SECTION-I This section contains 10multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out which ONLY ONE is correct. (+3, - 1)
1. Which is not correct in the case of ( ) 2 4 Cu CN
SECTION-II This section contains 9 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out which ONE OR MORE is/are correct. (+3, 0)
11. Which of the following is/are tetrahedral (a) 2 4 NiCl
(b) ( ) 3 4 Cu CN
(
(c) ( ) 2 2 4 Be H O + (
(d) ( ) 4 Ni CO 12. Which one of the following salts does not produce a complex ion ( ) 2 2 6 M H O + when dissolved in excess of water. (a) 4 CuSO (b) 4 ZnSO (c) 4 FeSO (d) ( ) 2 4 3 Al SO
13. Which of the following is/ are diamagnetic? (a) ( ) 4 Ni CO (b) | | 2 4 PtCl
(c) ( ) 3 2 6 Fe H O + (
(d) ( ) 4 6 Fe CN
(
14. Which of the following is/ are expected to be colored? (a) ( ) 2 2 4 Cu H O + (
(b) ( ) 2 4 Zn H O 2+ (
(c) ( ) 3 2 6 Sc H O + (
(d) ( ) 2 2 6 Fe H O + (
15. Which of the following can show geometrical isomerism? (a) ( ) 3 2 2 Pt NH Cl (
(b) ( ) ( ) 1 3 2 2 2 2 Co NH H O Br
(
(c) ( ) 2 2 5 Co H O Cl + (
(d) ( ) 4 Ni CO
16. For which of the following number of geometrical isomers is more than three? (a) ( ) 3 2 2 2 M NH Br Cl (
(b) ( ) 2 M en ClBr (
(c) ( ) 2 M gly Cl Br (
(d) ( ) 3 2 4 M NH Cl (
17. Which of the following is/ are optically active? (a) ( ) 3 2 2 Pt NH Cl (
(b) ( ) 2 2 M en Cl (
(c) ( ) 2 2 M gly Cl (
(d) ( ) 3 M en (
18. Which of the following is/ are paramagnetic? Head Office: Andheri: 26245223 MUMBAI / DELHI/ AKOLA / KOLKATA / LUCKNOW (a) ( ) 3 3 6 Cr NH + (
(b) ( ) 5 Fe CO (c) ( ) 3 3 6 CO NH + (
(d) ( ) 2 2 4 Zn H O + (
19. Which of the following complexes has square planer shape 2 dsp hybridization? (a) ( ) 2 4 Ni CN
(
(b) ( ) 3 6 Cu CN
(
(c) | | 2 4 PtCl
(d) | | 2 4 PdCl
SECTION-III (Integer Answer Type) This section contains 2 questions. The answer to each of the questions is a single digit integer, ranging from 0 to 9. The correct digit below the question number in the ORS is be bubbled. (+4, 0)
20. The number of ionisable halide ions in ( ) 3 2 Pt NH Cl Br Cl (