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South America
BASF S.A.
Av. Faria Lima, 3600/3624
04538-132 So Paulo SP Brazil
Phone: +55 11 3043-2233
Fax:
+55 11 3043-6989
e-mail: industrial-formulators-sa@basf.com
Asia Pacific
BASF East Asia
Regional Headquarters Ltd.
45th Floor, Jardine House
1 Connaught Place
Central Hong Kong China
Phone: +852 273 10111
Fax:
+852 273 49631
e-mail: industrial-formulators-hk@basf.com
www.basf.com/care-chemicals
Safety
We know of no ill effects that could have resulted from using our products for the purpose for which they are intended and from processing
them in accordance with current practice. According to the experience
we have gained up to now and other information at our disposal, our
products do not exert any harmful effects on health, provided that they
are used properly, due attention is given to the precautions necessary
for handling chemicals, and the information and advice given in our
safety data sheet are observed.
Labeling
Details about the classification and labeling of our products and further
advice on safe handling are contained in the current safety data sheets.
Note
This document, or any answers or information provided herein by BASF,
does not constitute a legally binding obligation of BASF. While the
descriptions, designs, data and information contained herein are presented in good faith and believed to be accurate, it is provided for your
guidance only. Because many factors may affect processing or application/use, we recommend that you make tests to determine the suitability
of a product for your particular purpose prior to use. It does not relieve
our customers from the obligation to perform a full inspection of the
products upon delivery or any other obligation. NO WARRANTIES OF
ANY KIND, EITHER EXPRESS OR IMPLIED, INCLUDING WARRANTIES
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE,
ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA
OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS,
DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE
INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL
THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE
CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE.
Europe
Chemical Solutions
for Emulsion
Polymerization
Emulsion Polymerization
At BASF we use our know-how to deliver high performance
products, of consistent high quality, to customers
in the Emulsion Polymerization industry. Emulsion
Polymerization is a complex technology employed
to produce a variety of polymer dispersions which
are then utilized in a variety of applications.
BASF SE
Home Care & Formulation Technologies
Europe
Carl-Bosch-Strae 38
67056 Ludwigshafen Germany
Phone: +49 621 60-0
Fax:
+49 621 60-42525
e-mail: industrial-formulators-eu@basf.com
BTC Europe GmbH
Maarweg 163/165
50825 Kln Germany
Phone: +49 221 95464-0
You will find further European contacts on:
www.btc-europe.com
North America
BASF Corporation
100 Campus Drive
07932 Florham Park, NJ USA
Phone: 800 526-1072
+1 973 245-6000
Fax:
+1 973 245-6002
e-mail: industrial-formulators-na@basf.com
South America
BASF S.A.
Av. Faria Lima, 3600/3624
04538-132 So Paulo SP Brazil
Phone: +55 11 3043-2233
Fax:
+55 11 3043-6989
e-mail: industrial-formulators-sa@basf.com
Asia Pacific
BASF East Asia
Regional Headquarters Ltd.
45th Floor, Jardine House
1 Connaught Place
Central Hong Kong China
Phone: +852 273 10111
Fax:
+852 273 49631
e-mail: industrial-formulators-hk@basf.com
www.basf.com/care-chemicals
Safety
We know of no ill effects that could have resulted from using our products for the purpose for which they are intended and from processing
them in accordance with current practice. According to the experience
we have gained up to now and other information at our disposal, our
products do not exert any harmful effects on health, provided that they
are used properly, due attention is given to the precautions necessary
for handling chemicals, and the information and advice given in our
safety data sheet are observed.
Labeling
Details about the classification and labeling of our products and further
advice on safe handling are contained in the current safety data sheets.
Note
This document, or any answers or information provided herein by BASF,
does not constitute a legally binding obligation of BASF. While the
descriptions, designs, data and information contained herein are presented in good faith and believed to be accurate, it is provided for your
guidance only. Because many factors may affect processing or application/use, we recommend that you make tests to determine the suitability
of a product for your particular purpose prior to use. It does not relieve
our customers from the obligation to perform a full inspection of the
products upon delivery or any other obligation. NO WARRANTIES OF
ANY KIND, EITHER EXPRESS OR IMPLIED, INCLUDING WARRANTIES
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE,
ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA
OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS,
DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE
INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL
THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE
CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE.
Europe
Chemical Solutions
for Emulsion
Polymerisation
Product Portfolio
Emulsion Polymerization
Product Portfolio
Emulsion Polymerization
Air/Nitrogen
Interphase
Water
Monomer solubilisation
in the micelle
Micelle
M
M
M
M M
M M
3.5 nm
5 nm
103 nm
Monomer droplet
Polymer
102 nm
Swollen micelle
Initiator molecule
Monomer molecule
Latex particle
Surfactant molecule
Negative potential
Nonionic surfactant
Cation
Steric
stabilization
Negative potential
Nonionic surfactant
Cation
Product Portfolio
Applications
Anionic Surfactants
ABS
SBR
Emulsion-PVC
Microsuspension-PVC
0 1.5b)
6.0 7.05)
Disponil EHS 47
Liquid
~ 45
02
0 0.5
10.0 11.52)
Liquid
~ 15
0 0.8
0 0.3
8.0 9.01)
Disponil SDS G*
Granules
~ 97
0 2.5
0 1.0
8.5 10.52)
Liquid
~ 30
0 1.0
0 0.25
7.5 9.55)
Disponil OCS 27
Paste like
~ 27
0 0.6
0 0.3
8.3 11.55)
Sodium
sulfate
[%]
Sodium
chloride
[%]
pH-value
Foaming agent
Styrene butadiene
0 7a)
Description
Active
matter
[%]
Wetting
Acrylic
~ 35
Product Name
Aggregate
condition
@ RT
Post polymerization
stabilization
Styrene acrylic
Liquid
Product Groups
APEO free
Alkyd emulsion
Performance
Disponil ALS 33
Basic surfactants
Excellent particle size control
Foaming agents,
e.g. for carpet backing, textile
Liquid
~ 25
0 0.7
0 0.2
7.0 8.55)
Disponil FES 27
Liquid
~ 27
0 0.5
0 0.1
6.4 7.55)
Disponil FES 32
Liquid
~ 31
0 0.8
7.0 8.55)
Liquid
~ 27
0 0.8
7.0 8.55)
Liquid
~ 30
0 0.8
7.0 8.55)
Disponil BES 20
Liquid
~ 29
0 1.0
7.0 8.55)
Disponil FES 77
Liquid
~ 33
0 0.8
7.0 8.55)
Disponil FES 61
Liquid
~ 32
0 0.8
7.0 8.55)
Basic surfactants
Especially for seed latex
Stable against hydrolysis
Suitable for all types of monomers
1) as is
a) ammonium sulfate
b) ammonium chloride
2) DIN EN 1262: 1% in water
c) s ulfate content (potentiometric titration with an
3) 3% in water
aqueous solution of barium chloride (c = 0,1 mol/l)
Alternatives to APEO-sulfates
Yield improved stabilization
properties in the latex over
alkyl sulfates
Adaptable to monomer system:
- lower ethoxylated products
more suitable for all acrylics
- medium ethoxylated products
more suitable for styrene acrylics.
- higher ethoxylated products
more suitable for vinyl acetate
homo- and copolymers and as
emulsifiers for alkyd resins.
Highly recommended as sole surfactant or as co-emulsifier Recommended as sole surfactant or as co-emulsifier Recommended as co-emulsifier
5
Product Portfolio
Applications
pH-value
Liquid
~ 30
0 1.0
5.0 6.0
3)
Disponil SUS IC 10
Liquid
~ 64.5
0 1.0
6.0 8.0
3)
Liquid
~ 75
0 1.0
5.5 7.55)
Disponil ODSLS
Mono-alkenyl sulfosuccinamate,
sodium salt
Partly
crystallized
~ 35
7.5 9.52)
Liquid
~ 100
Liquid
~ 51
0 3.0 a)
6.0 7.03)
Product Name
Description
Wetting
Sodium
chloride
[%]
SBR
Sodium
sulfate
[%]
ABS
Active
matter
[%]
Acrylic
Aggregate
condition
@ RT
Foaming agent
Post polymerization
stabilization
Alkyd emulsion
Microsuspension-PVC
Performance
Emulsion-PVC
Styrene butadiene
Styrene acrylic
Product Groups
APEO free
Anionic Surfactants
Other surfactants
Suitable for manufacturing of
small particle latices (hydrosols)
Disponil OSS 50 KS
a) potassium sulfate
1) as is
2) DIN EN 1262: 5% in water
3) DIN EN 1262: 10% in water
Highly recommended as sole surfactant or as co-emulsifier Recommended as sole surfactant or as co-emulsifier Recommendedas co-emulsifier
6
Product Portfolio
Applications
Acrylic
Styrene butadiene
ABS
SBR
Emulsion-PVC
Microsuspension-PVC
Alkyd emulsion
APEO free
Post polymerization
stabilization
Lutensol AT 18 20%
C16C18-Fatty alcohol + 18 EO
Liquid
~ 20
~ 922)
~ 15
Lutensol AT 25 E**
C16C18-Fatty alcohol + 25 EO
Solid
~ 100
~ 952)
~ 16
Lutensol XP 100
C10-Guerbet alcohol + 10 EO
Paste-like
~ 100
~ 791)
~ 15
Lutensol XP 149
C10-Guerbet alcohol + 14 EO
Liquid
~ 80
~ 782)
~ 16
Description
Aggregate
condition
@ RT
Active
matter
[%]
Cloud
point
[C]
Pour
point*
[C]
HLB
Foaming agent
Styrene acrylic
Performance
Wetting
Nonionic Surfactants
Alcohol ethoxylates
Basic non-ionic surfactants
Alternatives to alkylphenol
ethoxylates (APEOs)
Alternatives to alkylphenol
ethoxylates (APEOs)
Co-emulsifiers for improvement
of stabilization properties
Liquid to
paste like
~ 100
~ 19
~ 724)
9.5
Disponil OC 25
Solid
~ 100
~ 932)
~ 40
16.5
Disponil A 1080
Liquid
~ 80
~ 633)
< 10
14.0
Disponil A 1580
Liquid
~ 80
~ 733)
< 15
15.0
Disponil A 3065
Liquid
~ 65
~ 773)
< 10
16.5
Disponil A 4065
Liquid
~ 65
~ 763)
< 15
16.5
Liquid
~ 80
~ 682)
< 10
13.7
Liquid
~ 75
~ 803)
< 15
17.0
Liquid
~ 30
~ 803)
<5
18.0
Special surfactants
Alternatives to alkylphenol
ethoxylates (APEOs)
Co-emulsifiers for improvement
of stabilization properties
Emulsifiers for alkyd resins
Liquid
~ 80
~ 932)
<5
~ 16
Emulan TO 3070
Liquid
~ 70
~ 922)
<5
~ 17
Emulan TO 4070
Liquid
~ 70
~ 922)
<5
~ 18
1)
2)
3)
4)
EN
EN
EN
EN
1890
1890
1890
1890
Alternatives to alkylphenol
ethoxylates (APEOs)
Co-emulsifiers for improvement
of stabilization properties
Highly recommended as sole surfactant or as co-emulsifier Highly recommended as co-emulsifier Recommended as co-emulsifier
9
Product Portfolio
Applications
Nonionic Surfactants
Acrylic
Styrene butadiene
ABS
SBR
Emulsion-PVC
Microsuspension-PVC
Alkyd emulsion
APEO free
Post polymerization
stabilization
Foaming agent
C8-C10-Alkyl polyglucoside
Liquid
~ 64
100% renewable based
surfactant
C8-C14-Alkyl polyglucoside
Liquid
~ 50
Description
Aggregate
condition
@ RT
Active
matter
[%]
Cloud
point
[C]
Pour
point
[C]
HLB
Wetting
Styrene acrylic
Performance
Alkyl polyglycosides
Liquid
~ 100
~ 231)
~ -30
Pluronic PE 6400
Liquid
~ 100
~ 601)
~ 16
Pluronic PE 6800
Powder
~ 100
~ 882)
Pluronic PE 10100
Liquid
~ 100
~ 404)
~ -25
Pluronic PE 10500
Solid
~ 100
~ 752)
Liquid
~ 100
~ 501)
~9
Liquid
~ 100
~ 314)
~ -30
1)
2)
3)
4)
EN
EN
EN
EN
10
1890
1890
1890
1890
Block polymers with low
EO content show defoaming
behavior
Block polymers with high
EO content act as emulsifiers
and dispersants
Highly recommended as sole surfactant or as co-emulsifier Highly recommended as co-emulsifier Recommended as co-emulsifier
11
BASFSE
Home Care & Formulation Technologies
Europe
Carl-Bosch-Strae 38
67056 Ludwigshafen Germany
Phone: +49 621 60-0
Fax:
+49 621 60-42525
e-mail: industrial-formulators-eu@basf.com
BTC Europe GmbH
Maarweg 163 /165
50825 Kln Germany
Phone: +49 221 9 54 64-0
You will find further European contacts on:
www.btc-europe.com
North America
BASF Corporation
100 Campus Drive
07932 Florham Park, NJ USA
Phone: 800 526-1072
+1 973 245-6000
Fax:
+1 973 245-6002
e-mail: industrial-formulators-na@basf.com
South America
BASF S.A.
Av. Faria Lima, 3600/3624
04538-132 So Paulo SP Brazil
Phone: +55 11 3043-2233
Fax:
+55 11 3043-6989
e-mail: industrial-formulators-sa@basf.com
Asia Pacific
BASF East Asia
Regional Headquarters Ltd.
45th Floor, Jardine House
1 Connaught Place
Central Hong Kong China
Phone: +852 273 10111
Fax:
+852 273 49631
e-mail: industrial-formulators-hk@basf.com
www.basf.com/care-chemicals
Safety
We know of no ill effects that could have resulted from using our products for the purpose for which they are intended and from processing
them in accor-dance with current practice. According to the experience
we have gained up to now and other information at our disposal, our
products do not exert any harm-ful effects on health, provided that they
are used properly, due attention is given to the precautions necessary
for handling chemicals, and the information and advice given in our
safety data sheet are observed.
Labeling
Details about the classification and labeling of our products and further
advice on safe handling are contained in the current safety data sheets.
Note
This document, or any answers or information provided herein by BASF,
does not constitute a legally binding obligation of BASF. While the
descriptions, designs, data and information contained herein are presented in good faith and believed to be accurate, it is provided for your
guidance only. Because many factors may affect processing or application/use, we recommend that you make tests to determine the suitability
of a product for your particular purpose prior to use. It does not relieve
our customers from the obligation to perform a full inspection of the
products upon delivery or any other obligation. NO WARRANTIES OF
ANY KIND, EITHER EXPRESS OR IMPLIED, INCLUDING WARRANTIES
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE,
ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA
OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS,
DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE
INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL
THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE
CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE.
Europe
Registration
Emulsion Polymerization
Registration
Anionic Surfactants
Registration Status
AICS
Product Name
DSL
Australia Canada
IECSC
Reach*
ENCS
ECL
NZIOC
PICCS
CHEMINV
China
EU
Japan
Korea
TSCA
USA
Disponil EHS 47
Disponil SDS 15
Disponil SDS G
Disponil OCS 27
Disponil FES 32
Disponil BES 20
Disponil FES 77
Disponil FES 61
Disponil SUS IC 10
Disponil ODSLS
Other surfactants
Disponil OSS 50 KS
Nonionic Surfactants
Registration Status
AICS
Product Name
DSL
Australia Canada
IECSC
Reach*
ENCS
ECL
China
EU
Japan
Korea
NZIOC
PICCS
CHEMINV
TSCA
USA
Alcohol ethoxylates
Lutensol AT 18 20%
Lutensol AT 25 E
Lutensol XP 100
Lutensol XP 149
Disponil OC 25
Disponil A 1080
Disponil A 1580
Disponil A 3065
Disponil A 4065
Emulan TO 2080
Emulan TO 3070
Emulan TO 4070
Special surfactants
Alkyl polyglycosides
Pluronic PE 6400
Pluronic PE 6800
Pluronic PE 10100
Pluronic PE 10500
* The products in this european product catalogue as supplied by BASF in the EU/EEA are in compliance with the requirements of REACH, i.e. the ingredients
shall either be pre-registered, registered, exempted or there is no obligation to register due to small volume. But we strongly recommend to contact BASF prior to
import and for uses not covered by the Safety Data Sheet.
BASFSE
Home Care & Formulation Technologies
Europe
Carl-Bosch-Strae 38
67056 Ludwigshafen Germany
Phone: +49 621 60-0
Fax:
+49 621 60-42525
e-mail: industrial-formulators-eu@basf.com
BTC Europe GmbH
Maarweg 163 /165
50825 Kln Germany
Phone: +49 221 9 54 64-0
You will find further European contacts on:
www.btc-europe.com
North America
BASF Corporation
100 Campus Drive
07932 Florham Park, NJ USA
Phone: 800 526-1072
+1 973 245-6000
Fax:
+1 973 245-6002
e-mail: industrial-formulators-na@basf.com
South America
BASF S.A.
Av. Faria Lima, 3600/3624
04538-132 So Paulo SP Brazil
Phone: +55 11 3043-2233
Fax:
+55 11 3043-6989
e-mail: industrial-formulators-sa@basf.com
Asia Pacific
BASF East Asia
Regional Headquarters Ltd.
45th Floor, Jardine House
1 Connaught Place
Central Hong Kong China
Phone: +852 273 10111
Fax:
+852 273 49631
e-mail: industrial-formulators-hk@basf.com
www.basf.com/care-chemicals
Safety
We know of no ill effects that could have resulted from using our products for the purpose for which they are intended and from processing
them in accor-dance with current practice. According to the experience
we have gained up to now and other information at our disposal, our
products do not exert any harm-ful effects on health, provided that they
are used properly, due attention is given to the precautions necessary
for handling chemicals, and the information and advice given in our
safety data sheet are observed.
Labeling
Details about the classification and labeling of our products and further
advice on safe handling are contained in the current safety data sheets.
Note
This document and any information provided herein by BASF does not
constitute a legally binding obligation of BASF and is provided for your
guidance only. All information contained in this document is given in
good faith and is based on sources believed to be reliable and accurate
at the date of publication of this document. BASF SE and its affiliates do
not accept legal liability or responsibility for the content, veracity and/or
accuracy of the information or any consequences arising from its use.
Europe