CAREER POINT

PRACTICE PROBLEM SHEET

PHYSICS
Topic Atomic Structure-3

Question based on Spectrum and spectrum lines
Q.1 If the series limit wavelength of the Lyman series for hydrogen atom is 912 , then the series limit
wavelength for the Balmer series for the hydrogen atom is -
(1) 912 (2) 912 2 (3) 912 ()
2
912

Q.2 In hydrogen s!e"tr#m, the shortest wavelength in Balmer series is $ %he shortest wavelength in Bra"&ett
series will 'e -
(1) 2 (2) (3) 9 () 1(
Q.3 If the wave n#m'er of a s!e"tral line of Bra"&ett series of hydrogen is
))
9
times the *yd'erg "onstant$
+hat is the state from whi"h the transition has ta&en !la"e ,
(1) n - (2) n - . (3) n - ( () n - /
Q.4 0or the first mem'er of Balmer series of 1-s!e"tr#m, the wavelength is $ +hat is the wavelength of the
se"ond mem'er ,
(1)
3)
.
(2)
1(
3
(3)
9

()
2/
2)

Q.5 If 1 and 2 are the wavelengths of the first mem'ers of the Lyman and 2as"hen series res!e"tively, then 1 3
2 is 4
(1) 133 (2) 133) (3) /3.) () /31)5
Q.6 6le"trons in a "ertain energy level n - n1, "an emit 3 s!e"tral lines$ +hen they are in another energy level,
n - n2$ %hey "an emit ( s!e"tral lines$ %he s!eed of the ele"trons in the two or'its are in the ratio4
(1) 3 3 (2) 3 3 (3) 2 3 1 () 1 3 2
Q.7 0or an atom of ion having single ele"tron, the following wavelengths are o'served$ +hat is the val#e of
missing wavelength, x ,
(1) 2) mm (2) ) mm (3) () mm () 12) mm
Q.8 %he a""eleration of ele"tron in the first or'it of hydrogen atom is4
(1)
3
2

h
m
(2)
mr
h
2
2

(3)
3 2 2
2
r m
h

()
3 2
2 2
r
h m

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E!IEERI!
"PPS #$ - 0% 7is"#ssion on 3 3-6-214
Q.! 8 !arti"le of mass m moves aro#nd in a "ir"#lar or'it in a "entro symmetri" !otential field ( )
2
2
Kr
r u $
9sing Bohr:s ;#anti<ation r#le, find the !ermissi'le energy levels$
(1)
m
K nh
2
(2)
m
K nh

2
(3)
m
K nh
2
() =one
Question based on "oncept o# recoilin$ o# atom and application o# bo%r t%eor&
Q.1 %he re"oil s!eed of a hydrogen atom after it emits a !hoton in going from n - . state to
n - 1 state is >> m?s$
(1) .$2) m?s (2) 2$2/ m?s (3) $19 m?s () 3$33 m?s
Q.11 %he energy needed to deta"h the ele"tron of a 1-li&e ion in gro#nd state is ryd'erg$ +hat is the wavelength of
the radiation emitted, when ele"tron @#m! from the first eA"ited state to the gro#nd state -
(1) 3) (2) .)3 (3) 2). () 392
Q.12 %he radi#s of first or'it of hydrogen atom is )$.3 and the ele"tron is eAe"#ting ($. 1)
1.
revol#tions !er
se"ond$ %he magneti" moment of ele"tron will 'e -
(1) 9$3 1)
42
8m!-m
2
(2) ($. 1)
42/
8m!-m
2
(3) ($. 1)
42
8m!-m
2
() .$3 1)
42
8m!-m
2
Question based on 'educed mass
Q.13 B#!!ose a !arti"le (8) of "harge e;#al to "harge of ele"tron and mass (2me) (me 'eing mass of ele"tron)
revolves aro#nd the !roton in nearest allowed "ir"#lar or'it of radi#s r$ If the radi#s of first Bohr or'it for the
ele"tron is a), then the relation 'etween r and a) is -
(1) a) - r (2) a) - 5r (3) a) - 2r () a) -

r

(assa$e )14 - 15*
%he energy of ele"tron in any Bohr or'it was
Cal"#lated as
2 2 2
)
2
5 h n
e mZ
E

"onsidering
n#"le#s to 'e at rest$ %his ass#m!tion "o#ld 'e tr#e 'e"a#se mass of n#"le#s is D is "om!ared to that of
ele"tron as m$ B#"h that "enter of mass lies at "enter of n#"le#s$ 1owever if D E m, then 'oth sho#ld move
a'o#t "ommon "entre of mass then answer the following ;#estions ,
Q.14 8llowed energy or'its "an 'e eA!ressed as ,
(1)
,
_

m M
Ze
h n 1 1
2
2
2
2
)
(2)
,
_

M m
Ze
h n 1 1
2
2
2
2
)
(3) ( ) m M
Ze
h n

2
2
2
2
)
() =one of these
Q.15 If r is the distan"e 'etween n#"le#s and ele"tron, the distan"e of ele"tron from "entre of mass r1 is 3
(1)
2
r
(2) r
m M
m
+
(3) r
m M
M
+
() =one of these
Q.16 If the radi#s of first Bohr:s or'it is x, then de-Broglie wavelength of ele"tron in 3
rd
or'it is nearly-
(1) 2x (2) (x (3) 9x () x?3
ANSWERS +
1. ,3- 0or series limit of Balmer series,
ni - , nf - 2
1
1
]
1

2 2
1 1 1
i f
n n
R
or

1
2
1 1
2 2
R
R
1
]
1

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m m
R
1)
1) 912
1)9(/5))



-
912
2. ,2-
1
]
1

2
2
2
1
1 1 1
n n
R
0or shortest wavelength in Balmer series$
n1 - 2, n2 -
1
]
1

1 1
R
or
R

1
]
1

2 2
1

1
:
1
R
F

1(
:
R R
3.,2-

1
- *

,
_

))
9
- *

,
_

2 2
1
4

1
n
4. ,4-

1
- *
1
]
1

2 2
3
1
4
2
1
-
3(
.R
:
1

- *
1
]
1

2 2

1
4
2
1
-
1(
12

R
F

:
-
3(
.R

R 12
1(
5. ,4- 0or Lyman series, n1 - 1 and n2 - 2 for first
line

1
1
1
2
1
1
1 1
2 2
1
R
R R
1
]
1

1
]
1

0or 2as"hen series n1 - 3 and n2 - for first

line
1
/
1(
1
9
1

1
3
1 1
2 2
2
R
R R
1
]
1

1
]
1

1)5
/
/ ? 1
3 ?
2
1

R
R

6. ,1- =#m'er of emission s!e"tral lines
2
) 1 (

n n
N

2
) 1 (
3
1 1

n n
(in first
"ase)
or ) (
1
2
1
n n or (n1 4 3) (n1 G 2) -
)
%a&e !ositive root n1 - 3
8gain,
2
) 1 (
(
2 2

n n
(in se"ond "ase)
or ) 12
2
2
2
n n or (n2 4 ) (n2 G 3) - )
%a&e !ositive root, or n2 -
=ow, velo"ity of ele"tron
nh
KZe
v
2
2

1
2
1
1

n
n
v
v
7. ,4- 0rom *its "om'ination !rin"i!le
1 2 2 3 1 3
1 1 1
n n n n n n

+

Hr
()
1 1
)
1
+
x
or x - 12) mm
8. ,3-
!. ,1-
r
mv
Kr r u
dr
d
F
2
) (
or m Kr mv
2
and mvr -
2
nh

2
2
nh
m kr r
or
2
1

,
_

Km
nh
r
and
mv
2
- Kr
2
-

,
_

Km
nh
K
%6 - I6 G 26
-
m
K nh
Km
nh K
Km
nh
K

1
]
1

+
1
]
1

2 2 2
1
1.,3- m$v$ -
c
E
1
]
1

2 2
1
1
.
1
( $ 13 E
- 2$1 1)
415
J
v -
5 2/
15
1) 3 1) (/ $ 1
1) 1 $ 2

mc
E
F v - $19
m?s
11.,1- 1 red'#rg - 13$( eK
Bo, the energy needed to deta"h the ele"tron
is 13$( eK$
%he energy in the gro#nd state -
1 - 4 13$(eK
%he energy in first eA"ited state -
2 -

- 4 13$( eK
5 $ )
122

hc
- 3)
12.,1- D - i8 -
r
ev
2
r
2
- ef r
2
13.,3- 8!!ly "on"e!t of red#"ed mass

e
m a
r
)
F e
m 2

2
)
a
r
14.,4- m to 'e re!la"ed 'y red#"ed mass s#"h that
m M
1 1 1
+

15.,3- 0or "entre of mass at O ele"tron at A and n#"le#s
at B, the !osition of "entre of mass O from A is
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m M
Mr
m M
r M o m
r
+

+
+

1
16.,2- r3 - r1 n
2
- x 3
2
- 9x 2r - n,
x
x
n
r

(
3
9 2 2
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