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1. I N T R O D U C T I O N
The rate at which water is absorbed into concrete by
capillary suction can provide useful information relating
to the pore structure, permeation characteristics and
durability of the concrete surface zone that is penetrated
[1-18]. Water absorption tests on concrete can be
conducted in the laboratory, normally using specimens
dried in a standard way, or in the field.
In the laboratory the penetration depth after various
periods of wetting can be determined by direct observation
on split specimens [14], nuclear magnetic resonance
imaging [19] or by deduction based upon measured
specimen weight gains and a measured value of porosity
(e.g. [16]). The depth of water penetration usually
increases linearly with the square root of wetting time in
many porous materials, provided that porosity and initial
moisture content are uniform throughout the test
specimen [20]. The slope of this linear plot is termed
sorptivity [t2,14,16] and its units are m s -1/2. The term
sorptivity has also been used to describe the slope for
plots of volume (or weight) of water imbibed per unit
area of wetted surface versus square root of wetting time,
but the term 'absorption rate' is preferred in these cases.
It is worth noting that calculations of the depth of water
penetration from the weight or volume of water imbibed
involve the assumptions that porosity does not vary with
depth and that water penetrates as a sharp liquid front.
These assumptions are only approximations of reality in
a material like concrete [1,2,8,10,19-21]. A further
problem associated with laboratory testing is that the
method of drying can significantly affect the relative
values of absorption rate that are obtained. For example
drying to constant weight at either 105 or 50~ gave
relative values for various concretes that were quite
different to the relative values obtained by drying at 20~
[22,23]. Also differences of absorption rate between
concretes were less marked when drying to constant
weight at elevated temperature was used.
Under practical exposure conditions the moisture
conditions and pore structure in concrete will vary with
0025-5432/92 (~ RILEM
2. E X P E R I M E N T A L P R O C E D U R E
The reported work examines the effects of five exposure
conditions, five water/cement ratios, three periods of
moist curing and four cements upon water absorption:
the 30 combinations of these variables that were used in
the experimental programme are summarized in Table 1.
Workability of the concrete was measured 10 min after
the start of mixing; slump values were normally in the
range 10 to 30 mm. Weight changes of the test specimens
were monitored during the 1.5 year exposure period, and
carbonation depths were determined on the test specimens
immediately after completion of the absorption tests.
Carbonation depths were also measured on similar
companion specimens after a six-month exposure period.
Compressive strengths were measured on saturated,
100 mm cubes at ages of 1 day, 3 days, 28 days and 1.5
years. The cements used were blended from the materials
detailed in Table 2. Table 3 indicates the blend
proportions and the cement types according to draft ENV
197 [29].
The test specimens for the absorption and carbonation
tests were 100 mm cubes sealed against moisture exchange
on five faces. Sealing was accomplished firstly by applying
a bituminous waterproofing coat to the concrete; this
acted as an adhesive for the aluminium foil water-vapour
barrier. The final stage of sealing involved wrapping with
self-adhesive, weatherproof plastic tape to give mechanical
protection to the foil vapour barrier. The test specimens
were cured at 100% relative humidity and 20~ in their
moulds up to an age of 24 h. Subsequent moist curing
involved storage in sealed conditions at 20~ (without
loss or gain of moisture). The laboratory conditions
during exposure were 58 + 3% relative humidity and
20 _+ I~ Specimens exposed outside were stored on an
exposure site in South East England. Meteorological data
for the area indicated that relative humidities, tempera-
285
Table l Data for each test series a
Series
A & L 0.59
C
0.59
E
0.59
B
0.59
D
0.59
F
0.59
G
0.59
H
0.59
I
0.59
M
0.59
N
0.59
O
0.59
P
0.59
Q
0.59
R
0.59
S
0.71
T
0.71
U
0.71
V
0.47
W
0.47
X
0.47
Y
0.83
Z
0.83
1
0.83
2
0.35
3
0.35
4
0.35
5
0.59
6
0.59
opc
pfa
ggbfs
opc
pfa
ggbfs
opc
opc
opc
opc
pfa
ggbfs
opc
pfa
ggbfs
opc
pfa
ggbfs
opc
pfa
ggbfs
opc
pfa
ggbfs
opc
pfa
ggbfs
Filler
Filler
3
3
3
3
3
3
3
3
3
1
1
I
28
28
28
3
3
3
3
3
3
3
3
3
3
3
3
3
3
Lab
Lab
Lab
OS
OS
OS
OV
OH
Office
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
OS
22.6
13.3
10.0
22.3
13.3
9.8
20.4
21.0
21.0
11.0
5.8
3.0
44.0
28.2
30.7
13.6
7.0
6.6
29.7
20.8
17.2
10.9
5.4
4.9
53.8
34.0
31.2
21.0
20.6
42.1
29.5
33.9
42.8
30.0
33.1
40.5
39.7
41.6
41.7
29.5
30.9
44.0
28.2
30.7
28.5
18.8
21.1
55.0
40.5
46.6
19.6
12.3
16.0
70.8
56.9
60.5
40.7
39.9
a Fine aggregate: Thames Valley sand, 0-5 mm; coarse aggregate: Chertsey irregular gravel, 5-10 mm; fine:coarse aggregate
ratio = 1: 1.5 by weight.
b Free water content of concretes = 188 kg m -3.
c Lab = 60% relative humidity, 20~ OS = outside, concrete
exposed face sheltered; OV = outside, concrete exposed face
vertical; OH = outside, concrete exposed face horizontal.
286
Parrott
3. RESULTS AND D I S C U S S I O N
Composition (wt%):
SiO2
2.5
A1203
0.3
Fe203
0.1
CaO
54.1
MgO
SO 3
0.04
K 2 0 (total)
Insoluble
residue
LOI
Free lime
Apparent
particle density
(kg m - 3)
SSA (m 2 kg -1)
Residue (%):
45 I~m
150 lam
90 ~_m
0.05
42.5
-
P
(Portland
cement)
A
S
(pulverized (ground
fly ash)
granulated
blastfurnace
slag)
20.3
5.02
3.23
64.8
1.30
2.96
47.7
26.6
9.1
1.7
1.3
0.8
0.86
1.19
3.4
-
1.59
2.06
5.8
-
0.55
-
34.5
12.6
0.6
41.6
6.9
0.81
sulphide
0.68
0.43
2700
3110
2400
2920
1180
395
375
455
8.3
-
0.14
-
7.0
-
11.6
1.9
opc
pfa
ggbfs
Filler
Components by
weight (%)
100% P
70% P + 30% A
50% P + 50% S
95% P + 5% F
Class
CEI
CEIV ~
CEIII
CEI
42.5R
32.5R
42.5
42.5R
A
tN
287
w/0-0.83,
opt
3 d c u r e , lab
9
w/c-0.59,
pfa
l d c u r e , lab
.Q
w/c=0.59,
opt
l d c u r e , lab
Q
(n
.Q
(. 3
w/c'0.59,
opt
3 d c u r e , lab
2
[]
--~1
opt
w/c-0.59,
[]
3d c u r e , o s h e l t
0
0
50
100
150
200
250
300
4 hour absorption
A
(N
24 hour sbsorptlon
~A
==4
A
"t3
O
~3
0
W
..Q
t~
1
O
0.5
1.5
2.5
W a t e r a b s o r b e d after 1 hour ( k g / m 2
1 0 0 % opc
==s
[]
30% pfa
A
50%
ggbfs
[]
o
r- 4
5% limestone
[]
~2
0
W
.Q
[]
,- 1
0
0.3
/k
0
i
0.4
0.5
0.6
0.7
0.8
Free w a t e r / c e m e n t
0.9
ratio by w e i g h t
Fig. 3 Effect of water/cement ratio and cement type upon water absorption after 1.5 years of laboratory exposure (3 days moist
curing).
288
Parrott
2
(XX~
(XX)<
~XX~
~'XX)<
1.5
~/
" /
,,,xx~ k54,x-~
1
0.5
0
KXXN
//.",
KXXN
, /
,vvv
;.'" ." ; ." ]
K./VvN~
KXX~
///-'
, / / /
x;z;z: Kxx~
0
Q.
0
O.
0
Q.
0
"~
0
ID.
,-
>
|
"l~
-~
~
"J
~
0
|
"0
....
//'/i,
, / /,,
CA
.-
el
/ /
to
Q
eO
Q
cO
~L.
6
e,
...i
Exposure condition
Fig. 4 Effect of exposure condition upon water absorption after 1.5 years of exposure (3 days moist curing, 0.59 water/cement ratio).
Table 4 Effects of curing and Portland cement replacement
upon water absorption (kg m-2) after 1.5 years of laboratory
exposure and wetting for various times (0.59 water/cement
ratio)
Moist
100% opc
30% pfa
50% ggbfs
cure
(days)
lh
4h
24h
lh
4h
24h
lh
4h
24h
1
3
28
O4
289
o p t , lab
0
[]
pfa, lab
v
m
ggbf=, lab
[]
o
4
r-
l i m e s t o n e , lab
0
-=3
v,.
[]
"O
O
==2
0
m
..Q
~- I
o
A
v
Ii
0.5
15
2.5
W e i g h t loss in f i r s t 4 d a y s of e x p o s u r e ( % )
Fig. 5 Water absorption after 1.5 years of exposure versus weight loss during initial exposure.
o p t , lab
,, 5
to-
[]
pfa, lab
g g b f s , lab
A
[]
l i m e s t o n e , lab
O
[]
--
All c e m e n t s , o u t s i d e
[]
ID
~2
O
w
[]
AN
9 9
O []
0
o
10
20
30
40
50
60
C u b e s t r e n g t h at s t a r t of e x p o s u r e ( M P a )
Fig. 6 Water absorption after 1.5 years of exposure versus cube strength at start of exposure.
"" 6
opc, lab
0
[]
,,~ 5
pfa, lab
(I)
ggbfsT l a b
[]
o 4
l i m e s t o n e , lab
O
[]
All r
[]
0
~2
0
w
0
[]
'-. 1
99
0
0
J-
15
30
~O
45
0
l
60
/k
[]
O
.L~
75
90
S t r e n g t h of c u b e e x p o s e d 1 5 y e a r s ( M P a )
Fig. 7 Water absorption versus cube strength after 1.5 years of exposure.
outside
290
Parrott
25
0.5 yr r
lab
9
0.5 yr 9
"E 2 0
E
1.5 y r r
outside
lab
_o
r
1.5 yr r
15
outside
(3
(3
10
9
9 Qk
(3
(3(3~
e~
(3
~
0
W a t e r absorbed a f t e r 4 hours ( k g / m 2
Fig. 8 Carbonation depths at 0.5 and 1.5 years versus water absorption after 1.5 years of exposure.
4. C O N C L U S I O N S
The water absorption measurements on various concretes
exposed for 1.5 years under a range of environmental
conditions led to the following conclusions:
1. Water absorption after a given wetting time was
increased with an increase of water/cement ratio, a
reduction of moist curing time and partial replacement
of the Portland component of the cement with pulverized
fuel ash or ground granulated blastfurnace slag.
2. The 4 hour absorption after outdoor exposure was
less than that after laboratory exposure, especially if rain
could fall on the concrete surface.
3. Absorption results correlated approximately with
weight losses during initial exposure and with cube
strengths at the start of exposure for a wide range of
experimental conditions.
4. There was a near-linear relationship between
carbonation depths and absorption meas.ured in cover
concrete after 1.5 years of exposure for a wide range of
experimental conditions, including different exposure
conditions.
ACKNOWLEDGEMENTS
The conscientious assistance with the experimental
measurements of Mr P. Pearson and other technical staff
at BCA is gratefully acknowledged. This work was
supported by The British Cement Association and U K
cement manufacturers.
REFERENCES
29I
Cripwell, J. B., 'A comparison of the properties of OPC,
pfa and ggbs concretes in reinforced concrete tank walls
of slender section', Mag. Concr. Res. 42(152) (1990)
127-134.
19. Gummerson, R. J., Hall, C., Hoff, W., Hawkes, R., Holland,
G. and Moore, W., 'Unsaturated water flow within
porous materials observed by NMR imaging', Nature
281 (6 September 1979) 56-57.
20. Hall, C.r
sorptivity of mortars and concretes: a
review', Mag. Coner. Res. 41(147) (1989) 51-61.
21. Parrott, L. J., 'Measurement and modelling of porosity in
drying cement paste', Mater. Res. Soe. Symp. Proc. 85
(1987) 91-104.
22. Dhir, R. K , Hewlett, P. C. and Chart, Y. N., 'Near-surface
characteristics of concrete: assessment and development
of in situ test methods', Mag. Coner. Res. 39(141) (1987)
183-195.
23. Hudd, R. W., 'The effect of moisture content on in situ
permeability readings', in Proceedings of Workshop on
In Situ Measurement of Concrete Permeability, Loughborough University, December 1989.
24. Parrott, L. J., 'Moisture profiles in drying concrete', Adv.
Cement Res. 1(3) (1988) 164-170.
25. Idem, 'Characteristics of surface layers that affect the
durability of concrete', in Proceedings of Engineering
Foundation Conference on Advances in Cement Manufacture and Use, Potosi, July 1988, pp. 137-142.
26. Kropp, J. and Hilsdorf, H. K., 'Influence of carbonation
on the structure of hardened cement paste and water
transport', in Proceedings of International Colloquium
on Materials Science and Restoration, Esslingen, 1983,
pp. 153-157.
27. British Standard 1881: Part 5: 197, 6, 'Test for determining
the initial surface absorption of concrete' (British
Standards Institution, 1970) pp. 27-35.
28. RILEM Technical Committee 14-CPC Recommendation
No. 11.2, 'Absorption of water by capillarity', Mater.
Struct. 7(40) (1974) 295-297.
29. CEN Draft Standard, prENV 197, ' C e m e n t - Composition,
Specifications and Conformity' (June 1989).
30. Parrott, L. J., 'Factors influencing relative humidity in
concrete', to be published; also available as BCA Report
PP/525 (British Cement Association, Wexham Springs,
1990).
31. Chart, K. S. and Tan, T. H., 'Water movement and
durability of concrete structures', in Proceedings of
Fourth International Conference on Durability of
Building Materials and Components, Singapore, 1987,
pp. 404-411.
32. Hall, C., Hoff, W. D. and Skeldon, M., 'The sorptivity of
brick: dependence on the initial water content', J. Phys.
D: Appl. Phys. 16 (1983) 1875-80.
33. Millard, S. G., 'Effects of temperature and moisture upon
concrete permeability and resistivity measurements', in
Proceedings of Workshop on In Situ Measurement
of Concrete Permeability, Loughborough University,
December t989.
34. ASTM Committee C-9, 'Evaluating the effectiveness of
materials for curing concrete', Proposed ASTM Test
Method P198, in 'ASTM Standards' (February 1987)
pp. 915-918.
292
RESUME
Absorption d'eau dans le b~ton d'enrobage
On rend compte de mesures de l'absorption d'eau initiale
sur des bdtons exposbs pendant 18 mois en milieu fermb et
en plein air. Aprbs un temps donni d'humidification,
l'absorption d'eau augmentait avec l'accroissement du
rapport eau/ciment, la diminution de la conservation ~ l Ytat
humide et le remplacement partiel du composant de clinker
Parrott