Dow Industrial Water Treatment Scale Inhibitor and Dispersant

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Dow industrial water treatment scale inhibitor and dispersant

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2
Dow industrial water treatment polymers
based on acrylic (H2C = CH - COOH).
water-soluble polymer (molecular weight range 1000--100000).
homopolymer:
acrylic monomer is the only
copolymer:
acrylic acid with other monomers
other monomers include
:
acrylate
acid
acrylic acid monomer
nonionic acrylic monomers
polymerization process:
radical polymerization
random aggregation
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3
by changing the following parameters, you can get a polymer molecule design for different
scale:
number of monomer
monomer species
monomer ratio
molecular weight
polymerization method
through a combination of design parameters can be prepared to address any one scale for
industrial water treatment
The scale inhibitor and programs.
Of course, a polymer is not a panacea, we often need to be combined in different inhibitor,
Scale to achieve the best results.
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Industrial Water Treatment Scale
Na
Ca
Mg
K
Ba
Sr
CO
3
SO
4
PO
4
NO
3
Cl
F
SiO2
Green: soluble salt - Red: very low solubility salt
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Seeds effect
(
Seed treatment
)
+
Salt seed
Polymer segment
Adsorbed on the salt seed polymer
Polymer segment
Typically, when the salt does not reach a certain seed size, seed formation and dissolution rate is
A balance. By adsorption of the polymer, more conducive to the dissolution of the seed, upset
the balance tilting
To dissolve.
After the seeds dissolved, the polymer will again adsorbed onto other salts seed, so the cycle
Reciprocating.
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Dissociation
(
Crystallization decomposition
)
+
+
Crystals
Polymer chains
Wound crystalline polymer crystallization dissociation
Polymer chains
After the polymer is adsorbed onto the salt crystal, since the polymer itself
Internal stress makes crystallized gradually decomposed body dissociation, released at the same
time
The polymer will continue to adsorb to the other crystals.
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Dispersion
(
Particle dispersion
)
Polymer adsorbed on the surface to prevent accumulation of scale in the following way
:
Electrostatic repulsion
(COOH
, SO3
)
Sterically hindered
(
Nonionic monomers
)
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Dow industrial water treatment products
acrylic acid homopolymers
Acumer 1000 - Acumer 1010
Mw 2000
Acumer 1100 - Acumer 1110
Mw 4500
acrylic copolymer
Acumer 2200
Mw 2000
Acumer 6600
Mw 10000
vulcanized copolymer
Acumer 2000
Mw 4500
Acumer 2100
Mw 11000
polymer
Acumer 3100
Mw 4500
Acumer 5000
Mw 5000
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Industrial water treatment systems
cooling tower
closed system
open system
Open circulatory system
boiler
reverse osmosis membrane
9
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10
Exchanger
Cold fluid
Hot fluid
Recirculating
pump
Cooling
Tower
A = Make up (m
3
/ H)
t
1
= Outlet cooling tower temperature ( C)
Q = Recirculation rate (m
3
/ H)
t
2
= Inlet cooling tower temperature ( C)
E = Evaporation rate (m
3
/ H)
P = Blowdown rate (m
3
/ H)
Ev = Drifting rate (m
3
/ H)
C = Concentration factor
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Industrial scale type cooling tower system
calcium carbonate
The most common type of scale, insoluble in water
calcium sulfate
Another common type of calcium scale, greater than the solubility of calcium carbonate
phosphate / zinc complex
Anti-corrosion formulations commonly used in composite
iron
Scale circulating water system due to corrosion caused by iron
silicate and silica
Water containing some special kind of scale
soil
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Dow cooling tower with scale and dispersant
Acumer 1000 - Cooling Circuits
0
2
4
6
8
10
Carbonate Scale Inhibition
Sulfate Scale Inhibition
PO4 / Zn Precipitation
Control
Iron Dispersion
SiO2 Scale Inhibition
Clay Dispersion
0
2
4
6
8
10

Control
Iron Dispersion
Clay Dispersion
0
2
4
6
8
10
Control
Iron Dispersion
Clay Dispersion
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13
0
2
4
6
8
10
Control
Iron Dispersion
Clay Dispersion
0
2
4
6
8
10

Control
Iron Dispersion
Clay Dispersion
0
2
4
6
8
10
Control
Iron Dispersion
Clay Dispersion
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Organic dispersant - Acumer 6600 versus Acumer 3100
Acumer 6600 is a good inhibitor of inorganic salts, and he has some surface activity. As such,
Acumer 6600 is a good organic and inorganic dispersant.
0
2
4
6
8
10
Surf. Prop.
Iron Ox. Disp
Clay Disp.
CaCO3 Disp
PO4 Stab.
0
2
4
6
8
10
Surf. Prop.
Iron Ox. Disp
Clay Disp.
CaCO3 Disp
PO4 Stab.
Acumer 6600
Acumer 3100
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Industrial cooling tower system
Scale
:
Calcium carbonate is the main inhibitor type
generally used to Acumer 1000/1010
Acumer 1100/1110 have better results
Acumer 2200 especially for the high hardness of the water body
Acumer 2000/3100 applicable to iron water bodies
Acumer 5000 is a good inhibitor silicate or silica
Scale
/
Corrosion
:
zinc salts and phosphates are usually used to prevent corrosion, but need to precipitate zinc
oxide and phosphate were
Control
generally used to Acumer 2000
Acumer 3100 applicable to water containing iron
organic scale
:
prevent and limit the formation of biofilms and growth
Acumer 6600
Inhibitor can mix and match these to achieve the best results
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Industrial cooling tower system
Phosphonate-containing formulations
- Deionized water
40.7%
- Phosphoric acid (75%)
11.0%
- Potassium hydroxide
20.3%
- Potassium pyrophosphate
6.5%
- Hydroxyethylidene diphosphonic (HEDP)

4.0%
- Acumer 2000 or 3100
15.5%
- BTA
2.0%
Dosage: 80-140 ppm
Phosphorus and zinc compound formula
- Deionized water
59.9%
- Hydrochloric acid (20%)
10.0%
- Phosphoric acid (75%)
8.5%
- Zinc chloride (anhydrous)
4.0%
--2- Phosphate butane-1,2,4-tricarboxylic acid (PBTC) 5.0%
- Acumer 2000 or 3100
11.6%
- Benzotriazole
1.0%
Dosage: 80-140 ppm
Corrosion and Scale Reference formula
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Boiler
17
vaporation
Exchan
g
er
Bche
Recycled steam
Lost steam
Blowdown
Feed
water
Feeding pump
Feeding
tank
Make up
water
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Boiler scale system
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calcium carbonate
calcium sulfate
phosphate / zinc complex
iron
silica
soil
thermal stability
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Boiler system
Acumer 1000 - Boilers
0
2
4
6
8
10
Phosphate Dispersion
Iron Dispersion
Sludge Dispersion
Thermal Stability
0
2
4
6
8
10
Iron Dispersion
Sludge Dispersion
Thermal Stability
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Boiler system
0
2
4
6
8
10
Iron Dispersion
Sludge Dispersion
Thermal Stability
0
2
4
6
8
10
Iron Dispersion
Sludge Dispersion
Thermal Stability
0.0
2.0
4.0
6.0
8.0
10.0
Iron Dispersion
Sludge Dispersion
Thermal Stability
0
2
4
6
8
10
Iron Dispersion
Sludge Dispersion
Thermal Stability
17.
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Twenty one
Boiler system
Residual phosphate scale system
:
generally used to Acumer 2000
Acumer 3100 applicable to iron system
Acumer 2100 applicable to the system in contact with food (FDA certification)
other scale systems
:
recommended inhibitor complex system to achieve the best results scale
generally used to Acumer 1000/2000
Acumer 1000/2100 has passed FDA approval for food contact system
Acumer 1000/3100 applies to high iron content of the system
Acumer 1000/5000 applies to systems containing silicate or silica
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Twenty two
Boiler
Formulations containing phosphate
- Deionized water
75.0%
- Acumer 2000/3100
7.5%
- Hexametaphosphate
15.0%
- Potassium hydroxide
2.5%
Note: ratio of polymer phosphate can hard water
Degree mediation
Dosage: 15 to 50 ppm
All polymer formulation
- Deionized water
29.6%
- Acumer 1000
45.0%
- Acumer 3100
15.0%
- Sodium hydroxide
10.4%
Dosage: 25 to 100 ppm
Scale Reference formula

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Reverse osmosis membrane
Twenty three
Twenty three
membrane
feedwater
reject brine
permeate
dissolved solids
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Principle
Twenty four
Twenty four
membrane
water
brine
water
brine
applied
pressure
water
brine
osmotic
pressure
osmosis
equilibrium
reverse osmosis
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Ac 2200 - REVERSE OSMOSIS
0.0
2.0
4.0
6.0
8.0
10.0
CaCO3 Inhib.
CaSO4 Inhib.
SiO2 Inhib.
Iron Ox. Disp
Clay Disp.
0.0
2.0
4.0
6.0
8.0
10.0
CaCO3 Inhib.
CaSO4 Inhib.
SiO2 Inhib.
Iron Ox. Disp
Clay Disp.
0.0
2.0
4.0
6.0
8.0
10.0
CaCO3 Inhib.
CaSO4 Inhib.
SiO2 Inhib.
Iron Ox. Disp
Clay Disp.
C
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0.0
2.0
4.0
6.0
8.0
10.0
CaCO3 Inhib.
CaSO4 Inhib.
SiO2 Inhib.
Iron Ox. Disp
Clay Disp.
0.0
2.0
4.0
6.0
8.0
10.0
CaCO3 Inhib.
CaSO4 Inhib.
SiO2 Inhib.
Iron Ox. Disp
Clay Disp.
0.0
2.0
4.0
6.0
8.0
10.0
CaCO3 Inhib.
CaSO4 Inhib.
SiO2 Inhib.
Iron Ox. Disp
Clay Disp.
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Inhibitor type and amount of choice
Inhibitor type and amount of choice depends on the water quality of the analysis and design of
the entire plant
Design and construction criteria.
In general, the amount of water added to the scale inhibitor in
2-20ppm
inhibitor may be added depending on the design of the plant process step by step
You can also choose different combinations depending on the scale inhibitor type
inhibitors should be used directly after soft diluted before use, dilute ANTISCALANT
Fluid should be used up in one day
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RO system
Reverse osmosis membrane inhibitor of the benefits:
Prevent the formation of inorganic scale, improve efficiency films

Maintaining the efficiency of the reverse osmosis membrane permeate
Extend the life of reverse osmosis membrane, to maintain osmotic quality
Reverse osmosis membrane extend maintenance intervals

Reduce maintenance difficulty
Homopolymers and copolymers of acrylic acid suitable for calcium sulfate, calcium and
phosphate scale
Sulfated acrylic polymers and acrylic polymers suitable for iron oxide, calcium phosphate and
silicic acid
Salt or silica scale
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Dow Water Product Selection Guide
NAME
APPLICATION *
CHEMICAL NATURE
Mw
SOLIDS
pH
VISCO
DOSAGE as is
FEATURES / BENEFITS
(%)
(Typ, mPa.s)
(Typical, ppm)
Scale inhibitor for carbonates, sulphates and sparingly soluble salts and dispersant.
Particularly suitable for incorporation in acidic formulations.
Scale inhibitor for carbonates, sulphates and sparingly soluble salts and dispersant.
Particularly suitable for incorporation in neutral or alkaline formulations.
Scale inhibitor for carbonates, sulphates and oxalates. Specially designed to comply
with sugar industry regulations. Used alone or in acidic formulations
Scale inhibitor for carbonates, sulphates and oxalates. Specially designed to comply
with sugar industry regulations. Used alone or in neutral or alkaline formulations
Scale inhibitor for carbonates, sulphates and sparingly soluble salts and good dispersant.
Particularly suitable for incorporation in acidic formulations.
Scale inhibitor for carbonates, sulphates and sparingly soluble salts and good dispersant.
Particularly suitable for incorporation in neutral or alkaline formulations.
General purpose scale inhibitor and sludge dispersant
Very good thermal stability
Carboxylic sulphonated
Phosphates and zinc stabilizer for anti-scale / anti-corrosion water treatment formulations
copolymer
Excellent silt dispersant. Enhances corrosion inhibition.
Same properties as Acumer 2000. Good iron oxides dispersant
copolymer
Complies with FDA food additives regulation.
Carbonates and sulphates scale inhibitor. Particularly effective for harsh running
conditions (high pH, high temperature, high scalants concentration)
Sames properties as Acumer 2000. In addition, excellent efficiency in presence of
non ionic terpolymer
soluble iron where acrylic homopolymers fail. Excellent dispersant for iron oxides
Same properties as Acumer 3100. In addition, excellent scale inhibitor and
dispersant for silica and magnesium silicate.
Dispersant for organic and inorganic particles. Particularly effective as biofouling
inhibitor
Traceable polymer. Same properties as Acumer 1000. A tracer is incorporated in the
polymeric chain, allowing a quick and easy concentration measurement using a test kit.
copolymer
* B: Boilers - CC: Cooling Circuits - RO: Reverse Osmosis - TD: Thermal Desalination - PP:
Pulp and Paper
3,8 - 4,6
270
10--30
Optidose 3100
CC / B / RO
4500
43--44 2,1 - 3,0
160
10--30
Optidose 2000
CC / B / RO
4500 42,5 - 43,5
47--49 3,2 - 4,0
190
10--30
Optidose 1000
CC / B / RO
Acrylic homopolymer
2000
24--26 9,5 - 10,5
100
10--30
Acumer 6600
CC / RO
Carboxylic copolymer
10000
Acumer 5000
CC / B / RO
5000
44--46 2,3 - 2,9
400
10--30
2,1 - 3,0
160
10--30
Acumer 3100
CC / B / RO
4500
43--44
54--56 3,5 - 4,5
500
10--30
Acumer 2200
CC / RO / TD
Carboxylic copolymer
2000
3,8 - 4,6
270
10--30
Acumer 2100
B / PP
11000 36,5 - 37,5 4,3 - 5,3
225
10--30
Acumer 2000
CC / B / RO
4500 42,5 - 43,5
29--31 9,0 - 10,8
225
10--30
Acumer 1850
B
Carboxylate polymer
30000
44--46 6,5 - 7,5
850
10--30
Acumer 1110
CC / B / RO
Acrylic homopolymer
4500
47--49 3,2 - 4,0
800
10--30
Acumer 1100
CC / B / RO
Acrylic homopolymer
4500
42--44 6,5 - 8,0
180
10--25
Acumer 1051
SUGAR
Acrylic homopolymer
2150
47--49 3,2 - 4,0
190
10--20
Acumer 1050
SUGAR
Acrylic homopolymer
2150
42--44 6,5 - 8,0
180
10--30
Acumer 1010
CC / B / RO
Acrylic homopolymer
2000
47--49 3,2 - 4,0
190
10--30
Acumer 1000
CC / B / RO
Acrylic homopolymer
2000

Dow Industrial Water Treatment Scale Inhibitor and Dispersant

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Page 1

Dow industrial water treatment scale inhibitor and dispersant

Carbonate Scale Inhibition

Sulfate Scale Inhibition

- Hydroxyethylidene diphosphonic (HEDP)

Scale Reference formula

Prevent the formation of inorganic scale, improve efficiency films

Reverse osmosis membrane extend maintenance intervals

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