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ENGR 2220
a 0 = 0.2866 nm = 2.866 x 10 -8 cm
Atomic mass = 55.847 g/mol
3
-8
3
24
3
Volume of unit cell = a0 = (2.866 x 10 cm) 23.54 x10 cm / cell
23
(2)(55.847)
7.882 g / cm 3
( 23.54)(6.02 x10 23 )
2. The density of thorium, which has the FCC structure and one atom per lattice point, is 11.72 g/cm3.
The atomic weight of thorium is 232 g/mol. Calculate
(a) the lattice parameter; and
(b) the atomic radius of thorium.
Solution:
(a)
( number of atoms / cell )( atomic massof iron )
a 0 1.315297 x 10 22 cm 3 or
a 0 5.0856 x 10 8 cm
(b) From the relationship between atomic radius and lattice parameter
r=
( 2 )(5.0856 x 10 8 cm)
1.7980 x 10 8 cm
( 4)
3. Copper has an atomic radius of 0.1278 nm, an atomic weight of 63.5 g/mol and a density of 8.94
g/cm3. Determine whether it has a BCC or an FCC crystal structure.
Solution:
For BCC:
nA
3
a NA
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Assignment #1
ENGR 2220
4
-8
x (1.278 10 cm) /(unit cell ) (6.02210 23 atoms / mol )
3
= 8.21 g/cm3
For FCC
(2)(1.278 10
nA
nA
3
a N A (2 R 2 ) 3 N A
cm)(
2)
= 8.93 g/cm3
Solution:
(a)
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Assignment #1
ENGR 2220
5. Determine the Miller indices for planes A and B in the figure below:
Intercepts
-b
-1
Reciprocals of intercepts
-1
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Assignment #1
ENGR 2220
1 1 1
Enclosure
Intercepts
b/3
1/3
Reciprocals of intercepts
Enclosure
0 3 0
4 of 4