Beruflich Dokumente
Kultur Dokumente
Max-Planck-Institut fur Metallforschung Institut fur Werkstoffwissenschaft and Institut fur Metallkunde, Uni6ersitat Stuttgart,
70 174 Stuttgart, Germany
b
ETH Zurich, Institute of Metallurgy, Zurich, Switzerland
c
Metal Matrix Cast Composites, Unit 1, 101 Clematis A6e, Waltham, MA 02 154, USA
Received 27 January 1997
Abstract
An oxide-dispersion strengthened (ODS) Ni3Al(B)-alloy containing 5 at.% chromium, produced by powder metallurgy, was
zone-annealed to produce a coarse-grained microstructure. The creep properties were then investigated between 1000 and 1200C
at creep rates from 10 7 to 10 3 s 1 and the resulting experimental data were compared with several models of creep
deformation. As expected, the Rosler and Arzt model for the detachment of single dislocations from the dispersoids did not
satisfactorily explain the measured data. The model of Gohring and Arzt, which considers superdislocations, as present in ordered
Ni3Al, provided a much better correlation. The measured creep strengths were approximately five to ten times higher than those
of fine-grained ODS-Ni3Al; however, they were about 1000 times lower than those of commercial Ni-based alloys such as MA
6000. Suggestions for further development and experiments are made. 1997 Elsevier Science S.A.
Keywords: Ni3Al alloy; Oxide-dispersion; Creep
1. Introduction
2. Experimental procedures
U.E. Klotz et al. / Materials Science and Engineering A231 (1997) 198205
199
3. Results
MA 6000 [12]
1295 [13]
1160 [14]
1.5
39
0.2
4023
171
24
U.E. Klotz et al. / Materials Science and Engineering A231 (1997) 198205
200
Table 2
Results of phase-analysis
Only zone-annealed
g% particle-diameter (mm) 1.09 0.4
Volume fraction of g%
82.0
(%)
1.09 0.4
85.9
1.0 9 0.4
65.7
1.0 90.4
42.4
' '
p
6f
2
3
(1)
U.E. Klotz et al. / Materials Science and Engineering A231 (1997) 198205
201
Table 3
Results of creep tests, corrected data
Temp rature Strain rate
(s1)
(C)
logarithmic scale. The data in Fig. 4 have been corrected for the extent of melting during zone annealing
by dividing the measured creep force by the unaffected
cross-sectional area, which was determined from a
transverse micrograph. In Table 3 the measured data
are presented in full detail. Using this data a leastsquares fit was performed to determine the three creep
parameters A, Q and n in the generalized power-law
creep equation, Section 2 [17]:
Eb
Q
exp
kBT
kBT
o; =A
s
E
(2)
1000
1000
1000
1000
1000
1000
1000
1000
1000
1100
1100
1100
1100
1100
1100
1100
1100
1100
1100
1100
1100
1100
1100
1200
1200
1200
1200
1200
1200
1200
1200
1200
1200
1200
1200
1200
8108
5106
1104
4107
1106
2105
3104
2106
2107
1106
9105
8108
5107
5106
1105
3104
4105
1106
2105
5105
1103
3104
2107
5106
3105
2104
1105
7105
3104
1103
1106
5106
2105
1104
4104
2104
Stress
(MPa)
o/D
s/E110
126.6
198.8
312.6
137.3
157.0
254.8
361.1
162.4
132.5
89.6
155.1
70.6
82.1
110.2
121.6
196.7
126.9
87.4
125.7
155.0
196.6
175.2
55.9
55.3
64.0
94.8
59.7
73.6
90.8
103.4
45.6
56.0
66.0
76.9
31.3
55.0
6.8108
4.21010
8.11011
3.0109
8.1109
1.61011
2.51012
1.61010
1.4109
9.3108
8.31010
7.7107
4.6108
4.8109
9.3109
2.91011
3.71010
8.8108
1.91010
4.61010
1.11012
2.91011
1.6108
6.5108
3.8109
2.61010
1.2109
8.8109
3.81010
1.31011
1.2108
6.3108
2.5109
1.31010
4.9107
2.6108
8.9104
1.4103
2.19103
9.6104
1.10103
1.79103
2.53103
1.14103
9.3104
6.9104
1.20103
5.5104
6.4104
8.5104
9.4104
1.52103
9.8104
6.8104
9.7104
1.20103
1.52103
1.35103
4.3104
4.8104
5.5104
8.2104
5.1104
6.3104
7.8104
8.9104
3.9104
4.8104
5.7104
6.6104
2.7104
4.7104
yttria-dispersed NiCrAl measured in the 110 direction [18]. Values for the elastic modulus and volume
diffusivity at each test temperature are provided in
Table 4. The three unknowns in Eq. (2) were determined as A= 6.3 1026, Q= 697 kJ mol 1 and n=7.8.
Table 4
Physical constants used in analysis of the experimental data
Fig. 4. Maximum creep stress vs. strain rate for ODS Ni3Al.
Temperature (K)
E (GPa) [18]
1273
1373
1473
1.241016
1.081015
8.01015
142.6
129.6
116.0
202
U.E. Klotz et al. / Materials Science and Engineering A231 (1997) 198205
4. Discussion
U.E. Klotz et al. / Materials Science and Engineering A231 (1997) 198205
203
204
U.E. Klotz et al. / Materials Science and Engineering A231 (1997) 198205
5. Summary
U.E. Klotz et al. / Materials Science and Engineering A231 (1997) 198205
205
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