Beruflich Dokumente
Kultur Dokumente
Atmospheric Environment
journal homepage: www.elsevier.com/locate/atmosenv
National Lab of Auto Performance and Emission Test, School of Mechanical and Vehicular Engineering, Beijing Institute of Technology,
Beijing 100081, China
b
Vehicle Emission Control Center, Ministry of Environmental Protection, Beijing 100012, China
c
Beijing Automotive Research Institute Co., Ltd., Beijing 100079, China
h i g h l i g h t s
Distance-based and fuel-based emission factors of gaseous and PM from 7 inland ships were measured using PEMS.
Average distance-based emission factors of CO, HC and PM for manoeuvring mode are higher than those for cruise mode.
NOx in this study is nearly twice of estimated Tier 1 standard limit (in unit of g kg1 fuel).
Distance-based emission factors of four pollutants are higher with the increase of engine loads.
a r t i c l e i n f o
a b s t r a c t
Article history:
Received 17 December 2012
Received in revised form
21 August 2013
Accepted 24 August 2013
Ship emissions are widely recognized as a relevant source of the total air pollution and have a remarkable
impact on air quality of the sea, territorial waters and coastal areas. To assess this impact, various
emission models have been developed to calculate the emission inventory of ship based on ship activity
data. However, few studies in China have collected the emission factors of local ship which are decisive
factors in accurate assessment of ship emission inventory. This study intends to obtain emission data of
inland ships on the Grand Canal of China by conducting on-board emission tests. We measured CO, HC
NOx and PM emission from 7 inland ships of different engine powers, and derive distance-based and fuelbased emission factors on the basis of the cruise and manoeuvring (including port departure and port
arrival) operating modes. The results show that average distance-based emission factors of CO, HC and
PM for manoeuvring mode are higher than those for cruise mode. For NOx, average distance-based
emission factors for cruise mode are higher than those for port arrival mode but lower than those for
port departure mode. Particular number (PN) distribution analysis indicates that larger amounts of small
size PM (Dp < 0.01 mm) appeared on manoeuvring mode, which can affect regional air quality and human
health. The average fuel-based emission factor of NOx in this study is 1.4e4.3 times higher than those in
on-board studies. When compared with estimated Tier 1 standard limit (in unit of g kg1 fuel), NOx in
this study is nearly twice of Tier 1. The higher NOx emission indicates that stricter emission strategies and
policies should be implemented to control ship emission in China. It is noticeable that distance-based
emission factors of four pollutants are higher with the increase of engine loads.
Crown Copyright 2013 Published by Elsevier Ltd. All rights reserved.
Keywords:
Inland ships
Emission factors
PEMS
Operating modes
1. Introduction
With the rapid growth of water-borne commerce, marine activities, particularly those in Asia, have risen dramatically over the
past decade (Yau et al., 2012; Streets et al., 2000). However, various
research studies which attempt the estimation of global emissions
from shipping indicate that ship emission is one important source
of the total air pollution worldwide (Poplawski et al., 2011; Marmer
* Corresponding author. Tel.: 86 138 1097 1063; fax: 86 10 6891 2035.
E-mail address: fumingliang160@163.com (M. Fu).
1352-2310/$ e see front matter Crown Copyright 2013 Published by Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.atmosenv.2013.08.046
Numerous studies on the evaluation of the impact of atmospheric shipping emissions on air quality at the local scale and on
climate at the regional scale have been reported in literature over
the last decade. Some studies have focused on emission measurements for ships and the estimation of the magnitude of shipping
emissions to the atmosphere. Van der Zee et al. (2012) by measured
Nitrogen oxides (NO and NO2) and ultrane particles (particle
number (PN) concentration) at ve measuring sites in Amsterdam,
illustrate that ship exhausts have an impact on air quality near
houses along waterways. Other works have addressed the characterization of emissions from ships and their impact of ports on
adjacent urban areas by means of dispersion modeling. Studies in
Sweden (Isakson et al., 2001), Los Angeles (Minguilln et al., 2008),
Turkey (Kesgin and Vardar, 2001), Alaska (Mlders et al., 2010),
Greece (Tzannatos, 2010b), Vancouver (Lu et al., 2006) and Scotland
(Marr et al., 2007) assessed the contribution of ports to measured
concentrations of air pollution in cities.
In China, some papers focus on the impacts of ships emission
characteristics on air quality. Zhao et al. (2013) indicates that ship
trafc has a non-negligible contribution on ambient levels of ne
particles on Shanghai port. Meanwhile, other studies focus on
emission inventory of ships in China. Yang et al. (2007) develops an
air pollutant emission inventory for marine ships in the Shanghai
Port in 2003 based on the marine activity statistical data from 1998
and other experts previous studies. Zhang et al. (2010) develops
the Pearl River Delta regional ship emission inventory by categories
with the use of appropriate estimation and the collection of activities data. Yau et al. (2012) develops a detailed maritime emission
inventory for ocean-going vessels (OGVs) in Hong Kong by a
network model based on a bottom-up activity-based network
model. Unfortunately, emission factors used in the three papers are
taken directly from previous European and US ship emission
database, which might not reect the local conditions and performance of technologies. Therefore, it is of great importance to
improve the understanding of the emission characteristics of ships
in China for accurate estimation of ships emissions inventory.
The objective of this study is to improve the understanding of
inland ships emission levels in China by acquiring their real-world
emission factors on the Grand Canal. The Grand Canal, the longest
articial waterway in the world, is more than 3500 km long. Excavated over 1400 years ago, it links Hangzhou and Beijing, and has
strongly been beneting regional development since its accomplishment (Fig. 1(a)). In modern era, the Grand Canal still plays an
important role in supplying water for irrigation, transporting
cargoes, and recreational activities. The Grand Canal offered ample
223
facility to transport food and goods from south to north in the early
times. Meanwhile, it also greatly improved the administration and
defense of China as a whole, strengthening the economic and cultural intercourse between north and south, and contributing to the
prosperity of the area along the route (Yang et al., 2012; Wang, 2012).
In this work, we measured tailpipe of CO, HC, NOx, and PM
emissions of ships using a portable emission measurement system
(PEMS), then analyzed emission levels of inland ships on the basis
of the measurement results, and generated distance-based and
fuel-based emission factors for ships. We also compared fuel-based
emission factors with those presented in previous studies, and
compare these emission factors under different engine loads.
2. Experimental section
2.1. Study area
Sunan Canal, a part of the Grand Canal, is one of the busiest
transporting cargo waterways in China. This section of the canal
crosses the south of Jiangsu Province from Zhenjiang to Suzhou,
with its length 211 km and over 80 m width (Fig. 1(b)). As a result of
the rapid economic development of the Yangtze River Delta region
and subsequently intensive use of marine transportation, more
concerns have been focus on the air quality along the waterway.
In this study, typical sailing routing was selected to have on
board emission test, which are about 14 km from Zhenjiang to
Danyang.
2.2. Portable emission measurement system
A combined on-board emission test system was employed to
measure the emissions from inland ship under real driving conditions. This system has two main parts: SEMTECH-DS and Electrical
Low Pressure Impactor (ELPI). SEMTECH-DS is able to test instantaneous emissions of gaseous pollutants, such as CO2, CO, HC, and NOx.
This equipment is used for on-road emission monitoring of diesel
vehicles, and uses heated ame ionization detector (HFID) for total
hydrocarbon (THC), non-dispersive ultraviolet (NDUV) analyzer for
nitric oxide (NO) and nitrogen dioxide (NO2), non-dispersive infrared
(NDIR) for CO and carbon dioxide (CO2) measurements (Liu et al.,
2011). In addition, a temperature/pressure sensor and a GPS device
were included to monitor environmental situation and instantaneous location and speed. A whole-exhaust, mass ow measurement
device (SEMTECH EFM) built by Sensors Incorporated, was used to
measure the exhaust ow rate based on pitot tube technology. To
Fig. 1. (a) The territory of the Grand Canal of China, (b) The detail of test routing.
224
Table 1
Technical parameters of the ships.
ID
Ship type
Built
year
Engine rated
power (kw)/
rated speed
(rpm)
Ship
gross
weight
(ton)
Ship Length
width (m)
Test route
Cargo ship
2005
136/850
298
36 7
Cargo ship
2004
136/850
258
36 8
Cargo ship
2010
136/850
237
35 7
Cargo ship
2011
136/850
261
36 8
Cargo ship
2008
260/1200
399
43 5
Cargo ship
2009
300/1200
521
45 8
Cargo ship
2009
300/1000
493
45 8
Zhenjiang
to Danyang
Zhenjiang
to Danyang
Danyang
to Zhenjiang
Zhenjiang
to Danyang
Zhenjiang
to Danyang
Zhenjiang
to Danyang
Zhenjiang
to Danyang
assure the accuracy of the test results, the SEMTECH-DS was zeroed
with pure nitrogen before each test and was calibrated with standard
gases before the rst day of test (Huo et al., 2012a, 2012b).
ELPI is a real-time particle size spectrometer designed for real
time monitoring of aerosol particle size distribution, and measures
airborne particle size distribution in the size range of 7 nme10 mm
using 12 channels. It consists of three main components: a corona
charger, low-pressure cascade impactor and multichannel electrometer. Before testing, the instrument must be zeroed. Prior to
ELPI, the exhaust gas was diluted by two ejector dilutors (Dekati,
Finland) in series. The dilution air and diluted exhaust in the rst
dilutor were heated to 200 C in order to prevent condensation and
the second ejector dilutor was at room temperature to cool the
sample. The dilution ratio during test procedure was around 64,
which essentially inhibited all post-dilution particle dynamics, such
as coagulation and adsorption. This system has been successfully
used for emission measurements of diesel engines in China. More
details on experiment instruments were presented in our previous
studies (Wang et al., 2011; He et al., 2011; Zhang et al., 2009).
During the experiments, ELPI, dilution system and SEMTECH-DS
were supplied to the equipment through a 5 KVA YAMAHA
generator.
2.3. Test ships
Extensive work was undertaken on Zhenjiang port to ensure
that the tested ships are of the typical types on Grand Canal before
the experiment started. Result shows that percentage of cargo ship
on ship eet are more than 90%, while engine power ranges from
120 to 300 kW. The specication of selected equipments that had
been tested is given in Table 1.
FCl=s
(1)
The fuels used in all test inland ships are general diesel fuels,
which came from oil ships near the dock. The test objects were
fueled with petrodiesel, which could fulll the national standard
for light diesel oil. Basically, the fuel consists of about 86.0% carbon
and 13.4% hydrogen, with respect to the sulfur contents are
generally below 2000 ppm.
3. Result and discussion
3.1. Instantaneous emissions for different operating modes
To describe the real-world emissions prole of the tested ship,
an example of time traces of ship speed, exhaust ow rate and
concentrations of CO, HC, NOx and PM from No. 4 ship for different
operating modes is given in Fig. 3 (For cruise mode, we only show
part of data because all measured data are stable on this mode). As
shown in Fig. 3, ship speed on port departure mode continuously
accelerate until reach cruising speed, while decelerate from
cruising speed to docking on port arrival mode. On cruise mode,
ship speed is approximately 7 km h1. For exhaust ow rate and
four pollutant concentrations, the large peaks occur on manoeuvring mode (port departure and port arrival modes). The possible
reasons can be as follows: On port departure mode, ship rstly
moves backward to leave the berth, and then keep on acceleration
on the waterway. On port arrival mode, propeller churned backward to reduce ship speed. When driving speed slow down and
stop on berth. On the whole Manoeuvring mode, ship speed and
driving direction are variable to avoid trafc crash. In this case,
engine load and engine speed uctuate greatly on the process,
which results in the variation in pollutant concentrations. Note that
NOx concentration is higher during cruise mode, which can affect
human health, ecosystems and the environment of the coastal
areas.
Table 2
Average emission rates and fuel consumption for different operating modes.
Operating mode
Cruise
200
Port departure
Port arrival
(a)
9
6
3
0
Port departure
150
Port arrival
(b)
100
50
500
1000
1500
2000
500
Cruise
Port arrival
(c)
0.2
0.1
0
0
500
1000
1500
Port departure
900
Port arrival
(e)
600
0
500
1000
1500
Port arrival
300
0
500
1000
1500
2000
1200
Cruise
(d)
2000
PM concentration (mg/m3)
1800
2000
600
2000
2400
Cruise
1500
1200
Port departure
1000
CO concentration (%)
Cruise
0
0
1
Manoeuvring Port
197.8 67.2
248.2 46.3
departure
192.7 64.0
260.7 112.7
Port
arrival
Cruise
151.1 80.8
236.7 91.7
Manoeuvring Port
41.5 11.1
67.2 40.9
HC (g h1)
departure
Port
37.8 6.9
57.0 29.0
arrival
Cruise
40.0 10.7
57.8 41.6
Manoeuvring Port
709.1 191.9 826.4 276.8
NOx (g h1)
departure
Port
413.6 91.4
309.4 224.0
arrival
Cruise
1041.8 522.2 1549.6 730.8
Manoeuvring Port
47.3 41.3
70.8 13.2
PM (g h1)
departure
49.1 22.4
109.4 141.3
Port
arrival
Cruise
26.7 20.0
57.2 28.1
9.6 2.3
13.6 5.2
Fuel consumption Manoeuvring Port
departure
(l h1)
Port
6.1 1.8
6.9 1.7
arrival
Cruise
11.6 4.0
18.8 6.7
CO (g h
12
225
1500
Port departure
Cruise
Port arrival
1200
(f)
900
600
300
0
0
500
1000
1500
2000
Fig. 3. Instantaneous ship speed, exhaust ow rate and emission concentrations from No. 4 ship on different operating modes.
226
Table 3
Average emission factors for different operating modes.
Operating modes
1
Manoeuvring Port
Port
Cruise
1
HC (g km ) Manoeuvring Port
Port
Cruise
NOx (g km1) Manoeuvring Port
Port
Cruise
1
PM (g km ) Manoeuvring Port
Port
Cruise
CO (g km
departure
arrival
37.0
42.2
15.2
departure
6.9
arrival
7.8
4.4
departure 162.5
arrival
94.9
104.8
departure
11.9
arrival
10.5
2.7
14.3
4.0
4.9
2.8
3.3
1.7
29.4
26.9
33.1
13.4
1.8
1.7
55.2
67.1
35.1
11.5
13.6
10.7
184.0
98.0
170.0
21.6
27.4
6.4
9.9
29.3
13.7
5.9
7.6
2.8
88.6
57.9
69.2
11.9
40.2
2.8
Fig. 4. PM number distribution on different operating modes from No. 3 ship engine. I
is port departure mode; II is cruise mode; III is port arrival mode.
Table 4
Average number concentrations of PM from No. 3 ship for three operating modes.
Operating modes
Nucleation
mode
Accumulation
mode
Coarse mode
Manoeuvring Port
(5.6 6.4) 106 (3.1 4.4) 105 (1.2 3.2) 103
departure
Port
(6.4 4.4) 106 (2.4 1.9) 105 (1.7 3.2) 103
arrival
Cruise
(2.4 0.3) 105 (1.3 0.1) 105 (2.8 0.7) 102
30
20
10
120
100
Estimated Tier 1
emission limit
80
60
40
20
0
A
227
10
8
6
4
2
0
8
6
4
2
0
A
Fig. 5. CO, HC, NOx and PM fuel-based emission factors for cruise mode of several studies. Note that A is the fuel-based emission factors for cruise mode of this study; B is emission
factors for cruise mode of Moldanovas study (2009); C and D are the fuel-based emission factors of a tanker ship named Royal Sphere and a container ship named MSC Giovanna of
Sinha et al. (2003).
Table 5
Distance-based emission factors on different engine load from No. 1, No. 2, No. 4 and
No. 7 tested ships.
No. 1
No. 2
No. 4
No. 7
Engine load
CO (g km1)
HC (g km1)
NOx (g km1)
PM (g km1)
Low load
Middle load
High load
Low load
Middle load
High load
Low load
Middle load
High load
Low load
Middle load
High load
12.5
15.1
47.6
8.5
9.5
23.4
10.4
14.8
27.3
16.2
21.4
52.4
5.2
6.3
14.9
3.4
4.5
6.1
4.2
4.4
7.5
3.2
4.0
5.8
96.2
123.4
208.8
48.2
75.9
78.2
48.3
78.0
145.7
68.4
92.2
192.3
1.6
1.6
146.2
0.4
0.9
15.8
1.3
4.2
50.7
1.2
6.3
12.4
228
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