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DEPARTMENT OF CHEMICAL ENGINEERING

COURSE PLAN

Department : Chemical Engineering
Subject : Chemical Engg Thermodynamics I (CHE 207)
Semester & branch : III Semester
Name of the faculty :C R Girish
No of contact hours/week : 4


Test portion
Test no. Topics
1 LECTURE 1-26
2 LECTURE 27-45



Submitted by:



(Signature of the faculty)
Date:

Approved by:



(Signature of HOD)
Date:









MANIPAL INSTITUTE OF TECHNOLOGY
(A constituent college of Manipal University, Manipal)
Manipal Karnataka 576 104

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Course Objectives:
At the end of the course the student will be able to
To know the properties of pure fluids and of solutions.
To modify the thermodynamic properties with respect to solutions.
Evaluate the equilibrium, energy and transformation of energy for a
certain process.
Use the laws of thermodynamics to realistic problems faced in process
industries.
Applications of thermodynamics.

Scheme of valuation of internal assessment:
First Sessional: 20 marks
Second sessional : 20 marks
(The sum of two sessionals: 40 marks)
Five quizzes: 2 marks each for total 10 marks
Total internal marks: 50



















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Lecture
no.
Topic to be covered
1
Introduction, Scope and limitations of classical thermodynamics
2
Fundamental concepts and definitions, system and surroundings
3
Property, path, state and path functions
4
Intensive and extensive properties,Reversible and irreversible process
5
Equilibrium state and steady state, phase rule, zeroth law of
thermodynamics
6
Temperature and ideal gas temperature scale
7
Energy,heat and work, enthalpy, heat reservoir
8
Numericals on the above topic
9
First law of thermodynamics for cyclic process
10
Internal energy, first law for non flow process
11
First law for flow process
12
Numericals on the first law of thermodynamics
13
P-V-T relationships of gases
14
Ideal gas, assumptions
15
Definition, mathematical forms and uses
16
Equations of state for real gases
17
-do-
18
Numericals on equations of state
19
Compressibility factor, chart, determination methods
20
Reduced equation of state, three parameters correlation


4

Lecture
no.
Topic to be covered
21
Thermodynamic processes
22
Constant volume, constant pressure process
23
Constant enthalpy process
24
Application, limitation of first law, direction of change
25
Qualitative difference between heat and work
26
Second law of thermodynamics
27
Entropy definition, mathematical representation
28
Entropy calculations for various processes
29
-do-
30
Carnot principle, postulates
31
-do-
32
Numericals on the above topic
33
-do-
34
Third law of thermodynamics
35
Principle of increasing entropy
36
Classification of thermodynamic properties
37
Helmholtz and Gibbs free energy
38
Fundamental differential equations
39
Maxwells relation and applications
40
-do-
41
Clausius clapeyron equation

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Reference text books:
(1) K.V.Narayanan; A Text Book of Chemical Engineering
Thermodynamics
(2) J.M.Smith., H.C.Van Ness and M.M.Abbott; Introduction to Chemical
Engineering Thermodynamics

42
Differential equations for entropy and heat capacity
43
Joule Thomson coefficient, residual properties
44
Refrigeration
45
Carnot cycle, Vapor compression, air and absorption refrigeration
46
Heat pumps, liquefaction processes, expansion processes
47
Steam power plant
48
Internal combustion engines, otto cycle, Brayton cycle