Beruflich Dokumente
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a r t i c l e
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Article history:
Received 19 June 2008
Received in revised form 18 May 2009
Accepted 13 December 2009
Available online 21 January 2010
Keywords:
Combined cycle plants
Exergy analysis
Internal exergy efciency
Exergy ow diagrams
Value diagrams
Cycle-Tempo
a b s t r a c t
The application of the exergy concept for the thermodynamic evaluation of energy conversion systems
and chemical plants is steadily growing. However the general application of this concept is complicated
by the large variety of parameters that is used to present the results of such evaluations. Easily understandable diagrams that offer a quick overview of the main results of such an evaluation will be very
helpful.
Large power plants, as for example combined cycle plants, consist of a large number of apparatuses.
The thermodynamic modeling of these plants requires the computation of the thermodynamic properties
at inlets and outlets of all apparatuses. These results allow for the calculation of the exergy values at all
considered points after dening an appropriate environment. Using these exergy values exergy losses and
efciencies of all considered apparatuses can be determined.
However, additional parameters and methods for presenting losses are necessary to understand the
origin of exergy losses and the options for further improvements. Exergy efciencies of power cycles
show the actual losses but do in general not clearly indicate the potential for improvement. The use of
the so-called internal exergy efciency of a power cycle will be helpful to understand this potential. Also
value diagrams and exergy ow diagrams are very useful to understand the thermodynamic performance
of complicated systems.
In this paper the application of these tools is demonstrated for the evaluation of alternative designs of
combined cycle plants. Three system designs are established for this purpose and modeled using the
computer program Cycle-Tempo. The considered combined cycles use the same gas turbine but have different steam bottoming cycles. Differences do originate from the number of pressure levels at which
steam is generated in the HRSG (Heat Recovery Steam Generator). The evaluation includes respectively
a single pressure, double pressure and triple pressure HRSG. The steam pressures are optimized with
regard to overall plant efciency using a multi-parameter optimization procedure.
The evaluation shows that the application of the internal exergy efciency of a power cycle is in particular useful if the temperature of heat transfer from the cycle will be affected by the cycle performance,
i.e. in the case of gas turbine cycles. The value diagrams show how the increasing number of pressure levels of steam generation will reduce the losses due to heat transfer in the HRSG but also the exergy loss
due to the exhaust of ue gas to the stack. The exergy ow diagrams show that the main exergy losses
of combined cycle plants occur in the combustion process. Possibilities to reduce these losses are limited.
Serious improvement of the efciencies of future combined cycle plants is conceivable by applying high
temperature fuel cells.
2009 Elsevier Ltd. All rights reserved.
1. Introduction
Exergy analysis is frequently used for the thermodynamic evaluation of power plants. In general an exergy analysis will provide
additional knowledge about the thermodynamic losses in the system. However the signicance of an exergy analysis depends on
the insight that will be achieved with regard to the origin of losses
and the options for loss reductions. Therefore, graphs that allow a
* Corresponding author. Tel.: +31 15 278 2178; fax: +31 15 278 2460.
E-mail address: n.woudstra@tudelft.nl (N. Woudstra).
0196-8904/$ - see front matter 2009 Elsevier Ltd. All rights reserved.
doi:10.1016/j.enconman.2009.12.016
1100
Nomenclature
ex
Ex
Exloss
ExQ
h
LHVfuel
m
Q
s
T
TC
TH
T0
T
TC
TH
W
Wrev
bottoming cycle
cold
hot
inlet
outlet
topping cycle
Abbreviations
CC
Combined Cycle
GT
gas turbine (cycle)
HP
high pressure
HRSG
Heat Recovery Steam Generator
IP
intermediate pressure
LP
low pressure
ST
steam turbine (cycle)
1101
TC
W rev 1
QH
TH
TC
W gex; intern 1
QH
TH
gth; rev
W rev
TC
1
QH
TH
For real systems the efciency will always be lower because of friction and other losses in the cycle. If the effect of all losses in the cycle is included in the so-called internal exergy efciency (gex, intern)
the thermal cycle efciency can be written as:
gth
W
gex;
QH
intern
TC
1
TH
The Eqs. (1) and (2) show that the internal efciency is actually dened as:
gex; intern
W
W rev
This means that the internal exergy efciency is dened as the ratio
of two amounts of work. The internal exergy efciency can be used
to assess the thermodynamic quality of a power cycle or a combination of power cycles. In other papers this efciency is also called
second law efciency (i.e. [19]) but as efciencies based on the
second law can be dened in different ways a more specic name
is preferred.
The work derived from an amount of heat can determined for a
reversible cycle respectively an irreversible cycle then becomes:
Heat transfer to and from a power cycle in general does not occur at
constant temperatures. However to enable the universal use of Eqs.
(1), (2), (4), and (5) the constant temperatures of heat transfer have
to be replaced by the thermodynamic equivalent temperature (T).
Then the general equation for the efciency of a thermal power cycle becomes:
TC
!
6
TH
W W bc
gth tc
gex;
Q H; tc
gex;
intern;
CC gth;
intern; CC
1
TC
TH
7
rev
Thus the internal efciency of the combined cycle (gex, intern, CC) not
only includes the losses of the separate power cycles but also the
losses of the intermediate reservoir.
2.2. The thermodynamic equivalent temperature of heat transfer
Heat transfer to or from a uid ow will in general change the
temperature of the ow; only in case of phase changes of pure uids the temperature will remain constant. The exergy of the transferred heat can be determined with the following equation:
ExQ
out
in
T0
dQ
1
T
hot reservoir
TH
QH
topping
cycle
hot reservoir
TH
W tc
Q C,tc T C,tc
intermediate
reservoir
QH
Q H,bc TH,bc
W
bottoming
cycle
QC
W bc
QC
TC
cold reservoir
Fig. 1. General model of thermal power cycles.
TC
cold reservoir
Fig. 2. General model of a combined cycle system.
1102
ex in
ex out
Q
Fig. 3. System of heat transfer to a uid.
ExQ
out
in
T0
T0
Q
dQ 1
1
T
T
10
T0
m hout hin T 0 sout sin 1
m hout hin
T
11
hout hin
sout sin
12
T out T in
ln TTout
in
13
p2
(1-
T0
p1
2
4
2'
p2 > p1
4'
0
W shaft
T0
Q flue gas
LHV
ex fuel
s
Fig. 4. Simple gas turbine cycle (closed cycle).
Ex loss, combustion
Ex flue gas
1103
T0
T
Temperature [C]
(1-
600
500
400
300
200
100
W shaft, ST
Entropy [kJ/kg.K]
W shaft, GT
Q steam
LHV fuel
ex fuel
Ex loss, combustion
Ex loss, stack
Ex loss, condenser
600
Temperature [C]
0
500
400
300
200
100
Table 1
Overall results and some characteristic data of the combined cycle plants.
1 press.
2 press.
3 press.
MWe
364.26
0.5514
374.84
0.5674
0.0160
379.13
0.5739
0.0225
MW
C
C
C
660.62
17.12
1227.81
581.60
160.78
660.62
17.12
1227.81
582.43
119.03
660.62
17.12
1227.81
583.92
81.88
C
Bar
C
Bar
C
Bar
Bar
550.00
41.54
550.22
9.261
549.75
112.9
550.96
11.62
0.02643
0.02643
550.40
175.0
552.31
31.45
226.68
2.711
0.02643
600
Temperature [C]
Units
Overall results
Net electrical power
Thermal efciency
Increase in efciency
Entropy [kJ/kg.K]
500
400
300
200
100
Entropy [kJ/kg.K]
Fig. 7. (a) T,s-diagram of the single pressure steam cycle. (b) T,s-diagram of the
double pressure steam cycle. (c) T,s-diagram of the triple pressure steam cycle.
1104
31
31
3
2
3
HPT
IPT
301
LPT
304
306
1
5
5
41
323
301
304
305
306
302
303
302
303
H
307
305
361
325
42
6
7
320
322
359
324
403
323
403
321
322
404
HP-EVAP
402
402
321
9
378
43
401
319
360
320
IP-SH
HP-ECO 3
401
358
359
H
318
44
10
308
8
11
IP-EVAP
355
357
319
358
H
356
356
357
12
355
13
317
61
45
H
HP-ECO 2
IP-ECO 2
354
354
H
LP-Super Heater
366
46
14
318
377
10
62
15
353
363
LP-EVAP
365
376
H
374
373
375
364
16
316
Dearator
11
63
47
317
311
LP-ECO
362
353
372
313
361
H
IP-ECO 1
17
371
352
351
352
351 313
314
312
HP-ECO 1
64
315
312
314
316
H
315
341
48
18
12
343
19
DA-evap 342
H
342
20
341
309
311
310 331
331
332
H
310
308
309
307
21
15
Stack
sure of the HP, IP and LP steam turbines. Steam from the LP steam
generator is mixed with the IP outlet ow. The temperature of the
1105
Table 3
Results of the steam turbine cycles.
Units
1 press.
2 press.
3 press.
MW
MW
660.62
251.36
0.3805
1040.0
660.62
250.75
0.3796
1040.0
660.62
249.65
0.3779
1040.0
521.1
521.4
521.9
T H;
gth, rev, GT
gex, intern, GT
0.4989
0.7626
0.4987
0.7612
0.4982
0.7586
Exergy balance
Combustor
Fuel exergy
Exergy loss combustor
Exergy transferred to GT cycle
MW
MW
MW
691.48
204.61
486.87
691.48
204.61
486.87
691.48
204.61
486.87
MW
MW
MW
41.27
251.36
194.24
0.8590
41.20
250.75
194.92
0.8589
41.10
249.5
196.12
0.8586
gth, GT
TH
T C;
GT
GT cycle
Internal exergy loss
Net electrical power
Exergy of exhaust gas
gex, GT cycle
Units
1 press.
2 press.
3 press.
MW
MW
MW
400.28
300.73
112.90
0.3754
522.7
400.90
329.72
124.09
0.3763
529.7
402.02
355.91
129.48
0.3638
526.6
TC
295.2
295.2
295.2
gth, rev, ST
gex, intern, ST
0.4352
0.8626
0.4427
0.8501
0.4394
0.8279
MW
MW
MW
MW
133.51
112.90
4.38
16.23
0.8743
149.27
124.09
4.79
20.39
0.8589
160.32
129.48
5.27
25.57
0.8351
gth, ST
ST
Exergy balance
Exergy from HRSG to ST cycle
Net electrical power
Exergy from ST cycle to condenser
Internal exergy loss
gex, ST cycle
gex;GT cycle
Exproduct
Pelectr; net
Exsource
Exto GT cycle Exexhaust gas
14
1106
P
Um hout hin
T P
Um sout sin
15
intern; ST
gth;
rev; ST
Q_ H to ST
16
Table 4
Results of the combined cycle plants.
Combined cycle plant
Units
1 press.
2 press.
3 press.
TH
MW
MW
660.62
364.26
0.5514
1040.0
660.62
374.84
0.5674
1040.0
660.62
379.13
0.5739
1040.0
TC
295.2
295.2
295.2
gth, rev, CC
gex, intern, CC
gex, CC
0.7162
0.7699
0.8070
0.7162
0.7923
0.8157
0.7162
0.8014
0.8195
Exergy balance
Fuel exergy
Net electrical power
Overall exergy loss
Exergy efciency CC plant
MW
MW
MW
691.48
364.26
327.22
0.5268
691.48
374.84
316.64
0.5421
691.48
379.13
312.35
0.5483
gth, CC
Exto ST in HRSG
Um;w exout;
exin;
17
gex; ST cycle
Exproduct
Pelectr; net
Exsource
Exto ST cycle Exto condenser
18
The differences between the internal cycle efciency (gex, intern, ST)
and the exergy efciency of the cycle (gex, ST cycle) are much lower
than in the case of the gas turbine cycle.
3.2.3. Combined cycle plant
The CC plants are evaluated assuming that the gas turbine cycle
and the steam turbine cycle together are considered to be one thermal power cycle. The overall results of the CC plants are shown in
Table 4. The net electrical power generated by the combined cycle
equals the sum of the net electrical powers from the gas turbine
cycle and the steam cycle. Then the thermal efciency of the combined cycle increases from 0.5514 for the single pressure plant to
0.5739 for the triple pressure plant.
Heat transfer to the combined cycle occurs only in the combustor of the GT; therefore the (thermodynamic equivalent) temperature of heat transfer to the cycle is the same as for the gas turbine
cycle (1040 K). Heat transfer from the combined cycle to the environment occurs in the steam condenser (at 295.2 K). Thus the heat
transferred to the cycle as well as the thermal efciency of the
reversible cycle (gth, rev, CC) are the same for all the considered
cases. From Eq. (16) it will be clear that the differences in the thermal efciencies of the irreversible cycles are caused only by the differences in the internal efciencies of the cycles. Therefore
increasing the number of pressure levels for steam generation in
the HRSG will increase the internal efciencies (gex, intern, CC) from
0.7699 for the single pressure case to 0.8014 for the triple pressure
case.
The exergy efciency of the combined cycle can be calculated as
before for the GT and the ST cycles. But in this case also the exergy
that is discharged to the environment trough the stack has to be
subtracted in the denominator. The following equation is used:
Units
1 press.
2 press.
3 press.
Exergy balance
Exergy transferred from GT cycle
Exergy transferred to ST cycle
Exergy loss HRSG
Exergy ue gas to stack
MW
MW
MW
MW
194.24
133.51
29.64
31.09
194.92
149.27
23.12
22.53
196.12
160.32
18.99
16.81
gex; CC
Exproduct
Pelectr; net
Exsource
Exto GT cycle Exto stack Exto condenser
1107
the HRSG obviously inuences only the losses in the system parts
that have limited effect on the overall exergy loss of the CC plant.
More detailed insight into the effect of an increased number of
pressure levels can be obtained from the value diagrams of the
HRSGs. The value diagram for the single pressure case (Fig. 9)
shows that substantial exergy losses occur in most of the heat
exchangers and in particular in the stack. The value diagram for
the triple pressure case (Fig. 10) shows that further reductions of
the exergy losses in the HRSG and stack are possible. But it also
makes clear that further attempts to reduce these losses will have
only little effect.
19
The differences between the internal cycle efciency (gex, intern, CC)
and the exergy efciency of the cycle (gex, CC) are again much lower
than in the case of the gas turbine cycle.
The exergy balance of the combined cycle in Table 4 shows the
resulting overall exergy losses and the exergy efciencies of the
considered plants. The overall exergy loss is the difference between
the fuel exergy and the net electrical power; the exergy efciency
is calculated as the ratio of the net electrical power and the fuel
exergy and increases from 0.5268 for the single pressure case to
05483 for the triple pressure case.
The efciency increase results from differences of the heat
transfer in the HRSG. Therefore the exergy losses of the HRSG will
be discussed into more detail. The exergy balances of the HRSGs
are presented in Table 5. From the exergy transferred from the
GT cycle (194.24 MW) in the single pressure case 29.64 MW is lost
due to heat transfer in the HRSG, 133.51 MW is transferred to the
steam cycle and the remainder (31.09 MW) is passed to the stack.
It appears that by increasing the number of pressure levels the
reduction of the exergy loss to the stack is even higher than the
reduction of exergy loss due to heat transfer in the HRSG. The
reduction of exergy loss results in a signicant higher exergy transfer to the steam cycle for the triple pressure case (+20% when compared to the single pressure case). However the effect on the
overall plant efciency is somewhat mitigated by the slightly higher exergy losses of the ST cycle as shown in Table 3.
The effect of the increased number of pressure levels is demonstrated into more detail by the value diagrams of the HRSGs
shown in Figs. 9 and 10 for the single and triple pressure cases.
The shaded areas do represent the exergy loss. The temperature
curve of the ue gas, if cooled to environmental temperature after
leaving the stack, shows clearly the effect of condensing the water
vapor that is available in the ue gas.
An overview of all exergy losses and exergy ows of the
combined cycle plants is shown in the exergy ow diagrams
(Grassmann diagrams) in Figs. 11 and 12. The diagrams show the
reduced exergy losses of HRSG and stack for the triple pressure
case. However they also show that the larger exergy losses due
combustion and friction in the gas turbine cycle remain unaffected.
4. Discussion of results
4.1. Exergy ow diagram and value diagram
The exergy ow diagrams of the CC plants and the value diagrams of the HRSGs give a clear and useful overview of all exergy
losses. The exergy ow diagrams (Figs. 11 and 12) show that more
than 35% (205 + 41 MW) of the fuel exergy entering the CC plant is
lost due to combustion and friction in the gas turbine cycle. The
exergy losses in HRSG, stack and steam cycle together are only
11% (30 + 31 + 16 MW) in the case of the single pressure system
and are reduced to 9% for the triple pressure case. The increase
of the number of pressure levels at which steam is generated in
1108
1 - T 0 / T [-]
HP Superheat 317
HP Evaporato 316
400
0.5
300
HP-ECO 313
DA evap 342
200
Preheater 308
Temperature [C]
800
700
600
500
Reheater 303
100
Stack 107
15
0
0
33.7
92.5
223
274
282 301
465
Fig. 9. Value diagram of the HRSG with steam generated at 1 pressure level.
1 - T 0 / T [-]
HP Evaporato 322
HP end ECO 319
IP superheat 358
IP Evaporato 357
HP-ECO 2 317
IP-ECO 2 354
LP-superheat 366
LP Evaporato 365
LP-ECO 362
IP ECO 1 352
HP ECO 315
D.A. evapora 342
Heat Exchgr. 309
0.5
Temperature [C]
800
700
600
HP Superheat 323
Reheater 303
500
400
300
200
100
Stack 15
15
0
0
59.1
103
154
198
204
240
270280
283
315
316
318
322332
356
467
Fig. 10. Value diagram of the HRSG with steam generated at 3 pressure levels.
Ex fuel = 691 MW
Ex fuel = 691 MW
Ex to GT cycle = 487 MW
Ex to GT cycle = 487 MW
GT cycle Ex loss = 41 MW
GT cycle Exloss = 41 MW
Ex to HRSG = 194 MW
Ex to HRSG = 196 MW
HRSG Ex loss = 30 MW
HRSG Ex loss = 19 MW
Ex to SC = 134 MW
stack Exloss = 31 MW
Ex to SC = 160 MW
stack Exloss = 17 MW
PGT = 251 MW
Pe = 364 MW
condenser Ex loss = 4 MW
PST = 113 MW
Fig. 11. The exergy ow diagram (Grassmann diagram) of the CC plant with 1
pressure HRSG.
PGT = 250 MW
Pe = 379 MW
condenser Ex loss = 5 MW
PST = 129 MW
Fig. 12. The exergy ow diagram (Grassmann diagram) of the CC plant with 3
pressure HRSG.
19
00
00
17
15
00
00
13
11
00
90
70
0
30
50
0
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
efficiency
actual efficiency
Fig. 13. The effect of the temperature of heat transfer to the cycle on the efciency
of a thermal power cycle (the actual efciency is based on an internal cycle
efciency of 0.80).
1109
5. Conclusions
The application of combined cycles has resulted in a signicant
increase of power plant efciencies during the last decades. Overall
plant efciencies of about 60% are achievable today if heat from the
gas turbine exhaust gases is efciently used. The evaluation of
exergy losses in combined cycle plants shows that these losses
are mainly dominated by the exergy losses of thermal combustion.
Possibilities to reduce these losses are limited. The exergy ow diagrams (Figs. 11 and 12) show that the highest losses are caused by
(thermal) combustion of the fuel. The further enhancement of
overall power plant efciencies to 70% or even higher will require
the development of high temperature fuel cell systems like SOFC
GT hybrid systems
The comparison of CC plants with increasing number of pressure levels of steam generation in the HRSG shows that the efciency gain of a triple pressure system in comparison with a
single pressure system is caused by the reduction of the exergy loss
of heat transfer in the HRSG as well as the lower exergy of the ue
gasses discharged to the stack. The last effect is even more important than the reduction of exergy losses due to heat transfer as can
be learned from the value diagrams of the HRSGs (Figs. 9 and 10).
In the case of the triple pressure system the remaining exergy
losses of heat transfer and ue gas discharge together are about
5% of the fuel exergy. A further increase of the number of steam
pressure levels in the HRSG does not seem to be really benecial;
it enables only a small reduction of the overall exergy loss of the
plant.
Different parameters can be used to assess the thermodynamic
performance of power plants or the different cycles. The traditionally used thermal efciency does not indicate thermodynamic
losses correctly as it does not consider for the temperature of heat
transfer to and from the cycles. Therefore the application of exergy
efciencies should be recommended. Exergy efciencies however
just show the actual losses in the considered situation but do not
indicate clearly the difference with the ideal case. In order to see
how far the actual performance differs from the performance in
the ideal (reversible) case, the internal exergy efciency of a cycle
is a better indicator, in particular if the exergy transferred from the
cycle is seriously inuenced by the performance of the cycle itself.
An estimated value of the internal exergy efciency can be calculated with limited accuracy using available data from system calculations. Very accurate values of the internal exergy efciency
will require the additional computation of the reversible cycle.
1110
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