Beruflich Dokumente
Kultur Dokumente
water treatment
Reverse Osmosis: principles, theory and applications
Membrane types and configurations, fouling of membranes
Factors affecting Reverse Osmosis
Electrodialysis: principles and applications
Elements of a typical ED system
Source: www.peerlesswater.com
CE6301: Theory of Water Treatment
Fw = K (P )
Salt flux:
Fs = K (Cb C p )
product concentration
100%
Rejection = 1
feedwater concentration
(At constant
Pressure)
(At constant
Pressure)
Osmotic Pressure
Osmotic pressure (psi) = = 1.12(T + 273) mi
Temp (deg. C)
Membrane configurations
o
o
o
o
Source: maple.dnr.cornell.edu
Large-scale setup
Source: pure-aqua.com
CE6301: Theory of Water Treatment
Type of membranes
Ideal
Membrane
properties
o
o
o
o
Thin, imperfection-free
Water can pass through with little hindrance
Impermeable to ions
Capable of withstanding pressure
Two types
Polyamide membranes
o Subject to degradation by Cl2
or other oxidants
o not susceptible to biological
attack
o Do not hydrolize. Best within
pH 4-11
o Longer life (3-5 years)
Dr. Tanvir Ahmed
2. Molar Concentration:
Osmotic pressure is proportional to molar concentration at any
temperature
(see Table 10.4)
CE6301: Theory of Water Treatment
Fw (P )
Solute rejection:
Multivalent ion rejection > univalent ion rejection
Undissociated/poorly dissociated rejection < dissociated ions
Acid/base rejection < Salts of those acid/bases
Co-ion rejection (Rejection of Na as Na2SO4 > as NaCl)
Poor rejecAons for low mol. Wt. organic acids
Trace quanAAes of univalent ions
Electrodialysis
Electric energy is used to transfer ionized salts from feedwater
through selective membranes, leaving behind purified product water
Source: fumatech.com
Electrodialysis