JEE Advanced Full Test II Paper 1 Answers

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ANSWERS, HINTS & SOLUTIONS
FULL TEST II
PAPER-1
Q Q. .N NO O PHYSICS CHEMISTRY MATHEMATICS
1. A A C
2. C A D
3. B A A
4. C A B
5. C A B
6. A A C
7. A, B, C, D A, B, C, D A, C, D
8. A, B A, C, D A, C
9. C, D A, B, C A, B
10. B, C A, D A, D
11. B B C
12. B A B
13. B A A
14. C C A
15. A B C
16. B C D
17. A C C
18. A B B
19. C D C
20. D C D
21. C D B
22. D B D
23. C A A
A
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I
N
D
I
A

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S
T

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S

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AITS-FT-II (Paper-1)-PCM(Sol)-JEE(Advanced)/14

FI I TJEE Ltd., FI ITJ EE House, 29-A, Kal u Sarai , Sarvapri ya Vi har, New Del hi -110016, Ph 46106000, 26569493, Fax 26513942
2
P P h hy ys si i c cs s PART I

2. (v
1
coso)t =(v
2
cos|)t =30 3 . . . (1)
(v
1
sino)t
2
1
gt
2
+h =(v
2
sin|)t
2
1
gt
2
. . . (2)
from (1) and (2)
h =60 m

3. | =o tan u
2
2 2
1
g
2 u cos
o
u

| =o tan u
( )
2
2
1
g 1 tan
2 2g
o
+ u
o

tan
2
u 4 tan u +
4
1
| | |
+
|
o
\ .
=0

(, )

u
2go
u

If particle will not hit the target.
(b
2
4ac) <0
16 4
4
1
| | |
+
|
o
\ .
<0
4| >3o
4. At B, mg sin | =
2
B
mv
r
. . . (1)
Using energy considerations

2
B
1
mv
2
=mgr(cos o sin |) . . . (2)

B
A

Smooth
N
vB

From (1) and (2)
mg sin | =2mg(coso sin |)
2coso =3 sin |

7. Here the position y on the screen will correspond to maxima.

n D
y
d
=

30,000
n
= when n =1, 2, 3, 4, ..

8. a =kx
2

da
2kx
dx
= tan 60 =2k 3
1
k
2
=
a
2
x
2
=

2
dv x
v
dx 2
=
2 3
1
v x
C
2 6
= + at x =0, v =3 m/s

1
9
C
2
=

3
2
x
v 9
3
= +
hence a =1.5 and v 3 9 = +



3
9. Capillary height
2T cos
h
r g
u
=
h =59.6 mm
here 59.6 mm is greater than the protruding part hence water will rise in the capillary of
insufficient height 25 mm.
Now,
2T
R 0.6
hrg
= = mm

10. 10. Fluid particles passing through the bend are in circular
motion. The centripetal acceleration is provided by the
variation in pressure. In the section as shown

1 2 C
P A P A ma =

1 2
P P >
applying Bernoulli theorem at 1 and 2
i.e.,
2 2
1 1 1 1 2 2 2
1 1
P v gh P v gh
2 2
+ + = + +

2 2
1 1 1 2 2
1 1
P v P v
2 2
+ = + as
1 2
h h =

1 2
P P >

1 2
v v <

1
2
maC
P1A
P2A

15.
Ag
m sinu =5 10 sin 37 =5 10
3
5
=30 N

max AB C B
f (m m )gcos 48N = + u =
hence f =30 N

16.
C
3
m gsin 2 10 12N
5
u = =

max c
4
f mgcos 0.1 2 10 1.6N
5
= u = =
hence f =1.6 N

17.
A C B
T f f mgsin37 = + +
=91.6 N

T
fC
fa
mBg sin 37

18. Optical path difference between the beans arriving at P

2 1
x ( ) dsin A = + u
for maxima

2 1
( ) dsin n + u =
| |
2 1
1
sin n ( )
d
u =

1
n
sin 2 1
40
( | |
u =
| (
\ .


4
19. sin 1 u s

n
1 2 1 1
40
(
s s
(

or 20 n 60 s s
Hence number of maxima =60 20 =40

20. At C, phase difference

2 1
2
( )
t
| =
o
=80 t
Hence for maximum intensity will appear at C.
Now for minimum intensity at C
( 1)t
2
=

t
t 500
2( 1)
= =

nm



5
C Ch he em mi i s st tr r y y PART I I

3. Neither N nor F contain d-orbitals. Further in N
2
F
4
NN bond is shorter than in N
2
H
4
due to
s-character (Bents Rule).

4. Due to poor shielding effect of 3d electron the size of Br
ion nearly same as that of Cl
ion.

5.
C
8
H
7
OCl N
2
O
287 m

Molar mass of C
8
H
7
OCl =8 12 +7 1 +16 +35.5 =154.5 g
Molar mass of N
2
O =2 14 +16 =44g
According to Grahams Law of diffusion

8 7 2
8 7 2
C H OCl N O
C H OCl N O
M r
154.5
3.5 1.87: 1
r M 44
= = = =

2
N O
1.87
d 287
2.87
= =187
th
row from N
2
O side

8 7
C H OCl
1.0
d 287
2.87
= =100
th
row from weeping gas side
Therefore, the spectator from the side of N
2
O in the 187
th
row will be laughing and weeping
simultaneously Alternatively, the spectator from the side of weeping gas in 100
th
row will laugh
and weep.

6. OH
attacks at the more reactive (C=O) group, (containing more EWG or less EDG) Et is more
EDG than Me (due to +I effect here no H.C.). Therefore OH
attack (C=O) with (Me) group.

Me
Et
O
O
Me
Et
C
OH
O
O
OH
OH
3
H O
+
Me
Et
C
OH
O
OH

10. ( )
4 3 2 2
NH NO aq N O H O +

2 2 2 2
NH OH HNO N O 2H O + +
Hence, (A) and (D) are the correct answers.

13. Velocity =
6
Z
2.18 10
n

14. (i)
3
BrO
E M/ 5
=
(ii)
3
BrO
E M/ 6
=
ratio =6/5


6
17.
N H
2
Me
Me
OH
2
HNO
( ) A
N
+
Me
Me
OH
N
2
N
Me
Me
OH
1
2
3
( )
( )
2 4
C C bond
breaks Ring expansion
O
Me
Me
H
1
2
3
4
H
+
Me
Me
O (B)
3
RCO H
Baeyer Villiger
O
O
Me
Me
(C)
(Cyclic ester)
(Lactone)
( )
( )
4
2
i LiAlH
ii H O
OH
Me
Me
OH
(D)

18. ( ) ( )
3 3 3 3
2 2
0.8 15
35 0.15
12
5.25
2KIO Pb NO Pb IO 2KNO

=
=
+ +

1 mol of Pb(NO
3
) reacts with 2 mol of KIO
3

5.25 m mol of Pb(NO
3
)
2
reacts =2 5.25
=10.5 m mol
m mol of KIO
3
left =12 10.5
=1.5
Hence Pb(NO
3
)
2
is the limiting reagent

19.
( )
3
1.5mmol
IO 0.03M
15 35 mL
(
= =

+

20. Due to common ion
( ) 3
IO
left in the solution the solubility ( )

3
2
Pb IO decreases.
S =
( )
13 4
sp
2
K
2.7 10 10
9
0.03

=
=0.30 10
9

=3.0 10
10

21. pH range of all these indicators lies in between 2-12. Hence, all are suitable indicators.

22. Since curve is given for strong acid and strong base hence, pH at the end point is 7.



7
M Ma at th he em ma at ti i c cs s PART I I I

1. y =ax
2
+bx +c, vertex is (4, 2)
4 =
a 2
b
, b =8a, 2
a 4
b ac 4
2
=
c =2 +
a 4
b
2
=2 +16a
Now A =abc =8a
2
(2 +16a) =16(a
2
+8a
3
)

da
dA
=16(2a +24a
2
) <0 a e [1, 3]
A|
max
=144, A|
min
=3600 Difference =3456

2. x [x] ={x}
x [x +1] ={x} 1
( )
}
4
2
dx x f = ( ) 1 . 1
2
1
. 6 =3

1
1
2 3 4 -1 -2

3.
( )
}
+
x
0
2
0 x
t a x sin x
dt t
lim =
( ) x sin x
t a
dt t
lim
x
0
2
0 x

+
}
=
( ) x cos 1 x a
x
lim
2
0 x
+

=
x a .
2
x
sin 2
x
lim
2
2
0 x
+
=
a
2
=1 (given)
a =4

4. (3)
6
=729 <900 and (3)
7
=2187 >900

5. Now by property of triangles
RQ =
1
2
BC =
a
2

Similarly PQ =
c
2
, PR =
b
2

Area of AABC =
abc
4R

A
R Q
B
P
C

That of APQR =
a b c
222
4R'

Also area of AABC =4 (area of APQR)

abc abc R 2
32R' 16R R' 1
| |
= = =
|
\ .


8
6. Clearly 2 solutions

B
y =2x 3
y =logx 3

7. f(x) =cos t(|x| +[x])
f(0) =1, f(0 0) =cos t(1) =1
f(1/2) =cos t |
.
|
\
|
2
1
=0, f |
.
|
\
|
t = |
.
|
\
|

2
1
cos 0
2
1
=0
0
2
cos 0
2
1
f =
t
= |
.
|
\
|
+
for x e (0, 1) f(x) =cos tx
for x e (1, 0) f(x) =cos t (x 1) =cos tx

8. OP =5 2 sec u
OP
1
=5 2 cosec u
APP
1
P
2
=
u 2 sin
100

(A | PP
1
P
2
)
min
=100
u =t/4
OP =10
P =(10, 0), (10, 0) P
2
P
1
P
u
O

9. Let P(2, 1) goes 2 units along x +y =1 upto A and 5 units along x 2y =4 up to B
Slope of PA =1 =tan 135, slope of PB =
2
1
=tan u
sin u =
5
1
, cos u =
5
2

A (x
1
+r cos 135, y
1
=r sin 135) =(2 +2x
2
1
, 1 +2
2
1
) =(2 \2, \2 1)
B (x
1
+r cos u, y
1
+r sin u) =(2 +5
5
2
, 1 +
5
5
) =(2\5 +2, \5 1)

10. Slope of tangent =
a
b
b
1
a
1
=



9

2
2
t
1
4
t
4
dt
dx
dt
dy
dx
dy
=
= = <0
So, 0
a
b
<

a
b
>0

12.
( )
( )
2
1 P 1 x
A A B
P
P x B B
| |
= =
|
\ .
s 1
x
2
+x 1 > 0
x >
5 1
2
or x s
1 5
2

x is positive
x >
5 1
2

13.
2 2 2 2 2
a b c d a b c d
4 4
+ + + + + + | |
s
|
\ .

( )
2 2
16 e
8 e
16 4
s
64 +e
2
16e s 64 4e
2

5e
2
16e s 0
0 s e s
16
5

14. Let A(a, P(a)), B(b, P(b)), then slope of AB =P'(a) =P'(b) from LMVT - c e (a, b)
Where P'(c) =slope of AB

15. Given QT =QA =1
Let PQ =x, then
2
PT x 1 =
Then A TQP and A APO are similar triangles
Then
2
x 1
OT OA
x 1
+
= =

2
2
2(x 1)
1 x x 1 8
x 1
+
+ + + =

x =
5
3

A
P
Q
T
O

16. From above, OA =2 and AQ =1
coordinate of Q (2, 1)
equation is (x 2)
2
+(y 1)
2
=1

17. AORQ is a right angled triangle. Then O and R are the extremities of the diameter then the
coordinates of R(2 3, 2)
Equation of circle (x 0)(x 2 3) (y 0)(y 2) 0 + =
2 2
x y 2 3x 2y 0 + =


10
18. Perpendicular tangents intersect on the director circle of hyperbola and director circle of
rectangular hyperbola is a point circle. Hence centre of hyperbola is (1, 1) and equation of
asymptotes are (x 1) =0 and y 1 =0

19. Equation of hyperbola is xy x y +1 + =0
It passes through (3, 2) hence =2
Equation of hyperbola is xy =x +y +1

20. From the centre of hyperbola we can draw two real normals to the rectangular hyperbola

21. Taking point (r cos u, r sin u), we get
r
2
=
3 2
3 2sin 2
4
+
t | |
u +
|
\ .

r
max
=
3 2
3 2
+
, r
min
=1
Max exist when 2
4 2 8
t t t
u + = u =

22. Required equation is
2
2
x
y 1
3 2
3 2
+ =
+

23. Centre of circle be origin and its radius is the length of semi minor axis
Hence area =t

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ion nearly same as that of Cl

attack (C=O) with (Me) group.

left in the solution the solubility ( )

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