Beruflich Dokumente
Kultur Dokumente
AIEEE - 2009
S O LU T I O N
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CODE A
Instructions
1. The test is of 3 hours duration.
2. The Test Booklet consists of 90 questions. The maximum marks are 432.
3. There are three parts in the question paper. The distribution of marks subject wise in each part is as
under for each correct response.
Part A - PHYSICS (144 marks) – Questions No. 1 to 2 and 9 to 30 consist FOUR (4) marks each
and Question No. 3 to 8 consist EIGHT(8) marks each for each correct response.
Part B - CHEMISTRY (144 marks) – Questions No. 31 to 39 and 46 to 60 consist FOUR (4) marks
each and Question No. 40 to 45 consist EIGHT (8) marks each for each correct response.
Part C - MATHEMATICS (144 marks) – Questions No. 61 to 82 and 89 to 90 consist EIGHT (8)
marks each and Questions No. 83 to 88 consist EIGHT (8) marks each for each correct
response.
4. Candidates will be awarded marks as stated above in instruction No. 5 for correct response of each
question ¼ (one fourth) marks will be deducted for indicating incorrect response of each question.
No deduction from the total score will be made if no response is indicated for an item in the answer
sheet.
5. Use Blue/Black Ball Point Pen only for writing particulars/marking responses on Side-1 and Side-2
of the Answer Sheet. Use of pencil is strictly prohibited.
6. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty
in the Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
PHYSICS (iv) F → D + E + ε
1. STATEMENT – 1 where ε is the energy released ? In which
For a charged particle moving from point P to reaction is ε positive ?
point Q, the net work done by an electrostatic (1) (i) and (iv) (2) (i) and (iii)
field on the particle is independent of the path (3) (ii) and (iv) (4) (ii) and (iii).
connected point P to point Q. Key. (1)
STATEMENT – 2 Sol. Binding energy per nucleon of each product is
The net work done by a conservative force on an less than that of each reactants.
object moving along a closed loop is zero.
(1) Statement – 1 is True, Statement – 2 is 3. A p–n junction (4) shown in the figure can act
False. as a rectifier. An alternating current source (V)
(2) Statement – 1 is True, Statement – 2 is is connected in the circuit.
True; Statement – 2 is a correct explanation
for Statement – 1. D
~ R
(3) Statement – 1 is True, Statement – 2 is V
True; Statement – 2 is not the correct
explanation for Statement – 1. The current (I) in the resistor (R) can be shown
(4) Statement – 1 is False, Statement – 2 is by :
True. I
Key (3)
t
Sol. Statement–2 is not the correct explanation of (1)
statement–1. I
2.
(2) t
BC D E
I
Eb
A F
(3) t
I
M
The above is a plot of binding energy per
(4) t.
nucleon Eb, against the nuclear mass M; A, B,
C, D, E, F correspond to different nuclei. Key. (3)
Consider four reactions : Sol. Only +ve current passes though the diode.
(i) A + B → C + ε
4. The logic circuit shown below has the input
(ii) C → A + B + ε
waveforms 'A ' and 'B' as shown. Pick out the
(iii) D + E → F + ε
correct output waveform.
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y
hc h
Sol. = φ + (KE) max
λ t1 2t 3t 4t t
t
1 1
1240 1
⇒ = φ + 1.68 (4) .
400 Key. (3)
⇒ φ = 1.41 eV Sol. When ball strikes the surface its velocity will be
17. A particle has an initial velocity of 3iˆ + 4ˆj and reversed so correct option is (3).
20. A charge Q is placed at each of the opposite
an acceleration of 0.4iˆ + 0.3jˆ . It speed after 10 s corners of a square. A charge q is placed at each
is : of the other tow corners. If the net electrical
(1) 10 units (2) 7 2 units force on Q is zero, then Q/q equals:
(3) 7 units (4) 8.5 units. (1) −2 2 (2) –1
Key. (2) 1
r r r (3) 1 (4) − .
Sol. V = u + at 2
r
V = (3iˆ + 4ˆj) + 10(0.4iˆ + 0.3j)
ˆ Key. (1)
r
ˆ
V = 7i + 7 jˆ KQ Kq
r Sol. 2
= 2 2
⇒ | V |= 7 2 2a a
18. A motor cycle starts from rest and accelerates Q
⇒ =2 2
along a straight path at 2 m/s2. At the straight q
point of the motor cycle there is a stationary Q
electric siren. How far has the motor cycle gone So, = −2 2
q
when the driver hears the frequency of the siren -q Q
at 94% of its value when the motor cycle was at
rest ?
(Speed of wound = 330 ms–1)
(1) 49 m (2) 98 m
(3) 147 m (4) 196 m. -q
Q
Key. (2)
18. V = 2aS = 4S
21. A long metallic bar is carrying heat from one of
330 − V its ends to the other end under steady–state. The
Also, 94 = 100
330 variation of temperature θ along the length x of
33 × 6 the bar from its hot end is best described by
⇒ = 4S which of the following figures ?
10
⇒ S = 98 m θ
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AIEEE-PAPER 2009
Key. (3)
Tx Sol. p1 = p o sin 2 π(x − 1)t
T1 T2
p 2 = po sin 2π(x)t
x p 3 = po sin 2 π(x + 1)t
T1
p = p1 + p3 + p 2
T2
= 2p o sin 2πxt cos 2πt + p o sin 2 πxt
= p o sin 2πxt[2 cos πt + 1]
x ⇒ fbeat = 2.
L
T − T2
⇒ Tx = T1 − 1 x p
L
t
22. A transparent solid cylindrical rod has a .
2
refractive index of . It is surrounded by air.
3 24. The height at which the acceleration due to
A light ray is incident at the mid–point of one g
gravity becomes (where g = the acceleration
end of the rod as shown in the figure. 9
due to gravity on the surface of the earth) in
θ terms of R, the radius of the earth, is :
The incident angle θ for which the light ray R
(1) 2R (2)
grazes along the wall of the rod is : 2
1 3 (3) R/2 (4) 2R .
(1) sin −1 (2) sin −1
2 2 Key. (1)
GM GM
2 1 Sol. =
(3) sin −1 (4) sin −1 . 9R 2 (R + h)2
3 3
⇒ 3R = R + h
Key. (4)
⇒ h = 2R
2
Sol. 1 × sin 90 = sin(90 − α) 25. Two wires are made of the same material and
3 have the same volume. However wire 1 has
cross–section area A and wire 2 has cross–
α 90-α sectional area 3A. If the length of wire 1
θ increases by ∆x on applying force F, how much
force is needed to stretch wire 2 by the same
3 amount ?
⇒ cos α =
2 (1) F (2) 4F
3 1 (3) 6F (4) 9F.
So sin α = 1 − = Key. (4)
4 2
Sol. l1 = 3l 2
2
Now, 1 × sin θ = sin α F l
3 Y= × 1 …(i)
A ∆x
2 1 1
= × = F' l1 / 3
3 2 3 Y= × …(ii)
3A ∆x
1 F l1 F' l
⇒ θ = sin −1 × = × 1
3 A ∆x 3A 3∆x
23. Three sound waves of equal amplitudes have F' = 9F
frequencies (ν – 1), ν, (ν + 1). They superpose 26. In an experiment the angles are required to be
to give beats. The number of beats produced per measured using an instrument. 29 divisions of
second will be the main scale exactly coincide with the 30
(1) 4 (2) 3 divisions of the vernier scale. If the smallest
(3) 2 (4) 1. division of the main scale is half–a–degree
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Two moles of helium gas are taken over the 32. A liquid was mixed with ethanol and a drop of
cycle ABCDA, as shown in the P–T diagram. concentrated H2SO4 was added. A compound
5 A B with a fruity smell was formed. The liquid was:
2×10
(1) CH3OH (2) HCHO
P (Pa) (3) CH3COCH3 (4) CH3COOH
5
Key. (4)
1×10 C D Sol. Fruity smell is evolved due to formation of
T ester. CH3COOH + CH3CH2OH
300K T 500K conc. H 2SO 4
28. Assuming the gas to be ideal the work done on → CH3 COOC2 H5
ethylacetate
the gas in taking it from A to B is : (ester)
(1) 200 R (2) 300 R
(3) 400 R (4) 500 R. 33. Arrange the carbanions,
Key. (3) (CH3)3 C, CCl3 (CH3)2 CH, C6H5 CH 2 , in order of
Sol. W AB = nR(Tf–Ti) their decreasing stability:
= 2 × R(500 − 300)
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(1) C6H5 CH 2 > CCl3 > (CH3 )3 C > (CH 3 ) 2 CH (2) More easily liquiefiable gases are adsorbed
readily
(2) (CH3)2 CH > CCl3 > C 6 H5 CH 2 > (CH3 )3 C
(3) Under high pressure it results into multi
(3) CCl3 > C6 H 5 CH 2 > (CH 3 ) 2 CH > (CH 3 )3 C molecular layer on adsorbent surface
(4) (CH 3 )3 C > (CH 3 )2 CH > C6 H5 CH 2 > CCl3 (4) Enthalpy of adsorption (∆Hadorption) is low
Key. (3) and positive.
Sol. Due to the –I effect of three chlorine atoms and Key. (4)
Sol. Enthalpy of adsorption in physisorption is
due to pπ - dπ bonding CCl3− is extra stable.
negative
Carbanion follow stability order. ∆G = ∆H - T∆S
CCl3– > C6H5 CH 2 > (CH3 ) 2 CH > (CH 3 )3 C As the entropy decreases (∆S = –ve) the ∆H
must be negatie having a high magnitude.
34. The alkene that exhibits geometrical isomerism Therefore, the spontaneous adsorption will have
is: negative enthalpy change.
(1) propene (2) 2-methyl propene
(3) 2-butene (4) 2-methyl-2-butene 38. Which of the following on heating with aqueous
Key. (3) KOH, produces acetaldehyde?
Sol. 2-butene may exist as (1) CH3COCl (2) CH3CH2Cl
H3C CH3 H3C H (3) CH2ClCH2Cl (4) CH3CHCl2
Key. (4)
Sol. OH
H H H CH3 aq KOH
(cis) (trans) CH 3CHCl2 → H3C HC
OH
Due to restricted rotation around double bond it
exhibits geometric isomerism.
H
−H 2O
35. In which of the following arrangements, the H3C C
sequence is not strictly according to the property O
written against it?
(1) CO2 > SiO2 < SnO2 < PbO2 : increasing 39. In an atom, an electron is moving with a speed
oxidizing power of 600 m/s with an accuracy of 0.005%.
(2) HF < HCl < HBr < HI : increasing acid certainity with which the position of the electron
strength can be located is (h = 6.6 × 10–34 kg m2 s–1, mass
(3) NH3 < PH3 < As H3 < SbH3 : increasing of electron em = 9.1 × 10–31kg):
basic strength (1) 1.52 × 10–4m (2) 5.01 × 10–3m
(4) B < C < O < N : increasing first ionization (3) 1.92 × 10 m –3
(4) 3.84 × 10–3 m
enthalpy Key. (3)
Key. (3) Sol. ∆v = . = 9.1 × 10–31 kg
Sol. As the size of the central non-metal increasing ∆x = ?
appreciably, the basicity of hydride decreases. h
∆x × m ∆v ≥
36. The major product obtained on interaction of 4π
phenol with sodium hydroxide and carbon h
∆x ≥
dioxide is: 4m∆vπ
(1) benzoic acid (2) salicylaldehyde 6.6 × 10−34
(3) salicylic acid (4) phthalic acid ≥
4 × 9.1 × 10 −31 × 0.03 × 3.14
Key. (3) ≥ 1.9248 × 10–3
Sol. According to Kolbe’s reaction
OH OH
40. In a fuel cell methanol is used as fuel and
COOH oxygen gas is used as an oxidizer. The reaction
+
+ NaOH + CO 2 →H is
CH3OH(l) + 3/2O2(g) → CO2(g) + 2H2O(l)
At 298 K standard Gibb’s energies of formation
for CH3OH(l), H2O(l) and CO2 (g) are –166.2, –
37. Which of the following statement is incorrect
regarding physissorptions? 237.2 and –394.4 kJ mol–1 respectively. If
(1) It occurs because of van der Waal’s forces.
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AIEEE-2009-CODE-A
43. Given:
E 0Fe3+ /Fe =–0.036V, E 0Fe2+ / Fe =–0.439V. The value NH3
of standard electrode potential for the change, en
+
Fe3(aq) + e− → Fe2+ (aq) will be:
(1) –0.072 V (2) 0.385 V
(3) 0.770V (4) –0.270V en Co
Key. (3)
Sol. Fe3+ + 3e → Fe, E o = −0.036V
Fe2+ + 2e → Fe, E° = –0.439V NH3
Fe3+ + e → Fe2+, NH3
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AIEEE-PAPER 2009
47. Solid Ba(NO3)2 is gradually dissolved in a 1.0 × Sol. In highest oxidation states transition metals
–4
10 M Na2CO3 solution. At what concentration form anionic complexes rather than that of
2+
of Ba will a precipitate being to form? (Ksp for cationic complexes.
–9
Ba CO3 = 5.1 × 10 ):
(1) 4.1 × 10–5M (2) 5.1 × 10–5M 51. Calculate the wavelength (in nanometer)
(3) 8.1 × 10 M –8 –7
(4) 8.1 × 10 M associated with a proton moving at 1.0 ×
Key. (2) 103 ms–1
Sol. Na2CO3 → 2Na+ + CO23− (Mass of proton = 1.67 × 10–27 kg and h = 6.63 ×
-4
10–34Js):
1 × 10 M (1) 0.032 nm (2) 0.40 nm
BaCO3 Ba2+ + CO23− (3) 2.5 nm (4) 14.0 nm
2+
KSP = [Ba ] [ [CO23− ] Key. (2)
h 6.63 × 10−34
5.1 × 10-9 = [Ba2+ ] [1 × 10-4] Sol. λ = =
−9
mv 1.67 × 10− 27 × 1× 103
5.1× 10 6.63 × 10−34
[Ba2+ ] = −4 =
1× 10 1.67 × 10−24
= 5.1 × 10-5 M = 0.40 × 10-9 m
48. Which one of the following reactions of Xenon = 0.40 nm
compounds is not feasible?
(1) XeO3 + 6HF → XeF6 + 3H2O 52. A binary liquid solution is prepared by mixing
(2) 3XeF4 + 6H2O → 2Xe + Xe O3 + 12 HF + n-heptane and ethanol. Which one of the
1.5 O2 following statement is corret regarding the
(3) 2XeF2 + 2H2O → 2Xe + 4HF + O2 behaviour of the solution?
(4) XeF6 + RbF → Rb [XeF7] (1) The solution formed is an ideal solution
Key. (1) (2) The solution is non-ideal, showing +ve
deviation from Raoult’s Law
49. Using MO theory predict which of the following (3) The solution is non-ideal, showing –ve
species has the shortest bond length? deviation from Raoult’s Law
(1) O22+ (2) O2+ (4) n-heptane shows +ve deviation while
(3) O2– (4) O22– ethanol shows –ve deviation from Raoult’s
Key. (1) Law.
Sol. O22+ Key. (2)
1 Sol. On mixing n-heptane and ethanol; strong
B.O. = [N6 − Na] interactions are replaced by weak interaction
2 and hence it kes non-ideal solution with positive
1 deviation.
= [10 − 4]
2
B.O.= 3 53. The number of stereoisomers possible for a
So bond length is shortest compound of the molecular formula CH3 – CH
= CH – CH (OH) – Me is:
50. In context with the transition elements, which of (1) 3 (2) 2
the following statements is incorrect? (3) 4 (4) 6
(1) In addition to the normal oxidation states, Key. (3)
the zero oxidation state is also shown by Sol. CH3 H H CH3
these elements in complexes. C C H H C C
H C H
(2) In the highest oxidation states, the OH HO
Me Me
transition metal show basic character and
form cationic complexes. trans mirror image
(3) In the highest oxidation states of the first H
OH
five transition element (Sc to Mn), all the CH3 C
HO
H
4s and 3d electrons are used for bonding. C C CH3 C CH 3
H3 C
(4) Once the d5 configuration is exceeded, the H H C C
H H
tendency to involve all the 3d electrons in
bonding decreases. cis mirror image
Key. (2)
54. The IUPAC name of neopentane is:
(1) 2 – methylbutane
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x − 2 y −1 z + 2 1 1
68. Let the line = = lie in the plane x (1) (2)
3 −5 2 log10 4 − log10 3 log10 4 + log103
+ 3y – αz + β = 0. Then (α, β) equals 9 4
(1) (6, – 17) (2) (–6, 7) (3) (4)
log10 4 − log10 3 log10 4 − log10 3
(3) (5, –15) (4) (–5, 5)
Key: (1)
Key (2)
9
Sol.: 2 + 3 × 1 – α (–2) + β = 0 Sol.: P(x ≥ 1) ≥
10
2α + β = –5 ... (i)
9
3 – 15 – 2α = 0 ⇒ 1 − P ( x = 0) ≤
2α = –12 10
n
B = –5 + 12 = 7 1
3
⇒ ≥
(α, β) ≡ (–6, 7) 10 4
69. From 6 different novels and 3 different 3
n
1
dictionaries, 4 novels and 1 dictionary are to be ⇒ ≤
4 10
selected and arranged in a row on a shelf so that
the dictionary is always in the middle. Then the ⇒ n log10 3 4
− log10 ≤ −1
number of such arrangements is 1
⇒ n≥
(1) less than 500 log104 − log103
(2) at least 500 but less than 750 73. If P and Q are the points of intersection of the
(3) at least 750 but less than 1000 circles x2 + y2 + 3x + 7y + 2p – 5 = 0 and x2 + y2
(4) at least 1000 + 2x + 2y – p2 = 0, then there is a circle passing
Key (4) through P, Q and (1, 1) for
Sol.: N1N2N3 – N6, D1D2D3 (1) all values of p
The number of ways = 6c4 × 3c1 × 24 (2) all except one value of p
= 15 × 3 × 24 = 1080 (3) all except two values of p
π
70. ∫ [cot x]dx, where [.] denotes the greatest integer (4) exactly one value of p
0 Key: (2)
function, is equal to Sol.: Radical axis is x + 5y + p2 + 2p – 5 =0
(1) π/2 (2) 1 Equation of circle is
(3) –1 (4) – π/2 x2 + y2 + 3x + 7y + 2p – 5 + λ [x + 5y + p2 + 2p
Key: (4) –5]=0 …. (i)
π (i) passes through (1, 1)
Sol.: ∫ [cot x]dx − ( 2p + 7 )
0 ⇒ λ= 2
(p ≠ −1 )
π/ 2 ( p + 1)
∫ {[cot x ] + [ − cot x ]} dx
0
π/ 2
74. The projections of a vector on the three
π
= ∫
0
(−1) dx = −
2
coordinate axis are 6, –3, 2 respectively. The
direction cosines of the vector are
71. For real x, let f(x) = x3 + 5x + 1, then 6 −3 2
(1) f is one–one but not onto R (1) 6, –3, 2 (2) , ,
5 5 5
(2) f is onto R but not one–one 6 −3 2 −6 −3 2
(3) f is one–one and onto R (3) , , (4) , ,
7 7 7 7 7 7
(4) f is neither one–one nor onto R
Key : (3)
Key: (3)
6 −3 2
Sol.: f(x) = x3 + 5x + 1 Sol.: The DCS are , , .
7 7 7
f ′ ( x ) = 3x 2 + 5 > 0 ⇒ f is one–one
4
Q f is cubic ⇒ f is onto 75. If Z − = 2 , then the maximum value of |Z| is
z
‘f’ is one–one and onto.
equal to
1 (1) 3 +1 (2) 5 +1
72. In a binomial distribution B n, p = , if the (3) 2(4) 2 + 2
4
probability of at least one success is greater than Key: (2)
9 4
or equal to , then n is greater than Sol.: Z − = 2
10 z
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AIEEE-PAPER 2009
AP 1
= 79. The sum to infinity of the series
AQ 3
3AP = AQ 2 6 10 14
1 + + 2 + 3 4 + ... is
⇒ 9AP2 = AQ2 3 3 3 3
⇒ 9[(h – 1)2 + k2] = (h – 1)2 + k2 (1) 2(2) 3
5
(3) 4(4) 6
⇒ h 2 + k2 − h −1 = 0 Key : (2)
2
Locus of A(h, k) is 2 6 10 14
Sol.: Let S = 1 + ++ + + ....∞
5 3 32 33 34
x 2 + y2 − x − 1 = 0 S 1 2 6 10
2 = + + + + ....∞
5 3 3 32 33 34
∴ Circumcentre of ∆ ABC is , 0 ______________________________
4
2S 1 4 4 4
= 1 + + 2 + 3 + 4 + .....∞
77. The remainder left out when 8 – (62) is 2n 2n+1 3 3 3 3 3
divided by 9 is 4
4 2
(1) 0 (2) 2 = + 3
(3) 7 (4) 8 3 1
1−
Key: (2) 3
Sol.: 82n – (62)2n + 1 4 2
= + =2
⇒ (9 – 1)2n – (63 – 1)2n + 1 3 3
⇒ (2nC0 92n – 2nC1 92n – 1 + ….. + 2nC2n) 2S
=2 ⇒ S=3
– (2n + 1C0 632n + 1 – 2n + 1C1 632n + …. 3
– 2n +1C2n + 1 80. The differential equation which represents the
Clearly remainder is ‘2’. family of curves y = c1 ec x , where c1 and c2 are 2
y ' = c1c 2 e c2 x 3
y′ = c2 y ….. (from (i)] …..(ii)
y′′ = c2 y′ …..(iii) 2
y ' y ''
from (ii) & (iii) = ⇒ yy '' = (y ')2
y y' O 1
5
81. One ticket is selected at random from 50 tickets
numbered 00, 01, 02, ... , 49. Then the
probability that the sum of the digits on the ≡ x – 2y + 4 = 0
selected ticket is 8, given that the product of Required area
3
these digits is zero, equals
= ∫ (y − 2)2 + 1 − 2y + 4 dy
(1) 1/14 (2) 1/7 0
(3) 5/14 (4) 1/50 3
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AIEEE-PAPER 2009
2
∑ (x
i =1
i − x)2 ∑ (2i − (n + 1))
i =1
2
variance (σ ) = =
n n
n n n
⇒ x = 0, −1 = i =1 i =1 i =1
= n2 – 1
n
Since co–domain of function is not given.
So if we assume function 89. Statement 1: ~ (p ↔ ~ q) is equivalent to p ↔ q
(a) as onto then A is correct Statement 2 : ~ (p ↔ ~ q) is a tautology
(b) as not onto then none of the answer is (1) Statement–1 is true, Statement–2 is true,
correct. Statement–2 is a correct explanation for
87. Let f(x) = x|x| and g(x) = sinx statement–1
Statement 1 : gof is differentiable at x = 0 and (2) Statement–1 is true, Statement–2 is true;
its derivative is continuous at that point Statement–2 is not a correct explanation for
Statement 2: gof is twice differentiable at x = 0 statement–1.
(1) Statement–1 is true, Statement–2 is true, (3) Statement–1 is true, statement–2 is false.
Statement–2 is a correct explanation for (4) Statement–1 is false, Statement–2 is
statement–1 true
(2) Statement–1 is true, Statement–2 is true; Key: (3)
Statement–2 is not a correct explanation for
statement–1.
(3) Statement–1 is true, statement–2 is false.
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