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Greg Kerr
IB Chemistry HL
September 7, 2012
Lets start with copper Lab
Background
When a chemical changes take place, we may observe one or
more of the following:
A substance disappears.
A gas is given of
A color change takes place
A solid is precipitated
The temperature changes
A new odor appears.
Aim/Objective:
Through the various parts of the lab and reactions that take
place, we will observe and identify signs of chemical changes.
Starting with approximately 1.5 grams of copper, we strive to
recover the same amount of copper after five diferent reactions. In
addition, familiarize oneself with laboratory techniques and identify
the science of a chemical reaction
Materials/Equipment:
Small pieces of Copper
(Cu) 1.5 grams
Nitric acid (HNO3)
250 mL Beaker (2~3)
Weighing boat
Fume hood
Watch glass
3M Sodium Hydroxide
(NaOH)
IB Chemistry HL Lab 1
September 7, 2012
Stage One: Reaction between copper, Cu, and a
solution of nitric acid, HNO3, in water.
Procedure:
Given vial containing approx. 1.5 grams of copper.
Weigh vial and find mass of copper
Tip copper into 250 mL beaker
Mix 15mL of nitric acid solution with copper under
fume hood (gas produced is poisonous)
Put watch glass on top of beaker (to keep most of the
gas in for observation.
Observe. Has a chemical reaction occurred?
Observations:
During Reaction:
Gas is given of at the surface of the copper.
Possibly Hydrogen Gas
As the reaction progresses, the amount of gas
increases. The solution turns blue-green color.
A brown gas is formed, along with an unwelcoming
odor
Copper turns milky white
Temperature rises slightly
Copper eventually disappears. Solution left behind
is bluish, liquid, clear, transparent, with odor
(though possibly caused by odor of the brownish
gas produced)
Equation(s):
Cu(s) + 4NO3(aq)2NO2(g) + 2H20(l) + Cu(NO3)2(aq)
Procedure:
Add 40 mL of sodium hydroxide solution to solution in
beaker (yielded after stage 1) while stirring with glass
rod
Record observations
Observations:
During reaction:
A solid, dark blue precipitate forms
Color is darker than original solution, rather milky.
Temperature increase.
Equation:
Cu(NO3)2(aq) + 2NaOH(aq) Cu(OH)2(s) + 2NaNO3(aq)
1 mol of Copper (I) Nitrate solution + 2 mol of
Sodium Hydroxide solution yields 1 mol of Copper (I)
Hydroxide solid and 2 mols of Sodium Nitrate
solution.
Procedure:
Add 100 mL of distilled water to the beaker
Gently heat the beaker and its contents while stirring
with glass rod.
Observations:
During reaction:
Color of solution becomes even darker.
The precipitate turns into a greenish black particle
As heating continues, the greenish black particles
turn completely black, and retain a powdery
characteristic.
After the particles settle down, the solution above
it is colorless, odorless, liquid, clear, and
transparent.
Equation:
Cu(OH)2(s) + Heat CuO(s) + H20(l)
1 mol of Copper (I) Hydroxide solid + Heat yields 1
mol of Cupper (II) Oxide solid + 1 mol of water.
Procedure:
Carefully add 50mL of the acid solution to beaker. Stir
until no further reaction takes place.
Observe and record
Observations:
During reaction:
Solution turns blue green and ends up as bright
blue, clear, transparent, liquid solution.
Blackish powder disappears
Equation:
CuO (s)+H2SO4(aq) CuSO4(aq) + H2(l)
1 mol of Copper (I) Oxide + 1 mol of Sulfuric acid
solution yields 1 mol of Cupper (II) Sulfate + 1 mol of
Hydrogen gas.
Procedure:
Add 5 g of zinc metal to product in beaker. Place
watch glass on top of beaker
Observe any changes
Allow reaction to finish
Observe and record
Observations:
During reaction:
Bubbles from at the surface of the zinc pellets.
The zinc eventually turns blackish brown, and
finally disappears, leaving behind a solid, blackish
precipitate and a homogeneous, clear,
transparent, and colorless solution.
Equation (s):
Zn(s)+H2SO4 (aq)H2(g)+ZnSO4(aq)
Zn(s)+CuSO4(aq)Cu(s)+ZnSO4(aq)
1 mol of Zinc + 1 mol of Sulfuric acid yields 1 mol of
hydrogen gas + 1 mol of Zinc Sulfate
1 mol of Zinc + 1 mol of Copper (II) Sulfate + 1 mol
of Zinc Sulfate.
Stage 6: Recovery
Conclusion:
The initial mass of copper: 1.49 g 0.01g
The final mass of copper: 1.70 g 0.01g
The percentage discrepancy:
experimental valueexpected value
1.701.49
0.21
100 =
100 =
100 =0.1409 100 =14
expected value
1.49
1.49
Notice that that final weight of the copper is more than the
initial mass. We have take special care to wipe any water vapor from
the bottom of the evaporating dish after taking it of the water bath
to get an as accurate measurement of the mass of copper as
possible, but there is still surplus mass. I suspect there is some
residue zinc sulfate that contributed to this final mass of copper.
Nonetheless, I feel this lab was a success; during this lab, I
have familiarized myself with laboratory techniques and now I
definitely know the 6 signs of chemical change: gas produced, color
change, solid precipitated, heat change, substance disappears, odor
produced.