Chemical Sciences 2

2
1.
An aqueous solution of Ni(NO3)2 is green. Addition of aqueous NH3 causes the colour of the solution to
change to blue. If ethylenediamine is added to green solution, the colour changes to the violet. These three
different colours are due to the formation of:
(a) Ni NO3 2 , Ni H 2 O 6
and Ni NH 3 6
(b) Ni H 2 O 6 , Ni NH 3 4
(c) Ni H 2 O 6 , Ni NH 3 6
(d) Ni H 2 O 6 , Ni NH 3 6
2.
3.
and Ni en 2
and Ni en 2
and Ni en 3
The increasing order of t values of the d2 ions CrO 44 , MnO 34 , FeO 24 and RuO 24 is :
(a) FeO 24 MnO 34 CrO 44 RuO 24
(b) MnO34 CrO 44 FeO 24 RuO 24
(c) RuO 24 CrO 44 MnO 34 FeO 24
(d) CrO 44 MnO 34 FeO 24 RuO 24
When the two isomers of Pt NH3 2 Cl2 react with thiourea (tu), one product is Pt tu 4
and the other is
Pt NH 3 2 tu 2 . The initial isomers are respectively..
(a) cis Pt NH3 2 Cl2 and trans Pt NH 3 2 Cl2

(b) trans Pt NH 3 2 Cl2 and cis Pt NH3 2 Cl2
(c) square planar and tetrahedral
(d) tetrahedral and square planar
4.
The acid catalyzed hydrolysis of trans- Co en 2 Ax

(a) Square pyramidal intermediate
(c) Pentagonal bipyramidal intermediate
5.
gives cis-product only due to the formation of
(b) Trigonal bipyramidal intermediate

(d) Face capped octahedral intermediate.
Consider the following redox reactions

(I) Fe H 2O 6
(II) Co H 2O 6
Fe H 2 O 6
(III) Co NH 3 6
Co H 2 O 6
Fe H 2 O 6 Fe H 2O 6
3
Co NH 3 6
Co H 2O 6 Co H 2O 6
Co NH 3 6 Co NH 3 6
3
(IV) Fe CN 6 Fe CN 6 Fe CN 6 Fe CN 6
The increasing order of rate of electron transfer of these reactions is
(a) III < II < I < IV
(b) I < III < II < IV
(c) II < III < IV < I
6.
(d) I < II < III < IV
A solution containing 2.674 g of CoCl3.6H2O was passed through a cation exchanger. The eluted solution gave
4.305 g ppt. of AgCl with AgNO3 solution. The formula of the complex is (atomic mass, Ag = 108, Cl = 35.5,
molar mass of CoCl3.6H2O = 267.4)
(a) Co NH 3 5 Cl Cl2 .NH 3
(b) Co NH 3 6 Cl3
(c) Co NH 3 4 Cl2 Cl.2NH 3
(d) Co NH 3 3 Cl3 3NH 3
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3
7.
The asymmetric nature of visible absorption band of Ti H 2O 6

(a) Laportes allowed transition
(c) Dynamic Jahn Teller distortion
8.
9.
is due to
(b) Laportes forbidden transition

(d) Intensity stealing transtion
Number of geometrical isomers for Co gly 2 NH 3 py is:

(a) 3
(b) 4
(c) 5
(d) 6
The stabilization of highest oxidation states of transition metals by strong electronegative ligands is due to
bonding:
(a) d L d M (b) p L d M (c) d M p L (d) d M d L
10.
The spinels CO3O4 and Fe2NiO4 are respectively.

(a) Both are normal
(b) Both are inverse (c) Normal, inverse
(d) Inverse, normal
11.
A 100g particle is moving with velocity 100ms1. The wavelength of the particle is
(a) 6.61035 m
(b) 6.61025 m
(c) 6.6104 m
(d) 6.61020 m
12.
d-orbital involved in sp3d hybridization corresponding to square pyramidal geometry is

(a) d xy
13.
14.
(b) d yz
The HOMO in CO is
(a) -bonding
(b) -bonding
16.
(c) -antibonding
(d) -non bonding
h
4
(b) E t
h
4
(c) v.x
h
4m
(d) x.p
h
4m
The numbers of lone pair of electrons in XeF2, XeF4 and XeF6 are respectivley.
(a) 3, 2, 1
(b) 9, 14, 19
(c) 1, 2, 3
(d) 10, 15, 20
Metal carbonyl can exhibit the following resonating stretching frequency
(1) M
The highest C O
(a) 1
17.
(d) d z2
Which of the following is the uncertainty principle?

(a) v.x
15.
(c) d x 2 y2
(2) M
(3) M C O
stretching frequency for the above resonating structure will be
(b) 2
(c) 3
(d) Difficult to analyze
C
Which of the following statement is not true about elimination reaction

(a) This reaction is most common decomposition route for alkyl-ligand from the metal
(b) This process requireds a vacant co-ordination site on the metal
(c) The -hydrogen should not be present in the alkyl ligand present on the metal for -elimination.
(d) Some of the metal complex having -hydrogen inspite of there they do not undergoes -elimination.
18.
The -accepting properties of some PR3 ligands follow the ordering.

(a) PF3 P OPh 3 P OMe 3 PPh 3 PMe3
(b) P OPh 3 PF3 P OMe 3 PMe3 PPh 3
(c) PPh 3 PMe3 P OMe 3 P OPh 3 PF3
(d) PF3 P OMe3 3 P OPh 3 PPh 3 PMe3
4
19.
In the IR spectrum of free CH3 CH CH 2 , CC comes at 1652 cm1 but when this alkene is attached with
2
Pt it forms a compex such as K PtCl3 CH 3CH CH 2 the corresponding absorption should be
(a) Increase
(b) Decrease
(c) Remains unaffected
(d) Data is insufficient.
20.
Reaction of OsO4 with CO at 125C and 75 atm was found to result in stable compound A with emperical
formula OsC4O4. Compound A was found to excess of sodium metal followed by treatment with H3PO4 was
found to result in compound B with the molecular formula OsH2C4O4. Heating of B was found to result in
the release of a colourless gas and formation of a compound C with empirical formula OsHC4O4, C on
treatment with methyl Iodide was found to get converted to D with release of hydrocarbon gas D. On
further treatment with NaHg followed by methyl iodide gave E, with emperical formula OsC5H3O4 compound A E obey 18 electron rule and all of them show IR absorption in the vicenity of 2000cm1. On
account of above information which of the following is/are not correct.
(a) Compound B can exhibit 1H NMR spectrum at negative chemical shift value.
(b) Compound C has one metal-metal bond and all the Cos are terminal.
(c) Compound D is Os 2 CO 8 I 2 and evolution of the hydrocarbon gas is CH4.
(d) Compound D upon treatment with Na/Hg forms Os CO 4 I
21.
The correct combination of metal, number of carbonyl ligands and charge for metal carbonyl complex
M CO x
that satisfies the 18 electron rule is
(a) M Os, x 6, z 2
(b) M Fe, x 4, z 2
(c) M Ru, x 8, z 0
(d) M Ir, x 5, z 4
22.
The structure of carborane and metalloborane with the formula C2B8H14 and B3H7[Os(CO)3]2 are respectively.
(a) Nido, Nido
(b) Arachno, Closo
(c) Nido, Arachno
(d) Arachno, Nido
23.
The complexes of general formula fac Mo CO 3 phosphine 3 have the C O stretching bands as given
below
Phosphine:
(A) PF3
(B) P(OPh)3
(C) P(OMe)3 (D) PPh3
C O in cm 1 : (i) 1945
(ii) 1977
(iii) 2040
(iv) 2090
The correct combination of the phosphine and streching frequency is
(a) A-i, B-ii, C-iii, D-iv
(b) A-ii, B-i, C-iv, D-iii
(c) A-iv, B-iii, C-ii, D-i
(d) A-iii, B-iv, C-i, D-ii
24.
Consider the catalyst in Column-I and reaction in Column-II

Column-I
Column-II
(A) PdCl42, CuCl
(i) Wilkinsons catalyst
(B) Pd(dba)2(PPh3)2
(ii) Wacker process
(C) 4Co(CO)4
(iii) Suzuki coupling
(D) Rh(PPh)3Cl
(iv) Hydroformylation/Oxo process
the best match of a catalyst of column-I with the reaction under column-II is
(a) A-ii, B-i, C-iv, D-iii
(b) A-i, B-ii, C-iii, D-iv
(c) A-ii, B-iii, C-iv, D-i
(d) A-iv, B-iii, C-ii, D-i
5
25.
For the reaction, trans-[I rCl(CO)(PPh3)2]+ O2 P which of the following observation is not true.
(a) It is an example of oxidative addition.

(b) The O2 free is greater than that of the product
(c) The bond order of O2 decreases from 2 to 1
(d) The C O of the reactant is greater than that of the product.
26.
In photosynthetic ferrodoxin, the number of iron atoms, sulfur bridges and cysteine ligands are
Fe-atom
Sulfur bridge cysteene
(a)
4
4
4
(b)
2
4
4
(c)
3
2
4
(d)
2
2
4
27.
Which of the following enzyme is responsible for nitrogen fixation

(a) Nuclenase
(b) Arginase
(c) Nitrogenase
28.
Match the following

P. Hemocyanin
Q. Cytochrome
R. Valinomycin
S. Carboxy Peptidase
(a) P-5, Q-1, R-4, S-6

(c) P-5, Q-1, R-3, S-6
(d) Trypsin
1. electron transport
2. Siderophore
3. Organometallic enzyme
4. Ionophore
5. Oxygen carrier
6. Peptide hydrolysis.
(b) P-1, Q-5, R-4, S-6
(d) P-5, Q-4, R-1, S-6
29.
The metalloenzyme Galactose oxidase is responsible for

(a) Oxidation of aldehyde to acid
(b) Oxidation of alcohol to amine
(c) Oxidation of alcohol to aldehyde and hydrogen peroxide
(d) Reduction of aldehyde to alcohol
30.
The correct order of second ionization energy of carbon, nitrogen, oxygen and fluorine is
(a) C > N > O > F
(b) O > N > F> C
(c) O > F > N > C
(d) F > O > N > C
31.
Electronegativity of the following elements increases in the order

(a) C, N, Si, P
(b) N, Si, C, P
(c) Si, P, C, N
(d) P, Si, N, C
Which of the following has the highest ionization energy

(a) Al
(b) S
(c) Si
(d) P
32.
33.
Which of the following has maximum tendency to form uninegative ion in the gaseous state
(a) F
(b) Cl
(c) Br
(d) I
34.
When one mole of following alkali metals react with excess of water the maximum heat is generated in case of
(a) Li
(b) Na
(c) K
(d) S
Which one of the following molecules is planar
(a) PCl3
(b) ClO4
(c) CO32
(d) NH3
35.
36.
37.
In tetrathionate ion, S4O62, the number of sulphur atoms having zero oxidation state is:
(a) 1
(b) 2
(c) 3
(d) 4
PbI4 is not known because of
(a) Large size of lead
(b) Large size of iodine
(c) Nature of I oxidising

(d) Oxidising power of Pb(+IV)
6
38.
Which of the following is least basic

(a) CH3NH2
(b) NH3
(c) Pyridine
(d) RC N
39.
Which of the following nitrogen oxide is produced when Fe2+ reduces NO3.
(a) NO
(b) NO2
(c) N2O
(d) N2O3
40.
In which of the following pairs, both the species have the same hybridisation.
(a) SF4 , XeF4
41.
42.
43.
44.
An acid with peroxide linkage

(I) H2SO5
(II) H2S2O6
(a) I, II, III only
(b) I, III only
(d) CO 32 , PO 34
(III) H2S2O8
(c) II, IV only
(IV) H2S2O7
(d) IV only
(d) XeO2F2
The substance having lowest boiling point is

(a) HCl
(b) HF
(c) HBr
(d) HI
(c) 1.5
(d) None of these
The bond order of O2 in 3 g is:

(b) 2.5
Match the following

Column-I
(A) Strongest Bronsted acid
(B) Strongest Bronsted base
(C) Strongest base to H+ (gasphase)
(D) Strongest base to BMe3
Column-II
(i) 4-methyl pyridine
(ii) 2-methyl pyridine
(iii) TeH2
(iv) SbH3
(v) (CH3)3N
(vi) (CH3)2NH
(vii) PH3
(viii) NH3
(b) A-iii, B-viii, C-vi, D-ii
(d) A-iii, B-viii, C-v, D-i
(a) A-iv, B-vii, C-vi, D-ii

(c) A-iv, B-vii, C-v, D-i
46.
(c) ICl4 , SiCl4
The compound that cannot be formed by Xe is

(a) XeO3
(b) XeF4
(c) XeCl4
(a) 2
45.
(b) I3 , XeF2
The reaction given below can be explained by
BF3 2ClF
Cl 2 F BF4
(a) Lewis concept

(c) Lewis and unsonovich concept
(b) Unsanovich concept

(d) Lewis and Solvent concept
47.
Decreasing order of stability in water of following compound PbCl2, PbBr2, PbI2, PbS
(a) PbI2 > PbBr2 > PbCl2 > PbS
(b) PbS > PbI2 > PbBr2 > PbCl2
(c) PbCl2 > PbBr2 > PbI2 > PbS
(d) PbS > PbCl2 > PbBr2 > PbI2
48.
As it is well known that free radicals have high electron affinity therefore on the basis of electron affinity, what
(free radicals)
is the actual order of acidity in between SO , SO and OH
3
SO
(a) SO
3
2 OH (b) OH SO 3 SO 2 (c) SO 3 OH SO 2 (d) SO 3 SO 2 OH
49.
According to Fajans rule For a given anion colvant character of cation increases with decrease in size, and
hence in overall solubility of compounds decrease with increase in covalent character. On the basis of this rule
alkaline earth carbonate should follow MgCO3 < CaCO3 < SrCO3 < BaCO3 order of increasing solubility
(a) Rule is wrong but order is correct
(b) Rule is correct but order is incorrect
(c) Rule and order both are correct
(d) Rule and order both are incorrect.
7
50.
The correct match of following is

(1) Unsanovich concept
(2) Lux-food concept
(3) Solvent system concept
(4) Leebeg concept
(5) Ingold-Rabinson concept
(6) Lavasier concept
(a) 1-C, 2-F, 3-B, 4-H, 5-A, 6-D

(c) 1-G, 2-A, 3-B, 4-H, 5-F, 6-C
51.
(A) Oxides of N, P, S act as acid

(B) Cation works as acid
(C) Electron donor acts as base
(D) Electron pair donor acts as base
(E) O2 acceptor acts as base
(F) O2 donar acts as base
(G) Molecules having Hs replaced by metal
(H) Nucleophile acts as base
(I) Electrophile acts as base
(b) 1-C, 2-F, 3-B, 4-G, 5-H, 6-A
(d) 1-E, 2-A, 3-B, 4-F, 5-H, 6-C
The decay series of a radioactive element is as
A
B
C
D
in the series
(a) A and B are isobars
(c) A and D are isotopes
(b) A and C are isobars

(d) B and C are isotopes
52.
A certain nuclide has a half life of 40 days. If a sample containing 800 atoms is allowed to decay for 120 days.
The number of atoms that remain undecayed will be
(a) 0
(b) 100
(c) 200
(d) 400
53.
The atomic weight of thorium is 232 and its atomic number is 90. At the end of the disintegration of thorium,
lead with atomic weight 208 and atomic number 82 was obtained. The total number of and -particles
emitted in this process are
(a) 6 and 4
(b) 4 and 5
(c) 5 and 6
(d) 6 and 5
A radioactive element has a half life of one day. After three days the amount of the element left will be
54.
55.
56.
57.
58.
(a)
1
of the original amount
2
(b)
1
4
(c)
1
8
(d)
1
16
The activity of radio isotopes changes with

(a) Temperature
(c) Chemical environment
(b) Pressure
(d) None of these
A sample of rock from moon contains equal number of atoms of uranium and lead t1/2 for U 4.5 109 years .
The age of the rock would be
(a) 4.5109 years
(b) 9.0109 years
(c) 13.5109 years
(d) 2.25109 years
Which of the following statement is not correct?
(a) Nd(OH)3 is more basic than Eu(OH)3
(b) In lanthanoids series ionic radius of Ln3+ ion increase
(c) La is actually on element of transition series rather lanthanides.
(d) Atomic radius of Zr and Hf are same because of lanthanide contraction.
Which of following statement is correct?
(a) Lanthanoids shows more variable oxidation state than actinoids.
(b) Peak of specta of lanthanoids are more broader than actinoids of peaks.
(c) Lanthanoids rarely show isomerism
(d) Complex formation ability of actinoids is greater than that of Lanthanoids.
8
59.
Which of following is incorrect statement about spectra of lanthanoids?

(a) They show large number of peaks
(b) Intensity of absorption is weak
(c) Spectra are largely dependent on the ligand type
(d) They show sharp absorption
60.
Lanthanoids ions shows luminescence because

(a) Due to strong spleting of f-orbitals
(b) Due to strong contraction between f-orbital of metal and ligands.
(c) They have large number of microstates
(d) They have less number of microstates.
61.
Which of the following combination of most stable oxidation of actinoids is true?

(a) Th(IV), Pa(IV)
(b) U(V), Np(V)
(c) Lr(III), Nb(III)
(d) Th(VI), Pu(IV)
62.
The pair of lanthanodis having highest ionisation energy?

(a) Eu, Gd
(b) Dy, Yb
(c) Eu, Yb
(d) Sm, Eu
63.
Yellow colour solution of FeCl3 changes to light green when

(a) SnCl2 is added
(b) Zn is added
(c) H2S gas is passed (d) All are free
64.
NaOH
KCl conc.H 2SO4 K 2Cr2O 7
X
Y
X is reddish brown coloured gas soluble in NaOH forming (Y). X and Y are
65.
(a) Cr2 OCl2 , Na 2 CrO3
(b) Cr2 OCl2 , Na 2 CO3
(c) CrO 2Cl, NaCr2O 4
(d) CrO 2 Cl2 , Na 2CrO 4
Turnbulls blue and Prussians blue respectively are
I FeII FeII CN 6
III FeII FeIII CN 6

(a) I, II
II FeIII FeIII CN 6
(b) I, III
IV FeIII FeII CN 6
(c) III, IV
(d) IV, III
66.
Equivalent mass of a metal is 12g mol1. Hence equivalent mass of its oxides is
(a) 24 g mol1
(b) 0.21 g mol1
(c) 20 gmol1
(d) 34 gmol1
67.
How many gram of H3PO4 would be needed to neutralize 100 gm of [Mg(OH)2]

(a) 66.7 gm
(b) 25.2 gm
(c) 112.6 gm
(d) 166 gm
68.
Which one of the chelating agent is used to remove the excess of copper in the body?
(a) D-penicillamine
(b) HSC(CH3)2CH(NH2)CONH2
(c) Cisplatin
(d) None of these
69.
How many isomers are possible for C2B10H12?

(a) Three
(b) two
(c) one
(d) four
70.
In 57 Fe* Mossbauer experiment, source of 14.4 keV (equivalent to 3.481012 MHz) is moved towards
absorber at a velocity of 2.2 mm s1. The shift in frequency of the source for this sample is:
(a) 35.5 MHz
(b) 25.5 MHz
(c) 20.2 MHz
(d) 15.5 MHz
71.
If Mossbauer spectrum of Fe(Co)5 is recorded in the presence of a magnetic field, the original spectrum with
two lines changes into the one with
(a) Three lines
(b) Four lines
(c) Five lines
(d) Six lines
9
72.
If Os(CO)2(H)2(PR3)2 shows CO bands at 2022 and 1990 cm1 and OsH band at 1926 and 1871 cm1.
What will be the correct structure.
(a)
OC
Os
PR3
(b)
CO
73.
PR3
R3P
(c)
Os
CO
R3P
R3P
(d)
PR3
CO
O
C
Rh
Os
CO
R3P
CO
OC
S
O
Which one of the styx code of B10H14 is:

(a) 4044
(b) 4422
OC
(c) 4440
CO
O
O
Rh
(d)
O
Rh
OC
CO
OC
O
Rh
C
O
Rh
(b)
CO
OC
(c)
Rh
OC
OC
CO
Rh
(a)
75.
CO
Os
OC
A compound with molecular formula Rh2(CO)4SO4 exhibit IR bands at 2093, 2035 and 2014 cm1. Determine the structure of compounds.
OC
74.
CO
R3P
O
S
Rh
O
CO
Rh
CO
(d) 4620
The metal clusters [Mo2(HPO4)4]2, [Re2Cl4(PMe2Ph)4]+ and Re2Cl4(PMe2Ph)4 having the bond order respectively:
(a) 3.0, 3.5, 4.0
(b) 3.0, 3.5, 3.0
(c) 4.0, 3.5, 3.5
(d) 3.5, 3.0, 3.0
10
Chemical Sciences Test Series-II
Date: 24-11-2013
ANSWER KEY
1. (c)
2. (d)
3. (a)
4. (b)
5. (a)
6. (b)
7. (c)
8. (d)
9. (b)
10. (c)
11. (a)
12. (c)
13. (d)
14. (b)
15. (b)
16. (a)
17. (c)
18. (a)
19. (b)
20. (d)
21. (b)
22. (d)
23. (c)
24. (c)
25. (d)
26. (d)
27. (c)
28. (a)
29. (c)
30. (c)
31. (c)
32. (d)
33. (b)
34. (a)
35. (c)
36. (b)
37. (d)
38. (d)
39. (a)
40. (b)
41. (b)
42. (c)
43. (a)
44. (a)
45. (d)
46. (d)
47. (c)
48. (a)
49. (b)
50. (b)
51. (c)
52. (b)
53. (a)
54. (c)
55. (d)
56. (a)
57. (b)
58. (d)
59. (c)
60. (c)
61. (d)
62. (c)
63. (d)
64. (d)
65. (c)
66. (c)
67. (c)
68. (a)
69. (a)
70. (b)
71. (d)
72. (d)
73. (d)
74. (d)
75. (b)
2
1.
(a) Ni NO3 2 , Ni H 2 O 6
and Ni NH 3 6
(b) Ni H 2 O 6 , Ni NH 3 4
(c) Ni H 2 O 6 , Ni NH 3 6
(d) Ni H 2 O 6 , Ni NH 3 6
2.
3.
and Ni en 2
and Ni en 2
and Ni en 3
and the other is

4.

5.


(I) Fe H 2O 6
(II) Co H 2O 6
Fe H 2 O 6
(III) Co NH 3 6
Co H 2 O 6
3
Co NH 3 6
Co H 2O 6 Co H 2O 6
Co NH 3 6 Co NH 3 6
3
6.
(b) Co NH 3 6 Cl3
(d) Co NH 3 3 Cl3 3NH 3
3
7.

8.
9.
is due to


(a) 3
(b) 4
(c) 5
(d) 6
bonding:
10.

(a) Both are normal
(d) Inverse, normal
11.
(a) 6.61035 m
(b) 6.61025 m
(c) 6.6104 m
(d) 6.61020 m
12.

(a) d xy
13.
14.
(b) d yz
The HOMO in CO is
(a) -bonding
(b) -bonding
16.
(c) -antibonding
(d) -non bonding
h
4
(b) E t
h
4
(c) v.x
h
4m
(d) x.p
h
4m
(a) 3, 2, 1
(b) 9, 14, 19
(c) 1, 2, 3
(d) 10, 15, 20
(1) M
The highest C O
(a) 1
17.
(d) d z2

(a) v.x
15.
(c) d x 2 y2
(2) M
(3) M C O
(b) 2
(c) 3
C

18.

4
19.
2
(a) Increase
(b) Decrease
20.
21.
M CO x
(a) M Os, x 6, z 2
(b) M Fe, x 4, z 2
(c) M Ru, x 8, z 0
(d) M Ir, x 5, z 4
22.
(a) Nido, Nido
(b) Arachno, Closo
(c) Nido, Arachno
(d) Arachno, Nido
23.
below
Phosphine:
(A) PF3
(B) P(OPh)3
C O in cm 1 : (i) 1945
(ii) 1977
(iii) 2040
(iv) 2090
24.

Column-I
Column-II
(A) PdCl42, CuCl
(B) Pd(dba)2(PPh3)2
(ii) Wacker process
(C) 4Co(CO)4
(D) Rh(PPh)3Cl
5
25.

26.
Fe-atom
(a)
4
4
4
(b)
2
4
4
(c)
3
2
4
(d)
2
2
4
27.

(a) Nuclenase
(b) Arginase
(c) Nitrogenase
28.
Match the following

P. Hemocyanin
Q. Cytochrome
R. Valinomycin
(a) P-5, Q-1, R-4, S-6

(c) P-5, Q-1, R-3, S-6
(d) Trypsin
2. Siderophore
4. Ionophore
5. Oxygen carrier
(b) P-1, Q-5, R-4, S-6
(d) P-5, Q-4, R-1, S-6
29.

30.
(a) C > N > O > F
(b) O > N > F> C
(c) O > F > N > C
(d) F > O > N > C
31.

(a) C, N, Si, P
(b) N, Si, C, P
(c) Si, P, C, N
(d) P, Si, N, C

(a) Al
(b) S
(c) Si
(d) P
32.
33.
(a) F
(b) Cl
(c) Br
(d) I
34.
(a) Li
(b) Na
(c) K
(d) S
(a) PCl3
(b) ClO4
(c) CO32
(d) NH3
35.
36.
37.
(a) 1
(b) 2
(c) 3
(d) 4

6
38.

(a) CH3NH2
(b) NH3
(c) Pyridine
(d) RC N
39.
(a) NO
(b) NO2
(c) N2O
(d) N2O3
40.
(a) SF4 , XeF4
41.
42.
43.
44.

(I) H2SO5
(II) H2S2O6
(a) I, II, III only
(b) I, III only
(d) CO 32 , PO 34
(III) H2S2O8
(c) II, IV only
(IV) H2S2O7
(d) IV only
(d) XeO2F2

(a) HCl
(b) HF
(c) HBr
(d) HI
(c) 1.5
(d) None of these

(b) 2.5
Match the following

Column-I
Column-II
(iii) TeH2
(iv) SbH3
(v) (CH3)3N
(vi) (CH3)2NH
(vii) PH3
(viii) NH3

46.
(c) ICl4 , SiCl4

(a) XeO3
(b) XeF4
(c) XeCl4
(a) 2
45.
(b) I3 , XeF2
BF3 2ClF
Cl 2 F BF4
(a) Lewis concept


47.
48.
(free radicals)
3
SO
(a) SO
3
49.
7
50.

(4) Leebeg concept
(a) 1-C, 2-F, 3-B, 4-H, 5-A, 6-D

(c) 1-G, 2-A, 3-B, 4-H, 5-F, 6-C
51.

(b) 1-C, 2-F, 3-B, 4-G, 5-H, 6-A
(d) 1-E, 2-A, 3-B, 4-F, 5-H, 6-C
A
B
C
D
in the series

52.
(a) 0
(b) 100
(c) 200
(d) 400
53.
(a) 6 and 4
(b) 4 and 5
(c) 5 and 6
(d) 6 and 5
54.
55.
56.
57.
58.
(a)
1
2
(b)
1
4
(c)
1
8
(d)
1
16

(a) Temperature
(b) Pressure
(d) None of these
(a) 4.5109 years
(b) 9.0109 years
(c) 13.5109 years
(d) 2.25109 years
8
59.

60.

61.

(a) Th(IV), Pa(IV)
(b) U(V), Np(V)
(d) Th(VI), Pu(IV)
62.

(a) Eu, Gd
(b) Dy, Yb
(c) Eu, Yb
(d) Sm, Eu
63.

(a) SnCl2 is added
(b) Zn is added
64.
NaOH
X
Y
65.
I FeII FeII CN 6
III FeII FeIII CN 6

(a) I, II
II FeIII FeIII CN 6
(b) I, III
IV FeIII FeII CN 6
(c) III, IV
(d) IV, III
66.
(a) 24 g mol1
(b) 0.21 g mol1
(c) 20 gmol1
(d) 34 gmol1
67.

(a) 66.7 gm
(b) 25.2 gm
(c) 112.6 gm
(d) 166 gm
68.
(a) D-penicillamine
(c) Cisplatin
(d) None of these
69.

(a) Three
(b) two
(c) one
(d) four
70.
(a) 35.5 MHz
(b) 25.5 MHz
(c) 20.2 MHz
(d) 15.5 MHz
71.
(a) Three lines
(b) Four lines
(c) Five lines
(d) Six lines
9
72.
(a)
OC
Os
PR3
(b)
CO
73.
PR3
R3P
(c)
Os
CO
R3P
R3P
(d)
PR3
CO
O
C
Rh
Os
CO
R3P
CO
OC
S
O

(a) 4044
(b) 4422
OC
(c) 4440
CO
O
O
Rh
(d)
O
Rh
OC
CO
OC
O
Rh
C
O
Rh
(b)
CO
OC
(c)
Rh
OC
OC
CO
Rh
(a)
75.
CO
Os
OC
OC
74.
CO
R3P
O
S
Rh
O
CO
Rh
CO
(d) 4620
(a) 3.0, 3.5, 4.0
(b) 3.0, 3.5, 3.0
(c) 4.0, 3.5, 3.5
(d) 3.5, 3.0, 3.0
10
Date: 24-11-2013
ANSWER KEY
1. (c)
2. (d)
3. (a)
4. (b)
5. (a)
6. (b)
7. (c)
8. (d)
9. (b)
10. (c)
11. (a)
12. (c)
13. (d)
14. (b)
15. (b)
16. (a)
17. (c)
18. (a)
19. (b)
20. (d)
21. (b)
22. (d)
23. (c)
24. (c)
25. (d)
26. (d)
27. (c)
28. (a)
29. (c)
30. (c)
31. (c)
32. (d)
33. (b)
34. (a)
35. (c)
36. (b)
37. (d)
38. (d)
39. (a)
40. (b)
41. (b)
42. (c)
43. (a)
44. (a)
45. (d)
46. (d)
47. (c)
48. (a)
49. (b)
50. (b)
51. (c)
52. (b)
53. (a)
54. (c)
55. (d)
56. (a)
57. (b)
58. (d)
59. (c)
60. (c)
61. (d)
62. (c)
63. (d)
64. (d)
65. (c)
66. (c)
67. (c)
68. (a)
69. (a)
70. (b)
71. (d)
72. (d)
73. (d)
74. (d)
75. (b)
2
1.
(a) Ni NO3 2 , Ni H 2 O 6
and Ni NH 3 6
(b) Ni H 2 O 6 , Ni NH 3 4
(c) Ni H 2 O 6 , Ni NH 3 6
(d) Ni H 2 O 6 , Ni NH 3 6
2.
3.
and Ni en 2
and Ni en 2
and Ni en 3
and the other is

4.

5.


(I) Fe H 2O 6
(II) Co H 2O 6
Fe H 2 O 6
(III) Co NH 3 6
Co H 2 O 6
3
Co NH 3 6
Co H 2O 6 Co H 2O 6
Co NH 3 6 Co NH 3 6
3
6.
(b) Co NH 3 6 Cl3
(d) Co NH 3 3 Cl3 3NH 3
3
7.

8.
9.
is due to


(a) 3
(b) 4
(c) 5
(d) 6
bonding:
10.

(a) Both are normal
(d) Inverse, normal
11.
(a) 6.61035 m
(b) 6.61025 m
(c) 6.6104 m
(d) 6.61020 m
12.

(a) d xy
13.
14.
(b) d yz
The HOMO in CO is
(a) -bonding
(b) -bonding
16.
(c) -antibonding
(d) -non bonding
h
4
(b) E t
h
4
(c) v.x
h
4m
(d) x.p
h
4m
(a) 3, 2, 1
(b) 9, 14, 19
(c) 1, 2, 3
(d) 10, 15, 20
(1) M
The highest C O
(a) 1
17.
(d) d z2

(a) v.x
15.
(c) d x 2 y2
(2) M
(3) M C O
(b) 2
(c) 3
C

18.

4
19.
2
(a) Increase
(b) Decrease
20.
21.
M CO x
(a) M Os, x 6, z 2
(b) M Fe, x 4, z 2
(c) M Ru, x 8, z 0
(d) M Ir, x 5, z 4
22.
(a) Nido, Nido
(b) Arachno, Closo
(c) Nido, Arachno
(d) Arachno, Nido
23.
below
Phosphine:
(A) PF3
(B) P(OPh)3
C O in cm 1 : (i) 1945
(ii) 1977
(iii) 2040
(iv) 2090
24.

Column-I
Column-II
(A) PdCl42, CuCl
(B) Pd(dba)2(PPh3)2
(ii) Wacker process
(C) 4Co(CO)4
(D) Rh(PPh)3Cl
5
25.

26.
Fe-atom
(a)
4
4
4
(b)
2
4
4
(c)
3
2
4
(d)
2
2
4
27.

(a) Nuclenase
(b) Arginase
(c) Nitrogenase
28.
Match the following

P. Hemocyanin
Q. Cytochrome
R. Valinomycin
(a) P-5, Q-1, R-4, S-6

(c) P-5, Q-1, R-3, S-6
(d) Trypsin
2. Siderophore
4. Ionophore
5. Oxygen carrier
(b) P-1, Q-5, R-4, S-6
(d) P-5, Q-4, R-1, S-6
29.

30.
(a) C > N > O > F
(b) O > N > F> C
(c) O > F > N > C
(d) F > O > N > C
31.

(a) C, N, Si, P
(b) N, Si, C, P
(c) Si, P, C, N
(d) P, Si, N, C

(a) Al
(b) S
(c) Si
(d) P
32.
33.
(a) F
(b) Cl
(c) Br
(d) I
34.
(a) Li
(b) Na
(c) K
(d) S
(a) PCl3
(b) ClO4
(c) CO32
(d) NH3
35.
36.
37.
(a) 1
(b) 2
(c) 3
(d) 4

6
38.

(a) CH3NH2
(b) NH3
(c) Pyridine
(d) RC N
39.
(a) NO
(b) NO2
(c) N2O
(d) N2O3
40.
(a) SF4 , XeF4
41.
42.
43.
44.

(I) H2SO5
(II) H2S2O6
(a) I, II, III only
(b) I, III only
(d) CO 32 , PO 34
(III) H2S2O8
(c) II, IV only
(IV) H2S2O7
(d) IV only
(d) XeO2F2

(a) HCl
(b) HF
(c) HBr
(d) HI
(c) 1.5
(d) None of these

(b) 2.5
Match the following

Column-I
Column-II
(iii) TeH2
(iv) SbH3
(v) (CH3)3N
(vi) (CH3)2NH
(vii) PH3
(viii) NH3

46.
(c) ICl4 , SiCl4

(a) XeO3
(b) XeF4
(c) XeCl4
(a) 2
45.
(b) I3 , XeF2
BF3 2ClF
Cl 2 F BF4
(a) Lewis concept


47.
48.
(free radicals)
3
SO
(a) SO
3
49.
7
50.

(4) Leebeg concept
(a) 1-C, 2-F, 3-B, 4-H, 5-A, 6-D

(c) 1-G, 2-A, 3-B, 4-H, 5-F, 6-C
51.

(b) 1-C, 2-F, 3-B, 4-G, 5-H, 6-A
(d) 1-E, 2-A, 3-B, 4-F, 5-H, 6-C
A
B
C
D
in the series

52.
(a) 0
(b) 100
(c) 200
(d) 400
53.
(a) 6 and 4
(b) 4 and 5
(c) 5 and 6
(d) 6 and 5
54.
55.
56.
57.
58.
(a)
1
2
(b)
1
4
(c)
1
8
(d)
1
16

(a) Temperature
(b) Pressure
(d) None of these
(a) 4.5109 years
(b) 9.0109 years
(c) 13.5109 years
(d) 2.25109 years
8
59.

60.

61.

(a) Th(IV), Pa(IV)
(b) U(V), Np(V)
(d) Th(VI), Pu(IV)
62.

(a) Eu, Gd
(b) Dy, Yb
(c) Eu, Yb
(d) Sm, Eu
63.

(a) SnCl2 is added
(b) Zn is added
64.
NaOH
X
Y
65.
I FeII FeII CN 6
III FeII FeIII CN 6

(a) I, II
II FeIII FeIII CN 6
(b) I, III
IV FeIII FeII CN 6
(c) III, IV
(d) IV, III
66.
(a) 24 g mol1
(b) 0.21 g mol1
(c) 20 gmol1
(d) 34 gmol1
67.

(a) 66.7 gm
(b) 25.2 gm
(c) 112.6 gm
(d) 166 gm
68.
(a) D-penicillamine
(c) Cisplatin
(d) None of these
69.

(a) Three
(b) two
(c) one
(d) four
70.
(a) 35.5 MHz
(b) 25.5 MHz
(c) 20.2 MHz
(d) 15.5 MHz
71.
(a) Three lines
(b) Four lines
(c) Five lines
(d) Six lines
9
72.
(a)
OC
Os
PR3
(b)
CO
73.
PR3
R3P
(c)
Os
CO
R3P
R3P
(d)
PR3
CO
O
C
Rh
Os
CO
R3P
CO
OC
S
O

(a) 4044
(b) 4422
OC
(c) 4440
CO
O
O
Rh
(d)
O
Rh
OC
CO
OC
O
Rh
C
O
Rh
(b)
CO
OC
(c)
Rh
OC
OC
CO
Rh
(a)
75.
CO
Os
OC
OC
74.
CO
R3P
O
S
Rh
O
CO
Rh
CO
(d) 4620
(a) 3.0, 3.5, 4.0
(b) 3.0, 3.5, 3.0
(c) 4.0, 3.5, 3.5
(d) 3.5, 3.0, 3.0
10
Date: 24-11-2013
ANSWER KEY
1. (c)
2. (d)
3. (a)
4. (b)
5. (a)
6. (b)
7. (c)
8. (d)
9. (b)
10. (c)
11. (a)
12. (c)
13. (d)
14. (b)
15. (b)
16. (a)
17. (c)
18. (a)
19. (b)
20. (d)
21. (b)
22. (d)
23. (c)
24. (c)
25. (d)
26. (d)
27. (c)
28. (a)
29. (c)
30. (c)
31. (c)
32. (d)
33. (b)
34. (a)
35. (c)
36. (b)
37. (d)
38. (d)
39. (a)
40. (b)
41. (b)
42. (c)
43. (a)
44. (a)
45. (d)
46. (d)
47. (c)
48. (a)
49. (b)
50. (b)
51. (c)
52. (b)
53. (a)
54. (c)
55. (d)
56. (a)
57. (b)
58. (d)
59. (c)
60. (c)
61. (d)
62. (c)
63. (d)
64. (d)
65. (c)
66. (c)
67. (c)
68. (a)
69. (a)
70. (b)
71. (d)
72. (d)
73. (d)
74. (d)
75. (b)

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2

(b) MnO34 CrO 44 FeO 24 RuO 24

(c) RuO 24 CrO 44 MnO 34 FeO 24

(d) CrO 44 MnO 34 FeO 24 RuO 24

and the other is

Pt NH 3 2 tu 2 . The initial isomers are respectively..

(a) cis Pt NH3 2 Cl2 and trans Pt NH 3 2 Cl2

The acid catalyzed hydrolysis of trans- Co en 2 Ax

gives cis-product only due to the formation of

(b) Trigonal bipyramidal intermediate

Consider the following redox reactions

(d) I < II < III < IV

(c) Co NH 3 4 Cl2 Cl.2NH 3

(d) Co NH 3 3 Cl3 3NH 3

The asymmetric nature of visible absorption band of Ti H 2O 6

(b) Laportes forbidden transition

Number of geometrical isomers for Co gly 2 NH 3 py is:

The spinels CO3O4 and Fe2NiO4 are respectively.

(d) Inverse, normal

d-orbital involved in sp3d hybridization corresponding to square pyramidal geometry is

(d) -non bonding

Which of the following is the uncertainty principle?

Which of the following statement is not true about elimination reaction

The -accepting properties of some PR3 ligands follow the ordering.

that satisfies the 18 electron rule is

(C) P(OMe)3 (D) PPh3

Consider the catalyst in Column-I and reaction in Column-II

(a) It is an example of oxidative addition.

Which of the following enzyme is responsible for nitrogen fixation

Match the following

(a) P-5, Q-1, R-4, S-6

The metalloenzyme Galactose oxidase is responsible for

Electronegativity of the following elements increases in the order

Which of the following has the highest ionization energy

(c) Nature of I oxidising

Which of the following is least basic

An acid with peroxide linkage

The substance having lowest boiling point is

(d) None of these

The bond order of O2 in 3 g is:

Match the following

(a) A-iv, B-vii, C-vi, D-ii

(c) ICl4 , SiCl4

The compound that cannot be formed by Xe is

The reaction given below can be explained by

(a) Lewis concept

(b) Unsanovich concept

The correct match of following is

(a) 1-C, 2-F, 3-B, 4-H, 5-A, 6-D

(A) Oxides of N, P, S act as acid

The decay series of a radioactive element is as

(b) A and C are isobars

The activity of radio isotopes changes with

Which of following is incorrect statement about spectra of lanthanoids?

Lanthanoids ions shows luminescence because

Which of the following combination of most stable oxidation of actinoids is true?

The pair of lanthanodis having highest ionisation energy?

Yellow colour solution of FeCl3 changes to light green when

(a) Cr2 OCl2 , Na 2 CrO3

(b) Cr2 OCl2 , Na 2 CO3

(c) CrO 2Cl, NaCr2O 4

(d) CrO 2 Cl2 , Na 2CrO 4

Turnbulls blue and Prussians blue respectively are

III FeII FeIII CN 6