Narayana IIT Academy India JEE-MAIN Model Test

NARAYANA IIT ACADEMY
INDIA
Sec: Sr.IIT ALL STREAMS PHASE 1 Date: 09-02-14

GRAND TEST 6 Max Marks:360
JEE-MAIN_2011 MODEL

IMPORTANT INSTRUCTIONS:
There are three parts in the question paper A, B, C consisting of Physics, Maths and
Chemistry having 30 questions in each part of equal weightage. Each question is allotted 4
(four) marks for each correct response.
Candidates will be awarded marks as stated above in instruction for correct response of each
question. 1/ 4 (one fourth) marks will be deducted for indicating incorrect response of each
question. No deduction from the total score will be made if no response is indicated for an
item in the answer sheet.
There is only one correct response for each question. Filling up more than one response in each
question will be treated as wrong response and marks for wrong response will be deducted
accordingly as per instruction

PAPER SETTERS& VERIFIERSINFO
Subject
Paper Setters
(VSP-SPARK)
Paper Verifiers (Hyd-MDP)
MATHS
Mr.K.V.R-9949090113
K.SRINIVAS 9848268767
MURALIDHARRAO - 9908224630
PHYSICS
Mr. Srinivas-9893242371 PRASAD 7799557666
CHEMISTRY
Mr. M.R.-9912343665
G.N REDDY 9440434981
MALLIKARJUN 9441117456
MAKBUL - 9440886717

Narayana IITAcademy 09-02-14_Sr.IIT ALL STREAMS_PHASE-I_JEE MAIN_GTM-6

Sr.IIT ALL STREAMS _JEE-MAIN Space for rough work Page 2

PHYSICS
1. In a cylindrical region of radius R, a time varying magnetic field B kt = exists as
shown in the figure ( ) 0 k > . A charged particle having charge q located at a distance d
from centre of cylinder is situated at P. This charged particle is taken slowly form P to
via the path shown in the figure, with the help of an external agent. The work done
by this force (external agent) during the process, is

-
d
- P
q
R

a)
2
4
q R k
b)
2
q R d k
c)
3
2
q R k
d

d) zero
2. For a process on a system (gas enclosed in a vessel), the p V graph is shown in the
figure. For this process three statements are given as:
-
-
p
V
pV constant =

I. During the process, work done by the system is continuously increasing.
II. During the process, work done by the system is zero.
III. During the process, internal energy of the gas is continuously increasing.
IV. During the process, heat supplied to the system is continuously increasing.
a) all the four statements are correct b) only I and IV are correct
c) only II and IV are correct d) no statement is correct

3. The displacement x of a particle as a function of time t is shown in the figure. The
figure indicates:

t
x

a) the particle starts with a certain velocity, but the motion is retarded, and finally the
particle stops
b) the velocity of the particle is constant throughout
c) the acceleration of the particle is constant throughout
d) the particle starts with certain velocity and then its motion is uniformly accelerated
4. From a conducting ring of radius R which carries a charge Q (uniformly distributed)
along it periphery a small length dl is cut-off. The electric field at the centre due to the
remaining wire is
a)
2 3
0
8
Qdl
R
b)
2
0
4
Q
R
c) zero d) cannot be determined
5. The charge on two plates of a parallel plate capacitor of capacitance C are 3Q and Q,
respectively. The potential of the capacitor is [None of the plates of capacitor is
grounded].
a)
Q
C
b)
3Q
C
c)
4Q
C
d)
2Q
C


6. In the circuit shown in the figure, the charges on capacitors
1
C and
2
C are respectively
[In steady state].
1
E
2
E
1
C
2
C R

a)
1 1
C E and ( )
2 1 2
C E E + b)
1 1
C E and
2 2
C E
c)
1 1
C E and ( )
2 1 2
C E E d)
1 1
C E and
2
2 1
2 1
2
C E
C E
E
+

7. A battery of emf E and negligible internal resistance is connected to a resistor R.
Taking the heating effect of current and its further effects on circuit into the
considerations, indicate which of the plots shown in figure best represents the rate of
production of thermal energy in the resistor.
t
P
A
B
C
D

a) A b) B c) C d) D

8. A transparent sphere has its right half of the curved surface polished so that it acts as a
mirror. A paraxial light ray is incident from the left and emerges as shown in the
figure. The refractive index of the material of cylinder is:

-

a) 1.5 b) 1.7 c) 2.0 d) 2.3
9. A solid cylinder is performing pure rolling motion on a moving platform as shown.
Which of the relation between,
0
, , v R and v is correct?

-
R
0
v
v

a)
0
v R = b)
0
v v R = + c)
0
v v R = d)
0
v v =
10. In steady state find the current through branch containing inductor and voltage across
capacitor.
R
2R
C
L
2R
R
E

a) ,
2 2
E E
amp volt
R
b) ,
9 2
E E
amp volt
R

c) ,
3 4
E E
amp volt
R
d) ,
9 4
E E
amp volt
R


11. A doubly ionized
2
Li
+
ion in ground state absorbs 91.8 eV of energy. The increase in
angular momentum of electron is
34
[ 6.63 10 ] h J s
= .
a)
34
2.11 10 J s
b)
33
0.53 10 J s

c)
34
1.05 10 J s
d) cannot be computed
12. A sound source of frequency f sends waves of wavelength with speed v in some
medium. If the frequency is changed from 2 f to f , then the new wavelength and the
wave speed are respectively,
a) and v b) 2
2
and v
c)
2
and v
d)
4 2
v
and

13. A stationary source generates 5.0 Hz water waves whose speed is 2 m/s. A boat is
approaching the source at 10 m/s. The frequency of these waves as observed by a
person on the boat, is (assume Doppler Effect is valid)
a) 5 Hz b) 10 Hz c) 20 Hz d) 30 Hz
14. A stationary body of mass m is slowly lowered onto a massive platform of mass
( ) M m >> moving at a speed 4 m/s as shown in the figure. How far the body slides
along the platform? [Take
2
0.2 10 / and g m s = = ].

m
0.2 =
0
4 / v m s =
Smooth
M

a) 8 m b) 12 m c) 6 m d) 4 m

15. The potential energy of a particle of mass 5 kg moving in the x-y plane is given by
( ) 7 24 ; U x y J x = + and y being measured in metre. If the particle starts from origin
from rest, the magnitude of the conservative force acting on the particle is:
a) 25 units b) 24 units c) 7 units d) 84 units
16. A solid sphere of radius R is resting on a smooth horizontal surface. A constant force
F is applied at a height h from the bottom. Choose the correct alternative.

h

a) sphere will always slide whatever be the value of h.
b) sphere will roll without slipping if 0.4 h R = .
c) sphere will roll without slipping if 1.4 h R = .
d) sphere never be set into pure rolling
17. Two particles of masses m and M are initially at rest and infinitely separated from each
other. Due to mutual interaction (gravitational) they approach each other. Their
relative velocity of approach when they are at a distance d, is:
a)
2Gd
M m +
b)
( ) 2G M m
d
+
c)
( )
2GMm
M m d +
d)
2Gm
d


18. A point of mass 20 m kg = is suspended by a massless spring of spring constant
2000 / k N m = . The point mass is released from rest at 0 t = when elongation in the
spring is 15 cm. The equation of displacement of particle from its mean position as a
function of time is given by: [Take
2
10 / g m s = and downward direction as +ve].
(Assume Hookes law to be valid).
m
k

a) ( ) 10 sin 10
6
y cm t
| |
= +
|
\ .
b) ( ) ( ) 5 sin 10 y cm t =
c) ( ) 5 sin 10
2
y cm t
| |
= +
|
\ .
d) ( ) 5 sin 10
2
y cm t
| |
=
|
\ .

19. The length of an elastic string is a metre when the tension in it is 4 N and b metres
when the tension in it is 5 N. The length of string in metres when the tension in the
string is 9 N, is
a) a b + b) 5 4 b a c) 4 5 a b d) 9 5 b a


20. Two particles A and B are moving uniformly around concentric circular paths of radii
A
r and
B
r . If both the particles complete one rotation in the same time, then:
a) the ratio of their angular velocity is 1
b) the ratio of linear velocity is
A
B
r
r

c) the ratio of the force required for their motion may not be
A
B
r
r

d) all of the above
21. For CE configuration of a transistor,
a) input resistance is very small while output resistance is very high
b) input resistance is very large while output resistance is very small
c) both input and output resistances are very small
d) both input and output resistances are very large
22. A small mirror of area A and mass m is suspended by means of light thread, in vertical
plane. On the mirror, a beam of light of intensity I, is made to be incident
perpendicular to mirror, due to which mirror is displaced and thread makes a small
angle with the vertical. Assuming mirror to be totally reflecting, the value of is
[c speed of light, is in radians].
a)
2IA
cmg
b)
IA
cmg
c)
3IA
cmg
d)
2
IA
cmg

23. A piece of ice is floating in water. The fraction of volume of the piece of ice outside
the water is
3
[ 900 /
ice
kg m = and
3
1000 /
water
kg m = ].
a) 0.21 b) 0.01 c) 0.1 d) 0.9

24. Some physical quantities, a, b, c, x are related as
3 2
a b
x
c
= if the % error in , , a b c are
2% , 1% and 4% respectively, then % age error in x is
a) 8% b) 12% c) 4% d) 10%
25. Density of a liquid varies with depth as h = . A small ball of density
0
is released
from the surface of the liquid. Then(is A positive constant)
a) the ball will execute simple harmonic motion of amplitude
0

b) the mean position of the ball will be at a depth
0
2
from the free surface

c) the ball will sink to a maximum depth of
0

d) all of the above
26. The time taken by a transverse pulse to travel full length of a uniform rope of mass 0.1
kg and length 2.45 m hanging from the ceiling, is
a) 1 s b) 0.5 s c) 2 s d) 1.5 s
27. Two point white dots are 1 mm apart on a black paper. They are viewed by eye of
pupil diameter 3mm. Approximately, what is the maximum distance at which these
dots can be resolved by the eye? [Wavelength of light =500 nm].
a) 5 m b) 1 m c) 7 m d) 3 m


28. Which of the following statement leads us to identify the p-side of p-n junction
diode?(Beep is indication of flow of current)
a) when positive lead of multimeter is connected to one leg of diode and negative lead
of multimeter to other leg, then a beep is obtained
b) when p-side of diode is connected to negative lead of multimeter and n-side to
positive lead, then a beep is obtained
c) when one leg of diode is connected to ve lead of multimeter and other leg to +ve
lead, then no beep is obtained
d) both (a) and (c)
29. To identify whether a p-n-p transistor is working or not, using multimeter, which
statement serves the purpose?
a) the common lead of multimeter is connected to base and other lead to first emitter
and then to collector, only 1
st
connection shows the continuity
b) the common lead of multimeter is connected to base and other lead to first emitter
and then to collector, both the connections shows the continuity
c) the common lead of multimeter is connected to base and other lead to first emitter
and then to collector, none of the connection shows the continuity
d) all of the above
30. In measurement of mass of a given object by the principle of moments, the meter scale
is hung from its mid-point. A known weight of mass 2 kg is hung at one end of metre
scale and unknown weight of mass m kg is hung and 20 cm from the centre on other
side. The value of m is
a) 2 kg b) 5 kg c) 2.5 kg d) 0.8 kg


MATHEMATICS
31. If
1 2 3
, , p p p denote the distance of the plane 2 3 4 2 0 x y z + + = from the planes
2 3 4 6 0 x y z + + = ,4 6 8 3 0 x y z + + = and 2 3 4 6 0 x y z + = respectively, then
a)
1 2 3
8 0 p p p + = b)
2 2
3 2
16 p p = c)
2 2
2 1
8p p = d)
1 2 3
2 3 29 p p p + =
32. A ray of light incident at the point ( ) 2, 1 gets reflected from the tangent at ( ) 0, 1 to
the circle
2 2
1 x y + = . The reflected ray touches the circle. The equation of the line
along which the incident ray moved is
a) 4 3 11 0 x y + = b) 4 3 11 0 x y + + = c) 3 4 11 0 x y + = d) 3 4 11 0 x y + =
33. In a shop there are five types of ice-creams (each type is available unlimited).A child
buys six ice-creams.
Statement-1: The number of different ways the child can buy the six ice-creams is
10
5
C .
Statement-2: The number of different ways the child can buy the six ice-creams is
equal to the number of different ways of arranging 6 As and 4 Bs in a row.
a) Statement 1 is true, Statement 2 is true; Statement 2 is not a correct explanation for
Statement1.
b) Statement 1 is true, Staement2 is false.
c) Statement 1 is false, Statement 2 is true.
d) Statement 1 is true, Statement 2 is true, Statement 2 is a correct explanation for
Statement 1.

34. The mean deviation of items , , 2 .................., 2 x x y x y x ny + + + from mean (y >0) is
a)
( ) 1
2 1
n n y
n
+
+
b)
( ) 1
2 1
n y
n
+
+
c)
2 1
ny
n +
d)
( )
( )
2 1
1
n y
n n
+
+

35. If PQ is a double ordinate of the hyperbola
2 2
2 2
1
x y
a b
= such that OPQ is an equilateral
triangle, O being the center of hyperbola. Then the eccentricity e of the hyperbola
satisfies.
a) 1 2 3 e < < b)
3
3
e = c)
3
2
e = d)
2
3
e >
36. Let ; a i j k b i j k
. . . . . .
= + = + and c
be a unit vector perpendicular to a
and coplanar with

a
and b
, then c
is
a)
1
2
j k
. .
| |
+
|
\ .
b)
1
2
j k
. .
| |
|
\ .
c)
1
2
6
i j k
. . .
| |
+
|
\ .
d)
1
2
6
i j k
. . .
| |
+
|
\ .

37. Out of 3n consecutive natural numbers, 3 natural numbers are chosen at random with
replacement. The probability that the sum of the chosen numbers is divisible by 3 is
a)
( )
2
3 3 2
2
n n n +
b)
( )
( )( )
2
3 3 2
2 3 1 3 2
n n
n n
+

c)
( )
( )( )
2
3 3 2
3 1 3 2
n n
n n
+

d)
( )( )
( )
3 1 3 2
3 1
n n n
n

38. If
3 4
2
3 4
x
f x
x
| |
= +
|
+
\ .
, then ( ) f x dx
}
is
a)
2
3 4
log
3 4
x
x
e c
x
+

+
+
b)
8 4
log1
3 3
x x c +
c)
8 2
log1
3 3
x x c + + d)
8 2
log1
3 3
x x c + +

39. Let A be a 2 2 matrix with real entries. Let I be the 2 2 identity matrix. Denote by
( ) tr A , the sum of principal diagonal entries of A. Assume that
2
A I = .
Statement-1: If A I = and A I = , then det 1 A = .
Statement-2: If A I = and A I = , then ( ) 0 tr A = .
Statement1.
Statement 1.
40. Statement -1: If
2 0 1
5 1 0
0 1 3
A
(
(
=
(
(

then ( ) adj adjA A =
Statement-2: If A is a non-singular matrix of order n then ( )
( )
2
1 n
adj adjA A

=
Statement1.
Statement 1.

41. Statement-1: An equation of a common tangent to the parabola
2
16 3 y x = and the ellipse
2 2
2 4 x y + = is 2 2 3 y x = +
Statement-2: If the line ( )
4 3
, 0 y mx m
m
= + = is a common tangent to the parabola
2
16 3 y x = and the ellipse
2 2
2 4 x y + = , then m satisfies
4 2
2 24 m m + = .
Statement1.
d) Statement 1 is true, Statement 2 is true, Statement 2 is a correct explanation for Statement 1.
42. Statement-1: ( ) ( )
1
0
1 2 2
n
n n
r
r
r C n

=
+ = +
.
Statement-2: ( ) ( ) ( )
1
0
1 1 1
n
n n
n r
r
r
r C x x nx x

=
+ = + + +

Statement1.
Statement 1
43. The equation sin 1 0
2
x

+ = has one root in interval
a) 0,
2
| |
|
\ .
b) ,0
2
| |
|
\ .
c)
3
,
2
| |
|
\ .
d) ,
2
| |
|
\ .


44. One of the solution of differential equation
sin
dy y
dx y y x
=
is
a) ( ) cos 2008 sin y x y y + = + b) ( ) cos 2008 sin y x y y = +
c)
2 2
sin 420 x y + = d)
2
( cos ) 20 sin y x y y + = +
45. The sums of first n terms of two A.P.s are in the ratio ( ) ( ) 3 8 : 7 15 n n + + .The ratio of
their 12
th
terms is
a)
4
9
b)
7
16
c)
3
7
d)
16
7

46. A person is permitted to select at least one and at most n coins from a collection of
2 1 n + (distinct) coins. If the total number of ways in which he can select coins is 255,
then n equals
a) 4 b) 8 c) 16 d) 32
47. The statement ( ) p q q . v is
a) p q v b) p q . c) ( ) p q v d) ( ) p q .
48. In a ABC A , if
1
1 0
1
a b
c a
b c
= , then
2 2 2
sin sin A Sin B C + + is equal to
a)
9
4
b)
4
9
c) 1 d) 3 3
49. Let ( ) ( )( )( ) ( ) 1 2 3 .... 100 f x x x x x = + + + + and ( ) ( ) g x f x = . ( ) ( ) ( )
2
f x f x '' ' , then ( ) 0 g x = ,
has
a) no solution b) exactly one solution
c) exactly two solutions d) minimum three solutions

50. If ( ) f x be a continuous function for all real values of x and satisfies
( ) ( )
8 2
2
3
2
x
x
x
f t dt t f t dt = +
} }
, then ( )
1
1/2
f x dx
}
is equal to
a)
5
ln
8
| |
|
\ .
b)
1 8
ln
2 5
| |
|
\ .
c)
8
2ln
5
| |
|
\ .
d)
1 5
ln
2 8
| |
|
\ .

51. The number of distinct real values of for which the vectors
3 3
, i k i j
. . . .
+ and
( ) 2 sin i j k
. . .
+ are coplanar is
a) 0 b) 1 c) 2 d) 3
52. The maximum value of z satisfying the equation ( )
2 2 1 1
1
12 3
z z z + = is:
a) 2 b) 3 c) 4 d) 6
53 The shortest distance between the lines
1 2 3
2 3 4
x y z
= = and
2 4 5
3 4 5
x y z
= = is:
a) 1/ 6 b) 1/ 6 c)
( )
1/ 3 d) ( ) 1/3
54. If ( )
2
4
sin log
1
e
x
f x
x
| |

= |
`
|

\ . )
, then domain and range of ( ) f x are respectively given by:
a) ( ) | | 2,1 , 1,1 b) ( ) ( ) | | , 2 1, , 0,1
c) ( ) | | 0,1 , 1,1 d) ( ) ( ) ( ) , 2 1, , 0,1
55.
( )
3
0
1 sin cos log 1
lim
x
x x x
x
+ +
equals:
a) 1/2 b) -1/2 c) 0 d) 1
56. All the points on the curve sin y x x = + at which the tangent is parallel to x-axis lie on a/an:
a) straight line b) circle c) parabola d) ellipse

57. Two fair dice are rolled simultaneously. It is found that one of them shows odd prime
number. The probability that remaining die also shows an odd prime number, is equal to:
a) 1/5 b) 2/5 c) 3/5 d) 4/5
58. An investigator interviewed 100 students to determine their preferences for the three drinks,
Milk (M), Coffee (C) and Tea (T). He reported the following:
( ) 10 n M C T = , ( ) 20 n M C = , ( ) 30, n C T = ( ) 25, n M T = n (only C) =5,
n (only T) =8.Assuming that every student consumes atleast one of the above mentioned
drinks the number of correct statements from the following is:
1) ( ) 47 n M = 2) ( ) 45 n C = 3) ( ) 53 n T = 4) ( ) 20 n M C T
'
=
a) 1 b) 2 c) 3 d) 4
59. Area of the region bounded by the curves log y x x = and
( )
2
2 y x x = is:
a) 1/2 b) 7/12 c) 5/12 d) 13/12
60. If
( )
{ }
1 2
2 tan log 1 y x x x x
= + + ,then:
a) y increases in[0, ) b) y decreases in [0, )
c) y increases in ( ) ,0 d) y increases in ( ) ,


CHEMISTRY
61. Lemon juice normally has a pH of 2. If all the acid in the lemon juice is citric acid and
there are no citrate salts present, then what will be the citric acid(H.cit) concentration
in the lemon juice? (Assume that only the first hydrogen of citric acid is important).

( )
1
4 1
. . 8.4 10
a
H Cit H Cit K mol lit
+
+ =
a)
4
8.4 10 M
b)
4
4.2 10 M
c)
4
16.8 10 M
d)
2
12.0 10 M

62. One mole of an anhydrous salt AB dissolves in excess of water with the evolution of
21.0 J mol
-1
of heat. If the heat of hydration of AB is -29.4 J mol
-1
, then the heat of
dissolution of the hydrated salt AB is
a) 50.4 J mol
-1
b) 8.4 J mol
-1
c) -50.4 J mol
-1
d) -8.4 J mol
-1

63. The number of isomers of [Co (NH
3
)
3
Cl
3
] complex and secondary valency of the
metal ion in the complex respectively are.
a) 3 & 3 b) 2 & 3 c) 2 & 6 d) 3 & 6
64. The order of acidity of compounds I-IV, is-

2
CH OH
2
CO H OH
3
SO H
( ) I
( ) II
( ) III ( ) IV

a) I <III <II <IV b) IV <I <II <III
c) III <I <II <IV d) II <IV <III <I

65. A concentrated solution of copper sulphate, which is dark blue in colour, is mixed at
room temperature with a dilute solution of copper sulphate, which is light blue. For
this process-
a) Entropy change is positive, but enthalpy change is negative
b) Entropy and enthalpy changes are both positive
c) Entropy change is positive and enthalpy does not change
d) Entropy change is negative and enthalpy change is positive
66. Increasing the temperature increases the rate of reaction but does not increase the-
a) number of collisions b) activation energy
c) number of fruitful collisions d) average velocity of the reactant molecules
67. From equations 1 and 2,
1).
12 0
2( ) ( ) 2( ) 1
1
9.1 10 1000
2
g g g
CO CO O K at C
( + =

;
2).
12 0
2 ( ) 2( ) 2( ) 2
1
7.1 10 1000
2
l g g
H O H O K at C
( + =

The equilibrium constant for the reaction
2( ) 2( ) ( ) 2 ( ) g g g l
CO H CO H O + + at the same
temperature, is
a) 0.78 b) 2.0 c) 16.2 d) 1.28

68. Consider the reaction: ( ) ( ) ( )
2 2
2 2 NO g NO g O g + , In the figure below, identify the
curves X, Y and Z associated with the three species in the reaction

X
Y
Z C
o
n
c
e
n
t
r
a
t
i
o
n
Time

a) X =NO, Y =O
2
, Z =NO
2
b) X =O
2
, Y =NO, Z =NO
2

c) X =NO
2
, Y =NO, Z =O
2
d) X =O
2
, Y =NO
2
, Z =NO
69. Two isomeric compounds I and II are heated with HBr

OH OH
2
CH OH
3
OCH
( ) I
( ) II

The products obtained are
a)
OH OH
2
CH Br OH

b)
Br Br
2
CH OH
3
OCH

c)
Br Br
2
CH Br Br

d)
OH OH
2
CH OH
3
OCH
Br
Br


70. The number of possible enantiomeric pair(s) produced from the bromination
(Br
2
/CCl
4
) of I and II, respectively, are

3
H C
3
CH
3
H C
3
CH
3
H C
3
H C
2
CH
( ) I
( ) II

a) 0,1 b) 1, 0 c) 0, 2 d) 1, 1
71. For the reaction
0 1
, 7.5 A B H KJ mol
A = and
0 1 1
25 S JK mol

A = . The value of
0
G A and
the temperature at which the reaction reaches equilibrium are, respectively,
a) 0
1
KJ mol
and 400 K b) 2.5

1
KJ mol
and 400 K
c) 2.5KJ mol
and 200 K d) 0
1
300 KJ mol and K

72. The solubility product of ( )
2
Mg OH is
12
1.0 10
at 25
0
C. Aqueous NaOH solution is
added to a 0.01 M aqueous solution of
2
MgCl . The minimum pH at which precipitation
occurs at 25
0
C is
a) 7.2 b) 7.8 c) 8.0 d) 9.0

73. Diborane is formed from the elements as shown in equation (1)
( ) ( ) ( ) ( )
2 2 6
2 3 ............ 1 B s H g B H g +
Given that
( ) ( )
2 2
H O l H O g
0
1
44 H kJ A =
( ) ( ) ( )
2 2 3
2 3/ 2 B s O g B O s +
0
2
1273 H kJ A =
( ) ( ) ( ) ( )
2 6 2 2 3 2
3 3 B H g O g B O s H O g + +
0
3
2035 H kJ A =
( ) ( ) ( )
2 2 2
1/ 2 H g O g H O l +
0
4
286 H kJ A =
the
0
H A for the reaction (1) is-
a) 36 kJ b) 509 kJ c) 520 kJ d) 3550 kJ
74. The Crystal Field Stabilization Energy ( ) CFSE and the spin-only magnetic moment in
Bohr Magneton (BM) for the complex ( )
3
6
K Fe CN (

are, respectively-
a)
0
0.0A and 35BM b)
0
2.0 A 3BM
c)
0
0.4 A and 24BM d)
0
2.4 A and 0 BM
75. Conversion of Isopropyl chloride into Isopropyl alcohol can take place by both SN
1
&
SN
2
mechanism based on the conditions, from the following table
Mechanism No.of Intermediates No.of Transition states
SN
1
P Q
SN
2
R S
What is the value of (P +Q) - (R +S) is
a) 1 b) 2 c) 3 d) 4

76. When 2 Moles of Zn(s) is oxidized at 298 K, in Daniel cell
( )
0
1.1
cell
E V = , the standard
Gibbs free energy change
( )
0 1
G in kJ mol
A , is closed to
a) -212.3 b) -106.2 c) -424.6 d) -53.1
77. Number of P-O bonds in P
4
O
6
molecule is
a) 6 b) 8 c) 12 d) 16
78. The adsorption isotherm for a gas is given by the relation x =ap/ (l +bp) where x is
moles of gas adsorbed per gram of the adsorbent, p is the pressure of the gas, a and b
are constants. Then correct statement is
a) x increases with p
b) x remains unchanged with p
c) x decreases with p
d) x increases with p at low pressures and then remains the same at high pressure
79.
6
XeF onhydrolyses to give an oxide. The structures of XeF
6
and the oxide,
respectively, are-
a) octahedral and tetrahedral b) distorted octahedral and pyramidal
c) octahedral and pyramidal d) distorted octahedral and tetrahedral
80. When
4
MnO
oxidizes separately (i) oxalate ion in acidic medium (ii) HCl. The ratios of
2
4 2 4
: MnO C O

(

in (i) and
4
: MnO HCl
(

in (ii), in the respective balanced chemical
equations are respectively
a) 1:5 and 2:5 b) 2:5 and 1:8 c) 2:5 and 1:5 d) 5:2 and 1:8

81. The electron in hydrogen atom is in the first Bohrs orbit (n=1). The ratio of electronic
transition energies,
( ) 1 3 E n n A = = to ( ) 1 2 E n n A = = , is
a) 32/27 b) 16/27 c) 32/9 d) 8/9
82. What is the major product of the following reaction sequence?

C
2
HO CH OH
O
( )
( ) ( )
2
3
1
2 1
SOCl
CH ONa eq
( ) excess

a)
C
2
Cl CH
Cl
O

b)
C
2
ClCH
3
O CH
O

c)
C 3 2
CH O CH
3
CH
O

d)
C 3 2
CH O CH
Cl
O

83. 29.5 mg. of an organic compound containing nitrogen was digested according to
Kjeldahls method and the evolved
3
NH gas was absorbed in 20 mL of 0.1 M HCl
solution. The excess of acid required 15 mL of 0.1 M NaOH solution for complete
neutralization. The percentage of nitrogen in the compound is:
a) 29.5 b) 59.0 c) 47.4 d) 23.7


84. Which of the following statement(s) are correct.
(i) More number of oxidation states are exhibited by the actinoids than those by the
lanthanoids due to lesser energy difference between 5f and 6d in actinoids than 4f
and 5d orbitals in lanthanoids.
(ii) There is a gradual decrease in the radii of the trivalent ions with the increasing
atomic number in the lanthanoids series.
(iii) The 5f-orbitals are deeply seated than the 4f-orbitals in the atom.
(iv) Zr and Hf have about the same raidus due to lanthanoid contraction
a) (i), (ii), (iv) b) (i), (ii), (iii)
c) (i), (ii) d) (i), (ii), (iii), (iv)
85. With reference the scheme given, which of the given statement(s) about , , T U V and
W is (are) correct?

3
H C
4
L i A l H
( ) T
E x c e s s o f
( )
3
2
C H C O O
( ) U ( ) W
A
3
/ C r O H
+
| |
|
\ .
( ) V
O
O

(i) T is soluble in hot aqueous NaOH
(ii) U is optically active
(iii) Molecular formula of W is
10 18 4
C H O
(iv) V gives effervescence with aqueous
3
NaHCO
a) (i), (ii), (iii) b) (i), (iii), (iv) c) (i), (ii), (iv) d) (i), (iii)


86. Choose the correct reason(s) for the stability of the lyophobic colloids.
i) Preferential adsorption of ions on their surface from the solution
ii) Perferential adsorption of solvent on their surface from the solution
iii) Attraction between different particles having opposite charges on their surface
iv) Potential difference between the fixed layer and the diffused layer of opposite
charges around the colloidal particles.
a) (i), (ii), (iii) b) (i), (iii), (iv)
c) (i), (ii), (iv) d) (i), (iv)
87. Which of the following statement(s) are correct.
(i) ( ) D + glucopyranose and ( ) D glucopyranose are anomers.
(ii) The change in optical rotaion of freshly prepared solution of fructose with time is
known as mutaroation
(iii) Sugars can be detected by Molishs test.
(iv)Synthesis of each molecule of glucose in photosynthesis involves 10 molecules of
ATP.
(v) Biuret test is given by proteins.
a) (i), (ii), (iv), (v) b) (ii), (iii), (v)
c) (i), (ii), (iii), (v) d) (i), (ii), (iii), (iv), (v)

88. In which of the following arrangements, the sequence is not strictly according to the
property written against it?
a) HF HCl HBr HI < < < : increasing acid strength
b)
3 3 3 3
: NH PH AsH SbH < < < increasing basic strength
c) : B C O N < < < increasing 1
st
ionization enthalpy
d)
2 2 2
: GeO SnO PbO < < increasing oxidizing power
89. Four coins of the same size are placed on the corners of a square in such a way that
their centres coincide with the corners of the square. Radius of coins is R and edge of
square is 2R . What is maximum radius of a coin that can be placed in the gap of the
above square?
a) 0.155 R b) 0.225 R c) 0.414 R d) 0.732 R
90. During the extraction of iron in the blast furnace,
a) Coke acts as reducing agent in the lower zone and CO acts as reducing agent in the upper
zone
b) CO acts as reducing agent in the lower zone and Coke acts as reducing agent in the upper
zone
c) Coke acts as reducing agent in the lower zone and CO acts as reducing agent in the lower
zone
d) CO acts as reducing agent in the upper zone and Coke acts as reducing agent in the
upper zone

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from the free surface

be a unit vector perpendicular to a

and coplanar with

and 400 K b) 2.5

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