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Abstract
The investigation was conducted on a high-speed direct-injection diesel engine and was concerned
with the eects of exhaust gas recirculation (EGR) on diesel engine combustion and emissions. In
particular, the eects on combustion and emissions of carbon dioxide (CO2) and water vapour (H2O),
principal constituents of EGR, were analysed and quantied experimentally. The eects of increased
inlet temperature and thermal throttling of the inlet charge, both arising from the use of hot EGR, were
also investigated. Finally, tests were carried out during which the CO2 added to the engine air ow
increased the charge mass ow rate to the engine, rather than displacing some of the oxygen (O2) in the
inlet air. It was found that when CO2 or H2O displaced O2 in the inlet charge, both the chemical and
thermal eects on exhaust emissions were small. However, the dilution eect was substantial, and
resulted in very large reductions in exhaust NOx at the expense of higher particulate and unburnt
hydrocarbon emissions. Higher inlet charge temperature increased exhaust NOx and particulate
emissions, but reduced unburnt hydrocarbon emissions. Reduction in the inlet charge due to thermal
throttling reduces NOx emissions but raises all the other pollutants. Finally, when CO2 was additional
to the inlet air charge (rather than displacing O2), large reductions in NOx were recorded with little
increase in particulate emissions. # 1998 Elsevier Science Ltd. All rights reserved.
Keywords: Diesel combustion; Exhaust gas recirculation; Diesel pollutant emissions
1. Introduction
EGR is one of the most eective techniques currently available for reducing NOx emissions in
internal combustion engines. However, the application of EGR also incurs penalties. In the
case of diesel engines these include worsening specic fuel consumption and particulate
emissions [17]. In particular, EGR aggravates the trade-o between NOx and particulate
1359-4311/98/$19.00 # 1998 Elsevier Science Ltd. All rights reserved.
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emissions, especially at high loads [7, 8]. The application of EGR can also aect adversely the
lubricating oil quality and engine durability [911].
1.1. The eect of EGR on engine operation
Fig. 1 summarises the eects of EGR on the inlet charge composition of a diesel engine. In
the example of Fig. 1, 25% of the inlet air ow rate is removed and replaced by an equal
volume ow rate of hot EGR. It can be seen that the eect on the inlet charge is, rstly, a 14%
reduction in the charge mass ow rate. This is due to the reduction in the engine volumetric
eciency as a result of the rise in inlet charge temperature. Secondly, some of the inlet air is
displaced by carbon dioxide (CO2) and water vapour (H2O), which are principal constituents
of EGR. Thus, the application of hot EGR reduces the nitrogen (N2) ow rate to the engine
by about 15% and the oxygen ow rate by 19%. About one-fth of the reduction in the O2
ow rate is due to its displacement by CO2 and H2O present in the EGR, and the remainder
due to reduction in volumetric eciency.
The displacement of inlet charge with CO2 and H2O can alter the combustion process in
several ways, three of which will be considered in detail in this paper. The rst major eect to
be considered will be the reduction of oxygen concentration within the engine cylinders that is
available for combustion; this eect will be referred to as the dilution eect. The second eect
to be considered will be the higher specic heat capacities of both CO2 and H2O in comparison
to that of oxygen; this eect will be referred to as the thermal eect. Both CO2 and H2O can,
potentially, dissociate at the high temperatures prevailing during combustion and the products
of dissociation participate in the combustion process; this eect will be referred to as the
chemical eect of EGR.
Fig. 1. The eect on engine inlet charge of replacing 25% of the inlet air with hot (7008K) EGR (diesel engine at
32:1 AFR).
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When EGR is mixed with inlet air supplied to a diesel engine, the temperature of the inlet
charge to the engine increases; this can aect signicantly the compressed-charge temperature
and the combustion process. The higher inlet charge temperature also reduces the charge
density and the mass of inlet charge admitted to the engine cylinders. This eects will also be
considered in some detail in this paper.
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Fig. 2. Eects on nitric oxide emissions of carbon dioxide replacing oxygen in the inlet charge.
tenth of its original level. It is also interesting to note that once O2 in the inlet charge is
reduced from 23.3 to 17.3% (i.e. 6% of the inlet charge is replaced by CO2), strong
diminishing returns set in, with very little additional reduction in NO being obtained with
further substitution of O2 in the charge.
Fig. 2 also shows that the reduction in O2 concentration (dilution eect) accounts for most
of the observed reduction in NO. The dissociation of CO2 and its participation in the
combustion process (chemical eect) is seen to have had a much smaller eect on NO
emissions. The high specic heat capacity of CO2 (thermal eect) hardly inuenced the NO
emissions at all.
In order to isolate the eects on NO of the increase in ignition delay, the following test
was run: the O2 concentration in the inlet charge was reduced from 23.3 to 17.3%(m) and
the O2 was replaced by a mixture of N2 + Ar having the same mass and specic heat capacity
as the oxygen being replaced. This replacement of O2 in the inlet charge had the eect of
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Fig. 3. Nitric oxide emissions at constant inlet oxygen concentration (17.3%(m)) with ignition delay progressively
reduced using cetane improver.
prolonging the ignition delay from 7.98CA (when the engine was running with air only) to
11.78CA. Whilst the engine continued to run at this condition, the ignition delay was
progressively reduced from 11.7 back to 7.78CA by adding gradually increasing amounts of
ignition improver (2-ethyl hexyl nitrate) to the engine fuel. Fig. 3 shows that the eect
of ignition delay alone on NO is rather small in comparison with the eects of reducing
the oxygen available for combustion. Plots similar to that in Fig. 3 were produced for the
other exhaust emissions (NOx and Particulates) and the eects of ignition delay were conrmed
to be of secondary importance in comparison with the dilution eect on the levels of these
emissions.
Fig. 4 shows that the particulates increased more than four-fold when the O2 concentration
in the inlet charge was reduced from 23.3 to 16.3%(m) by replacing it with CO2. Fig. 4 also
shows clearly that the reduction in O2 availability for combustion (dilution eect) is responsible
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Fig. 4. Eect on total particulate emissions of carbon dioxide replacing oxygen in the inlet charge.
for the large increase in particulates. In fact, the dilution of the inlet charge can be seen to be
greater than the overall eect of CO2. However, the detrimental eect of dilution is moderated
to some extent by the chemical eect of CO2 which reduces the particulate emissions as shown
in Fig. 4. A chemical eect of CO2 in reducing particulate emissions (possibly through
suppression of soot formation or enhancement of the soot oxidation) was also reported by
other workers [1214].
The particulate mass emitted in the exhaust was analysed for volatile organic fraction
(VOF) and carbonaceous fraction (residual). This was achieved by placing the particulate
lters for 24 h in an evacuated oven which was continuously being purged with lowpressure nitrogen at 2008C. The loss in weight was then taken as being the VOF of the
particulates. The results showed that the increase in the particulate emissions with increasing
inlet charge dilution was mainly attributable to the increase in the carbon fraction of the
particulates [3].
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Fig. 5. Dierent eects of water vapour replacing oxygen in the inlet charge on nitrogen oxides emissions.
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Fig. 6. Dierent eects of water vapour replacing oxygen in the inlet charge on the particulate emissions.
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Fig. 7. Inuence on nitrogen oxides emissions of inlet charge temperature at constant inlet charge mass and oxygen
concentration (17.3%(m)).
Furthermore, Fig. 8 shows that virtually none of this increase can be attributed to the
shortening of the ignition. It is possible that the increasing inlet charge temperature led to an
acceleration of fuel pyrolysis in the fuel-rich regions of the spray core, resulting in accelerated
soot formation. At the same time, however, it is possible that soot oxidation was also
enhanced by the higher combustion temperature, but not to the same degree as soot formation
in the spray core.
3.4. Eects of thermal throttling on emissions
The inlet air mass ow rate to the no. 1 cylinder was progressively throttled from 10 to
8.5 g/s in steps of 0.5 g/s, whilst maintaining the inlet charge temperature constant (i.e.,
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Fig. 8. Inuence on particulate emissions of inlet charge temperature at constant inlet charge mass and oxygen
concentration (17.3%(m)).
isothermal throttling). Fig. 9 shows that throttling the inlet air has only a very small eect on
NO emissions. The small eect is due to two major but opposite eects, which tend to cancel
each other out. First, the reduction in the inlet charge air ow rate tends to raise the peak
cylinder gas temperature and NO production, because the same amount of energy is now
absorbed by a smaller trapped mass in the engine cylinder. Secondly, however, the reduction in
oxygen supply to the engine, resulting from throttling the air, tends to reduce the peak cylinder
gas temperature and NO production.
Fig. 10 shows that throttling the inlet air increases the smoke emission from the engine.
Again, this is the net result of two opposing eects. First, the reduction in the inlet charge air
ow rate tends to raise the peak cylinder gas temperature and, probably, the soot oxidation
rate, resulting in lower soot emission in the exhaust. Secondly, however, the reduction in
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oxygen supply to the engine, resulting from throttling the air, tends to reduce the soot
oxidation rate, resulting in increased soot emission. The second eect dominates the rst, and
the net result is an increase in soot (smoke) emission from the engine.
3.5. The eect of increasing inlet charge mass by CO2 addition
The basic dierence between the use of EGR in gasoline and diesel engines is that EGR
displaces air in diesel engines, whilst in gasoline engines the EGR mass is additional to the
mixture mass required for a given engine power output [6].
Tests were carried out during which, instead of CO2 displacing oxygen in the air supplied to
the engine, the CO2 mass was additional to the air mass ow rate. For these tests, the engine
was rst operated with an air ow rate of 10 g/s per cylinder, as in previous tests, and the
exhaust emissions were recorded. Then, 1 g/s per cylinder CO2 was added to the air mass ow
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rate and the emissions were again recorded. Because the addition of 1 g/s per cylinder CO2 to
the inlet air increased the ignition delay from about 8 to 9.88CA, ignition improver was used to
shorten the ignition delay back to 88CA. Fig. 11 shows that the addition of 1 g/s per cylinder
CO2 reduced the NOx level to almost one-third, with the change in ignition delay not being
responsible for any of this reduction.
Fig. 12 shows that the addition of the 1 g/s per cylinder CO2 increase particulates by about
30%. However, almost all this increase is attributable to the increase in ignition delay. When
the increase in delay is oset by ignition improver, the particulate emissions with and without
the additional 1 g/s CO2 are at about the same level.
The results from the addition of 1 g/s per cylinder CO2 are particularly interesting because:
(i) The O2/fuel ratio supplied to the engine is not altered, unlike the case of displacing O2 by
CO2; the generation of soot and particulate emissions is not, therefore, greatly aected.
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Fig. 11. Oxides of nitrogen emissions for test with carbon dioxide added to the inlet air and ignition delay
progressively reduced using cetane improver.
(ii) The extra mass of CO2 raises substantially the total heat absorbing capacity of the inlet
charge to the engine, leading to signicant reductions in combustion temperature and
substantial reductions in NOx emissions.
The addition of CO2 to the inlet air mass ow rate appears to be a very eective way of raising
the heat absorbing capacity of the inlet charge. In contrast, when CO2 displaced O2, as in the
tests described earlier in this paper, the higher specic heat capacity of CO2 hardly raised the
overall heat absorbing capacity of the inlet charge (this is demonstrated in ref. [3] which shows
EGR raising the overall specic heat capacity of the inlet charge from 1.26 to only 1.27 kJ/
kgK, or by less than 1%).
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Fig. 12. Particulate emissions for test with carbon dioxide added to the inlet air and ignition delay progressively
reduced using cetane improver.
4. Conclusions
(i) The introduction of CO2 and H2O in the inlet charge resulted in a reduction in NOx and an
increase in the particulate emissions (which, in the case of CO2, was dominated by dry
soot).
(ii) When some of the O2 in the inlet charge was replaced by CO2 or H2O, the dominant eect
on emissions was the reduction of oxygen availability for combustion (dilution eect); the
higher specic heat capacity of the CO2 or H2O in comparison to that of the O2 it replaced
(thermal eect), had virtually no eect on emissions.
(iii) `Chemical eects', resulting from the dissociation of the CO2 or H2O, were responsible for
only moderate eects on NOx and particulates.
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(iv) Increasing the inlet charge temperature (at constant inlet charge mass ow rate) resulted in
an increase in both NOx and particulate emissions. In practice, there will be benets from
cooling the EGR, in terms of reduced NOx and particulates.
(v) Throttling the inlet charge mass at constant inlet charge temperature (isothermal throttling)
has only a small eect on exhaust NOx but raises exhaust smoke emissions substantially.
(vi) Adding EGR to the air ow rate to the engine, rather than displacing some of the inlet
air, appears to be a more benecial way of utilising EGR in diesel engines. This way may
allow exhaust NOx emissions to be reduced substantially with little penalty of increased
particulate emissions.
Acknowledgements
The nancial support of the Engineering and Physical Sciences Research Council (EPSRC)
and the technical support of Ford Motor Company are gratefully acknowledged.
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