Beruflich Dokumente
Kultur Dokumente
01.12.2009
Volume (mL)
10mL
9.2mL
8.6mL
7.5mL
7mL
6.5mL
6mL
4.4mL
Calculations:
1.
2.
1.00mmHg
13.6mmH 2O
20 759.221mmHg
Pcylinder = 757.74 +
= .999atm
=
13.5
760mmHg
3.
4.
n air =
Pair =
Pair =
Pair =
Pair =
Pair =
5.
6.
PV
(.998)(.0043)
n air =
= 1.901 10 4 mol
RT
(.0821)(274.9)
n air RT
V
(1.905 10 4 )(.0821)(353)
.0098
(1.905 10 4 )(.0821)(348)
.009
(1.905 10 4 )(.0821)(343)
.0084
(1.905 10 4 )(.0821)(338)
.0073
(1.905 10 4 )(.0821)(333)
= .766
.0068
(1.905 10 4 )(.0821)(328)
= .604Pair =
= .814
.0063
(1.905 10 4 )(.0821)(323)
= .639Pair =
= .902
.0056
(1.905 10 4 )(.0821)(274.9)
= .724Pair =
= .935
.0046
= .563Pair =
H vap = m(R)
H vap = m(R)
44047.155J
5300.5(8.31) =
= 44.047
20209.92J
1000J
2432.4(8.31) =
= 20.20992
1000J
H vap = 44.047
H vap = 20.21
Questions:
6. Write out the long two point form of the Clausius-Clapeyron equation.
Why does the graphical method five a better value for the enthalpy or
vaporization?
P T H
1
1
ln vap 1 = vap
2 T1
P
vapT2 R T
The graphical method is more accurate because it takes into account more
than just two points, unlike the Clausius-Clapeyron equation. With more than
two points taken into account, the measurements will be much more accurate
and can appeal to a much broader set of data.
Possible Sources of Error:
Incorrect measurements
Too much/Too Little Water in the Graduated Cylinder
Our lowest temperature was not 0C
Incorrect Calculations
Neglecting the vapor pressure of Water
Not enough stirring during the procedure to distribute the temperature evenly
Percent Error:
Accepted Value: 41 KJ
44.047 41
100% = 7.431%error
41
20.21 41
100% = 50.707%error
41