Beruflich Dokumente
Kultur Dokumente
DOI 10.1007/s10854-012-0720-y
REVIEW
Received: 9 December 2011 / Accepted: 5 April 2012 / Published online: 19 April 2012
Springer Science+Business Media, LLC 2012
123
1 Introduction
Recent years, investigations on lead-free soldering have
been conducted worldwide according to the implementation of the directive on Waste Electrical and Electronic
Equipment (WEEE) and the directive and the Restriction of
the Use of Hazardous Substances in Electrical and Electronic Equipment (RoHS Directive) [13]. Therefore, many
Sn-rich alloy systems have been developed as alternative
candidate lead-free solders, which have attracted much
researches and trial applications in recent years [4]. Among
the various lead-free solder alloy choices as replacements
for conventional SnPb solders, SnAgCu (SAC) alloys are
currently the most popular because of their relatively good
soldering performance, excellent creep resistance, and
thermal fatigue reliability, as well as their compatibility
with current electronic components, meanwhile, SnAg,
SnCu, SnZn et al. are all proposed to replace the SnPb
alloys [5, 6]. However, understanding reliability of leadfree solder joints is still in its infancy compared to traditional SnPb solders, thus, further studies are needed.
Semiconductor packages are exposed to various environments, such as temperature, humidity, dust, shock and
vibration, the main cause for failure of electronic package
is temperature fatigue (55 %) and vibration fatigue (20 %),
in addition, humidity (19 %) and dust (6 %) also contribute
to the failure of electronic devices [7]. Since solder joints
provide the mechanical and electrical interconnect between
the package and the board in the electronic devices, they
are susceptible to failures during thermal cycling [8].
Temperature fluctuations caused by either power consumption or environmental changes, along with the
resulting thermal expansion mismatch between the various
package materials result in deformation stress in packages/
assemblies especially in solder interconnects [9], and
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174
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175
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176
(LTCC) modules with thermo-mechanically enhanced ballgrid-array (BGA) solder joint structure mounted on a
printed wiring board (PWB) was experimentally investigated by thermal cycling tests in the 0100 and
-40125 C temperature ranges [35]. After the thermal
cycling tests were completed, the test modules were
investigated by SEM. The investigation verified that the
primary failure mechanism was solder fatigue cracking in
both (all) test sets. It can also be noticed that the Sn90Pb
sphere joints are deformed whereas the PCSB joints have
retained their initial shape. The degree of deformation of
Sn90Pb solder joints correlated mainly with the magnitude
of the exposed temperature extremes and the joint distance
from the module neutral point. In the milder test condition,
secondary cracks appeared within the PCSB solder joints,
as shown in Fig. 6. Qu [36] found that reveal that the
failures mainly occur in the solderPCB interface in lower
load level based on experiment and simulation, the other
way round, in a higher load level, the cracks are more
possibly formed in solderpackage interface; comparing to
dropping in horizontal direction with package faces down,
the solder joints are much harder to fail when dropping in
vertical direction. An optimal height and smaller pitch of
solder joints lead to lowest SED and best reliability in the
drop test.
The need of ultra-dense and high I/O for integrated circuit
designs has driven the development of flip-chip technologies
in the contemporary electronic packaging industry. For flipchip ball grid array (FCBGA) package assemblies, the solder
interconnections serve as electrical and thermal paths as well
as structural supports [37]. Anand model was used to
establish the constitutive equation of Sn3.0Ag0.5Cu solder
by Zhang and Xue [38], the stress distribution of solder joints
was analyzed with underfill and without it. It is indicated that
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Fig. 7 A schematic of different failure modes for the peel test [40]
177
123
178
123
3 Constitutive models
3.1 Anand model
Anand and Brown et al. [5961] firstly proposed a simple
set of constitutive equations for materials with large, isotropic elastic-viscoplastic deformations but small elastic
deformations. There are two basic features in this Anand
model [62, 63]. First, this model needs no explicit yield
condition and no loading/unloading criterion. The plastic
strain is assumed to take place at all nonzero stress values,
although at low stresses the rate of plastic flow may be
immeasurably small. Second, this model employs a single
scalar as an internal variable to represent the isotropic
resistance to plastic flow offered by the internal state of the
material. For applying the Anand to describe the inelastic
deformation of solders, the physical mechanisms such as
temperature sensitivity, strain hardening, strain rate sensitivity, strain rate, and temperature history effects, etc.
should be taken into account.
179
The averaged isotropic resistance representing the isotropic strengthening mechanisms such as dislocation density, solid solution strengthening, subgrain, and grain size
effects is characterized by the internal variable s, which
depends on the temperature and rate-dependent strain history of the materials [64]. The flow function of the Anand
model is in hyperbolic sine shape:
1=m
nr
Q
e_ P A sinh
exp
1
S
kT
where So, initial value of deformation resistance; Q, activation energy; R, universal gas constant; A, pre-exponential
factor; n, multiplier of stress; m, strain rate sensitivity of
_
stress; ho, hardening/softening constant; s , coefficient for
deformation resistance saturation value; n, strain rate sensitively of saturation (deformation resistance) value; a,
strain rate sensitively of hardening or softening.
Table 1 Material parameters of Anand constitutive relation
Solder alloys
A/s-1
Q/R/J mol-1
Sn3.8Ag0.7Cu [65]
Sn3.8Ag0.7Cu0.03Ce [65]
24300
21200
8710
8026
n
5.8
5
s /MPa
0.183
0.130
65.3
57.6
0.019
0.0175
52.4
Sn3.5Ag [66]
177016
85459
0.207
Sn3.8Ag0.7Cu [67]
15.773
9883
1.0673
0.3686
Sn1.0Ag0.5Cu [67]
3.773
8076
0.9951
0.4454
Sn3.0Ag0.5Cu [68]
717.260
6067
0.130
3.1505
3.5833
29.0
0.0177
0.0352
0.0120
0.0436
ho/MPa
3541.2
4352.6
27782
So/MPa
1.9
2.3
39.5
28.5
1.6
0.0673T ? 28.6
1076.9
1.6832
3.2992
4507.5
2.1669
2.3479
2.22
2.45
14560
Sn3.5Ag [68]
344.716
6538
0.143
26.0
0.0447
23241
1.46
0.65
Sn0.7Cu [68]
764.166
5837
0.123
26.4
0.0430
11656
2.33
4.43
Sn37Pb [69]
6220
6525
3.33
0.27
36.86
0.022
60599
1.7811
3.1522
Sn3.8Ag0.7Cu [70]
107.65
7619
59.36
4.03
86.28
0.0046
9002
1.30
22.64
Sn3.5Ag [71]
52690
8765
0.182
76.944
0.018
7205.18
1.2321
30.36
Sn37Pb [72]
26
5797
10
0.25
83.12
0.043
Sn36Pb2Ag [73]
23000000
11262
11
0.303
80.79
0.0212
Sn3.5Ag [73]
22300
8900
0.182
73.81
0.018
Sn4.0Ag0.5Cu [74]
325
10561
10
0.32
42.1
0.02
Sn3.8Ag0.7Cu [75]
Sn40Pb [76]
2.23
14900000
8900
10830
6
11
0.182
0.303
73.81
80.415
0.018
0.0231
92148
4121.31
3321.15
800000
3321.15
2640.75
37.9
42.32
1.82
39.09
2.57
20
1.82
1.34
39.09
56.33
Sn97.5Pb [77]
3.25E12
15583
0.143
72.73
0.00437
3.73
15.09
Sn3.8Ag0.7Cu [78]
862
15516
25.57
0.55
18.7
0.034
195109
2.02
28.81
Sn8.5Sb [78]
2.23E8
13816.8
13.85
0.417
76.0
0.01
291215
2.34
48.15
Sn92.5Pb2.5Ag [79]
105200
11010
0.241
41.63
0.002
1.3
33.07
1787.02
1.24
1.38
1432
123
180
Garofalo-Arrhenius model:
Q
n
e_ cr C sinhar exp
RT
Dorn model:
Q
e_ cr Arn exp
RT
(a)
(b)
123
181
Solder alloys
C2(1/MPa)
C3
C4(K)
Sn1.3Ag0.2Cu0.05Ni [86]
8E ? 5
0.1
9020
Sn1.3Ag0.5Cu0.05Ni [86]
6E ? 4
0.11
8419
Sn2.7Ag0.4Cu0.05Ni [86]
2E ? 7
0.143
12026
Sn80Au [87]
4.62E ? 15
2E-5
2.07
12267
Sn3.5Ag0.7Cu [88]
4.61E ? 6
0.037
6.17
8400
Sn3.8Ag0.7Cu [17]
926(508-T)/T
(37.78 9 106-74414T)-1
3.3
6360
Sn3.5Ag [89]
98437
0.103
6.65
9561
Sn5Sb [89]
42409
0.04
4.5
6542
Sn9Zn [89]
81524
0.06
4.57
7841
Sn3.0Ag0.5Cu [90]
6.385E-6
0.08638
5.84
Sn3.8Ag0.7Cu [91]
Sn3.8Ag0.7Cu [92]
3.2E ? 4
441000
0.037
5E-9
5.1
4.2
159.97
6524
5412
Sn3.9Ag0.6Cu [93]
500000
0.01
5802
Sn3.5Ag [94]
18(553-T)/T
145.036 9 [1/(6386-11.55T)]
5.5
5802
Sn3.9Ag0.6Cu [95]
441000
0.005
4.2
5412
Sn36Pb2Ag [95]
462(508-T)/T
145.036 9 [1/(5478-10.79T)]
3.3
6360
100In [94]
40647(593-T)/T
145.036 9 [1/(274-0.47T)]
8356
Sn3.8Ag0.7Cu [96]
325000
0.05217
5.3
5800
SnAgCu0.03Ce [96]
284000
0.02432
6.1
6400
Sn3.5Ag [97]
900000
0.0653
5.5
8690
Sn37Pb [98]
10
0.2
5400
C1(1/s)
C2
C3(K)
12267
Sn80Au [87]
8.37E ? 5
2.07
Sn3.8Ag0.7Cu [95]
2.6E-5
3.69
4330.046
Sn3.8Ag0.7Cu [96]
1.5E-9
8.2
8538.78
Sn3.8Ag0.7Cu0.03Ce [96]
6.2E-11
8.0
9621.17
Sn3.5Ag [98]
5E-6
11
1179
Sn4.0Ag0.5Cu [98]
2E-21
18
9994
Sn3.5Ag [99]
7.087E-8
5.5
Sn3.5Ag [100]
6.62E-3
12
13048.7
Sn9Zn [100]
9.27
8.1
12014.4
Sn3.5Ag2Bi [101]
0.679
3.304
4630.186
7357.907
123
182
123
11
183
!1=c
12
123
184
NO K1 DWave K2
da
K3 DWave K4
dN
a
Nf No
da=dN
Nf C0 eacc
15
Nf W 0 wacc
16
123
1
14
18
1
19
20
21
22
23
b
c
s0f
Dcmax
o
S_ec
2Nf o c0f 2Nf o
r
2
G
185
24
where Dcmax is the maximum shear strain range, e_ r is saturation of ratcheting strain rate, co is the shear fatigue
ductility exponent, and S is a material constant that can be
determined by uniaxial ratchetingfatigue tests.
A fatigue life prediction methodology was developed by
Pierce [144], based on stress-strain, creep, and isothermal
fatigue data. The proposed fatigue life prediction methodology builds on current practices in fatigue prediction for
solder alloys, particularly the concepts of unpartitioned
energy methods in finite element analysis (FEA) and continuum damage mechanics.
pl
da
dNi
ZWf
W1pl
i
NCS;f
X da
da
pl
T;
a
dW
T;
a
DWjpl
pl
dW pl
dW
i
j
jN
CS;1
25
where da=dNi is the crack growth rate per cycle for the ith
cycle. Increments of plastic work are integrated from the
initial viscoplastic work of the ith cycle, W1pl , to the final
viscoplastic work of the same cycle, Wfpl . On the right hand
side is the numerical implementation of the crack growth
rate per cycle. The summation for this numerical estimate
is done from the first converged substep of the ith cycle,
i
i
NCS;1
, to the final converged substep of the ith cycle, NCS;f
.
Nozaki [145] studies the creepfatigue life evaluation of
Sn3.5Ag solder under push-pull loading using fast-fast,
fast-slow, slow-fast, slow-slow, and strain-hold strain
waves. The grain boundary sliding model (GBSM)
assumed that the grain boundary sliding rate is proportional
to the creepfatigue damage rate, so cycles to failure in any
strain wave (Nf ) is related to cycles to failure in respective
strain waves by
1
1
1
1
1
26
Npc Ncp Ncc Nth Nf
ln 0:5
DT ATC
2
1
0
1414
B
@e
1
1
T ATC 383
peak
C
A 12476 0:241A 719:9B
Weibull
AF
N 50
DT, temperature range (K); f, frequency (cph); Tpeak ,
peak temperature (K); F%, failure percentage, 0 \ F%
\ 100 %; c, shape parameter, 411 for CBGA; uWeibull ,
estimated uncertainty of the Weibull factor; uAF , estimated
uncertainty of the AF factor; uN 50 , estimated uncertainty
of N50 regression equation.
A new and simple empirical equation for predicting the
thermal-fatigue life of solder bumped flip chip on low-cost
PCB has been presented by Lau [147].
da
C1 10C2 C3 C1 C4 C4 =C1 C3 DW C1 1=C1 C3
dN
29
5 Conclusion
Miniaturization and high levels circuit integration are
driving forces for surface mount technology (SMT) devices
in finer pitches, higher speed, and greater packaging density. However, the reliability of solder joints has been
became a serious concern because solder joints in electronics components provide not only the mechanical
attachments but also electrical connections were investigated systematically. In addition, the transition for leadfree solder and lead-free process will bring many new
reliability problems, especially for the constitutive relation
models and fatigue life prediction equation. Upon
increasing to the concentration further, until now there are
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186
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