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Lecture 10
Polarization Techniques Corrosion Rate Determination
Keywords: Corrosion Rates, Polarization Diagrams, Linear Polarization Resistance.
A weighed sample coupon of metal introduced into the corrosion process and
after desired exposure period removed, cleaned of all corrosion products and
reweighed. Weight loss can be converted to average corrosion rate (mpy) using
Faradays law.
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Course Title: Advances in Corrosion Engineering
Course Co-ordinator: Prof. K. A. Natarajan, IISc Bangalore
Typical cathodic polarization curves with respect to Tafel behaviour are also
given. Extrapolation of cathodic and anodic Tafel slopes back to the corrosion
potential (Ecorr) are shown. Intersection point corresponds to corrosion current
density (icorr) or corrosion rate (Fig. 10.1).
ia = ic = icorr (mixed potential theory)
At least one decade of linearity in Tafel extrapolation is desirable to ensure good
accuracy. When concentration polarization and ohmic resistance come into the
picture, accuracy in Tafel extrapolation becomes more and more difficult. Steady
state polarization curves need be obtained to be more representative of corrosion
reactions.
2
Course Title: Advances in Corrosion Engineering
Course Co-ordinator: Prof. K. A. Natarajan, IISc Bangalore
3
Course Title: Advances in Corrosion Engineering
Course Co-ordinator: Prof. K. A. Natarajan, IISc Bangalore
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Course Title: Advances in Corrosion Engineering
Course Co-ordinator: Prof. K. A. Natarajan, IISc Bangalore
Current against overpotential for a reversible reaction such as the ferric ferrous
couple on a noble electrode surface is shown in Fig. 10.4.
Anodic and cathodic curves along with the resultant current behavior for
reversible reaction is illustrated.
Fe+++ + e = Fe++
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Course Title: Advances in Corrosion Engineering
Course Co-ordinator: Prof. K. A. Natarajan, IISc Bangalore
Fig 10.5 Polarization behaviour of metal M in unstirred aerated near neutral solution
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Course Title: Advances in Corrosion Engineering
Course Co-ordinator: Prof. K. A. Natarajan, IISc Bangalore
The extent of linearity of the potential current plot depends on a and c values.
Tafel slopes are necessary to calculate B.
Since B varies within a factor of 2 around a value of 0.065 V for long range Tafel
constants, corrosion rate (icorr) can be estimated within a factor of 2 (even of Tafel
constants are not available).
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Course Title: Advances in Corrosion Engineering
Course Co-ordinator: Prof. K. A. Natarajan, IISc Bangalore
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Course Title: Advances in Corrosion Engineering
Course Co-ordinator: Prof. K. A. Natarajan, IISc Bangalore