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Overview
Current process
New process
Economic comparison
Water removal
Removes free liquid water
refinery
The water goes to waste
quantities of gas
Solvent absorbs the sour gas
Sulfolane is used
used
Gas and material go
under high pressure
Material adsorbs the gas
( H2S, mercaptans, CO2)
Disadvantages
Requires high pressures
Slow cycle times
Mercury removal
Current Processes
Activated carbon through chemisorption. Activated
has extremely high surface area
Nitrogen Rejection
Processes that can reject
nitrogen
Cryogenic process
as nitrogen
Disadvantages
Must reach extremely low temperatures
Only useful for large scale production
permeability
P Dk
D = diffusion coefficient (cm2/s)
k = Henrys law sorption
coefficient (cm3/cm3cmHg)
P1
P2
P1 = Permeability of component 1
P2 = Permeability of component 2
Demethanizer
Demethanizer
The next step is to recover
the NGLs
Process
Cryogenics using a turboexpander can be used
used here
NGL recovery
NGL recovery
Now the rest of the
Process
Each sent to a
distillation column
Sweetening NGLs
Merox Processes
Mercaptan oxidation
Removes mercaptans from
Propane
Butane
Larger hydrocarbons
Novel Method
Technical information
compared
Novel Method
Advantage
More cost effective than any previous methods
Less environmental impacts than previous methods
Separates all contaminants
Separates each component
Everything is done using one process
Novel Method
Current Method
Description
4.88 meters tall, 2,02 meters in diameter
6.71 meters tall, 3.60 meters in diamter
530 square meters
615 square meters
38,000 gallon flow, 235 psi rise
Price ($)
$23,000
$58,000
$59,000
$69,000
$68,000
$277,000
Operating Costs
Utilities
Cooling Water
column reboiler
Pump
Total
Price ($/hr)
19,800 gallons/hr ($0.08/1000kg)
139 million BTU/hr ($6 per million BTU)
97.53 Kw ($0.06/Kw)
$5.98
$834
$5.85
$845.83
Economics - Demethanizer
Equipment
Column
Heat exchanger 1
Heat exchanger 2
Heat exchanger 3
Heat exchanger 4
Heat exchanger 5
Heat exchanger 6
Heat exchanger 7
Refrigerant
Expander
Compressor
Compressor 2
Compressor 3
Pump
Total
Cost of Equipment
Description
Price
Diamter of 1.53 meters, Height of 8.54 meters
Area of 1055 square meters
Area of 15.6square meters
Area of 113.12 square meters
Area of 25.2 square meters
Area of 261.7 square meters
Area of 6.8 square meters
Area of 11.5 square meters
For a 10 year period
1200 KW output
Compresseing to pressure of inlet for deethanization
Bringing methane back to pipeline pressure
$25,000
$118,287
$1,874
$12,796
$2,953
$29,440
$890
$1,417
$880,000
$370,000
$50,000
$190,000
$640,000
$3,000
$2,325,657
Operating Costs
Utility
Cooling water
Electricity
Total
Price ($/hr)
$1.17
$116.25
$117.42
Demthanizer - Simulation
Economics - Dethanizer
Cost of Equipment
Equipment
Column
Price
$32,000
Operating Costs
Utility
Reboiler
Price
(8 million Btu's needed, 6 dollars/million BTU)
$48
Deethanizer - Simulation
Economics
Current
A
B-best
100% C-worst
Current
A
B-best
70% C-worst
Built in Error
Novel Method - Error for the Worse
Equipment Costs
$16,800,000
Operating Costs
$435/hr
Current Process
Equipment Costs
$3,441,657
Operating Costs
$1,011/hr