Alkyl halide

DATE.28/09/2014
marks.120
1.

2.

(b)

A chloroderivative X on treatment
with Zn and HCl gave a hydrocarbon
with five carbon atoms in the molecule
when X is dissolved in ether and
treated with Na,2,2,5,5-tetra methyl
hexane is obtained. The compound X is

An alkyl halide of formula C6H13Cl on

treatment with potassium t-butoxide
gives two isomeric alkenes (C6H12).
Both alkenes on hydrogenation give
2,2, dimethyl butane. Isomeric alkenes
are
H3C

(b)
H3C

H3C

CH3

CH3

OH
CH3

(d)

CH3
H3C

CH3

OH

hydrolysis
KCN
5.
C2H5Br
B. The
A
compound (b) in above reaction is:

H3C
and

H2C

CH3

CH3

H3C

CH3

and
H3C

CH3
CH3

H3C
CH3
and

H2C

H2C

Br

NaNH 2
i) alc. KOH

A
B. A and B
ii) NaNH
CH CH Cl
2

Br

CH2

(a)Ethylenechloride

(b) Ac

(c)Propionic acid

(d) Et

PI3
Hydrolysis
KCN
6.
CH3OH
A
B

C. The compound C is

(aCH3OH

(b) HCOOH

(c)CH3CHO

(d) CH3COOH

7.
1chlorobutane
alcoholic KOH gives

CH3

CH3

(a)

CH3

CH3

3.

CH3

CH3

(c)

H3C

and

H2C

OH

OH

CH3

CH3

H3C

(a)

CH3

H3C CH3
(d) 2-chloro-2-methyl
butane

CH3

(d)

None of these

(c) 1-chloro 2,2,dimethyl propane

H3C

(c)

CH

On treatment with aqueous KOH gives

(b) 1-chloropropane
4.

CH3

(b)

(d)

CH

CH3

(a) 3-chloro 2,2, - dimethyl propane

H3C

(a)

(c)

CH2

CH3

on

reduction

(a)1butene

(b) 1butanol

(c)2butene

(d) 2butanol

8.
For a given alkyl group,
densities/b.pt./m.pt. are in the order

with

the

(a)RIRBrRCl

(b) RIRCIRBr

(c)RBrRIRCl

(d) RCl RBr RI

9.
The product obtained by reduction of
Benzyl bromide with LiAIH4 is

16.
Which of the following compound will
be least reactive towards NaOH.

Br

Br

(a)

(b)
CH3

(a) CH3Cl

CH3

(c)

(d)

Cl

(b)

CH3

(c)

10.
3-methyl -2-pentene on reaction with
HOCl gives

(d)
H3C

H3C

Cl

(a)3-chloro-3-methylpentanol-

11.

(b) 2,3-dichloro-3-methyl pentane

17.
An organic compound X(C4H9Br) on
treatment
with alc. KOH gave isomeric
(c) 2-chloro-3-methyl pentanol (d) 2,3-dimethyl
butanol
product with the formula C4H8. On
When ethanol and KI reacted in
ozonolysis one of these gave only
presence of Na2CO3, the yellow
product CH3CHO while the other gave
precipitate obtained was that of
two different products. The compound
X
(a)CH3I
(b) CHI3
(c)CH2I2

12.

(d) C2H5I

(a) 2-Bromobutane (b) 2-bromopentane

(c) 1,2 dibromo butane (d) 3-Bromopentene

The reaction,

Alcohol + HCl
Alkyl halide + H2O
is reversible. For the completion of the
forward reaction is used.

18.
n-butane reacts with Br2 at 130C to
give more amount of
Br

(a)
(b)
(b) concentrated
HCH
2SO4
H C

(a) anhydrous zinc chloride

Br

CH

(c) excess of water

13.

H3C

3
(d) Calcium
H3Cchloride
(c)
Br

The reaction

(d) all in equal amounts

H3C

19.
Cl
H3C

H3C
KOH

( aq )

CH3

OH

Cl- is an example of

H3C

(a)Reduction

(b) Oxidation

(c)isopropyl alcohol (d) n-propyl alcohol

(d) Nucleophilic substitution

(c)Neutralisation
14.

20.

In the reaction
X
C6 H 5 NH 2
C6 H 5 NC ,

Which of the following alcohols cant

be prepared by the action of a suitable
Grignard reagent on an aldehyde or
ketone followed by hydrolysis.
(a) Ethyl alcohol (b) Methanol

H3C

The reaction

OH

the

reagent `x is
(a)Br2 in chloroform (b)KOH in chloroform
(c)KCN in alkali
(d) KCN in chloroform.
15.
Alkyl halide reacts with an alcoholic
solution of ammonia to give a mixture of:

Br

(a)

Br
OH
(b

H3C

Br
H3C

OH

(c)

H3C
Br

(d
)

Br
H3C

(a)1 and 2 amine (b) 1, 2, 3 & quaternary

(c)1, 2 & 3 amines (d) 1 & 3 amine

with HBr gives

21.

Cl
+

i) H , H 2O
CuCN

A
B. B is
475K
ii) NaOH/CaO

Br

(b
)

NH2

(a)

OH

(c)
22.

Cl

Benzal chloride on hydrolysis gives

(b)Benzoicacid
(c)Benzaldehyde
(d)Benzotrialcohol

A
Br2 / FeBr3

30.

then the major product A is

CH3

CH3
Br

(b)
CH3

CH3

+
Br
50%

Br

50%

24.
Ethylidene chloride reacts with KOH
and gives
glycol

(b) HCHO
(d) none

25.
-phenyl ethyl chloride is the minor
product obtained by reaction of chlorine with
CH2

(a)

CH3

(b)
H

CH3
H3C

(c)

(b) bu

(c) butal chloride with KCN

(d) pr

halides

in

(a) Halide exchange

(b) Di

(c) Treatment of alcohols

(d) Ad

(a) Wurtz reaction

(b) Ko

(c) Cannizzaros reaction

(d) Fr

A mixture of ethyl iodide and n-propyl

iodide is subjected to Wurtz reaction.
Which of the following compounds is
not formed during the reaction ?
(c) Pentane (d)

CH3
Br

(d)

(a)ethylene
(c)ethanal

(a) propyl alcohol with KCN

(a) Butane
Br

(c)

(d) et

29.
Formation of alkane by the action of
Zn on alkyl halide is called

CH3

(a)

(c)ethyne

28.
Preparation of alkyl
laboratory is least preferred by

(a)Benzylalcohol

23.

(b) et

27.
Butane nitrile may be prepared by
heating

(d
)

(a)ethane

CH3

(d)

26.
One of the product of reaction of
alcoholic AgNO2 with ethyl bromide are

(b)Propane

Hexan

Key
1.

(c)

2.

(a)

28.

(b)

29.

(d)
30.

3.

(b)

4.

(c)

5.

(c)

6.

(d)

7.

(c)

8.

(d)

9.

(c)

10.

(c)

11.

(b)

12.

(a)

13.

(d)

14.

(b)

15.

(b)

16.

(c)

17.

(a)

18.

(a)

19.

(b)

20.

(c)

21.

(c)

22.

(b)

23.

(c)

24.

(a)

25.

(b)

26.

(d)

27.

(d)

(b)