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Preview Test: Quiz4_Alcohols_Chem332

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Preview Test: Quiz4_Alcohols_Chem332

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Chem 332 Quiz#2 Alcohols - Part of Exam#1

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Question 1

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Choose the best set of reagents for carrying out the chemical conversion (below).

A. 1)

TMS-Cl, Et3N
2) MeMgBr, ether
3) H3O+

B.

None of these Reagent Sets.

C. 1)

NaBH4, MeOH
2) MeOH

D. 1)

PBr3
2) MeOH

E.

1)
2)
3)
4)

LiAlH4, ether
H3O+
MeMgBr, ether
H3O+

Question 2
Give the common names for each of these compounds.

A. allyl

alcohol
ethylene glycol

ethylene glycol
ethanol
hydroquinone
B.

vinyl alcohol
propylene glycol
ethanol
quinone

C. vinyl

alcohol
ethylene glycol
ethanol
hydroquinone

D. allyl

alcohol
propylene glycol
ethanol
quinone

Question 3

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The best reagents for accomplishing this transformation are:

A. 1)

Hg(OAc)2, H2O
2) NaBH4

B.

1) BH3, THF
2) H2O2, -OH

C. 1)

OsO4, pyridine
2) NaHSO4, H2O

D. 1)

m-CPBA, CH2Cl2
2) H3O+

E.

None of these Reagent Sets.

Question 4

A highly useful and general method for the synthesis of alcohols is the addition of Grignard reagents to carbonyl
compounds. Show what Grignard reaction would NOT be used to prepare the alcohol (below).

A. Reactants
B.

Reactants B

C. Reactants

D. Reactants

Question 5

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Give the major organic product for the reaction below.

A. Compound
B.

Compound B

C. Compound

D. Compound

Question 6
Give the major organic product for the reaction below.

A. Compound
B.

Compound B

C. Compound

D. Compound

E.

None of these Compounds.

Question 7

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Give the major organic product for the reaction below.

A. Compound
B.

Compound B

C. Compound

D. Compound

E.

None of these Compounds

Question 8
Give the major organic product from the reaction below.

A. Compound
B.

Compound B

C. Compound

D. Compound

E.

None of these Compounds.

Question 9

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Choose the best set of reagents for carrying out the chemical conversion (below).

A. None
B.

of these Reagent Sets.

1) TMS-Cl, Et3N
2) MeMgBr, ether
3) H3O+

C. PCC,

CH2Cl2

D. 1)

NaBH4, ethanol
2) H3O+

E.

1) LiAlH4, ether
2) H3O+

Question 10
Choose the best set of reagents for carrying out the chemical conversion (below).

A. 1)

NaBH4, ethanol

1) NaBH4, ethanol
2) H3O+
B.

1) TMS-Cl, Et3N
2) MeMgBr, ether
3) H3O+

C. None
D. PCC,
E.

of these Reagent Sets.

CH2Cl2

1) PBr3
2) NaOH

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