All Stream Narayana Jee-Main Gtm-8 Final Key & Sol

NARAYANA IIT ACADEMY
INDIA
Sec: Sr.IIT- ALL STREAMS PHASE 1 Date: 16-02-14
GRAND TEST - 8
Max Marks:360
KEY SHEET
PHYSICS
1)4 2)2 3)2 4)1 5)2 6)3 7)3
8)3 9)3 10)3 11)2 12)3 13)3 14)3
15)3 16)3 17)1 18)4 19)1 20)4 21)2
22)2 23)4 24)2 25)4 26)1 27)1 28)2
29)2 30)3
MATHEMATICS
31)2 32) 1 33) 2 34)1 35)1 36)4 37) 4
38) 1 39)1 40)3 41)2 42)1 43)3 44)1
45)1 46)2 47)2 48)3 49)1 50)4 51)4
52)4 53)1 54)1 55) 4 56)2 57)1 58)1
59)4 60)3
CHEMISTRY
61)4 62)4 63)2 64)4 65)3 66)4 67)1
68)4 69)1 70)3 71)3 72)4 73) 3 74)3
75)2 76)4 77)2 78)4 79)3 80)1 81)2
82)1 83)1 84)4 85)1 86)4 87)4 88) 2
89)3 90)2

Narayana IIT Academy 16-02-14_Sr.IIT-ALL STREAMS_PHASE-I_JEE MAIN_GTM-8

Sr.IIT-ALL STREAMS_JEE-MAIN_Solutions Page 2
HINTS &SOLUTIONS

PHYSICS
1
2
0 0 0
0
1 2
2
I
I E C or E
C
c
c
= =

0 12 8
2 4
8.8 10 3 10
E
=

1
55.5NC
=
2 Conceptual
3 from input signals , we have

A B OUTPUT nand
GATE
0 0 1
1 0 1
0 0 1
1 1 0
0 0 1

The output signal is shown at (b)
4

A B Y
1
Y
2
Y Y
0 0 1 1 1 0
0 1 1 1 0 1
1 0 1 0 1 1
1 1 0 1 1 0

5

6
1 1.5
4
t and drift t km = = =

6
2
0
50cos37
v
R
=

2
40 ; 20 /
10
v
v m s = =
7 conceptual


8

9
( ) 30 20 5
di di
l i t ve
dt dt
= + =
30 30 2sec; 1
di
L at t i amp
dt
> = >
10 Basic concept of phasor
11 This error occur in all the instruments which utilizes screw or nut-bolt system
12 L.C of vernier =M.S.D V.S.D
| |
4
5 4.910 0.01 m mm
= =
L.C. of screw gauge =0.01mm

13

Let slope of line AC is
1
& m that of line DB is
2
m , then

2 2
1 2
1 1
ln 2 ln
m m
nRT nRT
m m
=

1
2
2
T
T
=
14 The temperature of these objects being identical the cooling rate will depend upon surface area. The
circular pate has the largest area and hence will cool faster than cube and sphere, Sphere having less
surface area than a cube will cool at the lower rate
15
2
4 4 0.05
2 ; 10
2 10
S
R cm P Pa
R

= A = = =


16

0
3
tan37
8 4
r
= =
6 r m =
( )
2
0
F P h g r t = +

( )
5
10 10 8000 10 36 t = +

5 7
1.8 36 10 2 10 t = =
17 since it is a conductor

0
V =potential at surface=0

0 0
0
4 4 2
q Q
a a tc tc
+ =

2
Q
q =
18
A at surface B C O
V V V V V = = = =
Charge is on the outer surface hence
inside
V remains constant

19 The potential at centre of sphere in which q charge is uniformly distributed throughout the volume is

0
1 3
4 2
C
q
V
R tc
=
By symmetry the potential at centre due to half sphere will be half of the complete sphere

0
1 3 / 2
4 2
C
q
V
R tc
=

0
1 3
4 2 2
Q q
Q
R tc
(
= =
(

20
1 2 1
2
1 2
;
2
r
v v v
A A v
v v
| |
= =
|
+
\ .

energy reflected
1
9
energy incident =
21



36 /
1.2
30
m s
l m = =
0.3m
22 Conservation of angular momentum

2 2 2
0
'
2 2 3
i f
mR mR ml
L L e e
(
= +
(

2
0
2 2
3
'
3 2
R
R l
e
e =
+

23
1 2 2 1 2
(1 cos )cos2 cos2 cos2 cos2 E a f t f t a f t a f t f t t t t t t = + = +

( ) ( )
2 1 2 1 2
1 1
cos2 cos2 cos2
2 2
E a f t a f f t a f f t t t t = + + +
This is a complex vibration consists of harmonic vibrations of frequencies ( ) ( )
2 1 2 1 2
, f f f and f f +
The highest is ( )
1 2 max
. f f So hv T | + = +
( )
max 1 2
T h f f | = +

( )
34
15 15
19
6.6 10
3.6 10 1.2 10 2.35
1.6 10
= +

17.45ev =
24 Apply conservation of momentum & energy

25 Let total sum of number of isotopes at the formation of the planet was
0
N and currently is N

0 1
0.2
2
t
X
N
N e N
| |
= =
|
\ .
.(i)

2 0
0.8
2
t
y
N
N e N
| |
= =
|
\ .
..(ii)
Dividing equation (ii) by (i)

( )
1 2
4
t
e

=
( )
1 2
ln4 t =

9
ln2 1 1
2ln2
10 2 4
t
(
=
(

9
8 10 t = years
26

At P,
( ) 8 3
,
d d
x
D
A
For 2
nd
maxim,

2
24
2 2
d
x
D
A = =

27
0 0 0
2 2 2
I I I
B i j k
R R R

. . .
| | | | | |
= + +
| | |
\ . \ . \ .

0
3
2
I
B
R
=
28 In steady state the capacitor is fully charges and is treated as open circuit, so no current flows
through branch containing capacitor in steady state, So, the circuit can be redrawn as

Potential difference across capacitor in steady state
6 6 V V V = =
(-ve sign signifies that left hand plate is of negative polarity )
Charge 1 6 6 CV C = = =

29 In steady state current through capacitor is zero. For zero deflection
A B
V V
So,
1
1
q
IR
C
=
And
1 2
2
2 2 1
q R C
IR
C R C
= =
30
( )
4
3 2
0
2
4
T
x
U x x dx x = +
}

Since there is no loss energy , so

4
2 2
1
1
3
4 2
x
x E mv + = = =

4 2
4 12 0 x x + =

2
4 16 48
2
x
+
=

4 8
6, 2
2

= = +
2 x =

MATHEMATICS
31 As z,iz 1 are collinear

( )
1 1
0 1
1 1 1 1 1 1
z z z z
iz iz i z z i

= =

[taking I common from
2
R ]

1 1 1
0
0 0 1
z z
z i z i i

=

[Using
1 1 3 2 3
C C C and C C ]
( ) ( ) 1 1 0 z z i z i z

| | | |
+ + =
| |
\ . \ .

0 z z z iz i z z i z z i

+ + + =
( ) ( ) 2 1 1 0 z z i z i z

+ =

1 1
0
2 2
i i
z z z z
+
=

1 1
2 21
i
z
+
=
Thus , z lies on a circle
32
As
1 2 3
, z z z = = circum centre of ABC A is 0
s
z = .Also, centriod of ABC A is 0
s
z = . Also
centroid of ( )
1 2 3
1
3
G
ABCis z z z z A = + + . If
H
z denotes the orthocentres of ABC A , then
( )
1
2
3
G H S
z z z = +
( ) ( ) ( )
1 2 3
1 1
2 0
3 3
H
z z z z + + = +

1 2 3 H
z z z z = + +
33 Let common root be o , then

2 2
3 1 0 2 1 0 p and q o o o o + + = + + =
Multiply the second expression by 3/2 and subtract from the first to obtain

3 1 1
2 2 2 3
p q
p q
o o
| |
= =
|

\ .

Thus, ( ) ( )
2
3 2 3 2 3 0 p p q p q + + =
34
2 1
2
n n n
a a a
+ +
+

( ) ( )
/ 2
0
2cos 2 4 cos2 cos 2 2
1 cos2
n x nx n x
dx
x
t + + +
=
}

( )
/ 2
0
2cos 2 2 0 n x dx
t
= + =
}


35
30
4
27 C

36 conceptual

37 We have

5 0 0 1 0 0
0 1 0 0 1 0
0 10 2 5 0 0 1
x
AB
x x
( (
( (
= =
( (
( (

1/5 x =
38
1
1 0
1
a a
b b
c c

Applying
2 2 1 3 3 1
C C C and C C C
And expand to obtain
( )( ) ( )( ) ( )( ) 1 1 1 1 1 1 0 a b c b a c a b + + + + + + =
Divide by ( )( )( ) 1 1 1 a b c + + +
39 Two tallest boy can be different groups in
( )( )
2 2 1
1 1
n
n
C C
ways
40 , 2
2
o
o o | o o | o
+
+ + = + = = =
41
3
2
0
4 13 | sin
3
x
t a
t t x
x
+ =

2
12 39 3sin / x x a x + =

2
12 39 3sin
a
x x
x
+ =
( )
2
6 3 sin 1
a
x
x
| |
=
|
\ .

sin 1, 6
6
a
x = =
42 From
2
sin sin 1, x x + = we get
2
sin cos x x = . Now, the given expression is equal to

( )
6 6 4 2
cos cos 3cos 3cos 1 1 x x x x + + +

( )
3
6 2
cos cos 1 1 x x = +
( )
3
3
sin sin 1 1 x x = +

( )
3
2
sin sin 1 1 1 0 x x = + = =

43 We have
1 1
sin2 S x | = =

2 1 2
cos2 S x x | = =

3 1 2 3
cos S x x x | = =

4 1 2 3 4
sin S x x x x | = =

So that
4
1 1 1 3
1 2 4
tan tan
1
i
i
S S
x
S S

=
=
+



1
sin2 cos
tan
1 cos2 sin
| |
| |

=

( )
( )
1
cos 2sin 1
tan
sin 2sin 1
| |
| |

( ) ( )
1 1
tan cot tan tan / 2 | t |

= =
/ 2 t | =
44 ( ) 33 87 y m x =
( )
1 87 33
33 87
2
m
A m
m
| |
=
|
\ .

2
2
0 0
dA d A
dm dm
= >

45 Perpendicular distance from centre to the line
1
2
=
common difference
1
1
2 1 2 2
2
2 2 4
or or

<

46 Common tangent nearer P is x=1
directrix of ellipse is x=1
e=1/2

1
,1
2
s
| |
=
|
\ .

47 Perpendicular bisector of the base must meet the parabola at the vertex of the triangle.
48 Let P( a,b,c) be the foot of the perpendicular from the origin to the plane, then direction rations of
OP are
0, 0, 0 a b c i.e, a,b,c
So the equation of the plane passing through P(a,b,c) the direction ratios of the normal to which are
a,b,c is
( ) ( ) ( ) 0 a x a b y b c z c + + =

2 2 2
ax by cz a b c + + = + +
49 Since ( ) ' 2 cos 0 , f x x for all x R = + > e so f is one-to-one. Moreover,
( ) ( ) f x as x and f x as x , hence the range of f is R. Therefore, f is onto as
well
50 Conceptual
51
( ) ( )
0
'9 lim
h
f x h f x
f x
h
+
=

( ) ( ) ( ) ( )
0 0
0
lim lim
0
h
h h
f x f h f x e g h
h h

+
| |
= =
|
\ .

( ) ( )
0
lim '
h h
h
e g h e g h
= +
( ) ( ) ' 0 0 4 g g = + =
Hence ( ) ( ) ( ) 4 10 10 0 f x x c but f g = + = =
So ( ) 4 f x x =


52 Conceptual
53 ( )
( )
( ) ( ) ( )
( )
( )
1/ 1/
1 2
1
n n
n n
f x x
f o f x
x
f x f x
= =
+
+

Similarly ( )
( )
1/
1 3
n
n
x
f o f o f x
x
=
+
and likewise ( ) ( )
( )
1/
.....
1
n
n
x
f o f o f n times x
nx
=
+

( )
( )
( )
1
1/ 0
2
1/
. 1
1
n
n
n n
n
n
x
x g x dx dx Put nx t
nx
= + =
+
} }

We get the above integral as

( )
1
1
1 1
1
n
n
t
dt t K
n t n n
= +
}

( )
( )
1
1 1
1
1
n
n
nx K
n n
= + +

54 ( ) ( ) h x h I t t + = +
Where sin4
x
I t dt
t
t
+
=
}

Put , t u t = + so that
( ) ( )
4
0
sin
x
I d t u u = +
}

( ) ( )
4
0
sin
x
d h x u u = =
}

( ) ( ) ( ) h x h h x t t + = +
55 conceptual

56 ( ) ( ) ( ) ( ) ( ) ( ) ( ) ( ) ( ) ( )
2 2
2 ' ' 2 0
d
f x g x f x f x g x g x f x g x f x
dx
+ = + = = ( (

Hence ( ) ( )
2 2
f x g x + is constant . Thus
( ) ( ) ( ) ( ) ( ) ( ) ( )
2
2 2 2 2 2
16 16 2 2 2 ' 2 16 16 32 f g f g f f + = + = + = + =

57 Let ( )
1/
1
x
y x = +
( )
2 3 4
1 1
log log 1 ...
2 3 4
x x x
y x x
x x
(
= + = + +
(

2 3
1 ..
2 3 4
x x x
= + +

2 2
1 .. ..
2 3 2 3
x x x x
a
y e ee
| | | |
+ + | |
| |
\ . \ .
=

2
2 2
1
1 ..... ..... ....
2 3 2! 2 3
x x x x
e
(
| | | |
= + + + + + (
| |
( \ . \ .

( ) ( )
2
2
1 1 1 1
0 0 .....
2 3 2 2
y e ex ex x x
(
| |
+ = + + + +
(
|
\ .
(

(0,(x) in terms containing x)


2
0
1
2
1 1 11
2
lim
3 8 24
x
y ex
e e
x
+
(
= + =
(

58 Conceptual
59 Conceptual
60 Vertex is (-2,1), length of the latus return =4a where a=1/2 latus rectum is
parallel to the tangent x+2=0 at the vertex, at a distance from it. So its
equation is x=-3/2,1+1) and (-3/2, 1-1) i.e (-3/2,2) and (-3/2,0). The point not
lying on ( ) 2 3 0 3/ 2,2 x y is + + =

CHEMISTRY

61
( )
( )
( )
( ) ( )
4 2
1
f
f
T KCl i KCl
T X i x i x
A
= = =
A

2
0.5
4
ix = =
for association of 3 molecules ( )
1
1 1 i x
n
o
| |
=
|
\ .

1
1 1 0.5
3
o
| |
= =
|
\ .

0.75 o =

62 The boyles temperature of both
2
H and He is very low.
63 Along the body diagonal two B
ions and one A
are removed
64 At high concentration of sulphide ions the cations of both II and IV groups are precipitated.
65 Follow CIP rules.
66 2 r n
2
1
2
n
r n
67 Depends on stability of carbocations
68 (i) Molecules move faster for which
T
M
greater. obviously
2
H molecule move faster.
69 Cannizzarrows reaction
70 Rate of reaction depends on leaving ability of the group
71 Nucleophilic substitution
72 In the partial hydrolisys of
6
Xe F different products formed or
4 2 2
XeO F and XeO F

73 Tollens reagent oxidizes aldehyde group only
74
3
B PH
2 2
A NaH PO
75 Conductivity
6 6 6
4
2 10 1 10 1 10 BaSO

= =

2 2
4
4
0 0 0
BaSO
Ba SO

+
= + Molar conductivities =
1 2 1
60 2 20 100ohm cm mol

+ =
In the case of sparingly soluble salt
4
6
0
1000 1000 10
100
BaSO V
K
C C

= = = =

3
5
10
10 /
100
C moles litre
= =

76
1
C epimers are called anomers
77 a) basic strength in vapour state depends on +I effect
c) +R group increase basic strength at para and decrease the basic strength at meta due to I.
d) Lesser the surface volume more the basic strength, hence NH
3
is more basic. ROH >H
2
O due to
+I effect of R group
78 Conceptual
79 Conceptual
80
3
B NH
2
C N
3 2
D Mg N
81 Conceptual


82

83 Iodoform reaction
84 Teflon, polystyrene and PVC are formed by addition polymerization
85 Conceptual
86 Ratio of concentration of reactants and products is same in all three.
87
0 t
Kt C C
88 Follow the structure of dichromate ion.

89

2
CH
2
H N
2
0
/
0.5
.........
NaNO HCl
C
N N =
2
N
H
or
H
+

90 Sod. Benzoate is metabolized to hippuric acid
6 5 2
. C H CO NH CH COOH

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