydraulic loads that produced HRT < 24 h. This is in agreement with the
minimum HRT values recommended in the current literature for CAP under the environmental
conditions found at Ginebra (Mara et al., 1992). Removal efficiencies obtained in the modified AP
configurations compared well with efficiencies of high-rate anaerobic reactors (UASBs) currently
used in the region and reported elsewhere (van Haandel and Lettinga, 1994; Rodriguez et al., 2001).
Figure 3 shows that MPAP had always a growing removal efficiency for COD
f
compared to the
other two ponds. This is characteristic of biological removal mechanisms enhanced by better
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HBAPe MPAPe CAPe HBAPrem MPAPrem CAPrem
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HBAPe MPAPe CAPe HBAPrem MPAPrem CAPrem
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Seminario Internacional sobre Mtodos Naturales para el Tratamiento de Aguas Residuales
Universidad del Valle/Instituto Cinara Pea, M. R. and Mara, D. D. 72
contact between substrate and biomass as a result of good mixing in the reactor. Notice that the
removal of COD
f
in the HBAP and CAP was always lower and had a tendency to decrease with
rising hydraulic loading rates.
MPAP registered also the best removal efficiency of TSS despite increases in the hydraulic loading
rate values. Meanwhile, the effluent VSS concentration steadily increased in all of the ponds but the
MPAP remained with the lowest effluent VSS concentration. Consequently, the VSS removal
efficiency decreased gradually in all of the ponds as the hydraulic loading rate increased. This
behaviour suggests that there is still room to improve biomass retention in all of the ponds. Process
control parameters (i.e. pH, ORP, VFA, SO
4
2-
and alkalinity) showed normal variations for well-
functioning anaerobic reactors (data not shown here).
Figure 4 shows the behaviour of the biosolids contents in each pond. The numbers 1 and 2
correspond to the sampling points which were located at L/3 and 2L/3 on the inlet-outlet line.
Figure 4. Biosolids concentration and VS/TS ratio at two internal points in each pond
The values of the VS/TS ratio suggest the presence of undigested organic matter in the sludge from
the first compartment (point 1) although the inert material fraction seems also important.
0
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3 6 7 9 12 14 16 18
Weeks in operation
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o
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a
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HBAP
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Weeks in operation
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MPAP
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Weeks in operation
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AP
Details on biosolids sampling and
laboratory analysis are available in Pea
(2002).
The concentration of both TS and VS in the
HBAP was consistently higher in the
sludge samples from the first compartment
(point 1) compared with the samples from
the third compartment (point 2). The
relation VS/TS in the first compartment
was very stable with an average value of
0.48 whereas for the third compartment it
was more variable with an average value of
0.42.
Seminario Internacional sobre Mtodos Naturales para el Tratamiento de Aguas Residuales
Universidad del Valle/Instituto Cinara Pea, M. R. and Mara, D. D. 73
TS and VS concentrations in the mixing pit of the MPAP were more variable. Part of this
variability, however, could be related to the sampling procedure since it was difficult sometimes to
keep the peristaltic pump intake hose fixed at the same point. The higher TS concentration found in
the samples from the settler may be related to the likely compaction of the sludge in this zone. The
ratio VS/TS in the mixing chamber was 0.50 on average. This value compares well with data from
the UASB reactor at Pedregal, Brazil (VS/TS = 0.55) and data reported on the start-up of the UASB
at Ginebra (VS/TS = 0.48). The VS/TS ratio in the settling compartment was 0.43 at the beginning
of the evaluation period but it increased to 0.48 during the second and third stages.
On the other hand, Figure 4 shows that concentrations of TS and VS at the sludge layer in the
conventional AP had a random pattern during the study. There was no clear trend for VS and TS
values at any of the two sampling points. The ratio VS/TS in the first third (point 1) of the AP was
more variable compared to the last third (point 2). The ratio in the former varied from 0.46 to 0.57,
which suggests an important contribution of fresh organic matter (VSS) to the ratio average value of
0.52. In contrast, this ratio was more constant in the sludge from the last third (0.44-0.50) of the AP.
This lower average value of 0.48 also suggests a more stable sludge towards the downstream end of
the AP. These results demonstrate the more unpredictable behaviour of the sludge layer in
conventional AP. Similar results to these were found by Warren (1998) working on the sludge
dynamics of a full-scale AP in Australia.
Figure 5 displays the average removal efficiencies of microbiological indicators at each pilot AP.
Figure 5. Average removals of FC, E. coli and helminth eggs in the pilot-scale AP
The removal of microbiological indicators was generally low in the pilot-scale APs as shown in
Figure 5. The removal of FC was slightly better in the MPAP compared to the other two AP. The
highest FC removals occurred during the second stage (HRT = 18 h) in all the ponds and they were
82.4, 90.5 and 89.1% for the HBAP, the MPAP and the CAP, respectively. These figures are in
agreement with data reported by Dixo et al. (1995) who studied the microbiological quality of an
UASB effluent post-treated in a facultative pond. The average FC removal in their UASB reactor
was 80%.
The removal of E. coli was higher in the CAP in all the stages. The maximum average removals
were 91, 81.4 and 65.9% for the CAP, the MPAP and the HBAP, respectively. The maximum
removals occurred in the first stage for the CAP and the MPAP and in the second stage for the
6
1
.
6
5
0
.
4
6
9
.
7
8
1
.
4
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9
.
9
9
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2
.
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.
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.
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.
8
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.
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e
m
o
v
a
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%
)
1 2 3
Stage
FC-hbap E.coli-hbap FC-mpap E.coli-mpap FC-ap E.coli-ap
60.0
64.0
53.0
44.0
51.0
45.0 45.0
67.0
37.0
0
10
20
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40
50
60
70
80
R
e
m
o
v
a
l
(
%
)
1 2 3
Stage
eggs-hbap eggs-mpap eggs-ap
Seminario Internacional sobre Mtodos Naturales para el Tratamiento de Aguas Residuales
Universidad del Valle/Instituto Cinara Pea, M. R. and Mara, D. D. 74
HBAP. These figures are similar to the average removal efficiency of around 80% for E. coli
reported by van Haandel and Lettinga (1994) in the UASB reactor at Pedregal, Brazil.
On the other hand, the average removal efficiency of helminth eggs was always better in the MPAP
compared to the other APs in all the stages. The highest average removal efficiencies of helminth
eggs were 67, 60 and 53% for the MPAP followed by the HBAP and then the CAP. The MPAP had
its best removal efficiency at stage 3 (HRT = 12 h), whereas HBAP and CAP yielded their best
efficiencies during stage 1 (HRT = 24 h). Dixo et al. (1995) found an average removal of helminth
eggs of 63% in a UASB reactor in northeast Brazil. Van Haandel and Lettinga (1994) reported an
average removal of 80% of the influent helminth eggs concentration in the UASB reactor at
Pedregal, Brazil.
The helminth eggs removal equation proposed by Ayres et al. (1992) for the design of WSP, was
applied to the experimental data. However, this equation underestimated the effluent concentration
of helminth eggs for all the APs with the exception of the MPAP operating at HRT = 12 h. In this
case, the predicted removal efficiency value was 68%, which is in agreement with the experimental
value of 67%. Anaerobic reactors are very efficient at removing organic matter whereas their
removal efficiency of pathogens is generally low. Probably with the exception of Vibrio cholerae
removed at in-pond Sulphide concentrations 3 mg/l (Oragui et al., 1993) and the removal by
settling of helminth eggs and the pathogenic protozoa Giardia spp. and Cryptosporidium spp.
(Grimason et al., 1993) in AP, there are very few other references in the literature regarding
pathogen removal in anaerobic ponds treating domestic wastewater. The results shown here are
supported by the ANOVA and Tukeys statistical tests run on the data sets. Detailed statistical
analyses of data can be found in Pea (2002).
The efficiencies found in the high-rate AP configurations for FC, E. coli and helminth eggs
conformed to removal values reported in the literature for anaerobic reactors. However, it seems
possible to improve these efficiencies if biomass retention is further enhanced in the high-rate AP.
The results reported herein show that improvements in the mixing features of conventional AP
enhance the organic matter removal mechanisms in these units. Improved organic matter removal
efficiencies were also achieved at HRT shorter than the minimum values currently recommended in
the literature for conventional anaerobic ponds. These results are promising in the sense that
important savings in land requirements along with higher removal efficiencies in the anaerobic
stage (i.e. high-rate anaerobic pond concept) will produce smaller WSP systems able to achieve
higher efficiencies without sacrificing simplicity and affordability for the users.
CONCLUSIONS
It is possible to improve the hydrodynamic features of classical AP configurations and their
concomitant degradation rates by introducing simple engineering modifications to current design
and construction practices. However, in so doing, simplicity and ease of O&M must not be
forgotten.
The high removal efficiencies of the modified AP compare well with data extensively reported in
the literature for high-rate systems (i.e. UASB, ABR). Improved mixing and contact leading to
enhanced mass transfer processes and better biomass retention are the mechanisms responsible for
improved process performance. These features support the high-rate AP concept.
The biosolids contents in the HBAP and the MPAP showed very similar features to those currently
seen in biosolids from high-rate anaerobic reactors. This support the development of a more active
biomass as a result of better contact and mass transfer processes from and to the bioflocs.
Seminario Internacional sobre Mtodos Naturales para el Tratamiento de Aguas Residuales
Universidad del Valle/Instituto Cinara Pea, M. R. and Mara, D. D. 75
The tendency to biomass losses (i.e. increasing effluent VSS concentration) at HRT between 18-12
h in the pilot AP evaluated shows the need to improving biomass retention mechanisms within the
lagoons. This may be achieved via the provision of in-pond high-rate sedimentation devices or
denser attachment surfaces to retain more effectively biosolids particles.
Further research at full-scale is needed in order to test the high-rate AP concept under real operating
conditions. In this way, O&M requirements will also be accurately determined.
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Influence on Organic Matter Removal. M.Sc dissertation. Universidad del Valle, Instituto
Cinara, Cali, Colombia. (in Spanish).
Ayres, R.M.; Alabaster, G.P.; Mara, D.D. and Lee, D.L. (1992). A design equation for human
intestinal nematode egg removal in waste stabilization ponds. Wat. Res. 26(6), 863-865.
Bailey, J.E. and Ollis, D.F. (1986). Biochemical Engineering Fundamentals, 2
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Ferrara, R.A. and Harleman, D.R.F. (1980). Dynamic nutrient cycle model for waste stabilisation
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rd
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th
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