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UEMK2113Chemical
EngineeringThermodynamics
Lecturer:PangYeanLing
MarksAllocation
COURSEWORKS:
1Test:20%,Assignment:20%
FINALEXAMINATION:60%
PASSINGMARK:50%
Textbook
1. Koretsky,M.D.(2004)Engineeringand
ChemicalThermodynamics,1stedition,John
Wiley&Sons.(ISBN:0471385867)
(NewEdition)Koretsky,M.D.(2013)
EngineeringandChemicalThermodynamics,
2ndedition,JohnWiley&Sons.
2. SmithJ.M.,VanNessH.C.,Abbott
M.M.(2004)IntroductiontoChemical
EngineeringThermodynamics,7thEd.Mc
GrawHill(ISBN:0072402962)
CONSULTATIONHOURS:
Monday:10am12pm;1pm3pm
Thursday:10am12pm;2pm4pm
*pleasemakeappointmentatleast2daysprior
totheconsultation
Email:pangyl@utar.edu.my
*tutorialclassstartingweek2
*noclassduringCNYweek(week6)
*tutorialclass(6.3.15)10.30am12.30pm
Venue:fromSD206changetoSA229
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CHAPTER1
Introduction
Applications:
SteamPowerPlant(Togenerateelectricity)
FuelCells
VapourCompressionRefrigerationCycle(Air
Conditioning)
TheAirSeparationPlant
TheGasTurbine(AirplaneFlying)
GasMixtures(Separation)
ChemicalReactions(Fuelburning,Chemical
Production)
LawsofThermodynamics
1ZerothLawofThermodynamics
2.FirstLawofThermodynamics
3.SecondLawofThermodynamics
4.ThirdLawofThermodynamics
ZerothLaw
Thezerothlawofthermodynamicsstatesthat
whentwobodieshaveequalityof
temperaturewithathirdbody,theyinturn
haveequalityoftemperaturewitheachother
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1stlawofThermodynamics
ConservationofEnergy
1stLaw
2ndLaw
2ndlawofthermodynamics
TheKelvinPlanckstatement:
Itisimpossibletobuildanenginewhich
operatinginacyclecanconvertalltheheatit
absorbsintowork.
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3rdLaw
3rdlawofthermodynamics
TheentropyofaperfectcrystalisZEROat
absolutezerotemperature
dS=(dQ/T)rev
Definition - Systems
1N=1kgm/s2
1Pa=1N/m2
1bar=10Pa=0.1Mpa
1atm=101325Pa
=14.7psi
g=9.806m/s2=32.174ft/s2
K=C+273.15
R=F+459.67
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Properties of a System
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Steady-Flow Processes
Pressure
Internal Energy
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Forms of Energy
Mechanical Energy
V2
mgZ
2
or
e u
V2
gZ
2
V
gZ
E m e m u
2
emech m
P V gz
Emech m
2
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Shaft power
2NT
W
sh
Spring work
Wspring
1
k x22 x12
2
W W
12
Welastic nAdx
1
Power to raise
a body
mgV
W
g
Wa
Wsurface sdA
1
Work to
accelerate a
body
Electrical
power
VI
W
e
Efficiency or Performance
1
mV22 V12
2
i.e. not W2 W1
Elastic work
Desired output
Required input
Combustion efficiency
combustion
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Rate form:
Examples
Win Wout
Emass,in Emass,out
5 kJ
Emass,in Emass,out
Win Wout
Emass,in Emass,out
153 12kJ
8 kJ
5 kJ
U KE PE
Ein Eout
Emass,in Emass,out
Emass,in Emass,out
Win Wout
Win Wout
dEsystem
Ein Eout
dt
Examples
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Entropy
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Entropy (2)
Q
dS 0
T int rev
Entropy (3)
A pure crystalline
substance at absolute zero
temperature is in perfect
order, and its entropy is
zero. This is known as the
third law of
thermodynamics.
T int rev
Entropy (4)
Entropy (2)
Q
dS 0
T int rev
1
Q
T int rev To
Q
1
int rev
Q
To
750
2.5 kJ/K
300
T int rev
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Add
heat
heat
Add
Add
heat
heat
Superheated vapour
Saturated vapour
(i.e. vapour not about
(i.e. last drop of liquid
just vaporised or vapour to condense)
about to condense)
Saturation pressure
(i.e. pressure at which a
pure substance changes
phase)
Saturation temperature
(i.e. temperature at
which a pure substance
changes phase)
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Saturation temperature
T-v
diagram
Regions for different phases of a pure substance may be represented in Tv, P-v, P-T and P-v-T diagrams.
T-v
diagram
(solidvapour), vaporization
(liquidvapour) and melting
(solidliquid) meet at the
triple point.
P-T
diagram
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v vf
vfg
mg
mf mg
u uf
ufg
h hf
hfg
s sf
sfg
Reference State
Values of properties u, h and s are always given with respect to a
reference state of zero value. For water, at 0.01 C, u = 0 and s = 0.
For refrigerant R-134a, at -40 C, h = 0 and s = 0.
P v = RT or PV =m RT
where R is the specific gas constant equal
to the universal gas constant (=8.3145
kJ/kmol-K) divided by the molecular
weight of the substance. For air
R=8.3145/29=0.287 kJ/kg-K.
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Tutorial1
Tutorial1:
No.2.1,2.9,2.52,2.53,2.54,3.5
(Koretsky,M.D.(2004)EngineeringandChemicalThermodynamics,1st
edition,JohnWiley&Sons)
No.2.18,2.23,2.77,2.78,2.79,3.21
(Koretsky,M.D.(2013)EngineeringandChemicalThermodynamics,2nd
edition,JohnWiley&Sons)
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