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Two classes of filler are suitable for extrusion processing, particularly when special profiles must be produced. Neuburg Siliceous Earth has a clear advantage here in terms of price to performance ratio. Surface-treated AKTISIL VM 56 wins on cost compared to untreated calcined clay.
Two classes of filler are suitable for extrusion processing, particularly when special profiles must be produced. Neuburg Siliceous Earth has a clear advantage here in terms of price to performance ratio. Surface-treated AKTISIL VM 56 wins on cost compared to untreated calcined clay.
Two classes of filler are suitable for extrusion processing, particularly when special profiles must be produced. Neuburg Siliceous Earth has a clear advantage here in terms of price to performance ratio. Surface-treated AKTISIL VM 56 wins on cost compared to untreated calcined clay.
Non-black Fillers in EPDM Extrusion Formulation (peroxide cured)
HOFFMANN MINERAL GmbH P.O. Box 14 60 D-86619 Neuburg (Donau) Phone (+49-84 31) 53-0 Fax (+49-84 31) 53-3 30 Internet: www.hoffmann-mineral.com e-Mail: info@hoffmann-mineral.com V M - 4 / 0 5 . 2 0 0 8 / A r t . - N r .
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Page 1
Summary
Two classes of filler are suitable for extrusion processing, particularly when special profiles must be produced. The products based on Neuburg Siliceous Earth and calcined clay produced the best extrusion properties among the non-black fillers tested. Neuburg Siliceous Earth has a clear advantage here in terms of price to performance ratio. Surface-treated AKTISIL VM 56 wins on cost compared to untreated calcined clay, at the same time providing better tensile strength, a higher modulus and a lower change of elongation at break after ageing.
Where emphasis is placed on mechanical properties, combining the active filler with carbon black or precipitated silica (or silicates in the case of non-black applications) is a solution. Here the recipe must be adapted to fit the specific needs involved.
Page 2 Non-black Fillers in EPDM Extrusion Formulation (peroxide cured)
Test Compound
EPDM, 55 % Ethylene, medium diene-content ML (1+8) 125 C, approx. 82 1
100 Zinc oxide 2
5 Stearic acid 2 Calcium oxide coated by special dispersion agents 80 % 10 Filler 250/110/75 Diethylene glycol (DEG), as indicated 0/3/5 Paraffinic oil 4
60 Triallyl-cyanurate 50 % 5
3 Bis(t-butylperoxy-isopropyl)benzene 40 % 6
8
Regarding precipitated silica and the different types of precipitated silicate additional compounds with 3 phr DEG were examined. To obtain an adequate cross linking the various hard clays need the use of 5 phr DEG.
Curing was carried out in a press at 180 C. The curing time was t 90 + 10 %.
Please mind! The following figures show trend analysis, which only can be the basis for specific problems solving.
Filler: Precipitated Silica Precipitated Silicates Carbon Black All others Loading: 75 phr 110 phr 110 phr 250 phr Open Mill Batch Temperature Time of mixing 150 x 300 mm 500 cm 50 C 15 to 20 min Extruder
Temperature of barrel Temperature of head d = 30 mm L/D = 15 70 C 110 C
Applied in this test compound: (1) Vistalon 7500 , Exxon (2) Zinkoxyd aktiv, Bayer (3) Kezadol GR, Kettlitz (4) Sunpar 2280, Sun Oil Company (5) TAC 50 %, Kettlitz (6) Perkadox 14/40, Akzo
Page 3 Contents
Index of Compound Costs Page 4
Properties of Raw Compound Mooney Viscosity ML (1+4) at 120 C Page 5 Mooney Scorch t 5 (ML) at 120 C Page 6 Extrudability (Quality), Rating Garvey-Profile Page 7 Extrudability (Quality), Torque of Extruder Page 8 Extrudability (Quantity), Maximum of Extrusion Speed Page 9 Extrudability (Quantity), Torque of Extruder Page 10 Rotorless Cure Meter, t 5 at 180 C Page 11 Rotorless Cure Meter, t 90 at 180 C Page 12
Properties after Air Ageing Change of Tensile Strength Page 21 Change of Elongation at Break Page 22 Change of Hardness Page 23 Change of Tear Resistance Page 24 Annex Pictures of extrusion profiles Page 25-27
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