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An understanding between the two types of oil, fresh and used, will
help to make this step clearer.
Not all of the vegetable oil molecules are destroyed this way however,
thus in used cooking oil there will still exist some fresh vegetable oil
molecules. In other words, there are still many stable bonds that
exist even in used oil and it is from these stable bonds that we
make bio diesel.
These stable vegetable oil molecules will follow the same rule as with
fresh cooking oil: 3.5g NaOH and 20% methanol by volume will convert
1 litre of oil to bio diesel.
In other words 3.5g NaOH, PLUS excess NaOH, will convert used oil to
biodiesel
What is needed:
Just as the titration allows us to prepare the chemicals for bio diesel
production, there are certain chemicals that have to be prepared for
the titration. These are:
• An indicator
• The solute
• The titrant
The indicator. The indicator indicates by colour, the “end point” of the
titration, or the point at which all the FFA’s have been neutralized,
leaving only stable molecules for conversion. The indicator changes
from yellow, when the oil is acidic, to pink, when most of the acidity is
neutralized. A good indicator that can be home made is one made
using 1 part tumeric to 5 parts alcohol.
The solute is the sample you wish to perform the titration on. It is
always 1ml of vegetable oil, dissolved in 10ml of pure alcohol.
Let us say for example that in our titration, instead of adding our
titrant slowly, we simply dumped 4ml of our titrant into our solute, and
the solute immediately turned pink.
We could say that 4ml of the titrant was sufficient to neutralize the
FFAs in our sample. However, it is possible it was really only 2.7ml
that was needed, but we did not test accurately enough to determine
that.
What is done therefore, is to add the titrant slowly, about 0.1ml drops
at a time. As mentioned above, every time we take a known volume of
water out of our water/NaOH solution, we are also taking out a known
amount of NaOH. So if we add drops of 0.1ml of water, we are also
taking 0.001g of NaOH in each drop.
Once the FFAs are neutralized, from yellow to pink, we take note of
how much of the titrant was used for this colour change to occur. If it
took ten 0.1ml drops of the titrant (1ml), we add 1 gram to the
3.5 grams we already know about. It the titration took twenty
0.1ml drops (2ml) we add 2 grams to our 3.5 grams. And so on.
• Step 5: Record the amount of the titrant that was added to the
solute.
E.g. Let us say that we added 1.2ml of titrant in the first trial, 1.4ml in
the second trial and 1.2ml again in the third trial. The average here is
1.3ml. Therefore we know that 1.3ml or 1.3 EXTRA grams is
required to neutralize JUST the FFAs in 1 litre of our oil sample.
We add 1.3 to our 3.5 grams (the amount needed for our stable vege
oil molecules) to have a total of 4.8 grams that would be needed
to neutralize the FFAs AND convert the stable oil to bio diesel.