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Carbon steel

From Wikipedia, the free encyclopedia

Carbon steel is steel in which the main interstitial alloying constituent is carbon in the range of 0.122.0%.
The American Iron and Steel Institute (AISI) defines carbon steel as the following: "Steel is considered to
be carbon steel when no minimum content is specified or required for chromium, cobalt, molybdenum,
nickel, niobium, titanium, tungsten, vanadium or zirconium, or any other element to be added to obtain a
desired alloying effect; when the specified minimum for copper does not exceed 0.40 percent; or when
the maximum content specified for any of the following elements does not exceed the percentages noted:
manganese 1.65, silicon 0.60, copper 0.60."[1]
The term "carbon steel" may also be used in reference to steel which is not stainless steel; in this use
carbon steel may include alloy steels.
As the carbon percentage content rises, steel has the ability to become harder and stronger through heat
treating; however it becomes less ductile. Regardless of the heat treatment, a higher carbon content
reduces weldability. In carbon steels, the higher carbon content lowers the melting point.[2]

Contents
1 Type
1.1 Mild and low-carbon steel
1.2 Higher carbon steels
2 Heat treatment
3 Case hardening
4 Forging temperature of steel
5 See also
6 References
7 Bibliography

Type
Carbon steel is broken down into four classes based on carbon content:

Mild and low-carbon steel


Mild steel, also known as plain-carbon steel, is the most common form of steel because its price is
relatively low while it provides material properties that are acceptable for many applications, more so
than iron. Low-carbon steel contains approximately 0.050.320% carbon[1] making it malleable and

ductile. Mild steel has a relatively low tensile strength, but it is cheap and easy to form; surface hardness
can be increased through carburizing.[3]
It is often used when large quantities of steel are needed, for example as structural steel. The density of
mild steel is approximately 7.85 g/cm3 (7850 kg/m3 or 0.284 lb/in3)[4] and the Young's modulus is 210 GPa
(30,000,000 psi).[5]
Low-carbon steels suffer from yield-point runout where the material has two yield points. The first yield
point (or upper yield point) is higher than the second and the yield drops dramatically after the upper
yield point. If a low-carbon steel is only stressed to some point between the upper and lower yield point
then the surface may develop Lder bands.[6] Low-carbon steels contain less carbon than other steels and
are easier to cold-form, making them easier to handle.[7]

Higher carbon steels


Carbon steels which can successfully undergo heat-treatment have a carbon content in the range of 0.30
1.70% by weight. Trace impurities of various other elements can have a significant effect on the quality of
the resulting steel. Trace amounts of sulfur in particular make the steel red-short, that is, brittle and
crumbly at working temperatures. Low-alloy carbon steel, such as A36 grade, contains about 0.05% sulfur
and melts around 1,4261,538 C (2,5992,800 F).[8] Manganese is often added to improve the
hardenability of low-carbon steels. These additions turn the material into a low-alloy steel by some
definitions, but AISI's definition of carbon steel allows up to 1.65% manganese by weight.
Low carbon steel
0.05-0.3% carbon content.
Medium carbon steel
Approximately 0.2500.6% carbon content.[1] Balances ductility and strength and has good wear
resistance; used for large parts, forging and automotive components.[9][10]
High-carbon steel (ASTM 304)
Approximately 0.92.5% carbon content.[1] Very strong, used for springs and high-strength wires.[11]
Ultra-high-carbon steel
Approximately 2.53.0% carbon content.[1] Steels that can be tempered to great hardness. Used for
special purposes like (non-industrial-purpose) knives, axles or punches. Most steels with more than 2.5%
carbon content are made using powder metallurgy. Note that steel with a carbon content above 2.14% is
considered cast iron.

Heat treatment

The purpose of heat treating carbon steel is to change the mechanical properties of steel, usually ductility,
hardness, yield strength, or impact resistance. Note that the
electrical and thermal conductivity are only slightly altered. As with
most strengthening techniques for steel, Young's modulus
(elasticity) is unaffected. All treatments of steel trade ductility for
increased strength and vice versa. Iron has a higher solubility for
carbon in the austenite phase; therefore all heat treatments,
except spheroidizing and process annealing, start by heating the
steel to a temperature at which the austenitic phase can exist. The
steel is then quenched (heat drawn out) at a high rate causing
cementite to precipitate and finally the remaining pure iron to
solidify. The rate at which the steel is cooled through the eutectoid
Iron-carbon phase diagram, showing
temperature affects the rate at which carbon diffuses out of
the temperature and carbon ranges
austenite and forms cementite. Generally speaking, cooling swiftly
for certain types of heat treatments.
will leave iron carbide finely dispersed and produce a fine grained
pearlite (until the martensite critical temperature is reached) and
cooling slowly will give a coarser pearlite. Cooling a hypoeutectoid steel (less than 0.77 wt% C) results in a
lamellar-pearlitic structure of iron carbide layers with -ferrite (pure iron) between. If it is hypereutectoid
steel (more than 0.77 wt% C) then the structure is full pearlite with small grains (larger than the pearlite
lamella) of cementite scattered throughout. The relative amounts of constituents are found using the
lever rule. The following is a list of the types of heat treatments possible:
Spheroidizing: Spheroidite forms when carbon steel is heated to approximately 700 C for over 30
hours. Spheroidite can form at lower temperatures but the time needed drastically increases, as this
is a diffusion-controlled process. The result is a structure of rods or spheres of cementite within
primary structure (ferrite or pearlite, depending on which side of the eutectoid you are on). The
purpose is to soften higher carbon steels and allow more formability. This is the softest and most
ductile form of steel. The image to the right shows where spheroidizing usually occurs.[12]
Full annealing: Carbon steel is heated to approximately 40 C above Ac3 or Ac1 for 1 hour; this
ensures all the ferrite transforms into austenite (although cementite might still exist if the carbon
content is greater than the eutectoid). The steel must then be cooled slowly, in the realm of 20C
(36F) per hour. Usually it is just furnace cooled, where the furnace is turned off with the steel still
inside. This results in a coarse pearlitic structure, which means the "bands" of pearlite are thick.[13]
Fully annealed steel is soft and ductile, with no internal stresses, which is often necessary for costeffective forming. Only spheroidized steel is softer and more ductile.[14]
Process annealing: A process used to relieve stress in a cold-worked carbon steel with less than 0.3
wt% C. The steel is usually heated up to 550650 C for 1 hour, but sometimes temperatures as high
as 700 C. The image rightward shows the area where process annealing occurs.
Isothermal annealing: It is a process in which hypoeutectoid steel is heated above the upper critical
temperature and this temperature is maintained for a time and then the temperature is brought
down below lower critical temperature and is again maintained. Then finally it is cooled at room

temperature. This method rids any temperature gradient.


Normalizing: Carbon steel is heated to approximately 55 C above Ac3 or Acm for 1 hour; this
ensures the steel completely transforms to austenite. The steel is then air-cooled, which is a cooling
rate of approximately 38 C (100 F) per minute. This results in a fine pearlitic structure, and a moreuniform structure. Normalized steel has a higher strength than annealed steel; it has a relatively
high strength and hardness.[15]
Quenching: Carbon steel with at least 0.4 wt% C is heated to normalizing temperatures and then
rapidly cooled (quenched) in water, brine, or oil to the critical temperature. The critical temperature
is dependent on the carbon content, but as a general rule is lower as the carbon content increases.
This results in a martensitic structure; a form of steel that possesses a super-saturated carbon
content in a deformed body-centered cubic (BCC) crystalline structure, properly termed bodycentered tetragonal (BCT), with much internal stress. Thus quenched steel is extremely hard but
brittle, usually too brittle for practical purposes. These internal stresses cause stress cracks on the
surface. Quenched steel is approximately three to four (with more carbon) fold harder than
normalized steel.[16]
Martempering (Marquenching): Martempering is not actually a tempering procedure, hence the
term "marquenching". It is a form of isothermal heat treatment applied after an initial quench of
typically in a molten salt bath at a temperature right above the "martensite start temperature". At
this temperature, residual stresses within the material are relieved and some bainite may be formed
from the retained austenite which did not have time to transform into anything else. In industry,
this is a process used to control the ductility and hardness of a material. With longer marquenching,
the ductility increases with a minimal loss in strength; the steel is held in this solution until the inner
and outer temperatures equalize. Then the steel is cooled at a moderate speed to keep the
temperature gradient minimal. Not only does this process reduce internal stresses and stress cracks,
but it also increases the impact resistance.[17]
Quench and tempering: This is the most common heat treatment encountered, because the final
properties can be precisely determined by the temperature and time of the tempering. Tempering
involves reheating quenched steel to a temperature below the eutectoid temperature then cooling.
The elevated temperature allows very small amounts of spheroidite to form, which restores
ductility, but reduces hardness. Actual temperatures and times are carefully chosen for each
composition.[18]
Austempering: The austempering process is the same as martempering, except the steel is held in
the molten salt bath through the bainite transformation temperatures, and then moderately cooled.
The resulting bainite steel has a greater ductility, higher impact resistance, and less distortion. The
disadvantage of austempering is it can only be used on a few steels, and it requires a special salt

bath.[19]

Case hardening
Case hardening processes harden only the exterior of the steel part, creating a hard, wear resistant skin
(the "case") but preserving a tough and ductile interior. Carbon steels are not very hardenable; therefore
wide pieces cannot be through-hardened. Alloy steels have a better hardenability, so they can throughharden and do not require case hardening. This property of carbon steel can be beneficial, because it gives
the surface good wear characteristics but leaves the core tough.

Forging temperature of steel


[20]

Steel Type

Maximum forging temperature (F /


C)

Burning temperature (F /
C)

1.5% carbon

1920 / 1049

2080 / 1138

1.1% carbon

1980 / 1082

2140 / 1171

0.9% carbon

2050 / 1121

2230 / 1221

0.5% carbon

2280 / 1249

2460 / 1349

0.2% carbon

2410 / 1321

2680 / 1471

3.0% nickel steel

2280 / 1249

2500 / 1371

3.0% nickelchromium steel

2280 / 1249

2500 / 1371

5.0% nickel (case-hardening)


steel

2320 / 1271

2640 / 1449

Chromiumvanadium steel

2280 / 1249

2460 / 1349

High-speed steel

2370 / 1299

2520 / 1382

Stainless steel

2340 / 1282

2520 / 1382

Austenitic chromiumnickel steel 2370 / 1299

2590 / 1421

Silico-manganese spring steel

2460 / 1349

See also
Cold working
Hot working
Welding
Forging

2280 / 1249

References
1. ^ a b c d e "Classification of Carbon and Low-Alloy Steels" (http://www.keytometals.com/Articles/Art62.htm)
2. ^ Knowles, Peter Reginald (1987), Design of structural steelwork (http://books.google.com/books?id=U6wX3C8ygcC&pg=PA1) (2nd ed.), Taylor & Francis, p. 1, ISBN 978-0-903384-59-9.
3. ^ Engineering fundamentals page on low-carbon steel
(http://efunda.com/materials/alloys/alloy_home/../carbon_steels/low_carbon.cfm)
4. ^ Elert, Glenn, Density of Steel (http://hypertextbook.com/facts/2004/KarenSutherland.shtml), retrieved
23 April 2009.
5. ^ Modulus of Elasticity, Strength Properties of Metals Iron and Steel
(http://www.engineersedge.com/manufacturing_spec/properties_of_metals_strength.htm), retrieved 23 April
2009.
6. ^ Degarmo, p. 377.
7. ^ "Low-carbon steels" (http://www.efunda.com/materials/alloys/carbon_steels/low_carbon.cfm). efunda.
Retrieved 2012-05-25.
8. ^ Ameristeel article on carbon steel (http://www.ameristeel.com/products/msds/docs/carbon_steel.pdf)
9. ^ Nishimura, Naoya; Murase, Katsuhiko; Ito, Toshihiro; Watanabe, Takeru; Nowak, Roman. "Ultrasonic
detection of spall damage induced by low-velocity repeated impact". Central European Journal of Engineering 2
(4): 650655. doi:10.2478/s13531-012-0013-5 (http://dx.doi.org/10.2478%2Fs13531-012-0013-5).
10. ^ Engineering fundamentals page on medium-carbon steel
(http://efunda.com/materials/alloys/alloy_home/../carbon_steels/medium_carbon.cfm)
11. ^ Engineering fundamentals page on high-carbon steel
(http://efunda.com/materials/alloys/alloy_home/../carbon_steels/high_carbon.cfm)
12. ^ Smith, p. 388
13. ^ Alvarenga HD, Van de Putte T, Van Steenberge N, Sietsma J, Terryn H (Apr 2009). "Influence of Carbide
Morphology and Microstructure on the Kinetics of Superficial Decarburization of C-Mn Steels". Metal Mater
Trans A. doi:10.1007/s11661-014-2600-y (http://dx.doi.org/10.1007%2Fs11661-014-2600-y).
14. ^ Smith, p. 386
15. ^ Smith, pp. 386387
16. ^ Smith, pp. 373377
17. ^ Smith, pp. 389390
18. ^ Smith, pp. 387388
19. ^ Smith, p. 391
20. ^ Brady, George S.; Clauser, Henry R. ; Vaccari A., John (1997). Materials Handbook (14th ed.). New York, NY:
McGraw-Hill. ISBN 0-07-007084-9.

Bibliography
Degarmo, E. Paul; Black, J T.; Kohser, Ronald A. (2003), Materials and Processes in Manufacturing
(9th ed.), Wiley, ISBN 0-471-65653-4.

Oberg, E.; et al. (1996), Machinery's Handbook (25th ed.), Industrial Press Inc, ISBN 0-8311-2599-3.
Smith, William F.; Hashemi, Javad (2006), Foundations of Materials Science and Engineering (4th
ed.), McGraw-Hill, ISBN 0-07-295358-6.
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Categories: Steels Metallurgical processes
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