Beruflich Dokumente
Kultur Dokumente
A Hydrogen and Oxygen Isotope Study of the San Cristobal Mine, Peru:
Implicationsof the Role of Water to Rock Ratio
for the Genesisof Wolframite Deposits
ANDREW CAMPBELL,*
Departmentof Geology,Harvard University,24 OxfordStreet,Cambridge,Massachusetts
02138
DANNY RYE,
Departmentof Geology,Yale University,Box6666, New Haven,Connecticut
06511
AND ULRICH
PETERSEN
exchanged
water becomes
depletedin isOand enrichedin iD as the temperature
of
exchangedecreases.
When the water to rock ratio is alsoallowedto vary, a wide varietyof
water compositions
is generated.The isotopiccomposition
of mineralsfrom SanCristobal
canbe interpretedasthe resultof depositionfrom a meteoricwaterwhichhasundergone
isotopicexchangewith a graniteat 400C, with a water to rock ratio rangingfrom 0.01 to
0.003. Isotopicdata takenfrom two other wolframitedeposits,PastoBueno(Landis,1972)
and Panasquiera
(Kelly and Rye, 1979) are reinterpretedusingthe modeldevelopedfor
SanCristobal.Bothsetsof dataare consistent
with the hypothesis
that wolframitedeposits
are formedby meteoricwaterswhichhaveexperiencedexchangeat very low water to rock
ratios(<0.05). The importanceof the low water to rock ratio maybe relatedto the way in
whichtungstenis leachedfrom a crystallizedpluton.
Introduction
SanCristobal,a modelis presentedwhich examines the San Cristobalregion.The rocksfrom the Dethe effect of isotopicexchangebetweenhydrother- vonianExcelsiorGroup are the oldestexposedin
mal solutions
andgraniticrocksasa functionof the the area. They consistprimarily of phylliteswith
temperatureof exchange
andthe waterto rockratio. minorlimestone,basalt,andquartzite.The thickness
of the Excelsiorphyllitesis diScult to estimate,not
* Present address:Department of Geoscience,New Mexico
Institute of Mining and Technology, Socorro, New Mexico
87801
0361-0128/84/363/1818-1552.50
Harrison(1943)estimates
the thickness
to be 2,000
1818
lgHot18
Fock$
Equado'.',..,Colombia
I
o ,
1819
\'
Colqui
LoOroya
Central
;', Railroad
Peru
LocationMap
50 Km
Kc
?San Cristobal
Vein
volcanicrocksof andesitic
andrhyoliticcomposition
whichare commonly
porphyritic.Abovethe volcanic
rockslie the Upper Triassicto Lower Jurassic
limestonesof the PucaraGroup.Thesedensegray- to
buff-colored limestones have a total thickness of 250
to 400 m. Interbedded with the Pucara limestone
are trachite and basalt flows. Above the Pucara
Chulec Fm.(Kc]
limestone,
andshale;in the SanCristobalregionit
is about220 m thick(Wilson,1963).Overlyingthe
GollarisquisgaFrn,(Kq]
Pucaro Fro.(dp]
Goyllarisquisga
Formationare the ChulecLimestone,
the Pariatambo
Shales,andthe Jumasha
Limestone,
all of Cretaceousage.Thesethree Cretaceousfor-
Mifu Fro,(Prn]
Excelsior Fm.(Oe]
Quartz monzonite(qmp]
general,the stratigraphic
thicknessof the post-
Veins
Replacement bodies
domehasbeena topographic
highsincethe Devonian (Lepry, 1981).
kilometers
2. Generalized
gelogic
mapof the SanCristobal
district
(modifiedfrom Petersen,1965).
1820
CAMPBELL,RYE,AND PETERSEN
are numeroussmallersubsidiary
branchesfrom these
veins. This study focusesonly on the Main vein,
which has been mined for a horizontal
distance of
PARAGENESIS
Augehte
--
Muscovite
Pyrite
Wolf remote
@uortz
holcopyrfte
I
--I
Spholerfte
Galena
Barite
Carbonate
....
I
I
I
!
FirstStage
Tungsten
Mnerolzoton
I
I
T
T
Bose Metal
MinerolizoOon
Carbonate
verticallinesindicatebrecciationbetweenstages.
Fluid inclusions
at SanCristobaloccurasprimary,
pseudosecondary,
and secondaryinclusions.Many
of the primaryinclusions
are large,isolatedinclusions
and are commonlyfound in the cores of crystals.
Another mode of occurrenceof primary inclusions
is in milky growthbands.These trainsof crystallographicallycontrolledinclusionsradiate out from
the cores of the crystals.The abundanceof these
small inclusionsassuresthat a high proportion of
the inclusionsin each crystalare of primary origin.
This is an importantfactorwhen extractinginclusion
fluidsfor isotopicanalysis.
The pseudosecondary
and secondaryinclusions
both occur as planesof inclusionscutting the cores
of crystals.Althoughit wasnot possibleto distinguish
between planesof secondaryand pseudosecondary
inclusionson a texturalbasis,they canbe separated
by their range of homogenizationtemperatures
(Campbell,1983).
Homogenizationtemperaturesfor all inclusions
fromaugelite,quartz,sphalerite,barite, andcarbonate are shownin Figure 4. The main populationof
homogenizationtemperaturesfor primary inclusions
in quartzoccursbetween230 and330C. A smaller
populationof homogenizationtemperatureswhich
occurs between
I Second
Stage I Third
Stage
I
is attributed
to
1821
20
16
12
Quarfz
Spholerite
2 -1_ i
Siderite
'
200
$00
400
cent.
tobal.Mineralsare arrangedparagenetically
startingat the top
with augelite.
poseof calculations
the temperatureat the peakin
The fi80 valuesfor 35 quartzsamplesare sumthe distribution
of temperatures,
300C,is assumed marizedin Table 1. As a check,mostsampleswere
to be the depositionaltemperaturefor quartz. analyzedat least twice. The averagevariationof
Freezing-point depressionmeasurementson fluid
thesemultiple analysesis about ___0.2
per mil. The
inclusionsyield freezing temperaturesof-1.6 to averageof the two, or three, analysesis used in
-3.9C whichcorrespond
to salinitiesof 2.7 to 6.3 latercalculations.
Thesefi80 valuesrangefrom9.8
equivalentweight percentNaC1.
to 14.4 per mil. In order to calculatethe isotopic
Alteration
composition
of water whichwouldbe in equilibrium
with
the
quartz
of theseisotopiccompositions,
the
Within the phyllites,wall-rockalterationnearthe
temperature
of
deposition
must
be
known.
As
stated
vein can be separatedinto three types.Closestto
the vein is a zone of silicification(2 m), the next above, a temperatureof 300C was used in this
zone consists
of sericiticand argillicalteration(3-5 calculationbecauseit representsthe peak in the
temperaturesfrom
m), and the outermostzone is characterized
by distributionof homogenization
fluid
inclusions
in
quartz.
Using
the oxygenisotope
abundantchlorite(7-14 m). The zoneof alteration
fractionation
equation
for
the
quartz-water
system
can be up to 20 m wide. In the volcanicrocksthe
from
Clayton
et
al.
(1972),
it
is
possible
to
calculate
silicifiedzoneis absentandthe sericiticandargillic the/isO values for water. The calculated values at
zone is only 3 m wide. However, the chlorite zone
StableIsotopeStudies
Wolframite
Manystudies
in therecentpasthavedemonstrated The sO valuesfor 14 wolframitesamples
are
the usefulness
of stableisotopesin elucidatingthe summarizedin Table 2. These values range from
origin and history of hydrothermalsolutionsand 0.6 to 4.6 per mil. If one assumes
that the wolframite
1822
CAMPBELL,
RYE,AND PETERSEN
TABLE
Sample
no.
SC-1
SC-2
% yield
1.
80
(%0)
98
12.6
100
12.5
90
14.6
103
12.2
AvgbO
Sample
()
no.
12.6
13.3
SC80-7
SC80-8
SC80-10
92
11.9
12.0
12.0
SC80-12
89
88
10.3
10.5
10.4
SC80-14
98
100
13.3
14.1
13.9
13.1
99
13.8
SC-5
102
93
13.4
13.5
13.5
SC-6
87
13.9
13.9
SC-7
100
11.1
11.2
98
11.3
SC-8
97
97
13.4
13.1
13.3
SC-9
98
12.8
12.7
SC80-16
96
12.5
94
98
13.1
13.2
13.2
SC80-21
98
14.3
14.2
SC-13
SC-16
SC-17
13.9
14.3
98
11.2
103
11.5
98
11.6
95
12.7
94
13.8
100
12.5
13.8
SC80-15
11.4
12.7
97
13.8
97
13.8
97
12.8
97
12.8
94
14.3
94
14.4
SC80-6
100
12.7
93
13.1
14.4
88
14.4
101
80
94
100
14.3
9.7
9.8
12.7
12.6
9.9
12.4
SC80-26
98
13.0
13.1
98
13.1
96
13.7
98
14.0
98
13.9
14.0
12.8
12.8
SC80-29
SC80-33
12.5
13.8
12.8
14.4
SC80-47
92
12.2
SC80-34
12.9
14.0
12.2
SC80-45
SC80-4
14.2
94
100
SC80-42
SC-25
94
11.6
SC80-23
SC80-40
SC-18
11.8
11.6
13.8
99
11.7
11.9
(%o)
11.6
97
96
97
95
AvgbO
96
99
SC-10B
(%0)
97
SC-4
SC-10A
bO
% yield
SC80-49
92
102
14.1
95
12.8
93
12.8
97
11.7
94
12.9
97
12.5
13.9
12.3
12.7
96
11.3
96
12.7
12.0
97
10.7
10.7
99
13.0
13.0
95
12.9
TABLE3.
Sampleno.
Sample
no.
% yield
SC80-16
SC80-21
SC-25
SC-10
SC80-33
SC-18
SC-9
SC80-45
SC-2
SC80-4
SC80-8
SC80-7
SC80-4
SC-8
1823
baC(%0)
bsO(%0)
lSo (%0)
SC80-35
SC80-38
SC80-26
SC80-42
SC80-21
SC80-44
0.6
1.0
1.0
1.5
1.5
1.6
1.7
2.3
3.3
3.6
4.1
4.1
4.6
4.6
89
98
98
98
97
98
101
95
93
104
100
97
100
-3.3
-3.3
-4.2
-4.8
-5.5
-6.3
2.5
4.1
2.7
4.5
3.4
2.4
Carbonate
The/51sO
valuesfor sixsideritesamples
are summarizedin Table 3. Thesevaluesrangefrom 2.4 to
4.5 per mil. Homogenizationtemperaturesfrom
inclusionsin two samplesindicatethat the siderite
wasdepositedat about 140C. Usinga fractionation
factor for FeCOa-H20 from Becker and Clayton
can be calculated
at 140C.
This
fluids were
extracted
from
TABLE4.
Hydrogenand OxygenIsotopeCompositions
of
14
I0
$10(%0) WOLFRAUITE
FIG. 5. Oxygenisotopecompositions
of quartzandwolframite
"pairs" (i.e., from the samehand sample)from San Cristobal
showingno correlation.
22 mono-
CO._
X 100
H20
SC-9
SC80-40
py
py
-82
-84
0.3
0.8
SC-9
SC80-33
SC-2
wolf
wolf
wolf
-60
-69
-84
1.0
1.1
0.7
SC-2
SC80-40
SC-10
SC80-47
SC80-42
SC80-5
SC80-29
SC80-29
SC80-38
qtz
qtz
qtz
ep
sp
sp
sp
sp
sp
-96
-107
-112
-96
-58
-74
-81
-84
-90
1.2
1.4
0.7
0.4
0.7
1.4
0.2
1.9
0.1
SC80-27
SC80-28
SC80-38
SC80-54
bar
bar
carb
carb
-128
-148
-86
-89
0.4
SC80-29
SC80-27
SC80-26
SC80-50
sp
sp
sp
py
-85
-89
-91
-56
12.5
20.0
4.5
4.7
4.5
4.6
0.2
0.3
0.2
0.4
Abbreviations:
bar = barite, carb -- carbonate,cp = chalcopyrite, py = pyrite, qtz = quartz, sp = sphalerite,wolf = wolframRe
1824
from -148 to -58 per mil, but the range for each
mineral is much smaller.The most negativevalues
are from barite and are thought to representlate
fluids trapped in secondaryinclusions.These late
fluidsprobablyrepresentmeteoricwater which inflitrated the systemafter mineralization.In Figure
6, the/tD valuesare shownasa functionof paragenesis.The relation of/tD valuesto paragenesisis not
montonicbut is rather more complex.The interpretationof thesedatawill be givenin the next section.
The CO./H.Oratiosshowthat CO.is a very minor
constituent(<2%) of the ore solution,exceptin the
carbonatestagewhen the CO./H.Omolarratio was
as high as 0.2.
factor.
is a reasonable
approximation
for the/taO valueof
the whole rock. The feldspar-water fractionation
factor
-40'
PY
$p
-8O
A = 18Oplag
-- 18OH
O= 2.68X 10a/T2 - 3.53,
-120
Bar (secondary
inclusions)
-160
Parogenesis
>
muscovite,
paragenesis.
between
1825
to rock ratio
/SMOW
c'
oo.
Wfwater -1
t- R6rock= Wfwater+ Rfrock,
600
70o % I
Grant
oho
-I0
--
f -- frock
i
frock
i
f -- hrock-water)
'
fwater(frock
-0
-I0
I0
20
btSO
(%,)
FIG. 7. Calculation of the effect of temperature on the
isotopic equilibrium between water and granite in a rockdominatedsystem.The pointsrepresentthe movementof the
center point of the exchangedwater box as the temperatureof
exchangedecreases.
ature:
ffwater
-- --
w + zr
i
fwater
q- --
zr
w + zr
-- Arock-water).
per mil. This is an approximateaveragefor the units, and z has been added to correct for the
fractionation
factorsof the varioushydrousminerals differentamountsof oxygenandhydrogenper weight
and agreeswell with the analysesfrom natural unit in water and rock. Water contains89 weight
systems
whichhavebeenusedto definethemagmatic percent oxygen,whereasgranite typically contains
water box. In the caseconsideredhere, the fD and only 45 to 50 weight percent, so the z for oxygen
is equalto 45 dividedby 89, or about0.5. A typical
f80 of the granitearefixedsothat
granitecontainsabout0.6 weight percentwater, so
06Owate
r 42.6 X 106
the z for hydrogenis equalto about0.006. A similar
0T
Ta
equationfor the effect of temperatureand water to
and
rock ratio on the isotopic compositionof water
0618Owater--5.3 X 106
exchangingwith rock is given by Ohmoto and Rye
(1974) with their discussionof Kuroko deposits.
OT
Ta
Figure 8 showsthe exchangecurvesfor meteoric
--
--
Therefore,
OOwate
r
--
42.6 X 106
01aOwater--5.3 X 106--
--8.
The aboveequations
showthat the slopeof the line functionof w/r. At high w/r, the water experiences
whichexpresses
the changein isotopiccomposition only an oxygenshift,but at low w/r, the fD is also
of exchanged
water asa functionof temperatureis affected.Furthermore,with increasing
w/r the water
constant.As the temperatureof exchangedecreases, compositioncurvesdiverge, whereas the rock comthe water becomesdepletedin 80 and enrichedin position curves converge.
deuterium
andtrendstowardthe isotopic
composi- It is interestingto note in Figure 8 the different
tion of seawater.
isotopiccompositions
for waterswhich can be genThissimplemodelis applicablenot onlyto granite erated by the water-rock interaction. Considerthe
but also to other related leucocratic rocks because exchange
curvefor 400C.At very low w/r (<0.001),
of the general nature of the fractionation factors the resultant water will have a fD heavier than
used.
magmaticwater. At w/r between 0.001 and 0.005
1826
exchangeable.
Different fractionationfactorscan be
usedto approximateother rock types.
Figure 8 alsoshowsthe composition
of granitein
equilibriumwith water at a different w/r. Dotted
linesconnectcoexisting
water androckcompositions.
Taylor (1978) has examinedthe effect of meteoric
water alteration on severallarge granitic batholiths
-40
o -80
-120
-160
-20
-/0
&O(%)
FIC. 8. Exchangecurvesfor meteoricwater (/iD = -140%o,
almostperfectlythe theoreticallycalculatedcurves.
Many of the analysesplot in the regionof the curve
whichcorresponds
to low w/r (0.01 - 0.001). These
values come from an area that is geographically
separatedfrom the area which hashigh w/r values.
The batholithsshow evidence of exchangeat low
w/r over a distanceof 10 to 20 km. This evidence
from naturalsystemsindicatesthat meteoricwater
canbe extensivelymodifiedisotopicallyby exchange
with graniticrocks.
in the Peruvian
Andes.
[]
Pymte
Spholerte
1827
SMOW
400C
-40
//
??
.'
-/
I Water
//Wolfram'de
L,51 I
Carbonate
/
-120
-160
-20
-I0 61e0(%0o) I0
[;'lc. 9. Isotope compositionalranges [or waters depositing extracted from San Cristobal sulfides falls within the
quartz, wolramite,and carbonate at San Cristobal. The solid sO rangeof the waterscalculated
to havedeposited
line is the exchangecurve or400C. '['he meteoric-magmatic the quartz and wolframite lends support to the
water mixing line (long dashes)is shown for comparison.The
that the D valuesmeasuredfor quartz
carbonatefluidscan be explainedby mixing of exchangedand assumption
andwolframitedo reflectthe originalwater responunexchangedmeteoric water.
tion.The isotopiccomposition
of the waterin equilibrium with wolframite was calculated with the
wolframite-water
fractionation
equationfromLandis
andRye (1974). Because
thisfractionation
equation
is empirically derived, it is not well known and
from which the quartz was depositedcannotbe dikes found near the vein supportthe idea that a
explained
in thisfashion
because
it hasa relatively magma was present and suggestthat it was of
lowD andhighsO. However,the compositional
leucocraticcomposition.
Other igneousrocksin the
rangesfor both mineralscan be explainedby a area which were intruded during the Tertiary, the
modelin which the San Cristobalpaleometeoricpresumedtime of mineralization,are quartz monwater exchangedwith a graniticrock at 400C with
a w/r ranging
fromabout0.01to 0.003.Anexchangezonite porphyriesis only 1 to 2 km southof the San
temperature of 400C is reasonable because fluid
inclusion
homogenization
temperatures
in the early
stagesof mineralization
rangeup to 400C. One
wouldexpectthat the temperature
of isotopicexchangewith the graniticrockto be slightlyhigher
1828
CAMPBELL,RYE,AND PETERSEN
value and then to mix with unexchangedmeteoric During eachcyclethe i80 remainsrelativelyconwater to obtain the correct /580 values, because stantandthe/SDincreases.
Betweencyclesthe/5180
phyllites are enriched in heavy oxygenrelative to decreasesmoderately and the/SD diminishesdrastically. One possibleexplanationfor this phenomenon
granite.
From the observations above it seems reasonable
temperature.
/SMOW
-4o-
""-'
'0 II
4ve
--.4-.
,,,/ .7-7
:
.,::3
'-
'/
/
Magmatic
Wo,
,r
Panasqueira
-120
to
Buena
-0
-/0
/0
Mineral
6SO(%0)
Vein quartz
3 to 8
6D (%0)
in the
area at the
time
of ore
3.8 to 10.3
-47
Wolframite
Cassiterite
3.8 to 4.9 g
4.7 to 5.8 a
-71
-124
4 to 84
water
-60 to -45
Vein muscovite
Main-stagesulfides
meteoric
1829
to -36
to -44
to -86
-87 to -47
Siderite
5.3 to 7.7
-60
Late-stagecarbonate
-4 to 5
-58 to -42
to -45
Assuming
a temperatureof 360C
Usingan empiricalfractionarian
factor
Assuming
no fractionbetweencassiteriteand water
Assumed
fromparagenetic
constraints
o / SMOW
/ Late Stale
/ Crlbnate
/ Muscovite
_.-4o
*...
---
Siderite
'
Wolfrorbit
-80
Carbonate waters
Water
I I %....MainStaqe
-I0
I0
Sulfi
I
20
$eo(%0)
FIC. 11. Isotopicdata form Panasqueira
(Kelly and Rye,
1979). With the exceptionof three data pointsfrom quartz
the earlier water is consistent.They all have bD (shownby the dashedlines) and the analysesfrom the late
valueswhich are higherthan that of the presumed carbonatestage,the data plot as a vertical band.
1830
CAMPBELL,RYE,AND PETERSEN
The three wolframite depositsdiscussedin this trationsin granitegreater than that of W by at least
study can be interpreted as having formed from an order of magnitude.Experimentaldata on the
meteoricwaterswhichhaveinteractedwith a granitic solubilityof wolframiteand the amountof tungsten
rock under conditions of low water to rock ratios.
which can be transported in solution is needed
What genetic significancemight this interpretation before a more quantitative argument may be adhaveconcerningthe generationof tungstendeposits vanced.
and how does this correlate with the observation
The aboveargumentassumes
that the wolframite
that most wolframite depositshave only minor as- was depositedfrom a solutionwhich containedno
sociatedbase metal sulfides?Another way to ask base metals rather than a solution which contained
thisquestionis, how mightsolutionsrich in tungsten basemetalsthat were not deposited.
but poor in basemetalsbe generated?This question
Size of Intrusion
can only be addressedspeculativelyuntil more inWhen dealingwith suchlow water to rock ratios,
formation is available on the behavior of tungsten
in magmaticand hydrothermalprocesses.The fol- the questionarisesasto whether the amountof rock
lowing discussionwill focus on the extraction of needed to generatean ore depositby this process
tungstenfrom granitic rocks and not considerthe is reasonable. The amount of water needed to transphyllites, which are another possiblesource. The port the coppercanbe calculatedfrom the tonnage
tungsten concentrationin shales and phyllites is of copperdepositedat SanCristobal.The SanCrissimilarto that in granite, althoughtungstenmay be tobal mine hasproducedabout5 million tonsof ore
concentratedin black shales as many metals are with an averagegrade of 1 percent copper. This is
(Vine and Tourtelot, 1970), but no pertinent data equal to 50,000 tons or 50,000,000 kg of copper.
are available.
Accordingto Crerar and Barnes(1976) it is possible
During magmatic crystallization tungsten seems to transportup to 1,000 ppm of copper in solution
to be excludedfrom the early crystallizingphases under conditions similar to those at San Cristobal.
(i.e., quartz, feldspar,and amphibole)and concen- This is supportedby fluid inclusionevidencefrom
trated in the residualmelt (Wedepohl, 1969). If the porphyry copper depositswhich indicatescopper
residualmelt doesnot migrateout of the granite to contentsin excessof 4,000 ppm (SawkinsandScherforma pegmatite,it will crystallizewithin the granite, kenbach,1981) and 2,000 ppm (Roberts,1975). If
a solutionwhichcandeposit
forming small veinlets and microveinletsbetween onearbitrarilyconsiders
crystals(Hibbard, 1980). Hibbard alsofeelsthat the 500 ppm of copper,then 10 kg of water are
ore metalstrapped in the late-stageveinletsmay be needed to transportthe copper. If we assumean
incorporated into sulfides, silicates, or alteration averagew/r of 0.005 from San Cristobal, then 2
mineralssuchassericiteor zeolites,dependingupon X 103 kg of rock are neededto alter the water
Volumetrically
thisis equalto 6 km3 of
what componentsare availablein the fluid. It may isotopically.
even be possiblefor tungstatesto form if the con- granite.
The amountof copper at San Cristobalwas used
centrationof tungstenis high enough.If this is true,
then later hydrothermalfluids passingthrough the in this calculation because there are better data for
rock may preferentiallyleach the metalswhich are the amount of copper which can be carried by
concentratedalongthesefracturesand grainbound- hydrothermalsolutionsthan of tungsten,and the D
aries becausethey are accessible.If only a small values of the waters extracted from chalcopyrite
amountof water passesthroughthe rock, then only indicate that it, too, was depositedfrom a highly
the most easily accessibleminerals are leached, exchangedwater. Becauseit accountsfor only the
10 kg of waterisa minimum
yieldinga solutionwhich is rich in tungstenbut not coppermineralization,
in basemetals.On the other hand, if a large amount estimate;an estimateof twice that, 2 X 10 kg of
of water is passedthroughthe rock, then a greater water maybe morerealisticfor depositingthe entire
calculation
1831
assess
the reasonableness
of this processis to calculatethe amountof granitewhichmustbe leached
to obtain the required amountof tungsten.If one
Acknowledgments
calculation
of 2 X 10 kg of rocldneededto alter May 2, 1983; April 5, 1984
of granite.
1153-1165.
Conclusions
176 p.
The resultsof the hydrogenand oxygenisotope
study show that the mineralizing solutionsat San Campbell,A. R., and Rye, D. M., 1982, Fluid inclusionand
stableisotopestudyof the San Cristobalmine, Peru [abs.]:
Cristobal have a distinctive isotopic pattern. The
Geol. Soc. America Abstractswith Programs,v. 14, p. 450.
water types are needed to accountfor the variation Lepry, L. A., 1981, The structural geology of the Yauli dome
region, Cordillera Occidental,Peru: Unpub. M.S. thesis,Univ.
in water compositions.The model, as presented
Arizona, 100 p.
here, is relatively simple,but it is flexibleand may Ohmoto,
H., and Rye, R. O., 1974, Hydrogen and oxygen
be adjustedto modelthe isotopicexchangebetween
isotopiccompositions
of fluidinclusions
in the Kurokodeposits,
water and manytypesof rocks.The significanceof
Japan: ECON. GEOL., v. 69, p. 947-953.
1832