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Computational Fluid Dynamics (CFD) For Maximum Oil Removal

15

th

Annual Produced Water Seminar, January 2005

Hilton NASA Clear Lake, Houston, Texas 77058

Chang-Ming Lee, Ph.D. and Ted Frankiewicz, Ph.D. NATCO Group Inc.

2950 North Loop West, Suite 750, Houston, TX 77092

Abstract

A new design of internals of a large diameter skim tank is discussed in this paper.

Both transient and steady-state CFD simulations were performed to assist the

development of the design. Excellent flow distribution was achieved on the inlet

distributor as the variance in mass flow rates out of the laterals is less than 0.5%. The

retention time of produced water was improved to almost 88.5% of the theoretical value

with installation of two large perforated plates. Flow path lines were also improved with

a much reduced recirculation pattern. This compares with a residence time of 43.4% of

the theoretical value for the case without the two large perforated plates. The CFD model

predicts that oil droplets size larger than 100 microns are expected to be fully skimmed

off without assistance from gas flotation for produced water at the design flow rate of

100,000 BBL/Day.

Introduction

The production of oil and gas is usually accompanied by the extraction of

associated water. After the initial bulk separation of the bulk produced fluids, the

produced water still contains finely dispersed solids and oil. In order to reduce the

contaminant content of dispersed oil in produced water, a large diameter skim tank can be

used. Separation is based on the difference between the specific gravity of oil and water

and the coalescence of small oil droplets. When the retention time is sufficient, oil floats

to the surface and can be separated by an overflow. This technique is only suitable for

removing dispersed oil with a sufficiently large particle size. Dissolved materials such as

benzene and heavy metals cannot be separated using this technique.

The large diameter skim tank or its modified version, parallel plate interceptor

(PPI) or corrugated plate interceptor (CPI), is mostly used as part of a set of techniques

for the removal of dispersed oil. In this paper, we discuss the development of a new

configuration of internals for a large diameter skim tank. The design of the internals was

developed with aid from a series of CFD (Computational Fluid Dynamics) simulations.

The objective of the CFD developed design is to provide a large diameter skim tank with

optimized flow patterns that maximize liquid residence time and improve oil/water

separation.

2

Tank Description

The skim tank is designed for a flow rate of 100,000 BWPD, has a diameter of 80

feet (24.384 m), and a height of 24 feet (7.3152 m). The drawing of the skim tank and

the inlet distributor are shown in Figure 1. The inlet distributor consists of a header and

eight parallel laterals. Because gas breakout in the oil/water settling zone could seriously

degrade separation performance, the fluid inlet incorporates a tangential entry

configuration to promote gas/liquid separation prior to liquid reaching the inlet

distributor. The open-end of each lateral is directed toward the wall of the skim tank and

employs the tank wall as the equivalent of momentum breaker and primary flow

deflector.

The skim tank has two large perforated plates. One is located near the inlet

distributor and another is located between the three water outlet nozzles and the oil

skimming collectors. The large plates are an assembly of several smaller pieces of

perforated sheets with thickness of 1/2 inch. The two oil skimming collectors are set at

different elevations and they are suitable for operating the skim tank at the high and low

levels of 22.5 feet and 17 feet, respectively. There are also three baffles surrounding the

outlet nozzles to prevent possible flow short circuiting. Among the three baffles, one

solid plate is positioned parallel to the large perforated plate and the other two perforated

baffles are both perpendicular to the solid baffle.

Model Simplification

The construction of the three-dimensional geometry was based on the dimensions

of the skim tank as provided by the field operator and some simplification was required

for modeling purpose. The three-dimensional model with a description of internal

components of the skim tank is shown in Figure 2. The perforated plates are modeled as

porous-jump boundaries of zero-thickness the mathematical equivalent of physical

fritted plates in order to avoid extremely complex meshing of the region around

individual orifices. The oil skimming troughs are simplified without the V-notch slot

details and their inclination. In addition, all of the internal piping is ignored.

During the first stage of the project, the bulk part of the tank volume positioned

between the two large perforated plates was excluded. As a result, more details and

tighter meshing could be applied in the inlet region. This permitted the study of the fluid

flow distribution through the inlet device with the computing time still constrained to a

manageable scale for running dynamic simulations. In the later stage of the project, the

bulk volume of the tank is taken into account but inlet boundaries are further simplified

and assume equal flow rate out of each lateral in order to study the flow pattern inside the

skim tank. The simplified tank model is shown in Figure 3 and meshing details of the

inlet region are shown in Figure 4.

3

Figure 1. AutoCAD drawing of the skim tank and inlet distributor.

4

Figure 2. 3-D Model of the entire skim tank with description of internal components.

Figure 3. Simplified skim tank model w/o the bulk volume between the large perforated plates.

Outlet

Baffle

Two Large Perforated Baffles

Oil Skimming Collectors

Inlet Distributors

Outlet

Nozzles

Outlet

Baffles

Inlet

Nozzle

5

Figure 4. Meshing details of the inlet region of the simplified skim tank model.

Meshing w/

Boundary

Layers

Total Cells = 1,519,160 ; Total Faces = 3,194,845

6

Meshing of the Flow Domain

For CFD, the computational approach differs from analytical (or theoretical)

solutions in that the CFD software only solves equations at specific points rather than for

the entire flow field. Properly choosing these points may become quite difficult -

especially for a very complex geometry and sometimes it may require hundreds of

thousands or millions of points. Before these specific points can be generated, the user

must first determine the size of the region to be modeled -- this is the so-called

computational domain. The computational meshing process breaks up the

computational domain in space, then the calculations (solving the fundamental equations

for mass, momentum and energy balance) are carried out at each node point

simultaneously or sequentially, depending on the selected solver.

The quality of the grid is extremely important and can strongly influence the

solution sometimes also determining whether or not a valid or a converged solution can

be achieved at all. The most important qualification about a computational meshing is

that it must define enough points to capture everything of interest that is happening in the

computational domain without becoming so extensive that unreasonable computation

times are required. If there are too few points included, some of the critical information

about the flow regime may be completely lost.

The types of meshing that arrange the spatial points in a roughly rectangular (or

hexahedral) arrangement are referred to as "structured" meshing. Another method of

mesh generation, which involves a triangular (or tetrahedral) layout of the computational

points, is called "unstructured" meshing. Sometimes, different meshes can be adapted in

different regions decomposed from the whole flow field to take advantage of specific

characteristics of the different meshing systems. Such a combination is so-called

hybrid meshing (also including prism/wedge and pyramid elements).

In this study, a hybrid meshing was constructed in the first stage of the study for

the simplified skim tank model without the bulk volume between the large perforated

plates. The hybrid meshing was comprised of 1,519,160 hybrid cells, and the total node

count was 367,855 with 3,194,845 faces. As described previously and shown in Figure 4,

the surface meshing of the inlet header and the laterals illustrates the details of the tighter

meshing scheme implemented near the region of the inlet distributors. In the later stage

of the study, a fully structured meshing was created including the bulk volume of the tank

between the two large perforated plates and there are a total of 695,620 hexahedral cells

with 730,041 nodes and 2,122,171 faces. The reduction of total cell count was due to the

relatively loose meshing scheme and a further simplification of the inlet boundaries.

7

Material Properties

The CFD software used in this study is capable of simulating multiple phase

flows of a computational domain with both structured or hybrid meshing. The fluids

used in this study were produced water and its associated oil content of 710 mg/liter.

Under the operating conditions, 35C and 101.3 kPa, the density of the produced water is

1104.3 kg/m

3

and its viscosity is 0.7225 cP, whereas, the density and viscosity of the oil

phase at operating conditions are 814.9 kg/m

3

and 3.54 cP, respectively.

Simulation Models

In this study for skim tank design, two different CFD simulation models were

employed. The following is the brief description of the two simulation models.

VOF (Volume of Fluid) Model: It is a multiphase model accepting simultaneous

different fluid flows. However, the phases are not interpenetrating. The volume fraction

of each phase within a computational cell is determined and used to volume-average the

properties of the individual fluids. No particle sizes can be specified for the incoming

phases and it is usually done with transient calculations with small time steps. This

model was used in the first stage study focusing on the flow rate through the inlet

distribution device.

Steady-State (Water Phase Only) Model: The Single-Phase Steady-State model is

used to develop the flow regime below the water surface. There was a virtual barrier at

the surface in order to generate realistic flow profiles for a totally water-filled tank

model. Once the flow regime has been calculated in the steady-state model, particles can

be injected at the inlet (or any other location of the operators choice) to visualize their

movement within the flow field. The properties of the particles (size, density, etc.) can

be chosen to simulate any of the phases being studied. Using this technique, it is possible

to determine particle sizes likely to be carried out with the opposite phase as well as

retention times of each phase within the skim tank.

Results and Discussions

Flow Rates of Inlet Distributor:

The mass flow rates in the inlet distributor through each lateral at different

simulation time from 100 to 120 seconds are listed in Table 1 and the corresponding plot

is shown in Figure 5. The above flow rates were calculated during the first stage study

using the VOF Model with transient simulation and a total simulation time of 120

seconds. Note that the variance in mass flow rates out of the laterals is less than 0.5%.

This constitutes excellent flow distribution from the inlet distributor.

8

Table 1: Mass Flow Rates through Inlet Distributor Laterals

Distributor Time Flow Ratio Time Flow Ratio Time Flow Ratio

Laterals 100 sec % 110 sec % 120 sec %

Arm-B1 25.234 12.55% 25.441 12.55% 25.390 12.54%

Arm-B2 24.401 12.14% 24.721 12.20% 24.785 12.24%

Arm-B3 24.684 12.28% 24.973 12.32% 25.019 12.36%

Arm-B4 26.301 13.08% 26.312 12.98% 26.141 12.91%

Arm-F1 25.280 12.58% 25.490 12.58% 25.442 12.57%

Arm-F2 24.316 12.10% 24.632 12.15% 24.690 12.20%

Arm-F3 24.525 12.20% 24.814 12.24% 24.860 12.28%

Arm-F4 26.278 13.07% 26.291 12.97% 26.122 12.90%

Summation 201.019 100.00% 202.674 100.00% 202.448 100.00%

Figure 5. Mass flow rates out of individual inlet distributor laterals.

9

Skim Tank Retention Time:

Oil and water separation is fundamentally a gravity separation process. Almost

any production facility can gain significant benefits from inclusion of a gravity separator

in the primary stage of produced water treatment. However, the primary limitation of

successful gravity separation is the size of the vessel required to provide adequate

retention time for full treatment and the efficient use of available tank volume. In CFD

simulations, produced water retention times were determined by injecting water

particles into the model and tracking their time to exit the outlet nozzles. The results

are shown in Figure 6 and Figure 7, in histogram plots and cumulative curves as a

percentage of total particles exiting, for skim tank internals without the two large

perforated plates and after the installation of the two large perforated plates.

A comparison of the theoretical (volumetric displacement) retention times for

produced water with the median retention times determined by CFD analysis also is

shown in the table on the right-hand-side in both Figures 6 and 7. The theoretical

retention time of the skim tank is 17,406 seconds based on a liquid level of 22.5 feet with

a total produced water flow rate of 100,000 BBL/Day. As can be seen from the tables,

water retention time for the skim tank without the two perforated plates was about 43.4%

of the theoretical value. This is a clear indication that short circuiting occurs inside the

skim tank. On the other hand, the retention time of produced water was improved to

almost 88.5% of the theoretical value after installation of the two large perforated plates.

Furthermore, minimum value of the retention time for the latter was 7434 seconds as

compared to 634 seconds for the former case. These results suggested a significant

improvement of effectively utilizing the bulk part of the tank volume when implementing

the design and installation of the two large perforated plates.

Fluid Flow Patterns:

As traced by the flow path-lines plots of the CFD software, the fluid flow paths,

colored by retention time, inside the skim tank without and with the two large perforated

plates are shown in Figures 8(a) and 8(b), respectively. In Figure 8(a), there are large

swirling patterns that are characteristics of severe recirculation and the presence of short-

circuiting flow paths inside the skim tank. In contrast, the path lines are improved in

Figure 8(b) with a much reduced recirculation pattern. In separate simulations, the

calculations showed similar flow patterns with a produced water flow rate of 30,000

BBL/Day and the skim tank liquid level set at 17 feet instead of the original 22.5 feet.

The plots of flow path lines for those low flow simulations are illustrated in Figures 9 (a)

and 9(b).

Carry-under of Oil droplets in Water Phase:

In order to evaluate the separation performance of the skim tank with designed

internals, the entrainment of oil droplets in the water phase was studied by the injection

of various sizes of oil particles into the water phase at the inlet and then determining

their potential for carry-under by following the particle tracks generated by the CFD

10

simulations. It should be noted that current CFD modeling is unable to simulate the

coalescence of oil droplets over time. Therefore, the separation performance illustrated

here is for the worst case scenario where the reverse emulsion is fully stabilized.

The CFD model used in these determinations was the single-phase steady-state

model with a virtual barrier placed at the surface as previously described. The side view

of the tank with particle tracking for 50 m, 75 m, and 100 m oil droplets are shown in

Figures 10, 11, and 12, respectively. Examination of these figures shows that there is

substantial entrainment of the 50 m oil droplets, only slight entrainment of the 75 m oil

droplets, and no entrainment of the 100 m droplets. In summary, with the

implementation of designed internals, the oil droplets of size larger than 100 microns are

expected to be readily skimmed off without extra assistance from gas flotation inside the

skim tank at a produced water flow rate of 100,000 BBL/Day. In a later study with a

lower produced water flow rate of 30,000 BBL/Day and skim tank liquid level set at 17

feet, the minimum oil droplet size that was readily skimmed off was reduced to about 50

microns.

Conclusions

Computational fluid dynamics simulations were performed on a large diameter

skim tank and the results indicate that a satisfactory performance of the tank can be

achieved with the proposed internal configuration under the specified produced water

flow rate provided that the incoming oil droplets are not too small and that bulk gas

evolution in the inlet region is eliminated or minimized. With the installation of two

large perforated plates, the Median value of the estimated retention time from particle

tracking is 88.5% of the calculated theoretical retention time. This suggests a very

effective utilization of the bulk part of the skim tank volume.

The results from transient CFD simulations demonstrate that an excellent flow

distribution through the inlet distributor is achieved with the variance in mass flow rates

out of each lateral being less than 0.5%. From the particle tracking results, the CFD

model predicts that oil droplets larger than 100 microns are expected to be fully skimmed

off without assistance from gas flotation at a produced water flow rate of 100,000

BBL/Day.

11

Figure 6. Retention time histogram and cumulative curve of skim tank without the two large perforated plates.

Full Tank Histogram (w/o 2 Perforated Plates)

0

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F

r

e

q

u

e

n

c

y

.%

10.%

20.%

30.%

40.%

50.%

60.%

70.%

80.%

90.%

100.%

Frequency

Cumulative %

12

Figure 7. Retention time histogram and cumulative curve of skim tank with the two large perforated plates.

Full Tank Histogram (w/ 2 Perforated Plates)

0

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Frequency

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13

(a)

(b)

Figure 8. Fluid flow path lines inside the skim tank

(a) Without large perforated plates.

(b) With two large perforated plates.

14

(a) (b)

Figure 9. Comparison of flow path lines under low flow rate of 30,000 BWPD and low liquid level at 17 feet.

(a) Skim tank without the large perforated plates. (b) Skim tank with two large perforated plates.

15

Figure 10. Particle tracking of oil droplets of 50 micron under designed flow rate.

Figure 11. Particle tracking of oil droplets of 75 micron under designed flow rate.

Side View

Particle Size = 50 micron

Side View

Particle Size = 75 micron

16

Figure 12. Particle tracking of oil droplets of 100 micron under designed flow rate.

Side View

Particle Size = 100 micron

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