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Surname
Other names
Pearson Edexcel
Centre Number
Candidate Number
International
Advanced Level
Chemistry
Advanced Subsidiary
Unit 2: Application of Core Principles of Chemistry
Sample Assessment
Time: 1 hour 30 minutes
Paper Reference
WCH02/01
Instructions
ACQUIRE
Total Marks
SECTION A
1
Solutions containing chlorate(I) ions are used as household bleaches and disinfectants. These
solutions decompose on heating as shown.
3Cl O Cl O3 + 2Cl
Which oxidation state is shown by chlorine in each of these three ions?
Cl O
Cl O3
Cl
+1
+3
+3
+1
+1
+5
+5
+1
In which species are the numbers of protons, neutrons and electrons all different?
A
3
27
13 Al
35
17 Cl
32 2
16 S
39 +
19 K
30
energy
/ kJ mol1
50
extent of reaction
Why does the rate of a gaseous reaction increase when the pressure is increased at a constant
temperature?
5
5 A solution of Sn2+ ions will reduce an acidified solution of MnO4 ions to Mn2+ ions. The Sn2+ ions
are oxidised to Sn4+ ions in this reaction.
How many moles of Mn2+ ions are formed when a solution containing 9.5 g of SnCl 2 (Mr: 190) is
added to an excess of acidified KMnO4 solution?
A
0.010
0.020
0.050
0.125
6 In which row of the table are all statements comparing the compounds of magnesium and barium
correct?
solubility of hydroxides
solubility of sulfates
solubility of
magnesium
hydroxide
solubility of barium
hydroxide
solubility of
magnesium sulfate
solubility of barium
sulfate
higher
lower
higher
lower
higher
lower
lower
higher
lower
higher
higher
lower
lower
higher
lower
higher
No reaction occurs.
It is a free radical.
It is a nucleophile.
It is an electrophile.
by a curly arrow from a lone pair on the OH ion to the C+ atom of 1-bromopropane
10
2.30 g of ethanol were mixed with an excess of aqueous acidified potassium dichromate(VI). The
reaction mixture was then boiled under reflux for one hour. The desired organic product was then
collected by distillation. The yield of product was 60.0 %.
What mass of product was collected?
A
1.32 g
1.38 g
1.80 g
3.20 g
1, 2 and 3
are
correct
1 and 2
only are
correct
2 and 3
only are
correct
1 only
is
correct
There are smaller interatomic distances in the metallic lattices of the Group II metals.
More electrons are available from each Group II metal atom for bonding the atom into the
metallic lattice.
Group II metals have a higher first ionisation energy than the corresponding Group I metal.
12 Valence shell electron pair repulsion theory should be used to answer this question.
13.
14.
BH3
CH3+
PH3
CH4
C.
CH3CHO
B.
CH2 F 2
D.
CH3OH
Chlorine
B.
Fluorine
C. Sodium chloride
D.
Sodium uoride
B.
90
109.5
D.
C. 120
180
Which types of hybridization are shown by the carbon atoms in the compound CH 2 = CH CH ?
I.
II.
III.
A.
sp
sp 2
sp
I and II only
B.
C.
D.
I, II and III
18.
A.
I and II only
B.
C.
D.
I, II and III
CH CH 2 CH 2 CHO
C.
CH CHCHCH
B.
CH COCH 2 CH
D.
CH2CH 2 CH 2 CH
SECTION B
21
+
2NO + 12H + 10I 2NH4 + 2H2O + 5I2
(i) Define oxidation in terms of electrons.
01 mark
.............................................................................................................................................
+
01 mark
................................................................................
01 mark
(iii) Identify the species formed by oxidation in this reaction............................................
(b) When chlorine gas is bubbled into an aqueous solution of sulphur dioxide, hydrogen
ions, sulphate ions and chloride ions are formed.
(i) Write a half-equation for the formation of chloride ions from chlorine.
01 mark
.............................................................................................................................................
(ii) Write a half-equation for the formation of hydrogen ions and sulphate ions from
sulphur dioxide and water.
01 mark
.............................................................................................................................................
(iii) Hence, deduce an overall equation for the reaction which occurs when chlorine is
bubbled into aqueous sulphur dioxide.
02 mark
.............................................................................................................................................
Total 08 Marks
22 An excess of potassium iodide was added to an aqueous solution of chlorine. In a titration the
3
3
liberated iodine required 28.2 cm of a 0.360 mol dm solution of sodium
thiosulphate for complete reaction.
(a) Calculate the number of moles of sodium thiosulphate used in the titration.
........................................................................................................................................................
.......................................................................................................................................................
(2 marks)
(b) Write an equation for the reaction between thiosulphate ions and iodine.
........................................................................................................................................................
(1 mark)
(c) Calculate the number of moles of iodine which reacted with the sodium thiosulphate
used in the titration.
........................................................................................................................................................
(1 mark)
(d) Write an equation for the reaction between potassium iodide and chlorine.
........................................................................................................................................................
(1 mark)
(e) Calculate the mass of chlorine in the original solution which reacted with potassium
iodide.
........................................................................................................................................................
........................................................................................................................................................
........................................................................................................................................................
........................................................................................................................................................
(3 marks)
(f) Name an indicator which could be used when a solution of iodine is titrated with sodium
thiosulphate solution from a burette. State the colour change at the end-point.
Indicator .......................................................................................................................................
Colour change ..............................................................................................................................
(2 marks)
10 Marks
23
(a) Samples of solid sodium fluoride, sodium chloride, sodium bromide and sodium iodide
are each warmed separately with concentrated sulphuric acid. All four
compounds react with concentrated sulphuric acid but only two can reduce it.
(i) Identify the two halides which do not reduce concentrated sulphuric acid. Write an
equation for the reaction which does occur with one of these two halides.
02 Marks
(ii) Identify the two halides which reduce concentrated sulphuric acid to sulphur
dioxide. Using half-equations for the oxidation and reduction processes,
deduce an overall equation for the formation of sulphur dioxide when
concentrated sulphuric acid reacts with one of these halides.
02 Marks
(iii) In addition to sulphur dioxide, two further reduction products are
formed when one of these two halides reacts with concentrated sulphuric acid.
Identify the two reduction products and write a half-equation to show the
formation of one of them from concentrated sulphuric acid.
02 marks
(b) How would you distinguish between separate solutions of sodium chloride, sodium
bromide and sodium iodide using solutions of silver nitrate and ammonia?
02 marks
(c) Ions of Group 7 elements take part in displacement reactions. These reactions can be used to
compare the reactivities of the elements within Group 7.
A student adds aqueous solutions of halogens to test-tubes containing solutions of halide
ions. The resulting mixtures are then shaken with cyclohexane, an organic solvent.
One of the students results is shown in the table.
experiment
number
1
2
3
experiment details
addition of Cl 2(aq) to I (aq) ions
[2]
(ii) Write the ionic equation for the reaction taking place in experiment 2.
...................................................................................................................................... [1]
(iii) These three experiments alone are unable to confirm the order of reactivity for Cl 2, Br2
and I2.
Suggest one further displacement reaction which could be carried out to confirm the
order of reactivity of Cl 2, Br2 and I2.
...........................................................................................................................................
...................................................................................................................................... [1]
(d) Chlorine gas reacts with water as shown below.
Cl 2(g) + H2O(l)
(i) Using oxidation numbers, explain why this reaction is an example of disproportionation.
...........................................................................................................................................
...........................................................................................................................................
..................................................................................................................................... [2]
(ii)
State one benefit for public health, of the reaction between chlorine gas and water.
...................................................................................................................................... [1]
(e) Group 2 elements and compounds show periodic trends. One trend is shown by the effect of
heat upon Group 2 carbonates.
A student carried out an experiment to find out the volume of carbon dioxide obtained by
heating a weighed sample of magnesium carbonate.
The student placed a 1.47 g sample of MgCO3 into a test-tube and heated it until there was
no further change in mass.
The following reaction took place.
MgCO3(s)
(i)
MgO(s) + CO2(g)
(ii)
What volume of CO2, in dm3, would have been given off when measured at room
temperature and pressure?
The molar mass of MgCO3 = 84.3 g mol1
(iii)
The student repeated the experiment a further three times, using the same number of
moles of CaCO3, SrCO3 and BaCO3.
What trend in the behaviour of the Group 2 carbonates would be observed by the
student?
...........................................................................................................................................
...................................................................................................................................... [2]
[Total Marks: 20]
24
(a)
In each of the following questions, you should draw the structure of the compound in
the space provided.
Draw the structure of the alkene that would form 1,2-dibromo-3-methylbutane when
reacted with bromine.
(1 mark)
(b)
Draw the structure of the alcohol with molecular formula C4H10O that is resistant to
oxidation by acidified potassium dichromate(VI).
(1 mark)
(c)
Draw the structure of the alkene that has a peak, due to its molecular ion, at m/z = 42
in its mass spectrum.
(1 mark)
(d)
............................................................................................................................................
(1 mark)
(e)
An aluminium chloride molecule reacts with a chloride ion to form the AlCl4 ion.
Name the type of bond formed in this reaction. Explain how this type of bond is
formed in the AlCl4 ion.
Type of bond ......................................................................................................................
Explanation .........................................................................................................................
............................................................................................................................................
............................................................................................................................................
(2 marks)
(f)
Aluminium chloride has a relative molecular mass of 267 in the gas phase.
Deduce the formula of the aluminium compound that has a relative molecular mass
of 267
............................................................................................................................................
(1 mark)
(g)
Deduce the name or formula of a compound that has the same number of atoms, the
same number of electrons and the same shape as the AlCl4 ion.
............................................................................................................................................
(1 mark)
(h)
(i)
(1 mark)
(ii) Explain why the TlCl2+ ion has the shape that you have drawn
............................................................................................................................................
............................................................................................................................................
............................................................................................................................................
(1 mark)
Total 10 Marks
25
K2Cr2O7(aq) / H2SO4(aq)
reflux
acid / heat
CH3CH2CH2CH2OH
K2Cr2O7(aq) / H2SO4(aq)
distil
CH3COOH / H2SO4
reflux
[4]
(b) Butan-1-ol can be prepared by the alkaline hydrolysis of 1-iodobutane.
CH3CH2CH2CH2I + OH
CH3CH2CH2CH2OH + I
The curly arrow model is used in reaction mechanisms to show the movement of electron
pairs.
Use the curly arrow model to outline the mechanism for the alkaline hydrolysis of
1-iodobutane.
In your answer, include the name of the mechanism, the type of bond fission and relevant
dipoles.
(ii)
26
(ii)
[2]
Some older breathalysers used the redox reaction between acidified dichromate(VI) ions
and ethanol. A colour change was seen which indicated the presence of ethanol in the
breath.
What is the colour change that would be seen in this breathalyser if ethanol was present
in the breath?
.. to ..
(iii)
[1]
Give an equation to show the reaction between acidified dichromate(VI) ions and
ethanol.
Use [O] to represent the acidified dichromate(VI) ions, the oxidising agent.
...................................................................................................................................... [2]
(b) Infrared spectroscopy and mass spectrometry are used in the search for organic molecules in
outer space.
Compound A has been analysed by infrared spectroscopy.
100
80
transmittance
(%)
60
40
20
4000
3500
3000
2500
2000
1500
1
wavenumber / cm
1000
500
10
20
30
m/z
40
50
60
(i)
(ii)
How does the mass spectrum confirm that compound A has a molecular formula of
C4H10?
...................................................................................................................................... [1]
(iii)
[1]
(iv)
Identify the fragment ions that give rise to the following peaks in the mass spectrum.
m/z 15 is .
m/z 29 is .
m/z 43 is .
(v)
[3]
Use your answer to part (iv) to identify which of the isomers in part (iii) is compound A.
Explain your reasoning.
[1]
[Total: 13]
Page 2
Mark Scheme
GCE A LEVEL May/June 2013
Question
Number
Key
1
2
3
C
D
A
4
5
D
B
6
7
Syllabus
9701
Question
Number
Key
11
12
13
14
15
B
D
B
A
C
D
16
17
C
A
9
10
A
C
18
19
20
A
C
B
Paper
11