Chapter 22 TB

Chapter 22 - The Transition Elements and Coordination Compounds
1. Which of the following is not a transition-metal?

A) cobalt
B) ruthenium
C) rhodium
D) vanadium
E) aluminum
A!" E #$!" 1 D%&" eas' (E&" )).1
*B+" %dentif' the transition elements on the ,eriodic table.
$*#" transition elements - ,eriodic trends .!C" general chemistr'
). Which of the following is not a characteristic of the transition metals?
A) variable o/idation state
B) the abilit' to form man' colored com,ounds
C) valence electrons in a d subshell
D) high electronegativit'
E) the abilit' to form com,le/ ions
A!" D #$!" 1 D%&" eas' (E&" )).1
*B+" !tate the three characteristics that set the transition elements a,art from the main-
grou, elements. $*#" transition elements - ,eriodic trends
.!C" general chemistr'
0. Which of the following is not a characteristic ,ro,ert' of transition-element com,ounds?
A) .ost of them are colored.
B) .ost of them are ,aramagnetic.
C) .ost of the metals e/hibit multi,le o/idation states.
D) .ost of the elements form man' com,le/es.
E) .ost of the elements1 u,on ioni2ing1 lose the d electrons first.
A!" E #$!" 1 D%&" eas' (E&" )).1
3. $ransition metals can be distinguished from main-grou, metals b' the fact that
A) main-grou, metals have onl' 41 or 4) o/idation states.
B) transition metals have higher relative atomic masses than main-grou, metals.
C) transition metals have a greater tendenc' to form colored com,ounds than main-
grou, metals.
D) main-grou, metals have higher relative atomic masses than transition metals.
E) onl' the main-grou, metals can form com,le/ ions.
A!" C #$!" 1 D%&" eas' (E&" )).1
5. An element with the electron configuration 67e89s
)
3f
13
5d
:
would belong to which class on
the ,eriodic table?
A) rare-earth elements
B) transition elements
C) al;aline-earth elements
D) halogens
E) none of the above
A!" B #$!" 1 D%&" eas' (E&" )).1
*B+" Write electron configurations of the transition elements.
$*#" transition elements - ,eriodic trends
<E=" electron configuration .!C" general chemistr'
9. $i has >>>>>>>>>> in its d orbitals.
A) 1 electron
B) ) electrons
C) 0 electrons
D) 3 electrons
E) none of these
A!" B #$!" 1 D%&" eas' (E&" )).1
:. &e has >>>>>>>>>> that is?are) un,aired in its d orbitals.
A) 0 electrons
B) 3 electrons
C) 1 electron
D) ) electrons
E) 5 electrons
A!" B #$!" 1 D%&" eas' (E&" )).1
@. 1s
)
)s
)
),
9
0s
)
0,
9
3s
)
0d
)
is the correct electron configuration for which of the following atoms?
A) $i
B) Ca
C) Ae
D) Br
E) none of these
A!" A #$!" 1 D%&" eas' (E&" )).1
C. $he ,henomenon called >>>>>>>>>> contraction is res,onsible for the great similarit' in
atomic si2e and chemistr' of 3d and 5d elements.
A) coordination
B) isomeric
C) lanthanide
D) transition
E) none of these
A!" C #$!" 1 D%&" eas' (E&" )).1
*B+" Describe trends in atomic radii of the transition elements.
$*#" transition elements - ,eriodic trends <E=" atomic radii
1D. Which of the following statements is incorrect concerning the 0d1 3d1 and 5d transition
series?
A) $here is a large increase in radius in going from the 0d to the 3d metals.
B) $here is a general increase in si2e going left to right across each series due to an
increasing number of electrons.
C) Eafnium through mercur' e/hibit what is referred to as the lanthanide contraction.
D) $he se,aration of hafnium and 2irconium found together in nature is difficult due to
their similar chemistries1 which are attributed to their virtuall' identical si2es.
E) $he transition metal from a ,eriod 9 grou, is similar in si2e to the ,eroid 5
transition metal sitting above it on the ,eriodic table.
A!" B #$!" 1 D%&" moderate (E&" )).1
*B+" Describe trends in atomic radii of the transition elements.
$*#" transition elements - ,eriodic trends <E=" atomic radii
11. What is the ma/imum o/idation state e/,ected for chromium?
A) 49
B) 40
C) 43
D) 4:
E) 45
A!" A #$!" 1 D%&" eas' (E&" )).1
*B+" Fearn the common o/idation states of the fourth-,eriod transition elements.
$*#" transition elements - ,eriodic trends <E=" o/idation state
1). Which of the following first-row transition elements is not able to have a 40 o/idation state?
A) !c
B) Cr
C) G
D) Bn
E) &e
A!" D #$!" 1 D%&" eas' (E&" )).1
10. What is the ma/imum o/idation state for rhenium1 (e?
A) 9
B) 0
C) )
D) :
E) 3
A!" D #$!" 1 D%&" eas' (E&" )).1
13. What is the ma/imum o/idation state for niobium1 b?
A) 3
B) 0
C) )
D) 9
E) 5
A!" E #$!" 1 D%&" eas' (E&" )).1
15. What is the ma/imum o/idation number for chromium?
A) :
B) 3
C) 9
D) 5
E) @
A!" C #$!" 1 D%&" eas' (E&" )).1
19. %n which of the following com,ounds is the metal atom not in a common o/idation state?
A) Cr*Cl)
B) i&)
C) Cu%
D) Bn?*0))
E) .n!*3
A!" A #$!" 1 D%&" moderate (E&" )).1
1:. A ,ro,ert' that man' re,resentative nonmetals and man' transition elements share is that
the' both have
A) color in man' com,ounds.
B) man' ,aramagnetic com,ounds.
C) high electronegativities.
D) man' com,ounds that observe the octet rule.
E) man' o/idation states.
A!" E #$!" 1 D%&" eas' (E&" )).1
1@. All of the following elements have the o/idation states listed e/ce,t
A) $i1 40.
B) Bn1 40.
C) G1 40.
D) Co1 40.
E) &e1 40.
A!" B #$!" 1 D%&" eas' (E&" )).1
1C. %n which com,ound is cobalt in the highest o/idation state?
A) Co)?C*)@
B) 6Co?E0)98Cl)
C) 6Co?E0)3Cl)8Cl
D) a)6CoCl38
E) <36Co&98
A!" C #$!" 1 D%&" eas' (E&" )).1
)D. $he o/idation number of which of the following elements is often 4) but can be as great
as 4:?
A) manganese
B) cobalt
C) aluminum
D) bismuth
E) chromium
A!" A #$!" 1 D%&" eas' (E&" )).1
)1. Which of the following statements about transition metals isHare correct?
1. $he si/th ,eriod elements have higher ioni2ation energies than the fourth and
fifth ,eriod element in their res,ective grou,s.
). $he total number of o/idation states observed for a fourth ,eriod element is
greatest for manganese ?grou, G%%B).
0. Covalent radii uniforml' decrease from left to right across each ,eriod.
A) 1 onl'
B) ) onl'
C) 0 onl'
D) 1 and )
E) 11 )1 and 0
A!" D #$!" 1 D%&" eas' (E&" )).1
)). Which of the following is a dar; green solid?
A) Cr*0
B) <Cr?!*3))I1)E)*
C) a)Cr)*:
D) a)Cr*3
E) Cr)*0
A!" E #$!" 1 D%&" eas' (E&" )).)
*B+" Fearn some of the common chromium com,ounds and their chemistr'.
$*#" transition elements .!C" general chemistr'
)0. What is the ,rinci,al ore of chromium?
A) chromite
B) chromate
C) chrome alum
D) stibnite
E) hematite
A!" A #$!" 1 D%&" eas' (E&" )).)
$*#" transition elements
)3. Which of the following is a ,roduct of the acidification of sodium chromate?
A) Cr*3
)-
?aq)
B) Cr)*:
)-
?aq)
C) Cr
04
?aq)
D) Cr*0?s)
E) Cr?s)
A!" B #$!" 1 D%&" eas' (E&" )).)
)5. Co,,er metal can be o/idi2ed b' which of the following acids?
A) E0#*3
B) E%
C) E)!*3
D) CE0C**E
E) EBr
A!" C #$!" 1 D%&" eas' (E&" )).)
*B+" Fearn some of the common co,,er com,ounds and their chemistr'.
)9. Common ores of co,,er ma' contain which of the following forms of co,,er?
1. $he free metal or native co,,er ?Cu?s))
). Cu)*?s) and Cu*?s)
0. Cu!?s)
A) 1 onl'
B) ) onl'
C) 0 onl'
D) 1 and )
E) 11 )1 and 0
A!" E #$!" 1 D%&" eas' (E&" )).)
):. %n which of these ,airs of elements can both elements normall' e/hibit multi,le o/idation
states?
A) < and *
B) Cs and Cl
C) .g and !e
D) Co and Cu
E) !c and Al
A!" D #$!" 1 D%&" eas' (E&" )).)
)@. Which of the following coordination com,ounds will immediatel' form a ,reci,itate when
combined with an Ag*0 solution?
A) <6Cr?E0))Cl38
B) <06Cr?C)98
C) 6Cr?E0)98Cl0
D) 6Cr?E0))?E)*)Cl08
E) 6Cr?E0)0Cl08
A!" C #$!" 1 D%&" moderate (E&" )).0
*B+" Define com,le/ ion1 com,le/ ?coordination com,ound)1 ligand1 and coordination
number.
$*#" transition elements - com,le/ ions and coordination com,ounds
<E=" structure of com,le/ - formula of a com,le/ .!C" general chemistr'
)C. $he formula for a ,latinum?%G) com,le/ is 6#t?E0))Br)8Cl). %n aJueous solution1 it will
dissociate into
A) 5 ions.
B) 3 ions.
C) 9 ions.
D) ) ions.
E) 0 ions.
A!" E #$!" 1 D%&" eas' (E&" )).0
number.
0D. What is the o/idation state of iron in <36&e?C)98?
A) 0
B) )
C) 3
D) 3
E) 6
A!" B #$!" 1 D%&" eas' (E&" )).0
number.
01. Which of the following is a necessar' characteristic of a ligand?
A) A ligand must be an anion.
B) A ligand must be an ion.
C) A ligand must be a Fewis base.
D) A ligand must be bidentate.
E) A ligand must be a Fewis acid.
A!" C #$!" 1 D%&" eas' (E&" )).0
number.
<E=" structure of com,le/ - ligand .!C" general chemistr'
0). $he bond between a metal cation and a ligand is best classified as a?n)
A) ,olar covalent bond.
B) ionic bond.
C) non,olar covalent bond.
D) ,ol'dentate bond.
E) coordinate covalent bond.
A!" E #$!" 1 D%&" eas' (E&" )).0
number.
<E=" structure of com,le/ - basic definitions .!C" general chemistr'
00. %n which of the following ions does the metal ion have a 0d
:
electron configuration?
A) 6iCl38
)K
B) 6.n?E)*)98
)4
C) 6CoCl38
)K
D) 6Co?E0)5Cl8
)4
E) 6Co?E0)3Cl)8
4
A!" C #$!" 1 D%&" eas' (E&" )).0
number.
03. What is the coordination number of iron in <06&e?o/)08?
o/ L
A) 9
B) 0
C) 3
D) 5
E) )
A!" A #$!" 1 D%&" moderate (E&" )).0
number.
05. What is the coordination number of cobalt in 6Co?en))Cl)8Cl?
en L
A) 9
B) 0
C) 3
D) 5
E) :
A!" A #$!" 1 D%&" moderate (E&" )).0
number.
09. %n com,le/es of ,latinum?%G)1 the coordination number is usuall'
A) 0.
B) 3.
C) 9.
D) ).
E) 1.
A!" C #$!" 1 D%&" moderate (E&" )).0
number.
<E=" structure of com,le/ - basic definitions .!C" general chemistr'
0:. $he free2ing ,oint of an aJueous D.D5D m solution of a ,latinum?%G) com,le/ having the
molecular formula #t?E0)0Cl3 is KD.1CMC. Which of the following eJuations best re,resents
what ha,,ens when #t?E0)0Cl3 dissociates in water? ?Kf for water is 1.@9MCHm.)
A) #t?E0)0Cl3?s) 6#t?E0)0Cl)8
)4
?aq) 4 )Cl
K
?aq)
B) #t?E0)0Cl3?s) 6#t?E0)0Cl08
4
?aq) 4 Cl
K
?aq)
C)
#t?E0)0Cl3?s) 6#t?E0)0Cl8
04
?aq) 4 0Cl
K
?aq)
D) #t?E0)0Cl3?s) 6#t?E0))Cl)8
)4
?aq) 4 )Cl
K
?aq) 4 E0?aq)
E) #t?E0)0Cl3?s) #t
34
?aq) 4 3Cl
K
?aq) 4 0E0?aq)
A!" B #$!" 1 D%&" difficult (E&" )).0
number.
0@. Which of the following s,ecies is least li;el' to function as a ligand in a transition-metal
coordination com,ound?
A) E0
B) C*0
)K
C) E)*
D) B&0
E) Cl
K
A!" D #$!" 1 D%&" eas' (E&" )).0
*B+" Aive e/am,les of a monodentate ligand1 bidentate ligand1 and ,ol'dentate ligand.
0C. Ag
4
forms man' com,le/es with a coordination number of ). !ome of these are
6Ag?E0))8
4
1 6Ag?C))8
K
1 and 6Ag?!)*0))8
0K
. Which of the following statements is true?
A) $he h'bridi2ation of Ag
4
is s,
)
.
B) %n these com,le/es1 Ag
4
is a Fewis base.
C) %n these com,le/es1 the ligands are monodentate.
D) $he h'bridi2ation of Ag
4
is ds,.
E) $he Ag
4
com,le/es are good reducing agents.
A!" C #$!" 1 D%&" eas' (E&" )).0
3D. Which of the following liJuids could best act as a bidentate ligand for a metal ion?
A) E)Cl
B) E0
C) ClCE)CE)E)
D) )E5
4
E) E)CE)CE)E)
A!" E #$!" 1 D%&" eas' (E&" )).0
31. Which of the following Fewis bases ma' not serve as a bidentate ligand?
A) C)*3
)K
B) E)CE)CE)E)
C) E*CE)CE)E)
D) E*CE)CE)*E
E) CE0E)
A!" E #$!" 1 D%&" eas' (E&" )).0
3). What is the correct %N#AC name for 6AuCl3?E)*))8
K
?
A) diaJuatetrachloroaurate?%) ion
B) diaJuatetrachloroaurate?%%%) ion
C) diaJuatetrachloroaurate?D) ion
D) diaJuatetrachlorogold?%%%) ion
E) diaJuatetrachlorogold?%) ion
A!" B #$!" 1 D%&" eas' (E&" )).3
*B+" Write the %N#AC name given the structural formula of a coordination com,ound.
?E/am,le )).1)
<E=" naming coordination com,ounds .!C" general chemistr'
30. What is the correct formula for sodium tetrachlorocu,rate?%%)?
A) a06CuCl38
B) a)6CuCl38
C) a6CuCl38
D) a36CuCl38
E) a)6CuCl98
A!" B #$!" 1 D%&" eas' (E&" )).3
*B+" Write the structural formula given the %N#AC name of a coordination com,ound.
?E/am,le )).))
33. What is the formula for the he/aaJuacobalt?%%) ion?
A) 6Co?E)*)98
)4
B) 6Co?E)*)38
)4
C) 6Co)?E)*)98
3K
D) 6Co)?E)*)98
)4
E) 6Co)?E)*)98
34
A!" A #$!" 1 D%&" eas' (E&" )).3
?E/am,le )).))
35. What is the formula for the ,entaammineh'dro/ovanadium?%%) ion?
A) 6G?E0)5?*E)58
)4
B) 6G?E0)5?*E)58
0K
C) 6G?E0)5?*E)8
)4
D) 6G?E0)5?*E)8
4
E) 6G?E0)?*E)58
0K
A!" D #$!" 1 D%&" eas' (E&" )).3
?E/am,le )).))
39. Which of the following are constitutional isomers?
%. coordination isomers
%%. lin;age isomers
%%%. geometric isomers
%G. o,tical isomers
A) %1 %%%1 and %G
B) %% and %%%
C) % and %%
D) % and %%% onl'
E) %% and %G onl'
A!" C #$!" 1 D%&" eas' (E&" )).5
*B+" Define constitutional isomers1 stereoisomers1 and geometric isomers.
<E=" structure and isomerism in coordination com,ounds - constitutional isomerism
3:. $he com,le/es 6i?E0)5Cl8Br and 6i?E0)5Br8Cl are what t',e of isomers?
A) geometric isomers
B) constitutional isomers
C) stereoisomers
D) lin;age isomers
E) o,tical isomers
A!" B #$!" 1 D%&" eas' (E&" )).5
*B+" Define constitutional isomers1 stereoisomers1 and geometric isomers.
3@. Eow man' geometric isomers are ,ossible for the sJuare ,lanar com,le/ 6#t?E0))BrCl8?
A) )
B) 3
C) 5
D) 1
E) 0
A!" A #$!" 1 D%&" eas' (E&" )).5
*B+" Decide whether geometric isomers are ,ossible. ?E/am,le )).0)
<E=" structure and isomerism in coordination com,ounds - stereoisomerism
3C. What is the total number of geometric isomers ,ossible for the octahedral com,le/
6Co?E0)0?E)*)08?
A) 1
B) 3
C) 5
D) )
E) 0
A!" D #$!" 1 D%&" eas' (E&" )).5
5D. Which com,le/ is ca,able of forming geometric isomers?
A) <06&eCl98
B) 6Co?E0)5Br8Br)
C) 6Co?E0)98Br0
D) 6#d?E0))Br)8
E) 6#t?E0)38Br)
A!" D #$!" 1 D%&" eas' (E&" )).5
51. .olecules that have nonsu,erim,osable mirror images are
A) multidentate.
B) racemic.
C) de/trorotator'.
D) chiral.
E) levorotator'.
A!" D #$!" 1 D%&" eas' (E&" )).5
*B+" Define enantiomers ?o,tical isomers).
5). Which of the following com,le/es can e/hibit o,tical isomerism? ?en L E)OCE)OCE)O
E) and is bidentate)
A) Co?E0)0Cl0
B) cis-Co?en))Cl)
C) trans-Co?en))Br)
D) cis-Co?E0)3Cl)
E) none of these
A!" B #$!" 1 D%&" eas' (E&" )).5
*B+" Decide whether o,tical isomers are ,ossible. ?E/am,le )).3)
50. Eow man' o,tical isomers do the cis and trans isomers of 6Co?en))Br)8
4
have?
A) cis1 1 and trans1 1
B) cis1 ) and trans1 D
C) cis1 D and trans1 D
D) cis1 D and trans1 )
E) cis1 ) and trans1 )
A!" B #$!" 1 D%&" moderate (E&" )).5
53. Which of the following com,ounds can e/hibit o,tical activit'?
A) 6Co?E0)3Cl)8Cl
B) 6Co?E)CE)CE)E))08Cl0
C) a)6CoCl38
D) 6Co?E0)98Cl0
E) Cr?C*)9
A!" B #$!" 1 D%&" eas' (E&" )).5
55. What bond h'bridi2ation is associated with octahedral com,le/es?
A) d
)
s,
0
B) s,
0
C) s,
D) ds,
0
E) ds,
)
A!" A #$!" 1 D%&" eas' (E&" )).9
*B+" Write the orbital diagram of a transition metal ion in a com,le/.
<E=" valence bond theor' of com,le/es .!C" general chemistr'
59. Which of the following best describes the com,le/ 6.n?E)*)98
)4
?
A) s,
0
h'bridi2ationP diamagnetic
B) d
)
s,
0
C) d
)
s,
0
h'bridi2ationP ,aramagnetic
D) ds,
0
E) s,
0
h'bridi2ationP ,aramagnetic
A!" C #$!" 1 D%&" eas' (E&" )).9
5:. Which of the following high-s,in com,le/es has the most un,aired electrons?
A) 6$i?E)*)98
)4
B) 6G?E)*)98
04
C) 6&e?E)*)98
04
D) 6Cr?E)*)98
04
E) 6!c?E)*)89
04
A!" C #$!" 1 D%&" eas' (E&" )).9
5@. According to valence bond theor'1 what h'brid orbitals are occu,ied b' the ligands in the
com,le/ 6.n?E)*)98
)4
?
A) ds,
0
B) s,
0
C) d
)
s,
0
D) s,
)
E) ds,
)
A!" C #$!" 1 D%&" moderate (E&" )).9
<E=" valence bond theor' .!C" general chemistr'
5C. Which of the metal ions in the following com,le/ ions has a d
5
electron configuration?
A) G?E)*)9
)4
B) (hCl9
3K
C) Co?C)3
K
D) &e?C)9
0K
E) .o?E0)9
04
A!" D #$!" 1 D%&" eas' (E&" )).9
9D. %n which of the following com,le/es does the transition metal have a d
@
configuration?
A) Cu?E)*)9
)4
B) &e?C)9
0K
C) i?C*)3
D) #tCl3
)K
E) Bn?E0)3
)4
A!" D #$!" 1 D%&" eas' (E&" )).9
<E=" valence bond theor' .!C" general chemistr'
91. Which of the following describes a d
9
metal-ion com,le/ with ligands that bond strongl' to
the metal ion?
A) #airing energ' is less than cr'stal field s,litting1 giving a low-s,in com,le/.
B) #airing energ' is greater than cr'stal field s,litting1 giving a low-s,in com,le/.
C) #airing energ' is less than cr'stal field s,litting1 giving a high-s,in com,le/.
D) A d
9
ion has onl' one ,ossible electron arrangement regardless of the ligands.
E) #airing energ' is greater than cr'stal field s,litting1 giving a high-s,in com,le/.
A!" A #$!" 1 D%&" moderate (E&" )).:
*B+" Define cr'stal field s,litting1 high-s,in com,le/1 low-s,in com,le/1 and ,airing
energ'. $*#" transition elements - com,le/ ions and coordination com,ounds
<E=" cr'stal field theor' - high-s,in and low-s,in com,le/ .!C" general chemistr'
9). Which combination leads to a high-s,in octahedral com,le/?
A) low ,airing energ' and a wea;-bonding ligand
B) high ,airing energ' and a wea;-bonding ligand
C) moderate ,airing energ' and a strong-bonding ligand
D) high ,airing energ' and a strong-bonding ligand
E) low ,airing energ' and a strong-bonding ligand
A!" B #$!" 1 D%&" moderate (E&" )).:
*B+" Define cr'stal field s,litting1 high-s,in com,le/1 low-s,in com,le/1 and ,airing
energ'. $*#" transition elements - com,le/ ions and coordination com,ounds
90. $he octahedral com,le/ he/ac'anoferrate?%%%) ion1 6&e?C)98
0K
1 is a low-s,in com,le/. Eow
man' un,aired electrons does the com,le/ have?
A) 5
B) 1
C) 3
D) D
E) 0
A!" B #$!" 1 D%&" eas' (E&" )).:
*B+" Describe the bonding in an octahedral com,le/ ion ?cr'stal field theor'). ?E/am,le
)).5) $*#" transition elements - com,le/ ions and coordination com,ounds
93. %f an octahedral iron?%%) com,le/ is diamagnetic1 which of the following sets of conditions
best describes the com,le/?
A) low s,in1 small
B) high s,in1 large
C) low s,in1 large
D) high s,in1 small
E) none of the above
A!" C #$!" 1 D%&" eas' (E&" )).:
95. Eow man' un,aired electrons are there in an octahedral cobalt?%%%) com,le/ with wea;-
bonding ligands?
A) 1
B) )
C) 3
D) 0
E) D
A!" C #$!" 1 D%&" moderate (E&" )).:
99. Which of the following com,ounds is ,aramagnetic?
A) Fi36&e?*))98
B) <06Co?C)98
C) <06!cCl98
D) a)6$iBr98
E) 6.n?E)*)98Cl)
A!" E #$!" 1 D%&" moderate (E&" )).:
9:. A com,le/ ion is a sJuare ,lanar com,le/. %t has a d
@
electron configuration. What is the
most reasonable d orbital scheme for this com,le/?
A)
B)
C)
D)
E)
A!" D #$!" 1 D%&" moderate (E&" )).:
*B+" Describe the bonding in a four-coordinate com,le/ ion ?cr'stal field theor').
?E/am,le )).9)
<E=" cr'stal field theor' - tetrahedral and sJuare ,lanar com,le/es
9@. $he com,le/ ion iCl3
)K
is tetrahedral. $he number of un,aired electrons in the com,le/ is
A) ).
B) 0.
C) D.
D) 3.
E) 1.
A!" A #$!" 1 D%&" moderate (E&" )).:
?E/am,le )).9)
9C. Eow man' un,aired electrons are there in the tetrahedral com,le/ ion 6&eCl38
K
?
A) 0
B) )
C) 1
D) 3
E) 5
A!" E #$!" 1 D%&" moderate (E&" )).:
?E/am,le )).9)
:D. Which of the following salts would not be e/,ected to be colored in aJueous solution?
A) iCl)
B) CuCl)
C) CrCl)
D) $iCl0
E) CdCl)
A!" E #$!" 1 D%&" eas' (E&" )).:
*B+" #redict the relative wavelengths of absor,tion of com,le/ ions. ?E/am,le )).:)
:1. Which of the following salts would not be e/,ected to be colored in aJueous solution?
A) CoCl)
B) &eCl)
C) CuCl)
D) CuCl
E) CrCl0
A!" D #$!" 1 D%&" eas' (E&" )).:
<E=" cr'stal field theor' - visible s,ectra of transition-metal com,le/es
:). Which of the following salts would not be e/,ected to be colored in aJueous solution?
A) Cr&0
B) i&)
C) $i&0
D) !c&0
E) .n&0
A!" D #$!" 1 D%&" eas' (E&" )).:
:0. Which of the following salts would be e/,ected to be colored in aJueous solution?
A) Al%0
B) Cu%
C) $iCl3
D) CrCl)
E) !c%0
A!" D #$!" 1 D%&" eas' (E&" )).:
:3. Which of the following statements concerning cr'stal field theor' is incorrect?
A) %n an isolated metal ion the d-orbitals have identical energies.
B) %n low s,in octahedral com,le/es the electrons are concentrated in the d/'1 d/21 and
d'2 orbitals.
C) Eigh s,in com,le/es have the minimum of un,aired electrons.
D) !trong bonding ligands favor a larger cr'stal field s,litting ?) than wea; bonding
ligands.
E) Fow s,in com,le/es are favored when the electron ,airing energ' ?P) is less than
the cr'stal field s,litting ?).
A!" C #$!" 1 D%&" eas' (E&" )).:
:5. Which of the following statements concerning cr'stal field theor' isHare correct?
1. $he visible absor,tion ma/ima of transition metal coordination com,le/es are a
measure of the cr'stal field s,litting ?).
). As the cr'stal field s,litting ?) of a coordination com,le/ increases1 the
wavelength of visible light absorbed decreases.
0. All tetrahedral com,le/es are high s,in.
A) 1 onl'
B) ) onl'
C) 0 onl'
D) 1 and )
E) 11 )1 and 0
A!" E #$!" 1 D%&" eas' (E&" )).:
*B+" Cr'stal &ield $heor'
:9. $he s,ectrochemical series is an arrangement of
A) ligands in order of their tendenc' to s,lit the d orbitals of a transition metal ion.
B) coordination com,ounds in order of increasing ligand field s,litting ?).
C) com,le/ ions in order of the wavelength of light absorbed.
D) ligands in the order of electronegativit'.
E) ligands in order of Fewis basicit'.
A!" A #$!" 1 D%&" moderate (E&" )).:
*B+" !,ectrochemical !eries

Chapter 22 TB

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Chapter 22 TB

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Chapter 22 - The Transition Elements and Coordination Compounds

1. Which of the following is not a transition-metal?

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