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1)
Ered = 0.52 V
Cu2+ + 2e- Cu
Ered = 0.34 V
2)
How many Faradays are required to produce 21.58 g of silver from a silver
nitrate solution?
3)
4)
5)
(a)
(b)
(c)
5.77 g of zinc is deposited at the cathode when a current of 7.1 amperes passes
through an electrolytic cell for 40. minutes. What is the oxidation state of the zinc
in the aqueous solution?
6)
(b)
(c)
(d)
Ered = 0.799 V
Ered = -0.136 V
Ered = 1.065 V
Ered = 1.359 V
Ered = -0.763 V
Ered = -0.277 V
Ered = 1.420 V
Ered = 0.540 V
Solutions
1)
reduction:
Cu+ + e- Cu
Ered = 0.52 V
oxidation:
Cu Cu2+ + 2e-
Eox = -0.34 V
Cu+ + e- Cu
Ered = 0.52 V
Eox = -0.34 V
Cu Cu2+ + 2e_______________________________________
Cu+ Cu2+ + e-
2)
Ecell = 0.18 V
m = 21.58 g Ag
1 F = 1 mol eAg+(aq) + e- Ag(s)
nF = 21.58 g Ag x 1 mol Ag/107.90 g Ag x 1 mol e-/1 mol Ag x 1 F/1 mol enF = 0.200 F
3)
4)
(a)
(b)
Pd2+ + 2e- Pd
Ered = 0.951 V
Cu Cu2+ + 2eEox = ?
________________________________________________________
Pd2+(aq) + Cu(s) Pd(s) + Cu2+(aq)
Ecell = Ered
Ecell = 0.609 V
Eox
5)
m = 5.77 g Zn
I = 7.1 A = 7.1 C/s
t = 40. min x 60 s/1 min = 2.4 x 103 s
Znx+(aq) + xe- Zn(s)
5.77 g Zn = 7.1 C/s 2.4 x 103 s 1 mol Zn/x mol e- 1 mol e-/96500 C
65.39 g Zn/1 mol Zn
x = 2, therefore Zn2+(aq) + 2e- Zn(s)
6)
(a)
(b)
(c)
(d)
Au(s) is the better oxidizing agent, therefore I-(aq) is the better reducing
agent.