Name: Chemistry 142

cid/Base Equilibria #1
Question 1. What ar€1ht:!1H+]and [OH-] in an aqueous solution prepared by dissolving 0.50g of HClO4 in 750 mL of
solution?

0.508 HQ04 I( l~f!C.1DL = (). t)c95D ~ Hu°Lj

If) (). 11 ~ttc-IDCf

{) . 0 05"'0 Hc.t D.t ::: 4{0. :t-X 16 3.E- +tc.J0 It "" ~t\+-::\

[o,*J,,- I. GJt...lo'4 "l5)< I a-I: COW]

Question2. What are the pH and pOH of an aqueous solution prepared by dissolving 0.36g of KOH in 250 mL of
solution.

O.3"gKDf-) y.~~~:~ "': :=:;).0 X /D7-~ f\[)ft

. V.?-5l- [DH-J
::.

p1 ~ -1°31 ('2.b\C.fO)
:- !. 5'tf
----

~f+~ IY.O ~ 1.SC(:; {2.41 -

Qu~"on3. ~a.'~~~~;I~~~N:H~O.2~~;f~t:Q J1m1

D.7-Lfl- Hcl X- Q.t>s-s ::: L 3 XID~~!iC,;I

\-\c.,!+Ajo.b~ --B J0..D + Hz..V (L-- - . ~

tJJ:>H ~-tk~ 0t~ ~
L'3XI'h::2.~.k~ -~rO)( \(f3M-,eQ, ifxI03~~ ~

\:nc(}= L~~"1 ~
~tf)(..fIi-~ Page1ot2
:::. ';)..x. r zr ~Jf- + ~.:::: -l fJV ~ XlffJ=t 1- -
 Name: Chemistry 142

Question 4. What is the conjugate base of each of the following?

a) HCI

c,-
b) H2P04-

ItfOLjJ--
c) CCI3COOH
CC)3CO 0-
Question 5. What is the conjugate acid of each of the following?

a) H2P04-

H3P~
b) NH3

P Il-y+
c) CO 32-

HcOi
Question 6. Identify the Br0nsted-Lowry acids and bases in the following equations.

a) CI02- + H2O ~ HCI02 + OW

1;~ ~ <-~ C..~~

b) HS04- + H2O ~ H30+ + S042-

~\~ \)~ C.~ G~bAAa-

c) NH4+ + NH2- ~ NH3 + NH3

1; L- J.;J ~. ~
t't ,y4
o-.1oMa- C. ~

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Name: Chemistry 142

!Acid/Base Equilibria #2
Question 1. Write the equation for the ionization for each of the following.

a) HF + l-+z..D ~ H--:sD"+ F-

b) CsHsN + H2O .:;;:::= ~ J-)SJJt-t+ + g) l-\ --

c) HC6HsO-4-~2-'D :;::: C ~~~O t- t1s'OT

d) CH3NH2 + ~ «).::;::: C~6'\H+-i +-81-+-

Question2. Calculate the pH of a O.SOMaqueous solution of ammonia. Kb = 1.8x 10-5.

pJ~3-\- 1+,,0~ P f,}: +-f) ~ --

~
Kb ~
~.w4+:J[J9l-.r:) . )~<6x16S- -- ~ ~

~~:J) Q.SO---Y
Q -S
~:::- ~. 0 X l 0 :::. <LDH-J

f 0 ~ - - ( <J~ C'3.C)'k \«j"3j

~ ::?-. ~'J..
fit"" ILf.<!;)a~2.'S'2 c {!.4D

Page 1 of 2
 Name: Chemistry 142

Question 3. A 0.20M solution of hypochlorous acid has a pH of 4.08. Calculate Ka for hypochlorous acid.

Hoc( ~- H+- t- [) C(-

[).VJ () C>

--lL -t7'- t~
G ($). 2-0 ..."r ~ ~

t< 0- J
::- j)-t + It(J -]
LJ+OC-tJ

f [-L- 4-.e 1);" [1-\ TJ~ l6tt.~ <6-<3,X[O-S- --y

1)+ '>-J -;;:<6. ~ ~ 1D~
~ c...1-::1 ~ '1 ;: "b."'> ..>--\ 0-S-
~]::: Q.W-'.L =0 <9.2-0-«,.~ W-S-:::OW

Ka.:; ~.6X16~l~.SXJO~ ~, '3.4,k.10'6

() . 2C)

Page 2 of2
Name:

Question
~
1.
Ch . try 142 Acid/Base Equilibria #3142
Chemistry

A 0.0010mole sample of NaOH is added to 1.0L of a solution that is 0.10M NH3 and 0.050MNH4Cl. What
is the pH of the solution after this addition?

a) Write the equation for the ionization of NH3 in water.

~ It~ + H~O ~- ,:)~l.t+t-OH-

. b) With which of the solutes will the added NaOH react? . - (i

~ Jj~f:)UUo- ~I;;twdi~~ fJ~-t'/'fk-~" #-
~t.JIa-I;~JM>
''b-L t) . &-«5 16)Jt1 7L-
~ ~"6NIItt-tw.e~
~

- (J ')/i"'::1U;W'='~'h~;J°!};~"~ ~ ~
l) t 60 10 P\~;L . if
d) Calculate the pH of the solution prior to adding the NaOH.

flH3 + H~.l) c-: PJtlt~ + 0ff-

0 .cso 0
D'l~
t~ tJ
-'~
e>.( C}()- Y !).~y ~
Ik'. -S' (0.5519 T\f)"J- - , -s-
(I,'b:::-/\~XID =:: ~ l:)' too-~ -.. ) ~-:;::: 3.b>l..lO {; fp~j

[~+ J"" l~0 ""It>-l~ '" 9-. 'D 1\/O-to .}f'!+ ~ 9. C:,

Page 1 of 2
 Name: Chemistry 142

e) Calculate the pH after the addition.

.4-
~ H--
}J H-~ 4- ~o ~ p~ of-

D.lOO 0 .0 $""0 C/
~..JW . oolO
~~+
0

--y.-
-- O.OOlO
rl'- ~--y-
k" -!:>- (Q. 04 ~ +1t)><- -s-- <'- ~
l\b :: 1.~x.tO ~
0" (Ol-~ ) '-/(':: ~.fQS-XID -= JJ7H-~

fO U-~ ~ te~ C1>. ~ X Ioj

Co = 4.y ~ / f If .::. '1'. SCc,

Question 2. To a fresh sample of the buffer in "Question I" calculate the change in pH after 0.010 moles of HCl are
added.

+ D -=-
oc:::::-IJ (.Ilt +- () \+-
Al*3
0.100 .D O 0
- C).OID -t O. 0 to
-)t
+ +
tJ .t)cro-'f
f), () Cot)r'l- (c

K b= I. <t< X.l D-~ )~

{(9.0f>O-t---Y . ;..s-

f). O~D-lL ) 1c.= ~ 1+)( to = [${J-J

fit: t:t. y~

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