Ch-1[mcq]

Sem:2
1.
The force which holds atoms together in an electrovalent bond is
(a)Vander Waal's force
(b)
Dipole attraction force
(c)Electrostatic force of attraction (d)
All the above
2.
Ionic compounds do not have
[RPMT 1997]
(a)
Hard and brittle nature
(b)
High melting and boiling point
(c)
Directional properties
(d)
Soluble in polar solvents
3.
The bond order of NO molecule is
a) 1.5
b) 2.0 c) 2.5 d) 3.0
4.
Anti-bonding molecular orbital is formed by
a) Addition of wave functions of atomic orbitals
b) Substration of wave functions of atomic orbitals
c) Multiplication of wave functions of atomic orbitals
d) None of these
5.
Amongst ClF3 , NH3 and BF3 molecules the one with non-planar geometry is
a) ClF3
b) NH3 c) BF3 d)None of these
6.
Which one in the following is not the resonance structure of
7.

8.

9.

10.

11.
12.

13.
14.
15.

16.
17.
18.

19.

Marks: 25
Time :40 min

a) O=C=O
b) O C O c) O C O d) O C O
Resonance is due to
a) Delocalization of sigma electrons
b) Delocalization of pi electrons
c) Migration of H atoms
d) Migration of protons
Resonating structures have different
a) Atomic arrangements b)Electronic arrangements
c) Functional groups
d) Alkyl groups
Which of the following statement is correct?
(a). Energy difference should be more between orbitals which undergo hybridization.
(b). Number of hybrid orbitals formed should be same as the number of atomic orbitals involved in
hybridization
(c). Hybrid orbitals arrange around the center of the atom unsymmetrically
(d). Hybrid orbitals can form bonds
Which one of the following is an incorrect statement
1.
(a)A pi bond is formed when a sigma already exists
(b). A pi bond may be formed by the overlapping of p or d orbitals
(c). A pi bond is formed by the overlapping of
hybrid orbitals
(d). A pi bond is formed by the lateral
overlapping of atomic orbitals
If the electron pair forming a bond between two atoms A and B is not in the centre, then the bond is
(a). Single bond (b).Polar covalent bond (c). Non-polar bond
(d). pi-bond
Highly ionic compound is formed by the combination of elements belonging to
(a). I A group and VII A gruop
(b). II A group VI A group
(c). III A group and V A group
(d). O group and VII A group
Molecule which contains 4 bonded pairs and 2 lone pairs of electrons on the central atom is
(a). XeF2 (b). CO2
(c). XeF4
(d). SF6
Molecule having maximum number of lone pairs of electrons on central atom is
(a). PH3 (b). H2S (c). CH4 (d). BrF5
A bond with maximum covalent character between non-metallic elements is formed
(a). between atoms of same size
(b). between identical atoms
(c). between chemically similar atoms
(d). between atoms which widely differ in their electronegativities
Pick up the molecule which has zero dipole moment
(a). NH3 (b). H2O
(c). BCI3
(d). SO2
The angle between two covalent bonds is maximum in
(a). H2O (b). CO2
(c) NH3 (d). CH4
Which of the following exists as a liquid at room temperature due to the formation of associated molecules
only
(a). Benzene
(b). Ammonia (c)Bromine
(d). Carbon disulphide
The types of bonds present in CuSO4. 5H2O are
(a). Electrovalent and covalent
(b) Electrovalent and co-ordinate covalent
(c). Electrovalent, covalent and co-ordinate covalent (d). Covalent and co-ordinate covalent

20.

21.
22.

23.
24.

25.

Strength of hydrogen bond is intermediate between

(a). Vander Waal forces and covalent bond
(b). Ionic bond and covalent bond
(c). Ionic bond and metallic bonding
(d) Resonance
The strongest hydrogen bond is present in
(a). H - F ....... H - F (b). H - O ....... H - O
(c). H - Cl ..... H - Cl
(d). H - N ....... H N
Water is a liquid while hydrogen sulphide is a gas because
(a). Water has higher molecular weight
(b). Hydrogen sulphide is a weak acid
(c). Sulphur has high electronegativity than oxygen
(d). Water molecules associate through hydrogen bonding
Generally Pi bond is formed from the lateral overlap of
(a). s-s orbitals
(b). p-p orbitals (c). d-d orbitals (d). both 2 and 3
Kossel - Lewis theory is based on
(a) JJ Thomsons atomic model
(b) Rutherfords atomic model
(c) Bohrs atomic model (d) Heisenbergs uncertainity principle

In which of the following ionization processes, the bond order has increased and the magnetic
behaviour has changed?
(a) N 2 N 2 (b) C2 C2 (c) NO NO
(d) O2 O2