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Printing date 23.02.2012

Safety data sheet

according to 1907/2006/EC, Article 31

Version number 3

Revision: 23.02.2012

1 Identification of the substance/mixture and of the company/undertaking

Product identifier

Trade name: calgonit Poly-Safe

Relevant identified uses of the substance or mixture and uses advised against Application of the substance / the preparation Product is for professional use only. Cleaning material/ Detergent

Details of the supplier of the safety data sheet Manufacturer/Supplier:

Calvatis GmbH, D-68526 Ladenburg, Dr. Albert-Reimann-Str. 16 a Tel.: +49(0)6203-105 0, Fax: +49(0)6203-105 111

Calvatis GmbH, A-4600 Wels, Kaiser-Josef-Platz 41 Tel.: +43(0)7242-42899 0, Fax: +43(0)7242-42899 22

Homepage: www.calvatis.com

Informing department:

Calvatis GmbH Germany, Laboratory, Tel.: +49(0)6203-105 190

Sicherheitsdatenblatt@calvatis.com Emergency telephone number:

Calvatis GmbH Germany, Tel.: +49 (0) 6203 105-200 This telephone number is attainable Monday to Friday 9.00 a.m to 15.00 p.m.

2 Hazards identification

Classification of the substance or mixture

Classification according to Directive 67/548/EEC or Directive 1999/45/EC

Classification system:

The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information furnished by supplier companies.

Label elements

Code letter and hazard designation of product:

elements Code letter and hazard designation of product: Xi Irritant Risk phrases: 36 Irritating to eyes.

Xi Irritant

Risk phrases:

36 Irritating to eyes.

Safety phrases:

26

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

39

Wear eye/face protection.

45

In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

Classification in accordance with Directive 75/324/EEC:

5 - 15 % : Phosphonates (as P) 5 % : EDTA Other hazards

Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable.

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3 Composition/information on ingredients Chemical characterization: Mixtures Solution of complexing agent and dispersants
3 Composition/information on ingredients
Chemical characterization: Mixtures Solution of complexing agent and dispersants in water.
Hazardous components:
CAS
EC
%
Sign
R-phrases
--------------------------------------------------------------------------------------------------
(Contd. on page 2)
GB

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Page 2/5

Printing date 23.02.2012

Safety data sheet

according to 1907/2006/EC, Article 31

Version number 3

Revision: 23.02.2012

Trade name: calgonit Poly-Safe

(Contd. of page 1)

phosphonate

15827-60-8

239-931-4

5 - 15

Xi

36

EDTA (40%)

64-02-8

200-573-9

5 - 15

Xi

20 - 36

sodium carbonate

 

497-19-8

207-838-8

1

-

5

Xi

36

Additional information For the wording of the listed risk phrases refer to section 16.

4 First aid measures

Description of first aid measures General information Remove soiled clothing. After skin contact Wash with water and soap. After eye contact Rinse opened eye for several minutes under running water. After swallowing Rinse out mouth and then drink plenty of water. Seek medical treatment. Information for doctor Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available.

5 Firefighting measures

Extinguishing media Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. Use fire fighting measures that suit the environment. Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment:

Wear personal protection equipment. Wear self-contained breathing apparatus. Additional information Product is not combustible.

6 Accidental release measures

Personal precautions, protective equipment and emergency procedures No special measures required. Environmental precautions: Do not allow product to reach sewage systems or water bodies in great quantities. Methods and material for containment and cleaning up:

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal.

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7 Handling and storage

Handling Precautions for safe handling No special measures required. Information about protection against explosions and fires: No special measures required.

Conditions for safe storage, including any incompatibilities Storage Requirements to be met by storerooms and containers: No special requirements. Further information about storage conditions:

Protect from frost. Keep container tightly sealed. Storage class VCI (Version 07/98): LGK 12 Specific end use(s) No further relevant information available.

GB

(Contd. on page 3)

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Printing date 23.02.2012

Safety data sheet

according to 1907/2006/EC, Article 31

Version number 3

Revision: 23.02.2012

Trade name: calgonit Poly-Safe

(Contd. of page 2)

8 Exposure controls/personal protection

Control parameters Components with limit values that require monitoring at the workplace:

The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: The lists that were valid during the compilation were used as basis.

Exposure controls Personal protective equipment General protective and hygienic measures Remove soiled clothing. Keep away from foodstuffs, beverages and food. Take off immediately all contaminated clothing Avoid contact with the eyes. Breathing equipment: Not required. Protection of hands:

Protectiv gloves recommended. Chemical protection gloves from butyl rubber or nitrile rubber of the category III in accordance with EN 374. Consider the data of the manufacturers at the permeability and break-through times as well as the special conditions on the job (mechanical load, contact duration). The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Material of gloves Protection gloves from butyl rubber or nitrile rubber. The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed safety glasses. Body protection: Protective clothes recommendable

9 Physical and chemical properties Information on basic physical and chemical properties General Information
9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form:
Fluid
Colour:
Colourless
Odour:
Nearly odourless
Odour threshold:
Not determined.
pH-value (10 g/l) at 20°C:
10.6
Change in condition
Boiling point/Boiling range:
> 100°C
Crystallisation temperature / range: 0°C
Flash point:
Not applicable
Inflammability (solid, gaseous)
Not applicable.
Self-inflammability:
Product is not selfigniting.
Critical values for explosion:
Oxidizing properties
no
Density at 20°C
1.12 g/cm3
Solubility in / Miscibility with
Water:
Other information
Fully miscible
No further relevant information available.

GB

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(Contd. on page 4)

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Printing date 23.02.2012

Safety data sheet

according to 1907/2006/EC, Article 31

Version number 3

Revision: 23.02.2012

Trade name: calgonit Poly-Safe

(Contd. of page 3)

10 Stability and reactivity

Reactivity Chemical stability Thermal decomposition / conditions to be avoided:

No decomposition if used and stored according to specifications. Possibility of hazardous reactions No dangerous reactions known Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information

Information on toxicological effects Acute toxicity: No data for the preparation available. Primary irritant effect:

on the skin: Generally not irritant. on the eye:

Contact with eyes may cause irritation. Irritant effect. Sensitization: No sensitizing effect known. Additional toxicological information:

The toxicological evaluation of the preparation took place in accordance with computation methods after GefStoffV / European Union preparing guideline.

12 Ecological information

Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Behaviour in environmental systems:

Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information:

COD-value: 68 g O2/kg product General notes:

If diluted solutions are properly feeded into biological purification plants no decline of the degradation activity is expected. During the introduction sourly or alkaline products in sewage systems it is to be made certain that the introduced waste water does not under and/or exceeds pH range of 6-10, since by pH shift disturbances in sewers and biological purification plants can occur. Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable. Other adverse effects No further relevant information available.

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13 Disposal considerations

Waste treatment methods Recommendation Must be specially treated with regard to official regulations. Waste disposal key number:

Corresponding to the regulation of the European Waste catalogue the relation of the waste key numbers has to be made specific to industry and process. European waste catalogue Corresponding to the regulation of the EWC the relation of the waste key numbers has to be made specific to industry and process.

Uncleaned packagings:

Contaminated packages must be completely emptied and may be reused after proper cleaning. Recommendation: Disposal must be made according to official regulations.

GB

(Contd. on page 5)

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Safety data sheet

according to 1907/2006/EC, Article 31

Printing date 23.02.2012

Version number 3

Revision: 23.02.2012

Trade name: calgonit Poly-Safe

 

(Contd. of page 4)

14 Transport information

UN-Number ADR, ADN, IMDG, IATA

Void

UN proper shipping name ADR, ADN, IMDG, IATA

Void

Transport hazard class(es)

ADR, ADN, IMDG, IATA Class

Void

Packing group ADR, IMDG, IATA

Void

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

15 Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

Designation according to EC guidelines:

The product has been labelled in accordance with EC Directives/relevant national laws.

Code letter and hazard designation of product:

laws. Code letter and hazard designation of product: Xi Irritant Risk phrases: 36 Irritating to eyes.

Xi Irritant

Risk phrases:

36 Irritating to eyes.

Safety phrases:

26

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

39

Wear eye/face protection.

45

In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

National regulations

Water hazard class (Germany): Water hazard class 2 (Self-assessment): hazardous for water.

Other regulations, limitations and prohibitive regulations Substances of very high concern (SVHC) according to REACH, Article 57 The product contains no substances from SVHC list. Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information The above information is based on our present knowledge about the product.
16 Other information
The above information is based on our present knowledge about the product. It does not guarantee specific
product features.
Relevant phrases
R 20
R 36
Harmful by inhalation.
Irritation to eyes.
Department issuing data specification sheet: Calvatis GmbH Germany, Laboratory
Contact: Labor
Reference to modifications:
Please take notice of the changes made in compare to the last version in the following sections: 2
Abbreviations and acronyms:
Sources KC-745863f
GB

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