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Jeet Society, F-5, Rohan Chembers

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Pune – 411029 Pune – 411038
Tel : (R) 25388583 (M) 9422521656
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Chemistry – I March 2006 Marks – 40

1. Attempt any Four – [Marks – 8]

i. State and explain Faraday’s second law of electrolysis.
ii. Why is dissociation of H2O low in acidic medium?
iii. Define – (1) Lyophilic sol (2) Recoil nucleus.
iv. Explain why silicon is a network solid and chlorine is a molecular solid.
v. Define – Hybridisation. Give different types of hybridization.
vi. Explain the role of adsorption indicator in precipitation titration.
2. A] Answer any ONE of the following. [Mark – 2]
i. Draw neat labeled diagram of a Daniel cell. Give net cell reaction in it.
ii. Explain the formation of Beryllium Difluoride molecule on the basis of hybridization.
B] Answer any ONE of the following. [Mark – 2]
i. Distinguish between exothermic and endothermic reactions.
ii. How bond energy is affected by – (1) Bond length (2) Bond polarity?
C] Answer the following questions : [Mark – 4]
i. Prove that Kw = [H+][OH–] for ionization of water at 298 K.
ii. Explain the terms – (1) Thixotropy (2) Imbibition
3. A] Answer the following. [Mark - ]
i. Explain the stability of nucleus on the basis of – (1) Nuclear forces. (2) Binding energy.
B] Answer any ONE of the following. [Mark – 4]
i. Define – Internal Energy. Explain different types of thermal energies.
ii. Define and explain metallic bond. Explain following properties of metallic solids
(1) electrical conductivity (2) metallic luster.
4. A] Solve any ONE of the following numerical examples.
i. PH of 0.05 Sodium Cyanide solution is 11.04. Calculate its degree of hydrolysis and hydrolysis constant.
ii. Enthalpies of CO2(g). H2O(l) and ethyl alcohol are – 395.5, – 285.4 and – 277 Kj/mole respectively. Calculate the
Heat of combustion of ethyl alcohol.
B] Solve any TWO of the following. [Mark – 4]
i. Write the cell reaction and calculate E.M.F. of following cell. pt Fe1M+2 , FE1M+3 Cl1M- Cl21 atm.|
Given : EoFe2+ / Fe3+ = – 0.771V and EoCl2/Cl – = – 1.3595V
ii. The decay constant of radio element is 4.62 x 10–2 per hour. What fraction of it remain after 40 hours.
iii. For the reaction H2(g) + ½ O2(g) → H2O(l) ∆ H = – 285.83 KJ at 298 K calculate ∆E (R = 8.314 J/K/mole)
5. A] Explain the formation of hydrogen molecule with the help of potential energy curve.
B] Answer any TWO of the following. [Mark – 4]
i. Give Nearest equation for an electrode potential. Explain the terms involved in it.
ii. Derive Ostwald’s dilution law for weak acid.
iii. Identify the dispersed phase and dispersion medium in the following.
Milk, fog, butter, biscuit.

Chemistry – II March 2006 Marks – 40

1. Attempt any Four – [Marks – 8]
a. (i) What happens when a mixed ether reacts with cold HI? b. Give classification of fibers.
b. What is the action of PC15 with (i) ETHANAL (ii) ETHANOL
c. How will you obtain? (i) Ethyl ethanoate from ethyl bromide. (ii) Acetic acid from Methyl Cyanide.
d. What happens when? (i) Vapours of ethanol are passed over heated alumina at 623 K.
(ii) Phenol is treated with bromine in presence of CS2 at 273 K.
e. What is optical activity? Is 2 – Chloro butane optically active? Why?
f. Describe Cannizzaro’s reaction.
2. A] Answer any ONE of the following. [Marks – 2]
a. What is the action of (i) Sodium carbonate with silicon, when fused. (ii) Potassium carbonate with Fluorine.
b. (i) How the name ‘Halogen’ is derived? (ii) What is the position of Silicon in Periodic Table?
B] Answer any ONE of the following. [Marks – 2]
a. How will you convert (i) ETHANAL into ETHANOL (ii) ETHANOL into ETHANAL
b. What is the action of (i) Acetaldehyde with Tollen’s reagent. (ii) Isopropyl alchohol with a mixture of K2Cr2O7
and dil H2SO4?
C] Answer the following. [Marks – 4]
a. How will you prepare (i) Acetone from a geminal dihalide. (ii) Acetaldehyde using a Grignard reagent?
b. What is the action of (i) Acetone with methyl magnesium iodide. (ii) Acetaldehyde with Phenyl hydrazine?
3. Answer the TWO of the following. [Marks – 8]
a. What are derived proteins? Give Millon’s test. b. Describe the preparation of Glucose from sucrose.
c. Write a note on ‘Saponification’.
B] Answer the TWO of the following. [Marks – 4]
a. Why are amines basic? Give one reaction showing their basic nature.
b. What is the action of following with diethyl amine. (i) acetic anhydride. (ii) NaNO2 and HCL
c. (i) Write the structure and IUPAC name of Isopropyl amine.
(ii) How will you convert ethyl amine into Ethanol?
4. Answer the TWO of the following. [Marks – 8]
2
a. Explain in detail SN reaction mechanism with energy profile diagram.
b. What are Phenols? How is Carbolic acid prepare from Isopropyl benzene?
c. (i) How is Ethanoic acid prepared from (1) acetaldehyde (2) Dry ice?
(ii) What is the action of ethanol with –
1) acetic acid in presence of conc. H2SO4 2) acetic anhydride in presence of pyridine?
5. A] Answer any ONE of the following. [Mark – 4]
a. How will you bring about the following conversions.
(i) Chloral to Chloroform (ii) Ethane to Ethylene dichloride (iii) Ethyl bromide to Ethylene
(iv) Chloroform to Phosgene
b. How is crystalline Silicon prepared? Give four uses of Fluorine.
B] Answer the following. [Mark – 4]
a. Write the reactions involved in polymerization of
1) Hexamethylene diammonium adipate. 2) Dihydroxy diethyl terephthalate.
b. How will you prepare methoxy ethane using diazomethane? What is the action of dil H2SO4 under pressure and
at high temp. with methoxy ethane?