Beruflich Dokumente
Kultur Dokumente
Sedimentation
Filtration
Disinfection
Safe Storage
Chlorine
Chemistry and dosing
Forms
Example application
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Chlorine disinfection
Since 1890s in England, took off in
th
early 20 century
Used in 98% of US utilities
Strong oxidant
Devastates cell wall, DNA, enzymes
Mechanisms not fully understood
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Chlorine speciation
Elemental Chlorine (Cl2 gas)
High Test Hypochlorite (HTH)
Calcium hypochlorite
Sodium hypochlorite (NaOCl) liquid
Electrolytic generation
All generate Free Chlorine
hypochlorous acid (HOCl)
hypochlorite (OCl-)
pKa 7.54
www.cdc.gov/safewater/
Double if turbid
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NaDCC Tablets
Sodium Dichloroisocyanurate
About 60% free chlorine
Reservoir chlorine
Guideline value of 40 mg/L
Easy to use
Source: www.medentech.com
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Viruses
2 30
Bacteria
0.04 0.08
0.01
0.1
10
100
1000
Ct99, mg-min/L
Source: WHO Guidelines for Drinking Water, 4th ed.
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Viruses
2 30
Bacteria
0.04 0.08
0.01
0.1
10
100
1000
Ct99, mg-min/L
Source: WHO Guidelines for Drinking Water, 4th ed.
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Viruses
2 30
Bacteria
0.04 0.08
0.01
0.1
10
100
1000
Ct99, mg-min/L
Source: WHO Guidelines for Drinking Water, 4th ed.
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Disinfection effectiveness
Protozoa 2-5 LRV
Cryptosporidium unaffected
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Combined chlorine
Free chlorine + Ammonia =
Chloramines
Monochloramine
Dichloramine
Trichloramine
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concentrations
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Organic carbon
Trihalomethanes (e.g. chloroform)
Haloacetic acids
Carcinogenic in laboratory animals at high
concentrations
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Other disinfectants
Chloramines
Chlorine dioxide
Ozone
Bromine
Silver
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Challenges
Residual protection
Simple to use
Low cost
Summary
Chlorine is widely used in both
conventional treatment and HWT
A variety of sources, all produce free
chlorine in water
Highly effective against bacteria
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