Brindley Final Packet Part I

Tutor: Jesse Salas

1. The work function for lithium is 4.6 x 10-19 J.
a. Calculate the lowest frequency of light that will cause
photoelectric emission.

b. What is the maximum energy of the electrons emitted when light

of 7.3 x 1014 Hz is used?
2. A 50.6 g sample of Mg(OH)2 is reacted with 45.0 g of HCl according to
the reaction:
Mg(OH)2 + 2 HCl --> MgCl2 + 2 H2O
a. What is the theoretical yield of MgCl2?
3. Name HCO3
4. Write the formula for Sulfurous Acid
5. How many photons are produced in a laser pulse of 0.528 J at 679 nm?

6. List the following by increasing wavelength: Ultraviolet, Radio, Gamma

7. As the frequency increases, the wavelength: Increases

Decreases

8. An electron wave making a standing wave in a hydrogen atom has a

wavelength of 8.33 x 10^-11 m. If the mass of the electron is 9.11 x
10^-31 kg, what is the velocity of the electron according to the de
broglie equation?

Brindley Final Packet Part II

Tutor: Amreen Maniar
1. Give the shorthand (noble gas) configuration for the following:
a. Cr3+
b. Au
c. Br2. Which set of four quantum numbers not possible?
a. n = 4 l = 2 m = -1 s = +1/2
b. n = 3 l = 0 m = 0 s = -1/2
c. n = 2 l = 2 m = 1 s =
d. n = 5 l = 3 m = -2 s = -1/2
3. ArrangethefollowinginorderofINCREASINGelectronegativity:Ru,Ge,S,Db
4. Arrange the following in order INCREASING atomic radius: Cs, Mo, Ga
5. Draw the molecular orbital diagrams for O2 and calculate the bond order. Is it
paramagnetic or diamagnetic?

6. For each of the following indicate if the compounds are polar or

nonpolar:
a. FCN
b. HCN
c. C2H6
d. CF2H2
7. Draw the resonance structures for O3+.
8. How many pi bonds are present in the following molecule?

9. UsingVSEPRmodel,predictthemoleculargeometry(molecularshape)andelectron
geometryofthefollowings:
O3 CO32 ICl2
NF3
SnCl3
10.Predicttheapproximatevalueforthebondanglesforeachcarbonindicatedinthefollowing
compounds:

11. Indicatethehybridizationoforbitalsbythecentralatomineachofthefollowing:
SO32
SO3
NH4+

Brindley Final Packet Part III

1. A 0.02837 g sample of gas occupies 10.0 mL at 293.0 K and 1.10 atm.
Upon further analysis, the compound is found to be 38.734% C and
61.266% F. What is the molecular formula of the compound?

2. What is the rms speed of Br2 at 300 K?

3. A sample of F2 (g) take 40.0 min to effuse through a membrane. How

long would it take the same number of moles of Ne (g) to effuse
through the same membrane?

4. Rand the gas molecules CO2, C2H6, H2, H2O, He in terms of increasing
rate of effusion.

5. A .731 gram sample of a metal, M, reacts completely with sulfuric acid

according to: M(s) + H2SO4 (aq) MSO4 (aq) + H2 (g). A volume of 250
mL of hydrogen is collected over water; the water level in the
collecting vessel is the same as the outside level. Atmospheric
pressure is 756.0 Torr and the temperature is 25 C. Vapor pressure of
water is 23.8 mmHg. Calculate the molar mass of the metal.

6. Two containers are connected together by a stopcock. H2 gas is in one

container and takes up 2.00 L at 1.00 atm. The other container has Cl2
gas that takes up 5.00 L at a pressure of 3.50 atm. Find the partial
pressures and total pressure.

7. A 3.05 g sample of ammonium nitrate is introduced into an evacuated

2.18 L flask and then heated to 250 C. What is the total gas pressure
in the flask at 250 C when the NH4NO3 has completely decomposed.
NH4NO3 N2O + 2H2O