Beruflich Dokumente
Kultur Dokumente
1. For the equilibrium that exists in an aqueous solution of nitrous acid (HNO2, a weak
acid), the equilibrium constant expression is:
a)
K=
[H+][NO2]
[HNO2]
b)
K=
[H+][N][O]2
[HNO2]
c)
K = [H+][NO2]
d)
[H+]2[NO2]
K = [HNO ]
2
e)
none of these
ANS:
a)
[H+][NO2]
K = [HNO ]
2
PAGE: 14.1
HCl/OClH2SO4/SO42NH4+/NH3
H3O+/OHnone of these
c)
NH4+/NH3
PAGE: 14.1
HA
is called:
a)
Ka
b)
Kb
c)
1
Ka
d)
Kw
Kb
e)
KwKa
ANS:
c)
1
Ka
PAGE: 14.1
321
CHAPTER 14
4. For the stepwise dissociation of aqueous H3PO4, which of the following is not a
conjugate acidbase pair?
a)
b)
c)
d)
e)
ANS: d)
PAGE: 14.1,7
HN3 + H2O
5.3 1010
1.9 109
1.9 105
5.3 104
1.9 109
ANS: d)
5.3 104
PAGE: 14.1
6. The hydrogen sulfate or bisulfate ion HSO4 can act as either an acid or a base in water
solution. In which of the following equations does HSO4 act as an acid?
a)
b)
c)
HSO4 + OH H2SO4 + O2
d)
e)
none of these
ANS: d)
322
PAGE: 14.1,2
CHAPTER 14
7. Using the following Ka values, indicate the correct order of base strength.
HNO2
Ka = 4.0 104
HF
Ka = 7.2 104
HCN
Ka = 6.2 1010
a)
b)
c)
d)
e)
none of these
ANS:
a)
PAGE: 14.2
8. At 0C, the ion-product constant of water, Kw, is 1.2 1015. The pH of pure water
at 0C is:
a)
b)
c)
d)
e)
7.00
6.88
7.56
7.46
none of these
ANS: d)
7.46
PAGE: 14.2,3
9. The equilibrium constants (Ka) for HCN and HF in H2O at 25C are 6.2 1010 and
7.2 104, respectively. The relative order of base strengths is:
a)
b)
c)
d)
e)
ANS:
PAGE: 14.2
323
CHAPTER 14
HOAc
HCN
HF
1 107
1.76 105
4.93 1010
3.53 104
c)
d)
e)
ClO4, F, OAc, CN
ANS:
e)
ClO4, F, OAc, CN
PAGE: 14.2
a strong base
a weak base
a strong acid
a weak acid
none of these
b)
a weak base
PAGE: 14.2
12. Which of the following is the equilibrium constant expression for the dissociation of the
weak acid HOCl?
[H+][OCl]
[HOCl]
a)
K=
b)
K = [H+][OCl]
c)
[HOCl]
K = [H+][OCl]
d)
K=
e)
none of these
ANS:
a)
[H+][O2][Cl]
[HOCl]
K=
[H+][OCl]
[HOCl]
PAGE: 14.1,2
1314. The following three equations represent equilibria that lie far to the right.
HNO3(aq) + CN(aq)
HCN(aq) + NO3(aq)
HCN(aq) + OH(aq)
H2O(l) + CN(aq)
H2O(l) + CH3O(aq)
CH2OH(aq) + OH(aq)
324
CHAPTER 14
HCN
HNO3
H2O
OH
CH3OH
ANS: b)
PAGE: 14.2
HNO3
CH3O
CH3OH
CN
H2O
NO3
ANS: a)
CH3O
PAGE: 14.2
15. Given that the Ka for HOCl is 3.5 x 10-8, calculate the K value for the reaction of HOCl
with OH-.
a)
b)
c)
d)
e)
ANS:
3.5 x 106
3.5 x 10-8
3.5 x 10-22
2.9 x 10-7
none of these
a)
3.5 x 106
PAGE: 14.2,6,8
2.3 M
11.7 M
5.0 103 M
2.0 1012 M
none of these
ANS: d)
2.0 1012 M
PAGE: 14.3
2.3 M
11.7 M
5.0 103 M
2.0 1012 M
none of these
c)
5.0 103 M
PAGE: 14.3
325
CHAPTER 14
4.5
10.5
9.5
6.3
none of these
c)
9.5
PAGE: 14.3
HNO2(aq)
H2O(l)
H3O+(aq)
NO(aq)
Two of these
e)
Two of these
PAGE: 14.1
20. In which of the following reactions does the H2PO4- ion act as an acid?
a)
b)
c)
d)
e)
ANS:
PAGE: 14.1
21. In deciding which of two acids is the stronger, one must know:
a)
b)
c)
d)
e)
ANS:
PAGE: 14.2
22. Which of the following is not true for a solution at 25C that has a hydroxide
concentration of 2.5 106 M?
a)
b)
c)
d)
e)
ANS:
Kw = 1 1014
The solution is acidic.
The solution is basic.
The [H] is 4 109 M.
The Kw is independent of what the solution contains.
c)
PAGE: 14.2
326
CHAPTER 14
2.0 1010 M
5.0 105 M
3.6 109 M
9.7 109 M
6.3 1010 M
a)
2.0 1010 M
PAGE: 14.3
0.600
2.50
12.0
1.20
13.4
ANS:
a)
0.600
PAGE: 14.4
25. Solid calcium hydroxide is dissolved in water until the pH of the solution is 10.94. The
hydroxide ion concentration [OH] of the solution is:
a)
b)
c)
d)
e)
ANS:
1.1 1011 M
3.06 M
8.7 104 M
1.0 1014 M
none of these
c)
8.7 104 M
PAGE: 14.3
This means that
none of these
PAGE: 14.3
[H+] = 1 1010 M
pOH = 6.7
[OH] = 7 105 M
pH = 4.2
At least two of the solutions are equally basic.
a)
[H+] = 1 1010 M
PAGE: 14.3
327
CHAPTER 14
-0.70
0.70
14.70
13.30
none of these
c)
14.70
PAGE: 14.4
-1.30
1.30
12.70
15.30
none of these
b)
1.30
PAGE: 14.4
30. For nitrous acid, HNO2, Ka = 4.0 104. Calculate the pH of 0.25 M HNO2.
a)
b)
c)
d)
e)
ANS:
2.00
2.30
2.70
3.70
none of these
a)
2.00
PAGE: 14.5
31. For weak acid, HX, Ka = 1.0 106. Calculate the pH of a 0.10 M solution of HX.
a)
b)
c)
d)
e)
ANS:
6.00
3.50
3.00
2.50
none of these
b)
3.50
PAGE: 14.5
32. Acetic acid (HC2H3O2) is a weak acid (Ka = 1.8 105). Calculate the pH of a 17.6 M
HC2H3O2 solution.
a)
b)
c)
d)
e)
ANS:
4.3
6.4
1.7
0.97
7.4
c)
1.7
PAGE: 14.5
328
CHAPTER 14
33. Determine the molarity of a solution of the weak acid HClO2 (Ka = 1.10 102) if it has a
pH of 1.25.
a)
b)
c)
d)
e)
ANS:
0.287 M
1.23 M
0.819 M
3.17 M
1.52 M
a)
0.287 M
PAGE: 14.5
3435. The following questions refer to a solution that contains 1.00 M hydrofluoric acid, HF
(Ka = 7.2 104), and 3.00 M hydrocyanic acid, HCN (Ka = 6.2 1010).
34. What is the pH of this mixture of weak acids?
a)
b)
c)
d)
e)
0.00
1.57
3.14
4.37
9.21
ANS: b)
1.57
PAGE: 14.5
4.31 105 M
4.28 107 M
6.9 108 M
6.2 1010 M
none of these
ANS: c)
6.9 108 M
PAGE: 14.5
36. How many moles of benzoic acid, a monoprotic acid with Ka = 6.4 105, must be
dissolved in 500. mL of H2O to produce a solution with pH = 2.50?
a)
b)
c)
d)
e)
ANS:
1.6 101
2.0 102
7.8 102
0.50
none of these
c)
7.8 102
PAGE: 14.5
329
CHAPTER 14
1.0 107 M
2.5 106 M
3.6 103 M
6.2 1010 M
none of these
b)
2.5 106 M
PAGE: 14.5
38. In a solution prepared by dissolving 0.100 mole of propionic acid in enough water to
make 1.00 L of solution, the pH is observed to be 1.35. The Ka for propionic acid
(HC3H5O2) is:
a)
b)
c)
d)
e)
ANS:
2.0 102
3.6 102
4.5 102
5.0 1012
none of these
b)
3.6 102
PAGE: 14.5
6.8 x 10-5
1.1 x 10-5
0.11
1.3 x 10-2
none of these
a)
6.8 x 10-5
PAGE: 14.5
40. A solution of 8.0 M formic acid (HCOOH) is 0.47% ionized. What is the Ka of formic
acid?
a)
b)
c)
d)
e)
ANS:
3.4 108
1.8 104
6.9 106
3.8 102
need more data
b)
1.8 104
PAGE: 14.5
330
CHAPTER 14
41. The pH of a 0.100 M solution of an aqueous weak acid (HA) is 3.20. The Ka for the
weak acid is:
a)
b)
c)
d)
e)
ANS:
6.3 104
7.2 105
4.0 106
3.2
none of these
c)
4.0 106
PAGE: 14.5
42. Saccharin is a monoprotic acid. If the pH of a 1.50 102 M solution of this acid is 5.53,
what is the Ka of saccharin?
a)
b)
c)
d)
e)
ANS:
2.0 104
2.9 106
5.8 1010
8.4 1012
none of these
c)
5.8 1010
PAGE: 14.5
43. The pH of a 0.13 M solution of a weak monoprotic acid, HA, is 2.92. Calculate the Ka for
this acid.
a)
b)
c)
d)
e)
0.13
1.2 103
1.4 106
1.1 105
1.3 1010
ANS: d)
1.1 105
PAGE: 14.5
44. A monoprotic weak acid when dissolved in water is 0.92% dissociated and produces a
solution with a pH of 3.42. Calculate the Ka of the acid.
a)
b)
c)
d)
e)
ANS:
1.4 x 10-7
2.8 x 10-3
3.5 x 10-6
Need to know the initial concentration of the acid.
None of these.
c)
3.5 x 10-6
PAGE: 14.5
331
CHAPTER 14
45. If an acid, HA, is 10.0% dissociated in a 1.0 M solution, what is the Ka for this acid?
a)
b)
c)
d)
e)
ANS:
9.1 102
1.1 102
8.1 101
6.3 102
none of these
b)
1.1 102
PAGE: 14.5
4.23
8.46
3.73
1.00
3.23
a)
4.23
PAGE: 14.5
47. Calculate the pOH of a 0.80 M solution of acetic acid (Ka = 1.8 105).
a)
b)
c)
d)
e)
9.25
2.42
4.74
11.58
7.87
ANS: d)
11.58
PAGE: 14.5
48. The pKa of HOCl is 7.5. Calculate the pH of a 0.5 M solution of HOCl.
a)
b)
c)
d)
e)
ANS:
7.5
6.5
3.9
10.1
0.3
c)
3.9
PAGE: 14.5
49. When 2.0 102 mol of nicotinic acid (a monoprotic acid) is dissolved in 350 mL of
water, the pH is 3.05. Calculate the Ka of nicotinic acid.
a)
b)
c)
d)
e)
ANS:
1.6 102
1.4 105
3.9 105
7.9 107
none of these
b)
1.4 105
PAGE: 14.5
332
CHAPTER 14
50. Approximately how much water should be added to 10.0 mL of 12.0 M HCl so that it
has the same pH as 0.90 M acetic acid (Ka = 1.8 x 10-5)?
a)
b)
c)
d)
e)
30 mL
300 mL
3L
30 L
300 L
ANS: d)
30 L
PAGE: 14.5
ANS: d)
PAGE: 14.2,3
52. What concentration of acetic acid (Ka = 1.80 105) has the same pH as that of
5.00 103 M HCl?
a)
b)
c)
d)
e)
ANS:
3.60 103 M
5.00 103 M
1.39 M
5.00 M
none of these
c)
1.39 M
PAGE: 14.4,5
HF + OCl
53. Given that Ka for HOCl is 3.5 108 and the Ka for HF is 7.2 104 (both at 25C), which
of the following is true concerning K for the above reaction at 25C?
a)
b)
c)
d)
e)
K is greater than 1.
K is less than 1.
K is equal to 1.
Cannot be determined with the above information.
None of these (a-d)
ANS: b)
K is less than 1
PAGE: 13.2,14.5
54. Assuming that the value for K in the above reaction is greater than 1, this means that HF
is a stronger acid than HOCl.
ANS: False
PAGE: 13.2,14.5
333
CHAPTER 14
Al3+ + 6H2O
b)
Al(OH2)63+
c)
OCl + H2O
d)
e)
CN + H+
None of these
Al(OH2)63+
Al(OH)(OH2)52+ + H+
HOCl + OH
HCN
Al(OH2)63+
Al(OH)(OH2)52+ + H+
PAGE: 14.1
OCl + H2O
HOCl + OH
PAGE: 14.6
57. Which of the following reactions is associated with the definition of Kb?
a)
Zn(OH2)62+
b)
CN + H+
HCN
c)
F + H2O
HF + OH
d)
Cr3+ + 6H2O
e)
none of these
ANS:
c)
F + H2O
[Zn(OH2)5OH]+ + H+
Cr(OH2)63+
HF + OH
PAGE: 14.6
13.30
13.00
0.20
0.10
none of these
a)
13.30
PAGE: 14.6
1.7
2.0
12.0
12.3
cannot calculate answer unless a volume is given
ANS: d)
12.3
PAGE: 14.6
334
CHAPTER 14
a)
b)
c)
d)
e)
ANS:
13.30
0.70
1.00
13.00
none of these
b)
0.70
PAGE: 14.6
14.00
13.00
1.00
0.10
none of these
b)
13.00
PAGE: 14.6
62. A 0.400-g sample of NaOH(s) is added to enough water to make 250.0 mL of solution.
The pH of this solution is:
a)
b)
c)
d)
e)
12.000
1.398
2.000
12.602
none of these
ANS: d)
12.602
PAGE: 14.6
2.30
3.50
11.70
5.00
10.50
ANS:
c)
11.70
PAGE: 14.6
6465. The following questions refer to a 0.70 M solution of hypochlorous acid, HClO.
64. The Ka for the acid is 3.5 108. Determine the percent dissociation.
a)
b)
c)
d)
e)
1.3%
0.84%
0.41%
0.22%
0.15%
ANS: d)
0.22%
PAGE: 14.5
335
CHAPTER 14
65. If the molarity was decreased to 0.3 M, which of the following statements would be
true?
a)
b)
c)
d)
e)
ANS: e)
Two of these.
PAGE: 14.5
10.4
20.3
14.5
8.50
none of these
c)
14.5
PAGE: 14.6
67. The pain killer morphine is a weak base when added to water. The reaction produces
one mole of hydroxide ions for every one mole of morphine that dissolves. The Kb is
1.60 106. What is the pH of a 5.00 103 M solution of morphine?
a)
b)
c)
d)
e)
ANS:
8.23
9.95
11.3
10.2
none of these
b)
9.95
PAGE: 14.6
68. Determine the pH of a 0.060 M solution of H2SO4. The dissociation occurs in two steps.
Ka1 is extremely large; Ka2 is 1.2 102.
a)
b)
c)
d)
e)
1.4
1.3
1.2
1.1
1.0
ANS: d)
1.1
PAGE: 14.7
0.50 M
2.9 105 M
1.8 109 M
3.3 1010 M
none of these
336
CHAPTER 14
ANS:
b)
2.9 105 M
PAGE: 14.6
4.36
9.64
0.070
9.30
none of these
b)
9.64
PAGE: 14.6
8.15
5.88
9.12
11.24
none of these
c)
9.12
PAGE: 14.6
72. Calculate the percentage of pyridine (C5H5N) that forms pyridinium ion, C5H5NH+, in a
0.10 M aqueous solution of pyridine (Kb = 1.7 109):
a)
b)
c)
d)
e)
ANS:
0.0060%
1.6%
0.77%
0.060%
0.013%
e)
0.013%
PAGE: 14.6
73. Which of the following aqueous solutions will have the highest pH?
For NH3, Kb = 1.8 105; for C2H3O2, Kb = 5.6 1010.
a)
b)
c)
d)
e)
ANS:
2.0 M NaOH
2.0 M NH3
2.0 M HC2H3O2
2.0 M HCl
all the same
a)
2.0 M NaOH
PAGE: 14.6
13.72
7.00
4.78
2.52
none of these
337
CHAPTER 14
ANS:
e)
none of these
PAGE: 14.6
338
CHAPTER 14
NH3 + H2O
is:
a)
1
Kb(NH3)
b)
1
Ka(NH4+)
c)
Kw
Ka(NH4+)
d)
Kw
Kb(NH3)
e)
Kb(NH3)
Kw
ANS:
a)
1
Kb(NH3)
PAGE: 14.6
7681. Calculate the pH of the following aqueous solutions. Choose your answer from the
following pH ranges:
a)
b)
c)
d)
e)
pH 0.002.99
pH 3.005.99
pH 6.008.99
pH 9.00 10.99
pH 11.0014.00
pH 3.005.99
PAGE: 14.5
pH 6.008.99
PAGE: 14.8
pH 9.0010.99
PAGE: 14.6
pH 3.005.99
PAGE: 14.8
pH 3.005.99
PAGE: 14.7
339
CHAPTER 14
pH 3.005.99
PAGE: 14.7
340
CHAPTER 14
82. A 0.10-mol sample of a diprotic acid, H2A, is dissolved in 250 mL of water. The Ka1 of
this acid is 1.0 105 and Ka2 is 1.0 1010. Calculate the concentration of A2 in this
solution.
a)
b)
c)
d)
e)
1.0 105 M
2.0 103 M
4.0 106 M
1.0 1010 M
0.40 M
ANS: d)
1.0 1010 M
PAGE: 14.7
83. The pH in a solution of 1.0 M H2A (Ka1 = 1.0 106; Ka2 = 1.0 1010) is:
a)
b)
c)
d)
e)
8.00
7.00
6.00
3.00
none of these
ANS: d)
3.00
PAGE: 14.7
84. Calculate the pH of a 0.05 M solution of ascorbic acid (Ka1 = 7.9 105; Ka2 = 1.6 1012).
a)
b)
c)
d)
e)
ANS:
1.3
2.7
3.1
5.4
6.5
b)
2.7
PAGE: 14.7
7.5 106 M
6.6 104 M
1.3 102 M
7.5 1013 M
none of these
ANS: d)
7.5 1013 M
PAGE: 14.7,8
341
CHAPTER 14
86. The dihydrogenphosphate ion, H2PO4, has both a conjugate acid and a conjugate base.
These are, respectively:
a)
H3PO4, PO43
b)
H3PO4, HPO42
c)
H2PO4, HPO42
d)
HPO42, PO43
e)
HPO42, H3PO4
ANS:
H3PO4, HPO42
b)
PAGE: 14.7
Ka = 1.8 105
Ka1 = 4.3 107
Ka2 = 5.6 1011
87. HOAc
H2CO3
HOAc
NaOAc
Na2CO3
H2CO3
NaHCO3
c)
Na2CO3
PAGE: 14.7,8
88. The conjugate acid and conjugate base of bicarbonate ion, HCO3, are, respectively:
a)
H3O+ and OH
b)
c)
H2CO3 and OH
d)
e)
CO32 and OH
ANS: d)
PAGE: 14.7
89. Which of the following species is present in the greatest concentration in a 0.100 M
H2SO4 solution in H2O?
a)
H3O+
b)
HSO4
c)
H2SO4
d)
All species are in equilibrium and therefore have the same concentration.
e)
SO42
ANS:
a)
H3O+
PAGE: 14.7
342
CHAPTER 14
90. The pH of a 0.150 M solution of a weak base is 10.98. Calculate the pH of a 0.0400 M
solution of the base.
a)
b)
c)
d)
e)
ANS:
10.5
10.7
11.2
11.5
none of these
b)
10.7
PAGE: 14.6
91. Which of the following is the correct order for increasing pHs for HNO3, KCl, NH4Cl,
KOH, and NaC2H3O2? (Ka for HC2H3O2 is 1.80 105, Ka for NH4+ is 5.56 1010).
a)
b)
c)
d)
e)
ANS: d)
PAGE: 14.8
92. Which of the following is the strongest base? (Kb for NH3 is 1.8 105, Ka2 for H2SO4 is
1.2 102, Ka3 for H3PO4 is 4.8 1013)
NH3, HSO4, PO43, or NO3
a)
b)
c)
d)
e)
NH3
HSO4
NO3
PO43
Two of these are equally strong.
ANS: d)
PO43
PAGE: 14.6-8
93. The salt BX, when dissolved in water, produces an acidic solution. Which of the
following could be true?
a)
b)
c)
d)
e)
HX is a weak acid.
HX is a strong acid.
The cation B+ is a weak acid.
All of these could be true.
Only two of these (a and c) could be true.
ANS: d)
PAGE: 14.8
343
CHAPTER 14
94. Calculate the Ka for an unknown monoprotic acid HX, given that a solution of 0.10 M
LiX has a pH of 8.90.
a)
b)
c)
d)
e)
ANS:
7.9 106
4.3 108
6.2 1010
2.6 1010
1.6 105
e)
1.6 105
PAGE: 14.8
95. The sodium salt, NaA, of a weak acid is dissolved in water; no other substance is added.
Which of these statements (to a close approximation) is true?
a)
b)
c)
d)
e)
[H+] = [A]
[H+] = [OH]
[A] = [OH]
[HA] = [OH]
none of these
ANS: d)
[HA] = [OH]
PAGE: 14.8
96. The [H3O+] of a 0.15 M solution of NH4Cl in H2O at 25C is (Kb for NH3 = 1.8 105):
a)
b)
c)
d)
ANS:
3.6 103 M
4.9 105 M
9.1 106 M
8.2 1010 M
c)
9.1 106 M
PAGE: 14.8
97. Calculate the pH of a 0.30 M solution of NH4Cl. (Kb for NH3 = 1.8 105)
a)
b)
c)
d)
e)
3.33
4.89
9.11
7.00
11.67
ANS:
b)
4.89
PAGE: 14.8
HCN + OH
Kb =
[HCN][OH]
[CN]
6.2 1024
6.2 104
1.6 105
1.6 1023
none of these
c)
1.6 105
PAGE: 14.8
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99. If you know Kb for ammonia, NH3, you can calculate the equilibrium constant, Ka, for
the following reaction:
NH4+
NH3 + H+
by the equation:
a)
b)
c)
d)
ANS:
Ka = KwKb
Ka = Kw/Kb
Ka = 1/Kb
Ka = Kb/Kw
b)
Ka = Kw/Kb
PAGE: 14.8
100. Which of the following would give the highest pH when dissolved in water to form a
0.10 M solution?
a)
b)
c)
d)
e)
ANS:
a strong acid
a weak acid
the potassium salt of a weak acid
the potassium salt of a strong acid
the ammonium salt of a strong acid
c)
PAGE: 14.8
101. Which of the following is true about the pH of a solution of sulfuric acid?
a)
b)
c)
d)
e)
ANS:
PAGE: 14.7
10.5
7.0
9.2
1.4
4.5
b)
7.0
PAGE: 14.8
345
CHAPTER 14
6.60 x 10-17
1.05 x 10-5
3.80 x 10-4
2.63 x 10-11
none of these
c)
3.80 x 10-4
PAGE: 14.8
104. The hydrogen halides (HF, HCl, HBr, and HI) are all polar molecules. The strength of
the acid each forms in water is based on which of the following?
a)
b)
c)
d)
e)
ANS: d)
two of these
PAGE: 14.9
105. Which factor listed below is most important in determining the strength of an oxyacid?
a)
b)
c)
d)
e)
ANS: d)
PAGE: 14.9
106110. Use the following choices to describe an aqueous solution made from each of the
following substances.
a) acidic
b) neutral
c) basic
d) cannot tell
e) None of these (a-d)
106. solid sodium nitrate (NaNO3)
ANS: b)
neutral
PAGE: 14.8
neutral
PAGE: 14.8
346
CHAPTER 14
ANS: c)
basic
PAGE: 14.8
347
CHAPTER 14
neutral
PAGE: 14.8
acidic
PAGE: 14.8
7.0
greater than 7.0
less than 7.0
not enough information is given
none of these (a-d)
a)
7.0
PAGE: 14.8
7.0
greater than 7.0
less than 7.0
not enough information is given
none of these (a-d)
b)
PAGE: 14.8
P4O10
KCl
CO2
NH4Cl
none of these
e)
none of these
PAGE: 14.8,10
114. Calculate the pH of a 0.20 M solution of NaC2H3O2 (for HC2H3O2 Ka = 1.8 10-5).
a)
b)
c)
d)
e)
ANS:
4.98
9.02
5.44
8.56
none of these
b)
9.02
PAGE: 14.8
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CHAPTER 14
115. Which of the following would produce the most acidic solution?
a)
b)
c)
d)
e)
HOCl2
HOCl
HOBr
HOI
HOAt
ANS:
a)
HOCl2
PAGE: 14.9
12.0
11.7
7.0
2.3
2.0
a)
12.0
PAGE: 14.10
117. Which of the species below, when dissolved in H2O, will not produce a basic solution?
a)
b)
c)
d)
e)
ANS:
SO2
NH3
BaO
Ba(OH)2
none of these
a)
PAGE: 14.10
SO2
PAGE: 14.2
119123. Determine whether the following oxides produce an acidic, basic, or neutral solution
when dissolved in water:
119. K2O
ANS: basic
PAGE: 14.10
120. NO2
ANS: acidic
PAGE: 14.10
121. Cl2O
ANS: acidic
PAGE: 14.10
122. CaO
ANS: basic
PAGE: 14.10
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CHAPTER 14
123. SO2
ANS: acidic
PAGE: 14.10
124. Explain why 0.1 M NaCN is basic while 0.1 M NaNO3 is neutral.
ANS: See Sec. 14.8 of Zumdahl, Chemistry.
PAGE: 14.8
125. Explain why Al2(SO4)3 produces an acidic solution when it is dissolved in water.
ANS: See Sec. 14.8 of Zumdahl, Chemistry.
350
PAGE: 14.8