Beruflich Dokumente
Kultur Dokumente
4 marks
Q13) How are the following properties of crystals affected by Schottky &
Frenkel
defects?(i) density (ii) electrical conductivity
Q13) (a) In reference to crystal structure, explain the meaning of C.N.(b)
What is
the no. of atoms in a unit cell of FCC & BCC structure
Q14) Cu crystallizes into a FCC lattice with edge length 3.61 x 10 -8 cm.
Calculate
the density of Cu? (Cu = 63.5 g/mol)
2010 AI
Q1) What type of interaction hold the molecules together in a polar molecular
solid?
Q19 ) The density of Cu metal is 8.95 g / cm3 If the radius of Cu atom be
127.8pm
Is the unit cell simple cubic , BCC or FCC?
( Cu = 63.54 g /mol , NA = 6.02 x 10 23 mol-1)
Q1) What type of semiconductor is obtained when Si is doped with As?
Q19) Ag crystallizes in FCC cubic unit cell. Each side of the unit cell has a
length
of 409 pm. What is the radius of Ag atom.
Q1)Write distinguishing feature of metallic solids.
Q19) Ag crystallizes in FCC cubic unit cell. If the edge length of unit cell is
4.07 x 10-8 cm. and density 10.5 g/cm3. Calculate the atomic mass of
Ag
(NA = 6.02 x 10 23 mol-1)
2010 D
Q1)Write distinguishing feature of metallic solids from an ionic solid.
Q19)In one unit cell of CaF2 there are 4Ca2+ and 8 F- ions.Ca2+ are arranged in
FCC lattice.The F- ions fill all tetrahedral holes in the FCC lattice of Ca2+
ions,The edge of the unit cell is 5.46 x 10 -8 cm in length,the density of
solid
is 3.18 g/cm3.Calculate Avogadros no. (M.M. of CaF2 =78.08 g/mol)
Q1) Which point defect in crystal of solid does not change the density of solid
Q1) Which point defect in crystal of solid decreases the density of solid
2010 F
Q1) What is the no. of atoms in a unit cell of a simple cubic crystal?
Q19) Fe has a BCC unit cell with a cell edge of 286.65 pm. The density of Fe
is
7.87 g/cm3. Calculate Avogadros no. (at. Mass Fe=56 g/mol)
NEW SAMPLE PAPER I
Q1) Why LiCl acquires pink colour when heated in Li vapours.
Q17) Sodium crystallizes in BCC unit cell. Calculate the approximate no. of
unit
cells in 9.2 g of sodium (Na = 23)
Q18) What is a semiconductor? Describe the two main types of
semiconductors.
NEW SAMPLE PAPER II
Q10) KF has CCP structure. Calculate the radius of unit cell if the side of the
cube or edge length is 400 pm.How many F- ions and octahedral
voids are
there in this unit cell.
Q11) Give reasons:
2012 AI
Q1) how may the conductivity of an intrinsic semiconductor be increased?
Q19) copper crystallizes with FCC unit cell. if the radius of Cu atom is
127.8 pm, calculate the density of Cu metal. (at.mass of Cu = 63.55 u
and NA = 6.02 x 10 23 /mol)
Q19)iron has BCC unit cell with cell dimension of 286.65 pm. Density of iron
is
7.87 g/cm3.use this information to calculate Avogadros number.
(at.mass of Fe = 56.0u)
Q1) which stoichiometric defect increases the density of a solid?
Q1) what are n-type semiconductors?
2012 D
Q1) What is meant by doping?
Q19) Tungsten crystallizes in body centred cubic unit cell.If the edge of the
unit
cell is 316.5 pm.What is the radius of tungsten atom?
Q19) Iron has a body centred cubic unit cell with a cell dimension of 286.65
pm
The density of iron is 7.874 g/cm3 Use this information to Calculate
Avogadros number.(at. Mass of Fe = 55.845 u)
Q1)Write a point of differences between a metallic solid and an ionic solid
other
than metallic luster.
2012F
Q1)What is meant by the term forbidden zone in reference to band theory of
solids?
Q19) Iron has a body centred cubic unit cell with a cell dimension of 286.65
pm
The density of iron is 7.874 g/cm3 Use this information to Calculate
Avogadros number.(at. Mass of Fe = 55.845 u)
Q19) Silver crystallizes in FCC unit cell.If the radius of silver atom is 145 pm,
what is the length of each side of unit cell?
Q1)Write a point of differences between a metallic solid and an ionic solid
other
than metallic luster.
Q1) Define paramagnetism with an example.
2013 AI
Q9) account for the following:
(i)
schottky defects lower the density related solids.
(ii)
Conductivity of silicon increases on doping it with phosphorus
Q10) aluminium crystallizes in a fcc structure .atomic radius of the metal is
125
pm. What is the length of the side of the unit cell of the metal?
Q9) (a) why does presence of excess of lithium makes LiCl crystals pink?
(b ) a solid with cubic crystal is made of two elements P and Q. atoms of Q
are at the corners of the cube and P at the body centre . what is the formula
of the compound.
Q13) (a) what change occurswhen AgCl is doped with CdCl2?
( b ) what type of semiconductor is produced when silicn is doped with
boron
Solid state
FORMULAE :
LIMITING RADIUS RATIO
FOR CsCl STRUCTURE
5 marks
Q4) (a) If density of water of a lake is 1.25 g/mol & 1 kg of lake water
contains
92g of Na+ ions. Calculate the molarity of Na+ ions in this lake
water.
(b)Calculate the mass of a non volatile solute ( mol mass 40 g/mol)
which
should be dissolved in 114 g of octane to reduce its V.P. to 80 %
(M.M. of octane = 114 g /mol )
2008 D COMPTT
Q28) (a) The depression of F.P. of water observed for the same molar concn of
acetic acid, trichloroacetic acid & triflouroacetic acid increases in
the
order as stated above .Explain .
( b )Calculate the depression in F.P. of water when 20 g of
CH3CH2CH(Cl) COOH is added to 500 g of water.
(Ka =1.4 x10-3, Kf= 1.86KKg /mol)
Q28) (a) State Henrys law & mention its two important applications.
(b) Henrys law constant for CO2 dissolving in water is 1.67 x 10 8 Pa at
298 K. Calculate the quantity of CO 2 in 1L of soda water when
packed under 2.5 atm CO2 pressure at 298 K.
2008 AI COMPTT
Q9) What is meant by negative deviation from Raoults law? Draw diagram to
illustrate the relationship between V.P. & mole fraction of components in
a
solution to represent negative deviation.
Q20) The b.p. elevation of 0.3g of acetic acid in 100g benzene is 0.0633K.
Calculate the molar mass of acetic acid from this data.What conclusion
can
you draw about the molecular state of the solute in solution?
(Kb for benzene = 2.53KKg/mol)
Q18) Distinguish between the terms molality & molarity.Under what
conditions
are the molarity & molality of a solution nearly the same?
Q26) The F.P. of a solution containing 0.2 g of acetic acid in 20 g of benzene
is
lowered by 0.450 Calculate (i) the mol.mass of acetic acid from this
data.
(ii) vant Hoff factor
(Kf benzene = 5.12 K Kg/mol) What conclusion can you draw from the
value of
vant Hoff factor obtained.
Q13) What are non ideal solutions? Give one example.Explain as to why non
ideal
solution deviate from Raoults law.
Q21) Calculate the amount of KCl which must be added to 100 g of water so
that
water freezes at
20C Assume that KCl undergoes complete
dissociation.
(Kf = 1.86KKg/mol , K=39,Cl=35.5)
2009 AI
Q28) (a) Define (i) mole fraction (ii) vant Hoff factor
(b)100mg of a protein is dissolved in enough water to make 10 ml of a
solution.If this solution has an O.P. of 13.3 mm Hg at 25 0CWhat is the
molar mass of protein? (R= 0.0821 Latm/mol/K & 760 mm Hg=1atm)
Q28) (a) What is meant by (i) Colligative property (ii) molality of solution
(b)What concentration of N2 should be present in a glass of water at
room temp.?Assume temp. of 250C , a total pressure of 1 atm & mole
fraction of N2 in air of 0.78
(KH for N2 = 8.42 x 10 7 M/mmHg)
2009 D
Q13) Differentiate between molality & molarity of solution.What is the effect
of
change in temp. of a solution on its molality or molarity?
Q19) Calculate F.P. depression expected for 0.0711 m aq.solution of Na 2SO4.
If
this solution actually freezes at 0.320C What would be the value of
vant
Hoff factor (Kf for water = 1.86KKg/mol)
2009 F
Q2) What is reverse osmosis?
2009 D COMPTT
Q5) Define the term Osmotic Pressure.
Q6) State the main advantage of molality over molarity as the unit of
Concentration
Q27) Calculate the amount of NaCl which must be added to 1 kg of water is
depressed by 3K. ( Kf = 1.86KKg/mol, Na=23,Cl=35.5)
Q5) State Raoults law for solution of volatile liquid.
Q6) Define ideal solution
Q19) A solution of urea in water has a b.p. 373.128K Calculate the F.P. of the
same solution. (Kf = 1.86Km-1 , Kb=0.52Km-1)
Q23) 0.1 mole of acetic acid was dissolved in 1 kg of benzene. Depression in
F.P.
of benzene was determined to be 0.256K. What is the state of
solution?
(Kf for benzene = 5.12K/m)
2010 AI
Q9) Define the term osmosis and osmotic pressure.What is the advantage of
using O.P. as compared to other colligative properties for the
determination
of molar masses of solute in solution.
Q20) What mass of NaCl ( M.M. = 58.5 g/mol) must be dissolved in 65 g of
water
to lower the F.P. by 7.5 0C ? The F.P. depression constant Kf for water is
1.86 Kkg/mol. Assume that vant Hoff factor for NaCl is 1.87.
Q20) What mass of ethylene glycol (M.M = 62 g/mol) must be added to 5.5
kg of
water to lower the F.P. of water from 0 0 C to 10 0C ?
(Kf for water = 1.86 Kkg/mol)
Q20) 15 g of an unknown molecular substance was dissolved in 450 g of
water .
The resulting solution freezes at 0.340C What is the molar mass of
substance?
(Kf for water = 1.86 Kkg/mol)
Q2) Differentiate between molarity and molality of a solution.
2010 D
2011 AI
Q11)State the following.
(a) Raoults law in its general formin reference to solutions
(b)Henrys law about partial pressure of a gas in a mixture
Q19) A solution prepared by dissolving 8.95 mg of a gene fragment in 35 ml
of
Water has an O.P. of 0.335 Torr at 25 0 V Assuming that the gene
fragment
is a non electrolyte,calculate its molar mass.
Q19)What mass of NaCl must be dissolved in 65 g of water to lower the F.P. of
water by7.5 0C?TheKf for water is1.86 0C/m. Assume vant Hoff factor
for
NaCl is1.87(M.M. of NaCl is 1.87(M.M. of NaCl=58.5 g)
Q2)What is reverse osmosis?
Q3)Differentiate between molarity and molality values for solution.What is
the
effect of change in temperature on molarity and molality values?
2011 D
Q28) (a) Differentiate between molarity and molality for a solution. How does
a
change in temperature influence their values.
(b ) Calculate F.P. of aq. solution containing 10.5 g of MgBr2 in 200g of
water (MM of MgBr2 = 184g) (Kf for water = 1.86 Kkg/mol)
Q28) (a) Define osmosis and osmotic pressure. Is the O.P.of a solution a
colligative property? Explain.
(b )Calculate the b.p. of a solution prepared by adding 15 g of NaCl to
250 g
of water.(Kf for water = 0.512 Kkg/mol , M.M. of NaCl = 58.44g)
Q28) (a) repeated
(b ) What would be the M.M. of a compound if 6.21 g of it dissolved in
24 g of
chloroform a solution that has a b.p. of 68.04 0C. The b.p. of pure
chloroform is 61.7 0C . ( Kb for chloroform = 3.63 0C/m)
2011 F
Q2) State Henrys law about partial pressure of a gas in a mixture.
Q9) Differentiate between molarity and molality for a solution. Explain how
molarity value of a solution can be converted into its molality.
Q10) A 0.561 m solution of an unknown electrolyte depresses the F.P. of
water
by 2.93 0C. What is vant Hoff factor for this electrolyte. (Kf = 1.86
0C
/kg/mol)
2010 D COMPTT
Q5) Define the term Osmotic Pressure.
Q6) State the main advantage of molality over molarity as the unit of
concentration.
Q27) Calculate the amount of NaCl which must be added to one kg of water
so
that the F.P. of water is depressed by 3K.
(Kf = 1.86 Kkg /mol,Na =23, Cl=35.5)
Q4) State Raoults law for a solution of volatile liquids
Q19) A solution of urea in water has a b.p. of 373.128K.Calculate the F.P. of
the
Same solution.(Kf for water = 1.86K/m , Kb = 0.52 K/m)
Q1) Define an ideal solution.
2012 F
SOLUTION:
FORMULAE
Tb = Kb. wB .1000
MB .wA
Tf = Kf. wB .1000
MB .wA
.V=
wB . R T
MB
= i
THE VALUE OF
NOT GIVEN
Kb * m
Kf * m
CRT
i
RAOULTS LAW:
FOR VOLATILE COMPONENT:
P1 = P01 *X1
P2 = P02 * X2
TOTAL V.P. OF SOLUTION
P = P1 + P2
EXPRESSION OF CONCENTRATION:
MOLE FRACTION
XA = nA/nA +nB
<
1 (ASSO)
>
(DISSO)
for KCl = 2
,for CH3COOH
DEGREE OF DISSOCIATION
=
i - 1 / n -1
DEGREE OF ASSOCIATION
=
i - 1 / 1/n -1
Question Bank
(Electrochemistry)
5 marks
2012D
Q28)(a) What type of battery is the lead storage battery ?Write the anode
and
cathode reaction and the overall reaction occurring in a lead storage
battery when current is drawn from it.
(b)In the button cell, widely used in watches, the following reaction
takes
place.
Zn +Ag2O + H2O Zn2+ + 2Ag + 2OHDetermine E0 and G0 for the reaction
(E0 Ag+/Ag = +0.80V , E0 Zn2+ /Zn = -0.76 V)
Q28)(a) Define molar conductivity of a solution and explain how molar
conductivity changes with change in concentration of a solution for
a
weak and a strong electrolyte.
(b)The resistance of a conductivity cell containing0.001M KCl solution
at
298 K is 1500.What is the cell constant if the conductivity of
0.001M KCl
Solution at 298 K is 0.146 x 10 -3 Scm-1?
2012F
Q28) (a) What type of battery is the lead storage battery ?Write the anode
and
cathode reaction and the overall reaction occurring in a lead storage
battery when current is drawn from it.
(b) A voltaic cell is set up at 250C with the Half cells
Ag+ (0.001M)/Ag and Cu2+(0.1M)/Cu
What should be its cell potential?(E0cell = 0.46V)
Q28) (a) Define molar conductivity of a solution and explain how molar
conductivity changes with change in concentration of a solution for
a
weak and a strong electrolyte.
(b)A strip of nickel metal is placed in a 1 molar solution of Ni(NO3)2
and a strip of silver metal is placed in a 1 molar solution of
AgNO3.Anelectrochemical cell is created when the two solutions are
connected by a salt bridge and the two strips are connected by wires
to volt meter.
(i) Write the balanced equation for the overall reaction occurring in
the cell and calculate the cell potential.
(ii)Calculate the cell potential,E at 250C for the cell, if the initial
concentration of Ni(NO3)2 is 0.1 molar and the initial concentration of
AgNO3 is 1 molar.
(E0 Ag+/Ag = +0.80V , E0 Ni2+/Ni = - 0.25V)
2013 AI
Q11) the standard electrode potential (E0) for Daniell cell is +1.1 V. Calculate
the
G 0 for the reaction
Zn(s) + Cu 2+ Zn2+ + Cu(s)
( 1F = 96500 C mol-1)
Q26 ) Calculate emf of the following cell at 25 0C
Ag(s) /Ag + (10 -3M)// Cu 2+ (10 -1 M)/Cu (s)
(Given E 0 Cell= + 0.46 V and log 10 n = n
Formulae
ELECTROCHEMISTRY:
NERNST EQUATION FOR HALF CELL:
E = E0 2.303RT log 1
nF
[Mn+]
E = E0 0.059
nF
log 1
[Mn+]
= E0cathde - E0 anode
Zn Zn
Cu
2+
Zn / Zn
2+
// Cu
2+
/ Cu
R
+ 2e
2+
+ 2e Cu
Ecell = E0cell 2.303RT log [Zn2+]
2F
[Cu2+]
2+
Zn + Cu
Mg Mg
Cr
2+
Mg / Mg
2+
2+
Zn + Cu
// Cr3+ / Cr
R
+ 2e
3+
+ 3e Cr
Ecell = E0cell 2.303RT log [Mg2+] 3
6F
[Cr3+]
3+
3Mg2++2Cr
3Mg + 2Cr
Pt /Br2 /Br- // H+ / H2 / Pt
- Br2 + 2e
2 Br
P
2H + 2e H2
Ecell = E0cell 2.303RT log 1
Br2 + H2
2F
[Br - ] [H+]2
2 Br- + 2H+
Pt / I2 / I- // Cl - / Cl2 / Pt
2I
I2 + 2e
Cl2 + 2e 2Cl
I2 + 2Cl
[I - ]2
2F
EQUILIBRIUM CONSTANT Kc
E0cell x nF
2.303RT
m = K x 1000 / C
CELL CONSTANT = l /A
KOHLRAUSCH LAW:
=-nFE
cell
Al2(SO4)3 = 2 0 Al
CH3COOH =
3+
+ 3 0 SO4
2-
DEGREE OF DISSOCIATION:
= /
K = C 2 / (1 )
FARADAYS LAW
ELECTRIC CHARGE REQUIRED IN F = 1F FOR Na+ , 2 F FOR Ca2+
R
2I - + Cl2
MnO4 - Mn
2+
NEEDS 5 F .
Q=I*t
Question Bank
(Chemical Kinetics)
5 marks
(ii) Derive the relation between half life of a first order reaction & its rate
const.
2008 D
Q2) Define the term order of reaction for chemical reaction
[N2O5] mol/L
1
1.13 x10-2
2
0.84 x10-2
3
0.62 x10-2
Determine (i) order of reaction
Rate of disappearance of
N2O5(mol/L/min)
34 x 10-5
25 x 10-5
18 x 10-5
(ii)rate const.
(iii) rate law
2009 AI
Q10) Define (a) elementary step in a reaction
( b) rate of reaction
Q19) A first order reaction has a rate const. of 0.0051 min-1 If we begin with
0.10 M concentration of reactant.What concentration of reactant will
be
left over after 3 hours
Q20) For a decomposition reaction the values of rate const. k at two different
temp. are given below
K1 = 2.15 x 10-8 L /mol/s at 650K
K2= 2.39 x 10-7 L/mol/s at 700K
Calculate Ea for this reaction (R = 8.314J/mol/K)
Q14) Define activation energy of a reaction and order of reaction
2009 D
Q9) A reaction is second order w.r.t. A How is the rate of this reaction altered
if
the concentration of A is (i) doubled (ii) reduced to half
2009 F
All Questions are repeated
2009 D COMPTT
Q4) Why does the rate of a reaction not remain const. throughout the
reaction
Process
Q16) Explain the term order of a reaction.Derive the unit for first order rate
const.
Q17) Show that for a first order reaction,the time required for half life period
is
independent f initial concentration.
2010 AI
Q28) (a) Explain the terms: (i) Rate of reaction (ii) Activation energy of a
reaction
(b) The decomposition of PH 3 proceeds according to the following
equation.
4PH3 P4 + 6H2 It is found that the reaction follows the following
rate
equation Rate = k [PH3] The half life of PH3 is 39.9 s at120 0C
(i) How much time is required for 3/4th of PH3 to decompose?
(ii) What fraction of the original sampeof PH3 remain behind after one
minute.
Q28) (a) Explain the terms: (i) Order of reaction (ii) molecularity of a reaction
( b) The rate of reaction increases four times when the temperature
changes from 300K to 320 K Calculate Ea ,assuming that it does
not change with temperature . ( R = 8.314J/K/mol)
2010 D
Q2) Define order of reaction
Q10) A reaction is of first order in reactant A and second order in reactant
B.How is the rate of this reaction affected when (i) [B] alone is
increased to
three times (ii) [A] as well as [B] are doubled.
0.4
0
0.289
20
0.209
40
0.151
60
0.109
80
(a) Calculate the rate constant. Include units with your answer.
(b)What will be the concentration of N2O5 after 100 min.
(c) Calculate the initial rate of reaction.
2011F
Q28) Repeated questions
Q28) Repeated questions
2010 D COMPTT
Q4) Why does rate of reaction not remain constant throughout the reaction
Process?
Q16)Explain the term order of reaction Derive the unit for first order rate
constant.
Q17)Show that for the first order reaction the time required for half life period
is
independent of initial concentration.
2010 AI COMPTT
Q28) (a) Explain difference between the average rate and instantaneous rate
of
Reaction.
(b ) In pseudo first order hydrolysis of ester in water, the following results are
obtained.
T in seconds
[Ester] M
0
0.55
30
0.31
60
0.17
90
0.085
(i)
Initial [NO](M)
1
2
3
4
Initial
rate
of
disappearance of
Cl2 (M/min)
0.60
1.20
2.40
?
0.15
0.15
0.15
0.30
0.30
0.15
0.25
0.25
(a) Write the expression for rate law.
(b)Calculate the value of rate constant and specify its units.
(c) What is the initial rate of disappearance of Cl2 in expt.4?
2012F
Q10) Define the following terms:
(i)
Order of reaction
(ii)
Activation energy of a reaction
Q21) Consider the reaction 2A + B C+ D
Following results were obtained in experiments designed to study the
rate
of reaction .
Expt. No.
Initial
rate
formation
of
[A]
[B]
[D] (M/min)
1
0.1
0.1
1.5 x 10 -3
2
0.2
0.2
3.0 x 10-3
3
0.2
0.4
6.0 x 10 -3
(a) Write the rate law for the reaction
(b)Calculate the value of rate constant for the reaction.
(c) Which of the following possible reaction mechanism is consistent with
the rate law found in (a)?
(i)
A + B C + E (slow)
A + E D (fast)
(ii)
B C + E (slow)
A + E F (fast)
A + F D (fast)
2013 AI
Q12) (a) For a reaction A + B P , the rate law is
given by,
R = k [A]1/2[B]2
What is the order of this reaction?
( b ) A first order reaction is found to have a rate constant k=5.5 x 10
-14 -1
s Find the half life of the reaction.
Q19) The rate of reaction becomes four times when the temperature changes
from293 K to 313 K.Calculatethe energy of activation (Ea) of thereaction
assuming that it does not change with temperature.
[R = 8.314 J K -1, log4 = 0.6021]
FORMULAE:
i.
ii.
iii.
iv.
v.
Rate Expression:
rav = - [R] / t = + [P] / t
r ins = - d[R] / t = + d [P] / t
RATE = - [R] / t = + [P] / t
Unit of k = mol/l/s
Unit of k = /s
-1
Ea/RT
Question Bank
(Surface Chemistry)
4 marks
Q21) What are lyophilic & lyophobic sols? Give one example of each type
which
one of these two types of sols is easily coagulated & why?
Q3) Which
has a higher enthalpy of
adsorption,physisorption or
chemisorption?
Q22) What is observed when (i) an electrolye KCl is added to hydrated ferric
oxide sol.
(ii)an electric current is passed through a colloidal solution
(iii)a beam of strong light is passed through a colloidal solution
2008 AI
Q21) Differntiate between multimolecular & macromolecular colloids? Give
one
example of each. How are these two types of colloids different from
associated colloids.
Q3) Define electrophoresis briefly.
2008 .F
All question repeated
2008 D COMPTT
Q2)Why does physisorption decrease withincrease in temp.?
Q22) What is observed when (i) a beam of light is passed through colloidal
Solution (ii)An elctrolyte NaCl is added to hydrated Fe2O3 sol
(iii) An electric current is passed through a colloidal solution
Q7) In chemisorption why x/m initially increases& then decreases with rise in
temp.
Q24) (a)What is the difference between a colloidal solution & an emulsion?
Give
one example of each
(b) What are emulsifiers?
2008 AI COMPTT
Q3) How does adsorption of a gas on a solid surface vary with increase in
Pressure?
Q20) Explain with example: (a) Peptization (ii) gel (iii) dialysis
Q11) Distinguish between homogeneous & heterogeneous catalysis?What
role
does adsorption play in heterogeneous catalysis?
Q12) Distinguish between micelles & colloidal particles. Give one example
of
each.
2009 AI
Q2) What is the coagulation process?
Q22)What happens in the following activities & why?
(i)
An electrolyte is added to a hydrate ferric oxide sol in water
(ii)
A beam of light is passed through a colloidal solution
(iii) An electric current is passed through a colloidal solution
2009 D
Q2) Define the term Tyndall effect.
Q22)How are the following colloids different from each other with respect of
dispersion medium & dispersed phase?Give one example of each type
(i)
an aerosol (ii) a hydrosol (iii) an emulsion
Q21) Differntiate between multimolecular & macromolecular colloids? Give
one
example of each. How are these two types of colloids different from
associated colloids.
2009 F
Q21) Write three special features of chemisorption which are not found in
physisorption.
2009 D COMPTT
Q3) Name two types of adsorption phenomenon
Q18) How are associated colloids different frommacro molecular colloids?
Give
one example of each type.
Q1) What is the sign of H & S when a gas is adsorbed by an adsorbent?
Q9) What are emulsions? State one application of emulsification
Q14) What is the difference between a colloidal solution & emulsion? What is
the
role of emulsifier in forming emulsion
2010 AI
Q12) Describe the following:
(i) Tyndall effect (ii) Shape selective catalysis
Q13) What is meant by coagulation of a colloidal solution? Name any method
by
which the coagulation of lyophobic sol can be carried out.
Q13) Define the following terms:
(i) Peptization (ii) Reversible sol
2010 D
Q3) What is an emulsion?
Q21) Differntiate between multimolecular & macromolecular colloids? Give
one
example of each. How are these two types of colloids different from
associated colloids.
Q3) Give an example of shape selective catalyst.
Q20) How are the following colloids different from each other in respect of
their
dispersion medium and dispersion phase?Give one example of each
(i)
aerosol (ii) emulsion (iii) hydrosol
2010 F
Q21)State what is observed when (i) an electrolyte NaCl is added to hydrated
ferric oxide sol (ii) an electric current is passed through a colloidal
solution
( iii )a beam of light is passed through colloidal solution
Q21) Write three features of chemisorptions which is not found in
physisorption.Illustrate your answer with suitable example.
NEW SAMPLE PAPER I
Q4) Which of the following is most effective electrolyte in coagulation of
Fe2O3.H2O/Fe3+ sol
KCl,AlCl3,MgCl2,K4[Fe(CN)6]
Q20)Give reasons for the following observations:
(a) Peptizing agent is added to convert ppt into colloidal solution
(b)Cottrells smoke precipitator is fitted at the mouth of chimney used in
factories
(c) Colloidal gold is used for intramuscular injection
(i)
Electrophoresis
(ii)
Coagulation
(iii) Tyndall effect
Q6) Distinguish between physisorption and chemisorptions.
Q25) What is an adsorption isotherm? Describe Freundlich adsorption
isotherm.
Q3) Why is adsorption always exothermic?
Q22) Discuss the effect of pressure and temperature on adsorption of gases
on
solids.Describe the application adsorption in controlling humidity.
2012 AI
Q22) explain the following terms giving suitable example for each:
(i)
Aerosol
(ii)
Emulsion
(iii) Micelle
Q22) write three distinct features of chemisorptions which are not found in
physisorptions.
2012 D
Q11) Name the two groups into which phenomenon of catalysis can be
divided. Give an example of each group with the chemical equation
involved.
Q12) What is meant by coagulation of a colloidal solution? Describe briefly
any
three methods by which coagulation of lyophobic sols can be carried
out.
Q11) Describe a conspicuous change observed when
(a) A solution of NaCl is added to a sol of hydrated ferric oxide.
(b)A beam of light is passed through a solution of NaCl and then through a
sol
Q12) Explain the following terms giving one example of each:
(i)
Micelles
(ii)
Aerosol.
2012 F
Q2)Why is the adsorption phenomenon always exothermic?
Q22) Define the following terms giving one suitable example for each:
(i)
Electrophoresis
(ii)
Micelles
(iii) Peptization
Q2) What is meant by shape selective catalysis?
Q22) Differentiate among a homogeneous solution, a suspension and a
colloidal
solution, giving a suitable example of each.
Q22)Present a classification of colloids where dispersion medium is
water.State
the chatacteristics and one example of each of these classes.
2013 AI
Q1) Of physisorption or chemisorptions , which has a higher enthalpy of
formation?
Q20) What are the characteristics of the following colloids? Give one example
of each.
(i)
Multimolecular colloids
(ii)
Lyophobic sols
(iii) Emulsions
Q19) define the following terms giving an example of each:
(i)
Associated colloids
(ii)
Lyophilic sol
(iii) Adsorption
Q1) what is especially observed when a beam of light is passed through
colloidal solution
Q19) define the following terms giving an example of each:
(i)
Macromolecular sol
(ii)
Peptization
(iii) Emulsion
Question Bank
(General Principles & Processes of Isolation of Elements)
3
marks
SAMPLE PAPER- 1 (OLD)
Q22) Account for (a) the reduction of metalic oxide is easier if the metal
formed
is in liquid state at the temp. of reduction.
(b)the reduction of Cr2O3 with Al is thermodynamically feasible,yet it
does not occur at room temp.
(c) Pine oil is used in froth floatation method
SAMPLE PAPER- 2 (OLD)
Q1) An ore of sample Galena is contaminated with Zinc Blende.Name one
chemical which is used to concentrate galena selectively by froth
floatation
method
Q11) Gf for MgO & CO at 1273K & 2273K are given
Gf [MgO] = -941KJ/molat 1273K & Gf [CO]= - 439KJ/mol
Gf [MgO] = -314 KJ/molat 2273K & Gf [CO]= - 628 KJ/mol
Predict the temp. at which C can be used as a reducing agent for MgO(s).
SAMPLE PAPER- 3 (OLD)
Q21) (a) Name the method used for refining of (i) Ni (ii) Zr
(b) The extraction of gold by leaching with NaCN involves both Oxidation
&
Reduction. Justify giving equation
2008 D
Q22) State briefly the principles which serves as basis for the following
operations in metallurgy
(I)Froth floatation process
(ii)Zone refining
(iii )Refining by liquation
Q21) Explain the basic principles
(i)
Vapour phase reefing
(ii)
Electrolytic refining
(iii) Zone refining
2008 AI
Q22) What chemical principle is involved in choosing a R.A. for getting the
metal from its oxide ore? Consider the metallic oxide,Al2O3 & Fe2O3 &
Justify the choice of R.A. in each case
2008 F
Q23) Describe the role of (a) Depressant in Froth floatation process.
(b) silica in the extraction of Cu from copper pyrite ore
2013AI
Q2) Name the method used for refining of copper metal.
Q13) (a) Name the method used for removing gangue from sulphide ores.
( b) How is wrought iron different from steel?
Question Bank
(The p-Block Elements)
8 marks
added into this T.T. On cooling the gas A changed into a colourless gas
B
(i) Identify the gases A& B
(ii) Write the equations for the reactions involved.
Q16) (a) Why does Cl2 water lose its yellow colour on standing
( b)What happens when Cl2 water reacts with cold dil soln. of
NaOH. Write equation only
Q22) Write down the equations for hydrolysis of XeF4 & XeF6.Which of these
two
reactions is a redox reaction.
2008 D
Q4) In which one of the two structures NO 2+ & NO2-, the bond angle has a
higher
value?
Q16) Reasons: (i) NH3 is stronger base than PH3
(ii) S in vapour state exhibits a paramagnetic behaviour
Q17) Draw structures of (i) SF4 (ii) XeF4
Q23) Write equations (i) Cl2 reacts with hot conc. soln. of NaOH
(ii)orthophosphorous acid is heated
(iii)PtF6 & Xe are mixed together
Q23) Complete the equation: (i) Ca3P2 + H2O
(ii) Cu2+ + NH3 (aq) (excess)
(iii) F2 (g) + H2O (l)
(iv)XeF4 + H2O
(v)O3 + I- + H2O
2008 AI
Q4) Why is the bond angle in PH3 molecule lesser than that in NH3 molecule
Q12) (i) which neutral molecule would be isoelectronic with ClO(ii)Of Bi (V) & Sb(V) which may be stronger O.A.& why?
Q29) Reasons: (i) S in vapour state exhibits a paramagnetic behaviour
(ii) NH3 has greater affinity for protons than PH3
(iii) The ve value of electron gain enthalpy of F is less than
that of Cl
(iv)SF6 is much less reactive than SF4
(v)Of the noble gases only Xe is known to form well established
chemical compounds.
Q29) (a) Describe the favourable conditions for the manufacture of
(i) NH3 by Habers process
(ii) H2SO4 by Contact process
( b ) Draw the structures of (i) PCl5 (ii) S8 (iii) ClF3
Q4) Which is a stronger acid in aq. Soln. of HF or HCl
Q12) Reasons(i) P shows marked tendency for catenation but N shows little
tendency for catenation
( ii )The electron gain enthalpy with ve sign for O (-141 KJ/mol) is
less
than that for S(-200KJ/mol)
Q30) ( a) complete (repeated)
( b )Draw structures of (i) H2S2O7(ii) NO3Q30) (a)Reasons: (i) P4 is more reactive than N2
(ii) All bonds in PCl5 are not equal in length.
(iii) S in vapour state exhibits a paramagnetic behaviour
(c) Draw the structures of (i) BrF3 (ii) XeF2
2008 F
Q4)Which is stronger acid in aq.soln. HCl or HI?
Q29) ( a )Complete : (repeated)
O3 + I- + H2O
( b )Draw the structures of (i) XeF4 (ii) H2S2O7
( c ) Draw the structures of (i) HClO4 (ii)BrF3
2008 D COMPTT
Q3) N does not form any pentahalide like P why?
Q11) Reasons:(i) O2 molecule has formula O2 while S has S8
(ii)
H2S is less acidic than H2Te
Q29) (a) Arrange HClO,HClO2,HClO3,HClO4 in order of acidic strength. Give
reason.
(b)Write equation for Cl2 water reacts with conc. soln. of NaOH Justify
that
this is a disproportionation reaction.
(c) Give one use of ClF3
Q29) (a) Why do some noble gases form compounds with F & O only.
(b) How are the following compounds prepared fro XeF6
(i) XeOF4 (ii)XeO3
(c) Draw structure of BrF3
Q3) Why is N2 very unreactive as compared to P4
Q4) When HCl reacts with finely powdered iron it forms FeCl 2 & not FeCl3
why?
Q22) (a) How are interhalogen compounds formulated & how are they
prepared?
(b) which neutral molecule would be isoelectronic with ClOQ23) (a) How does Xe atom forms compounds even though the Xe atom has
a
closed shell electronic configuration
(b) Draw structures of XeOF4
(c) Complete XeF4 + H2O
2008 AI COMPTT
Q5) F exhibits only 1 oxidation state in its compound whereas other
halogens
exhibit many other oxidation state why?
Q24) (i) Draw structure of SO2 molecule .Comment.
On the nature of two S-O bonds formed in it Are the two S-O bonds in
this
molecule equal?
( ii ) What happens when white P is heated with conc. NaOH soln.in an
inert
gas atmosphere.
Q1) Why are halogens mostly coloured?
Q20) (i) Why is BiH3 the strongest R.A. among all the hydrides of gr 15
elements.
(ii) H2O is liquid while H2S is a gas why?
(iii) Why is Ka2<<Ka1 for H2SO4 in water
2009 AI
Q4) Why is red P less reactive than white P
Q12) Complete (i) XeF2 + H2O
(ii) PH3 + HgCl2
Q29) (a)Draw structures of (i) H2S2O8(ii) HClO4
(b) How would you account for the following :
(i) NH3 is stronger base than PH3
(ii) F2 is a stronger O.A. than Cl2
(iii)S shows greater tendency for catenation than O.
Q29) (a)Draw structures of (i) H2S2O7(ii) HClO3
(b) How would you account for the following :
(i)
In the structure of HNO3 the N-O bond (121pm) is shorter than N-OH
bond (140pm)
(ii)
All P-Cl bonds in PCl5 are not equivalent.
(iii) ICl is more reactive than I2
Q29)(a)Draw structures of (i) H3PO2(ii) BrF3
(b) How would you account for the following :
(i)
No chemical compound of He is known
(ii)
Bond dissociation energy of F2 is less than that of Cl2
(iii) P shows greater tendency for catenation than N.
Q30) (a)Draw structures of (i) H2S2O7(ii) XeF4
(b) How would you account for the following :
(i) The ve value of electron gain enthalpy is less for F than that for Cl
(ii) F2 is a stronger O.A. than Cl2
(iii)HF has a much higher b.p. than HCl
2009 D
Q21)(i)Why is Bi(V) stronger O.A. than Sb(V)
(ii)Complete : P4 + NaOH + H2O
O3 + I- + H2O
(iii)Draw structure of XeF4 , BrF3
Q23) Reasons:
(i)
NH3 is stronger base than PH3
(ii)S shows greater tendency for catenation than O.
(iii)Bond dissociation energy of F2 is less than that of Cl2
(iv) In the structure of HNO3 the N-O bond (121pm) is shorter than N-OH
bond (140pm)
(v) SF4 is easily hydrolysed wheras SF6 is not
(vi)XeF2 has a linear sructure & not a bent angular structure
Q24) Explain :
(i)
F does not exhibit any +ve oxidation state
(ii)
The majority of known noble gas compounds are those of Xe
(iii) P is much more reactive than N
2009 F
Q29) (a) Complete (i) XeF2 + PF5
(ii)Cl2 + NaOH (hot& conc.)
(b) Explain(i) S in vap. State exhibit paramagnetism
(ii)+3 oxidation state becomes more & more stable from As
to Bi in
the group
Q29) Complete (i)PCl5 + H2O (excess)
(ii) F2 + H2O
Reasons: (i) No chemical compound of He is known
(ii)In soln of H2SO4 in water Ka2 is less than Ka1
(iii)P shows greater tendency for catenation than N.
Q30) Complete (i) SO2 + MnO4- + H2O
(ii) HgCl2+ PH3
Explain (i) S shows greater tendency for catenation than O.
(ii) F is stronger O.A. than Cl
(iii)The + 5 oxidation state becomes less stable down the group in
gr.15 of
the Periodic Table.
Q30) (i) Complete (a) : P4 + NaOH + H2O
(b) Cu + HNO3 (dil)
(ii) Explain (a) H2O is liquid while H2S is a gas
(b) Fe dissolves in HCl to form FeCl2 & not FeCl3
(ii)
Q12) draw structure and predict the shape of (i) H3PO3 (ii) XeOF4
Q22) suggest the possible reason for the following observations:
(i)
In the solid state , PCl5 behaves as an ionic species.
(ii)
H2S is more acidic than water
(iii) Fluorine forms the largest number of interhalogen compounds
amongst the halogens.
Q17) draw the structure and predict the shape of (i) XeO3 (ii) BrF3
Q26) give reasons for the following:
(i)
N2 is not particularly reactive
(ii)
Halogens are strong oxidizing agents
(iii) SF6 is less reactive thanSF4
2010 AI COMPTT:
Q5) what is the covalence of nitrogen in N2O5?
Q6) why are the two S O bonds in SO2 molecule of equal strength?
Q22) answer the following:
(a) Complete the equation XeF6 + H2O (excess)
(b)What happens when H3PO3 is heated?
(c) Why is ICl more reactive than I2?
Q23) account for the following:
(i)
Halogens are coloured
(ii)
Nitrogen shows weaker tendency for catenation than phosphorus
(iii) H2S is less acidic than H2Te
Q4) why are pentahalides of metals more covalent than its trihalides?
Q23) account for the following:
(i)
Halogensare strong oxidizing agents.
(ii)
NH3 is clearly basic while PH3 is feebly basic.
(iii) Oxygen is involved in hydrogen bondingwhile chlorine is not.
Q1) why is BiH3 the strongest reducing agent amongst the hydrides of group
15
elements?
Q20) account for the following:
(i)
Unlike other halogens , fluorine forms only one oxoacid ,HOF
(ii)
Nitrogen exist as a diatomic molecule whereas phosphorus exist as
P4
(iii) the two S O bonds in SO2 molecule are equal .
2012 AI
Q4) which is stronger reducing agent , SbH3 or BiH3, and why?
Q12) explain the following facts giving appropriate reason in each case:
(i)
NF3 is an exothermic compound whereas NCl3 is not.
(ii)
All the bonds in SF4 are not equivalent.
Q29) (a) Draw the molecular structures of the following compounds:
(i)
N2O5
(ii)
XeOF4
(b) explain the following observations:
(i) sulphur has a greater tendency for catenation than oxygen.
(ii) ICl is more reactive than I2.
(iii) Despite lower value of its electron gain enthalpy with negative
sign,F2 is a stronger oxidizing agent than Cl2.
Q29)(a) complete the following observations:
(i)
Cu + HNO3 (dilute)
(ii)
XeF4 + O2F2
(b) explain the following observations:
(i) phosphorus has a greater tendency for catenation than nitrogen.
(ii) oxygen is a gas but sulphur is a solid
(iii) The halogens are coloured. Why?
Q30) (a) Draw the molecular structures of the following compounds:
(i)
H3PO2
(ii)
ClF3
(b) explain the following observations:
(i) nitrogen is much less reactive than phosphorus.
(ii) despite having greater polarity,HF boils at a lower temperature than
water.
(iii) sulphur has a greater tendency for catenation than oxygen in the
same group.
Q30) (a) Draw the molecular structures of the following compounds:
(i)
N2O5
(ii)
HClO4
(b) explain the following observations:
(i) H2S is more acidic than H2O.
(ii) Fluorine does not exhibit any positive oxidation state.
(iii) Helium forms no real chemical compound.
Q4) what is the basicity of H3PO2 acid and why?
2012 D
Q3) Which one of PCl4 + and PCl4 is not likely to exist and why?
Q14) Explain the following giving an appropriate reason in each case.
(i)
O2 and F2 both stabilize higher oxidation states of metals but O2
exceeds F2 in doing so.
(ii)
Structures of Xenon fluorides can not be explained by Valence Bond
approach.
Q29) (a) Complete the following chemical reaction equations:
(i)
P4 + SO2Cl2
(ii)
XeF6 + H2O
(b) Predict the shape and angle(90 0 or more or less) in each of the
following cases:
(i) SO32- and the angle O-S-O
(ii) ClF3 and the angle F-Cl-F
(iii) XeF2 and the angle F- Xe F
Q29) (a) Complete the following chemical equation:
(i)
NaOH + Cl2
(hot and conc.)
(ii)
XeF4 + O2F2
(b) Drawthe structures of the following molecules:
(i) H3PO2
(ii) H2S2O7
(iii) XeOF4
Q3) Of PH3 and H2S which is more acidic and why?
Q30)(a) Draw molecular structures of following compounds:
(i)
XeF6
(ii)
H2S2O8
(b) Explain the following observations:
(i) The molecules NH3 and NF3 have dipole moments which are of
opposite direction.
(ii) All the bonds in PCl5 molecules are not equivalent.
(iii) S in vapour state exhibits paramagnetism.
Q30) (a) Complete the following chemical equations:
(i)
XeF4 + SbF5
(ii)
Cl2 + F2 (excess)
(b) Explain each of the following:
(i)Nitrogen is much less reactive than phosphorus
(ii) The stability of +5 oxidation state decreases down group 15
(iii) The bond angles (O-N-O) are not of the same value in NO2- and NO2+
(iii)
Question Bank
(The d & f Block elements)
5 marks
SAMPLE PAPER- 1 (OLD)
Q14) A mixed oxide of Fe & Cr,Cr 2O3 is fused with Na2CO3 in the presence of
air to
form a yellow compound (A), On acidification the compound (A) forms
an
orange coloured compound (B) which is strong O.A. Identify ( i ) the
compounds (A) & (B)(ii)Write balanced equation for each step.
Q23) Explain (a) Transition metals act as catalyst
(b) Cr group elements have highest m.p. in their respective
series.
(c ) Transition metals form coloured complexes
SAMPLE PAPER- 2 (OLD)
Q30) (a)A blackish brown coloured solid A when fused with alkali metal
hydroxide in presence of air produces a dark green coloured compound B
which on electrolytic oxidation in alkaline medium gives a dark purple
compound C.Identify A,B,C& write the reactions involved.
(b) What happens when an acidic solution of green compound B is
allowed to stand for sometime?
Give the equation involved What is this type of reaction called?
Q30) Reasons: (a) T.E. have high enthalpy of atomization
(b) Among the lanthanoids,Ce(III) is easily oxidized to Ce(IV)
(c ) Fe 3+ /Fe 2+ redox couple has less +ve electrode potential than
Mn 3+ / Mn 2+ couple
(d)Cu (I) has d10 configuration while Cu (II) has d 9 configuration ,still
Cu (II)
is more stable in aq. solution than Cu (I).
(e)The second & third transition series elements have almost similar
atomic radii.
SAMPLE PAPER- 3 (OLD)
Q29) (a) Out of Ag2SO4,CuF2,MgF2& CuCl. Which compound will be coloured &
why?
(b) Explain: (i) CrO4 2- is strong O.A.while MnO42- not.
(ii) Zr & Hf have identical sizes
(iii)The lowest oxidation state of Mn is basic while the highest is
acidic
(iv)Mn (II) shows maximum paramagnetic character amongst the
divalent ions of the first transition series.
Q29) (a) In the titration of FeSO4 withKMnO4 in the acidic medium,why is dil.
H2SO4used instead of HCl?
( b) Reasons: (i) Among transition metals the highest oxidation state is
exhibited in oxoanions of a metal
(ii)T.E. form a no. of interstitial compounds.
(iii)Zn2+ salts are white while Cu2+ salts are blue
(iv)Ce4+ is used as an O.A. in volumetric analysis
2008 D
Q29)Reasons: (i) T.E. & many of their compounds act as a good catalyst.
(ii)Actinoid contraction is greater than lanthanoid contraction
3+
/ Mn
2+
Cr 3+ / Cr 2+.
(iv)Sc(21) does not exhibit variable oxidation state & yet it is
regarded
as a T.E.
(v) With d4 configuration , Cr2+ act as a R.A. but Mn3+ acts as an
O.A.
Q29)(a) What may be the possible oxidation state of T.E. with the following d
electronic configuration in the ground state of their atoms
3d34S2,3d54S2& 3d64S2.Indicate relative stability of oxidation state in
each
case.
(b) Write the steps involved in the preparation of (i)Na 2CrO4 from chromite
ore
(ii) K2MnO4 from pyrolusite ore
2008 AI
Q13) Complete the equations(i) oxidation of Fe2+ by Cr2O72-in acidic medium
(ii) oxidation of S2O32- by MnO4- in neutral aq. medium
Q23) Reason: (i) The T.E.generally form coloured compounds (ii) With 3d4
configuration,Cr2+ act as a R.A.but Mn3+ act as an O.A. (at. Mass
Cr=24,
Mn=25) (iii )The actinoids exhibit a larger no. of oxidation state than
the
corresponding lanthanoids.
2008 F
Q13) Compare the relative stability of +2 oxidation state in aq. Solution for
the
metals having their atoms the outer configuration 3d 34S2,3d54S2&
3d64S2
Q23) (a) Complete (i) Cr2O72- + H+ + Fe2+
(ii)MnO4- + I- + H+
(b) How many unpaired electrons are present in Mn 2+ ion?How does it
influence mag.behaviourof Mn2+ ions?
2008 D COMPTT
Q12) Reasons(i)There are irregularities in the e.c. of actinoids.
(ii)
Compounds of T.E. are often coloured
Q24) (a) Describe the commercial preparation of KmnO4 from pyrolusite
ore.
( b ) Write ionic equation to represent the reaction of acidified KmnO4
solution with oxalic acid.
Q15)Reasons: (a) T.E. are well known to form complex compounds ( b )The
second & third members in Each group of T.E. have very similar at.
Radii
Q12) Reasons: Why do d block elements generally exhibit large no. of
oxidation
states than those exhibited by the f block elements
2008 AI COMPTT
Q29) Reasons: (i) The actinoids exhibit a larger no. of oxidation state as
compared to Lanthanoids in general.
( ii) Though a T.E. (Sc=21) does not exhibit variable oxidation state.
( b) (i) Describe how K2Cr2O7 is prepared from chromate
2-
<
(ii)
( b) Explain the following:
(i)
La 3+ (57) and Lu 3+ (71) do not show any colour in solution
(ii)
Among the divalent cations in the first series of T.E. , Mn exhibits
the maximum paramagnetism.
(iii) Cu + is not known in aqueous solution.
2010 D
Q13) Explain
(i)
Generally there is increase in density of elements from Ti-22 to Cu29 in the first series of T.E.
(ii)
T.E. and their compounds are generally found to be good catalysts in
chemical reaction.
Q23) How would you account for the following
(i)
The at. Radii of elements of the 5 d series of T.E. arevirtually the
same as those of the corresponding members of 4 d series.
(ii)
E0 value for Mn3+/Mn2+ couple is much more +ve than for
Cr3+/Cr2+ or Fe3+/Fe2+ couple
(iii) The highest oxidation state of ametal is exhibited in its oxide or
fluoride
Q13) Explain:
(i)
The T.E. generally form coloured compounds
(ii)
Zn is not regarded as a T.E.
2010 F
Q13)Describe preparation of
(i)
K2Cr2O7 from Na2CrO4
(ii)
KMnO4 from K2MnO4
Q22)Explain:
(i)
The enthalpy of atomization of transition metals are quite high
(ii)
There is close similarity in physical and chemical property of 4d and
5 d series of the T.E. much more than expected on the basis of usual
family relationship.
(iii)The members in the actinoid series exhibit large no. of oxidation state
than the corresponding member in the lanthanoid series.
Q22) Explain:
(i)
The T.E. have great tendencyfor complex formation
(ii)
There is a gradual decrease in the atomic size of T.E. in a series with
increasing at.no.
(iii)La and Lu do not show colouration in the solution.(at.no La = 57,Lu =
71)
(i)
(ii)
2011D
Q13)assign reason for the following:
(i)
Copper(I) ion is not known in aqueous solution
(ii)
Actinoids exhibit greater range of oxidation states than lanthanoids.
Q23) complete the following chemical equations:
(i)
Cr2O7 2- + H2S + H+
(ii)
KMnO4 (heated)
(iii) MnO4- + C2O42- + H+
Q13)assign reason for each of the following:
(i)
Transition metals generally form coloured compounds.
(ii)
Mn exhibits the highest oxidation state of +7 among the 3d series of
transition elements.
2011 F
Q29) (a) complete the following Reactions in aqueous medium:
(i)
Cr2O7 2- + H2S + H+
(ii)
MnO4- + C2O42- + H+
(b ) how would you account for the following:
(i)
Metal-metal bonding is more extensive in the 4d and 5d series of
transition elements than the 3d series.
(ii)
Mn(III) undergoes disproportionation reaction easily
(iii) Co(II) is easily oxidised in the presence of strong ligands.
Q29)(a) complete the following chemical equations:
(i)
Fe3+ + I -
(ii)
CrO42- + H+
(b ) explain the following:
(i)
Copper(I) ion is not known in aqueous solution
(ii)
With d4 configuration Cr(II) is reducing whereas Mn(III) is oxidizing
(iii) Transition metals in general act as good catalysts
2010D COMPTT
Q29)(a) give reasons for the following observations:
(i)
Copper(I) ion is not known in aqueous solution
(ii)
Mn(II) ion shows maximum paramagnetic character amonst the
bivalent ions of first transition series.
(iii) Sc(21) salts are white.
(b ) Describe the reactions involved in the preparation of K2Cr2O7 from
chromite ore
Q29) (a) Describe the following characteristics of the first series of the
transition metals and their trends in the series (Sc to Zn)
(i)
Atomic radii (ii) oxidation states (iii) ionization enthalpies
(c) Name the important alloy which contains some of the lanthanoid
metals. Mention its two uses.
2010 AI COMPTT:
Q29) (a) write the electronic configuration of Ce3+ion,and calculate the
magnetic moment on the basis of spin only formula.(Ce = 58)
(b) account for the following:
(i) the enthalpy of atomization of the transition metals are high.
(ii) the lowest oxide of a transition metal is basic, the highest is
amphoteric /acidic.
(ii)
3 marks
(ii)
Linkage isomerism
(iii) Ambidentate ligand
Q23) Compare the following complexes with respect to structural shapes of
units,magnetic behaviour
& hybrid orbitals involved in units [Co(NH3)6]3+ , [Cr(NH3)6]3+,Ni(CO)4
(Co=27,Cr=24,NI=28)
Q23) Explain (i) Low spin octahedral complexes of Ni are not known.
(ii) The complexes are known for transition elements only
(iii)CO is stronger ligand than NH3 for many metals.
Q23) Compare the following complexes with respect to structural shapes of
units,magnetic behaviour & hybrid orbitals involved in units
(i)
[Ni(CN)4]2(ii) [NiCl4]2- (iii) [CoF6]32009 D
Q23) For the complex [Fe(en)2Cl2]Cl Identify
a) Oxidation no. of Fe.
b) Hybrid orbitals & shape of complex
c) Magnetic behaviour of complex
d) No. of geometrical isomers
e) Whether there is an optical isomer also
f) Name of the complex
Q24) Compare the following complexes with respect to structural
shapes,magnetic behavior & hybridization (i) [CoF 4]2(ii)
[Cr(H2O)2(C2O4)]
(iii) [Fe(CN)6]42009 F
Q24) Three geometrical isomers are possible for [Co(en)(H 2O)2(NH3)2]3+. Draw
molecular structures of these three isomers & indicate which one of
them
is chiral
Q24) Compare with respect to molecular shape and magnetic behavior
(i)
[Cr(NH3)6]3+ (ii)[Fe(CN)6]4- (iii) [NiCl4]2Q24) Explain giving example
( i ) Linkage isomerism (ii) Outer orbital complex (iii) A bidentate ligand
2009 D COMPTT
Q24)(a) Square planar complexes of (MX2L2Type) with C.N. of 4 exhibit
geometrical isomerism whereas tetrahedral complexes with similar
composition do not why?
(b)Describe the type of structural shapes ,magnetic behaviour &
hybridization
of [Co(NH3)4Cl2]Cl (at.no of Co =27)
2010 AI
Q 22) Reasons :
(i) Ni does not form low spin octahedral complexes.
(ii) The complexes are known for the T.E. only.
(iii) Co 2+ is easily oxidized to Co 3+ in the presence of strong ligand.
Q25 ) Write the name , the state of hybridization , shape and the magnetic
behaviour of the following :
(i) [CoCl4] 2- , [Ni(CN)4] 2- ,[Cr(H2O)2 (C2O4)2 ]
(at. No. Co = 27 , Ni = 28 , Cr = 24)
2010 D
Q5)Give an example of linkage isomerism.
(v)
(vi)
2011 F
Q3)what do you understand by denticity of a ligand?
Q15) name the following coordination compounds and draw their structures:
(i)
[CoCl2(en)2]Cl
(ii)
[Pt(NH3)2Cl(NO2)]
(Co=27,Pt=78)
Q3) why is CO a stronger ligand than Cl- ?
Q17) draw the structures of isomers ,if any, and write the names of the
following
complexes:
(i)
[Cr(NH3)4Cl2]+
(ii)
[Co(en)3]3+
(Cr=24,Co=27)
Q3)name the following coordination compound:
K3[CrF6]
Q15) give the name ,the stereochemistry and the magnetic behavior of the
following complexes:
(i)
[Co(NH3)5Cl]Cl2
(ii)
K2[Ni(CN)4]
2010DCOMPTT
Q23)(a) square planar complexes(of MX2L2 type) with coordination number
of 4
exhibit geometrical isomerism whereas tetrahedral complexes with
similar
composition, do not. why?
(b)describe the type of hybridization,shape and magnetic property of
[Co(NH3)4Cl2]Cl
(Co=27)
2010AICOMPTT
Q24) write the IUPAC name and deduce the geometry and magnetic behavior
of the complex K4[Mn(CN)6]
(Mn=25)
2012 AI
Q24) name the following coordination entities and draw the structures of
their
stereo isomers:
(i)
[Co(en)2Cl2]+
(ii)
[Cr(C2O4)3]3(iii) [Co(NH3)3Cl3]
( atomic no. Cr = 24 , Co = 27)
Q24) name the following coordination entities and draw the structures :
(i)
[Fe(CN)6]4
(ii)
[Cr(NH3)4Cl2]+
(iii) [Ni(CN)4]2(atomic no. Fe = 26, Cr = 24, Ni = 28)
2012D
Q23) Give the formula of each of the following coordination entities.
(i)
Co3+ ion is bound to one Cl- , one NH3 molecule and two bidentate
ethylene diamine molecules
(ii)
Ni2+ ion is bound to two water molecules and two oxalate ions.
Write the name and magnetic behavior of each of the above
coordination entities.(at.no.Co=27,Ni=28)
Q22) State reasons for each of the following situations:
(i)
Co2+ is easily oxidized to Co3+ in presenceof strong ligand
(ii)
CO is a stronger complexing reagent than NH3
(iii) The molecular shape of Ni(CO)4 is not same as that of [Ni(CN)4]2Q23) write the name,the structure and the magnetic behavior of each one of
the
following complexes:
(i)
[Pt(NH3)2Cl(NO2)]
(ii)
[Co(NH3)4Cl2]Cl
(iii) [Ni(CO)4]
(at.no. Co=27,Ni=28,Pt=78)
2012F
Q24) Explain the following:
(i)
The complexes are known for transition elements only.
(ii)
Nickel(II) does not form low spin octahedral complexes.
(iii) [Fe(CN)6]4- and [Fe(H2O)6]2+ are of different colours in dilute
solutions.
Q24) Name the following complexes and draw the structures of one possible
isomer of each:
(i)
[Cr(C2O4)3]3(ii)
[Pt(NH3)2Cl2]
(iii) [Co(en)2Cl2]+
2013 AI
Q22) For the complex [NiCl4]2- , write
(i)
The IUPAC name.
(ii)
The hybridization type.
(iii) The shape of the complex
(Atomic no. of Ni =28)
Q22) what is meant by crystal field splitting energy? On the basis of crystal
field theory ,write the electronic configuration of d4 in terms of t2g and eg in
an octahedral field when
(i)
o > P
(ii)
o < P
Question Bank
(Haloalkanes & Haloarenes) 4 marks
IUPAC
Q1) IUPAC name of CH3CH=C(CH3)CH(Br)CH3
Q2) IUPAC name of CH3CH=C(CH3)CH2Br
Q3) IUPAC name of CH3C(CH3)=C(Br)CH2OH
Q4) IUPAC name of CH3CH=CHCH2Br
Q5) IUPAC name of
(i)
CH3CH2Br + NaI (dry acetone)
(ii)
C6H5N2Cl + Cu/HCl
(iii)Complete CH3CH2CH=CH2 + HBr (peroxide)
Q3) Complete the reaction: (i) C6H5N2Cl + KI
(ii) CH2=CH2 + Br2 (CCl4)
(i)
C6H11OH + SOCl2
Q4) Write the major product
(i)CH3CH=C(CH3)2 + HBr
(ii) C6H5ONa + C2H5Cl
Q5)Complete the reaction
CH3CH=CH2 + HBr (peroxide) X +NaI(acetone)Y
QUESTION
Q1) In each of the following pairs of organic compounds. Identify the
compound
which will undergo SN1 reaction faster? (a) (CH3)3Cl & CH3CH2CH(Cl)CH3
(a) C6H5Cl & C6H5CH2Cl
Q2) The treatment of an alkyl chloride with aq. KOH leads to the formation of
an
Alcohol whereas in the presence ofalc.KOH , alkene is the major product.
Q3) A solution of KOH hydrolyses CH3CHClCH2CH3 and CH3CH2CH2CH2Cl
Which will be hydrolysed easily?
Q4)(i) State one use of each DDT and Iodoform
(ii)
Which couple reacts faster in SN2 displacement and why?
(a)1-Bromopentane or 2-Bromopentane
(b) 1-Bromo-2-methyl butane or 2-Bromo-2-methyl butane
Q5) Explain:
(i)G.R. should be prepared under anhydrous condition.
(ii)C6H5CHClCH3 is hydrolysed more easily with KOH than
C6H5CH2Cl.
Q6)Arrange the following in the decrease order of reactivity towards SN2
displacement reaction and give reason in support of your answer.
(i) C2H5Br ,C2H5I ,C2H5Cl.
(ii)(CH3)3CBr ,CH3CH2CHBrCH3 , CH3CH2CH2CH2Br
Q7)Rearrange the compounds of each of following set in order of reactivity
towards SN2 displacement
(i)2-Bromo-2-methylbutane , 1-Bromopentane ,2-Bromopentane
(ii) 1-Bromo-3-methyl butane , 2-Bromo-2-methyl butane , 3-Bromo-2-methyl
Butane
(iii)1-Bromo butane ,1-Bromo-2,2-dimethyl propane ,1-Bromo-2-methyl
butane
NAME REACTIONS
DISTINGUISHING TEST
2011 D
Q5) write the IUPAC name of (CH3)3CCH2Br
Q25) answer the following:
(i)
Haloalkanes easily dissolve in organic solvent, why?
(ii)
What is known as a racemic mixture? give an example.
(iii) Of the two bromoderivatives,C6H5CH(CH3)Br and C6H5CH(C6H5)Br
which on is more reactive in SN1 substitution reaction and why?
2011 F
Q4) which will react faster in SN2 displacement,1-bromopentane or
2- Bromopentane and why?
4 marks
MECHANISM
1) Formation of diethyl ether from ethyl alcohol.
2) Alcohols reacts both as electrophile & as nucleophiles in their reactions
3) Acid catalysed dehydration of an alcohol forming an alkene
4) Acid catalysed hydration of an alkene forming an alcohol
5) Preparation of ethoxyethane from ethanol.Does the reaction follow SN1
or SN2 pathway.
REASONS
1) Ethoxy ethane is soluble in water?
2) Phenol is more acidic than ethanol
3) Which is stronger acid phenol or cresol? Why?
4) Phenols do not give protonation reaction readily?
5) m- amino phenol is stronger acid than o- aminophenol
6) Alcohols act as weak base.
7) Propanol has higher b. p. than that of hydrocarbon Butane.
8) Preparation of ether by acid dehydration of 20 &30 alcohol is not a
suitable method
9) Ethanol has higher b.p. than methoxy methane.
10)
Alcohols are comparatively more soluble in water than
hydrocarbon of comparable M.M
11)
O- & p- nitrophenols are more acidic than phenol
12)
Ethers have low b.p.
13)
The b.p. of ethanol is higher than that of methoxy methane
14)
O-nitrophenol is more acidic than o-methoxy phenol
CONVERSION/WORD PROBLEM
1) Ethyl alcohol to acetaldehyde
2) Butan-2-one to Butan-2-ol
3) Phenol to 2,4,6-tribromophenol
4) phenol to benzoquinone
5) Propanone to 2- Methyl propan-2-ol
6) Propene to Propan- 2- ol
7) Benzyl chloride to Benzyl alcohol
8) Methyl Mg Bromide to 2-Methyl propan-2-ol
9) Ethyl Mg Bromide to propan-1-ol
10) Ethenol to ethene
COMPLETE EQUATIONS
1) Write the products obtained when benzyl phenyl ether is heated with HI
QUESTION
1) Name the reagents & write chemical equation for preparation of
(a) ethoxy benzene
(b)2- Methyl-2-methoxy propane
2) Addition of G.R. to a carbonyl group of a comp. forming an adduct
followed by hydrolysis?
3) Acid catalysed dehydration of an alcohol forming an alkene
4) Acid catalysed hydration of an alkene forming an alcohol
5) How do you account for the miscibility of ethoxy ethane with water?
6) Which is a stronger acid phenol or cresol?Explain
7) Give possible explaination for the following
(a) O-nitrophenol is more acidic than o-methoxy phenol
(b)Alcohols are easilyprotonated in comparison to phenol.
(c) The relative ease of dehydration of alcohol is 30>20>10
NAME REACTIONS
1) Reimer Tiemann reaction
2) Williamsons synthesis
3) Kolbes reaction
4) Friedel Crafts reaction
DISTINGUISHING TEST
1) phenol & cyclohexanol
2) Propan-2-ol & benzyl alcohol
3) Phenol & benzyl alcohol
4) Butan-2-ol & 2-Methyl propan-2-ol
5) Ethanol & phenol
6) 1- propanol & 2- propanol
7) Phenol & benzoic acid
8) Isopropyl alcohol and n-propyl alcohol
9) Methyl ethanoate and ethyl methanoate
2011D
Q14) Explain the following giving one example for each:
(i)
Reimer Tiemann reaction
(ii)
Friedel Craft acetylation of anisole
Q15) How would you obtain
(i)
Picric acid (2,4,6 Trinitrophenol) from phenol
(ii)
2-Methylpropene from 2- Methylpropanol
2011F
Q5) write IUPAC name of (CH3)2C = C(Br) CH2OH
Q26) How would you obtain
(i)
Benzoquinone from phenol
(ii)
Propan-2-ol from propene
(iii) 2-Methylpropan-2-ol from methyl magnesium bromide
2010DCOMPTT
Q1) write IUPAC name of (CH3)2C(OH)CH2 CO CH3
Q2) write structure of 2-Methyl-2-thoxypentane
Q11) give one chemical test to distinguish between the following pairs of
compounds:
(i)
Phenol and benzoic acid
(ii)
1-Propanol and 2-Propanol
2010 AI COMPTT
Q13)Describe the mechanism of hydration of ethane to yield ethanol
Q14) write chemical equation each to illustrate the following reactions:
(i)
Reimer tiemann reaction
(ii)
Williamsons synthesis
2012 AI
Q14) Explain the following behaviours:
(i)
Alcohols are more soluble in water than the hydrocarbons of
comparable molecular masses.
(ii)
Ortho nitrophenol is more acidic than ortho methoxyphenol.
Q15) explain the mechanism of acid catalysed hydration of an alkene to form
corresponding alcohol.
2012 D
Q5) Draw structural formula of 2-methylpropan-2-ol.
Q25) Draw the structure and name the product formed if the following
alcohols
are oxidized. Assume that an excess of oxidizing agent is used.
Q5) Draw the structure of hex-1-en-3-ol.
2012 F
Q5) Write the IUPAC name of CH3 CH=CH-CH(OH)CH2CH3.
Q25) State the products of the following reactions:
(i)
CH3CH2CH2OCH3 + HBr
(ii)
C6H5OC2H5 + HBr
(iii) (CH3)3COC2H5 + HI
Q5) Of the two alcohols:
(a) CH2=CHCH2OH
(b)CH2=CHCH2CH2OH,
Which one will react more easily with conc. HCl in the presence of ZnCl2?
Q5) Write the IUPAC name of CH3O CH2CH(CH3)2
2013 AI
Q16) Explain the mechanism of the following reaction:
CH3-CH2-OH (H+ and 443 K) CH2=CH2 + H2O
Q17) Write the equations involved in the following reactions:
(i) Reimer Tiemann reaction
(ii ) Williamsons ether synthesis.
Question Bank
(Organic compounds containing aldehydes, ketones & carboxylic
acids)
6marks
IUPAC
(i) (CH3)2C=CHCOCH3
(ii) 4-Methylpent-3-en-2-one
(iii)CH3COCH2COCH3
(iv) CH3COCH2CH(Cl)CH3
(v)CH3CCCH=CHCOOH
(vi)OH)C6H5COC6H5OH
(vii)C6H5CON(CH3)2
(viii)1-Phenylpentan-1-one
(ix)3-Oxopentanal
(x)(CH3)2CHCOCH(CH3)2
(xi)CH3CH2COC6H5
(xii)2-Methylcyclopent-3-enecarboxylic acid
(xiii)(CH3)2C=CHCOCH3
(xiv)4-Chloropentan-2-one
(xv) 2,6-Dimethyl phenol
MECHANISM
1)Explain the mechanism of a nucleophilic attack on the carbonyl gr. Of an
aldehyde
or
a
ketone.
REASONS
(i)Aldehydes are more reactive than ketones towards nucleophile
(i)
The b.p. of aldehydes & ketones are lower than corresponding acids.
(ii)
The aldehydes & ketones undergo a no. of addition reactions
(iii) Monochloroethanoic acid has a higher pKa value than
dichloroethanoic acid
(iv) Ethanoic acid is weaker acid than benzoic acid
(v)
Benzoic acid does not undergo F/C reaction.
(vi) pKa value of chloroacetic acid is lower than pKa value of acetic acid.
(vii) P-nitrobenzoic acid has higher Ka value than benzoic acid
(viii) Acetone is highly soluble in water but benzophenone is not.
CONVERSION/WORD PROBLEM
Q1) An organic compound (A)having M.F. C 8H8O forms an orange red ppt (B)
with 2,4-DNP reagent. Compound (A) gives a yellow ppt (C) when heated in
presence of I2 & NaOH alongwith a colourless compound (D).(A) does not
reduce Tollens reagent or Feh. Soln. nor does it decolourise Br 2 water. On
drastic oxidation of (A) with chromic acid,a carboxylic acid (E) of M.F. C 7H6O2
is formed. Deduce the structures of org. compds. (A) to(E).
Q2) An organic compound A with M.F. C 5H8O2is reduced to n-pentane on
treatment with Zn-Hg/HCl. A forms a dioxime with hydroxylamine &gives a
positive iodoform test & Tollens test Identify the compound A & deduce its
structure.
Q3) An unknown aldehyde A on reacting with alkali gives -hydroxyaldehyde
which loses water to form an unsaturated aldehyde , 2- butenal.Another
aldehyde B undergoes disproportionation reaction in presence of conc.alkali
to form products C & D. C is aryl alcohol with the formula C7H8O.
(i)
Identify A & B
(ii)
Wrute the sequence of reactions involved.
(iii) Name the product when B reacts with Zn/Hg & HCl.
Q4) A compound X (C2H4O) on oxidation gives Y (C 2H4O2). X undergoes
haloform reaction. On treatment with HCN , X forms a product Z which on
hydrolysis gives 2- hydroxyl propanoic acid
(i)Write structures of X & Y
(ii)Name the product when X reacts with dil. NaOH
(iii)Write the equation for the reactions involved.
Q5) An organic compound contains 69.77% C ,11.63% H ,& rest is O. The
molar mass of the compound is 86.It does not reduce Tollens reagent but
forms an addition compound with NaHSO 3 & gives a positive iodoform test.
On vigorous oxidation it gives ethanoic & propanoic
acid.Deduce the
possible structure of org. compd.
Q6)An org.compd.A(C7H6Cl2) on treatment with NaOH soln. gives another
compd. B (C7H6O). B on oxidation gives an acid C (C 7H6O2) which on
treatment with a mixture of conc. HNO3 & conc.H2SO4 gives a compd. D
(ii)
(iii)
(iv)
(v)
(vi)
(vii)
(viii)
2011 D
Q6) 3-Methylbutanal (IUPAC)
Q29) (a) give chemical test to distinguish between:
(i)
Propanal and propanone
(ii)
Benzaldehyde and acetophenone
(b)How would you obtain:
(i)
But-2-enal from ethanol
(ii)
Butanoic acid from butanol
(iii) Benzoic acid from ethyl benzene
Q29) (a) describe the following chemical equation
(i)
Cannizaros reaction
(ii)
decarboxylation
(b) Complete
(i)
Ethyl benzene (KMnO4/KOH ) and heat
(ii)
phthalic acid (SOCl2) and heat
(iii) Benzamide (H3O+) and heat
2011 F
Q6) Write the structure of following
3-oxopentanal
Q30) (a) give chemical test to distinguish between:
(i)
Propanal and propanone
(ii) Benzaldehyde and acetophenone
(b) How would you obtain:
(i)
But-2-enal from ethanol
(ii)
Butanoic acid from butanol
(iii) Benzoic acid from ethyl benzene
Q30) (a) describe the following chemical equation
(i) Cannizaros reaction
(ii) decarboxylation
(b) Complete
(i) Ethyl benzene (KMnO4/KOH ) and heat
(ii) phthalic acid (SOCl2) and heat
(iii) Benzamide (H3O+) and heat
2010 DCOMPTT
Q1) write IUPAC name of (CH3)2C(OH)CH2COCH3
Q30)An organic compound (A) on treatment with acetic acid in the presence
of
sulphuric acid produces an ester (B). (A) on mild oxidation gives (C) (C)
with
50%KOH followed by acidification with dilute HCl generates (A) and
(D).(D)with PCl5 followed by reaction wit ammonia gives (E).(E) on
dehydration produces hydrocyanic acid.Identify the
compoundsA,B,C,D,E.
Q30)Identify A,B,C,D,E in the following sequence of reactions:
A (Cl2) CHCl3 (NaOH) B (C6H5COClC (C6H6 /AlCl3D + E
Q8) write the IUPAC name of the following (CH3)2CH CO CH(CH3)2
Q5) write the IUPAC name of the following CH3CH2COC6H5
2010AI COMPTT
Q8) write the IUPAC name of the following CH2CH2CH2CHCHO(cyclic
structure)
Q30)An organic compound A on treatment with ethyl alcohol gives a
carboxylic
acid B and compound. Hydrolysis of C under acidified condition gives B
and
D.Oxidation of D with KMnO4 also givesB. B on heating with Ca(OH)2
gives
E having molecular formula C3H6O. E does not give Tollens test and
does
not reduce Fehlings solution but forms a 2,4-dinitrophenyl hydrazone.
Identify A,B,C,D and E.
Q30) Identify A,B,C,D and E.
C6H5CH3 + CrO3 +
(CH3CO)2O (273-283K) A (heat,H2O) B
(conc.NaOH)
C+ C6H5COONa
C6H5CH3(KMnO4,KOH ,HEAT) D ( H3O+) E
Q7)C6H4Cl COCH3 (IUPAC name)
2012 AI
Q6) CH3-CH2-CH = CH- CHO (IUPAC name)
Q6) Ph-CH = CH CHO (IUPAC name)
Q30)(a) write a suitable chemical equation to complete each of the following
Transformations:
(i)
Butan-1-ol to butanoic acid
(ii)
4-Methylacetophenone to benzene-1,4-dicarboxylic acid
(b) An organic compound with molecular formula C9H10O forms 2,4-DNP
derivative,reduces Tollens reagent and undergoes Cannizaros
reaction.On vigorous oxidation it gives 1,2-benzenedicarboxylic
acid.Identify the compound.
Q30) (a) give chemical tests to distinguish between
(i)
Propanol and propanone
(ii)
Benzaldehyde and acetophenone
(b) arrange the following compounds in an increasing order of their
property as indicated:
(i)
Acetaldehyde,acetone,methyl
tert-butyl
ketone
(reactivity
towards HCN)
(ii)
Benzoic acid,3,4-dinitro benzoic acid ,4-methoxy benzoic acid
(acid strength)
(iii) CH3CH2CH(Br)COOH,CH3CH(Br)CH2COOH,(CH3)2CHCOOH (acid
strength)
2012 D
Q6) Arrange the following compounds in an increasing order of their
reactivity in
nucleophilic addition reactions: ethanol,propanal,propanone,butanone.
Q30) (a) Illustrate the following name reactions giving suitable example in
each
case:
(i)
Clemmensen reduction
(ii)
Hell-Volhard Zelinsky reaction
(b) How are the following conversions carried out?
(i) ethyl cyanide to ethanoic acid
(ii)Butan-1-ol to butanoicacid
(iii) Benzoic acid to m-bromobenzoic acid
Q30) (a) Illustrate the following reactions giving suitable example for each.
(i)
(ii)
(iii)
Cross-Aldol condensation
Decarboxylation
(b)Give simple test to distinguish between the following pairs of
compounds.
(i) Pentan-2-one and Pentan-3-one
(ii) Benzaldehyde and acetophenone
Phenol and benzoic acid .
2012 F
Q6) Draw the molecular structureof the compound,4-methylpent-3en-2-one.
Q30) (a) Describe the mechanism of the addition of Grignard reagent to the
carbonyl group of a compound to form an adduct which on hydrolysis
yields an alcohol.
(b) Draw thestructures of the following compounds:
(i) 3-Methylbutanal
(ii)Hexane-1,6-dioic acid
(iii) p-Nitropropiophenone
Q30) (a) Illustrate the following rections giving a suitable chemical equation
for each:
(i)
Cannizaro reaction
(ii)
Hell-Volhard-Zelinsky reaction
(b) How would you bring about the following conversions?Write the
complete equation in each case:
(i) Ethanal to 3-Hydroxybutanal
(ii)Benzoic acid to m-nitrobenzyl alcohol
(iii)Benzaldehyde to Benzophenone
2013 AI
Q5) Rearrange the following compounds in the increasing order of their
b.p.
CH3CHO ,CH3CH2OH , CH3CH2CH3
Q30) (a) How will you convert the following:
(i)
Propanone to Prpan-2-ol
(ii)
Ethanal to 2-hydroxy propanoic acid
(iii) Toluene to benzoic acid
( b ) give simple chemical test to distinguish between:
(i)
Pentan-2-one and Pentan-3-one
(ii)
Ethanal and Propanal
Q30) ( a) Write products of the following reactions:
(i)
CH3 CO CH3 (Zn-Hg , conc. HCl)
(ii)
CH3 CO Cl + H2 (Pd BaSO4)
(iii) C6H5COOH (Br2/FeBr3)
( b) Which of each pair shown here would you expect to e stronger?
(i)
F-CH2-COOH or Cl-CH2-COOH
(ii)
C6H5OH or CH3COOH
Q4) ethanal is soluble in water.why?
Question Bank
(Organic compounds containing nitrogen)
4 marks
IUPAC
1) Write IUPAC name of
CH3-N(C2H5)-CO-CH3
2) Write IUPAC name of H2NCH2CH2CH=CH2
MECHANISM
1)Show the mechanism of acylation of ethanamine and write the IUPAC name
of
the
product
formed.
REASONS
1) Direct nitration of aniline is not carried out. Explain why?
2) Predict giving reason the order of basicity (i) gaseous phase (ii) in
aqueous solution (CH3)3N , (CH3)2NH , CH3NH2,NH3
3) pKb for aniline is more than methylamine
4) Methyamine solution reacts with FeCl3 solution to give ppt of Fe(OH)3
5) Primary amines have higher b.p. than tertiary amine.
6) AgCl dissolves in aq. Methylamine solution
7) Presence of a base is needed in the ammonolysis of alkyl halide.
8) Aromatic primary amines can not be prepared by Gabriel Phthalimide
synthesis.
9) Alkyl amines are stronger bases than ammonia.
10)
Aliphatic amines are stronger bases than aromatic amines.
11)
B.P. of methyl amine is lower than that of methanol
12)
Aniline does not undergo Friedel Craft alkylation reaction
13)
Although -NH2 gr. Is o & -p directing ,nitration of aniline give m
derivative alongwith o & -p derivatives.
14)
Ethyl amine is soluble in water whereas aniline is insoluble.
15)
Amines act as nucleophiles.
16)
Gabriel phthalimide synthesis is preferred for synthesizing
primary amines.
CONVERSION/WORD PROBLEM
1) How can you convert an amide into an amine having one C less than the
starting compound?
(a)Name the reaction
(b)Give IUPAC name & structure of amine obtained by the above method if
tha amide is 3-chlorbutanamide.
2) (i) Benzene diazonium chloride to nitro benzene
(ii)aniline to Benzene diazonium chloride
(iii)Ethylamide to methyl amine
(iv)Aniline to nitro benzene
(v)Ethanamine to N-ethyl ethanamide
(vi)Chloroethane to propan-1-amin
(vii) aniline to iodobenzene
3) Identify A and B (i) CH3CH2Cl (NaCN) A (reduction Ni/H2) B
(ii) C6H5NH2 (NaNO2/HCl) A (C6H5NH2 , OH-) B
4)Aniline to sulphanilic acid
5)An organic compound (A) on treatment with NH3 followed by heating forms
compound (B) which on heating with Br2 and KOH forms a compound (C)
having M.F. (C6H7N).Give the structures of A,B and C.and write the
reactions involved.
COMPLETE EQUATIONS
1) Complete & name the reaction.
(i)
RNH2 + CHCl3 + 3KOH
(ii)
RCONH2+Br2+4NaOH
2) (i)
LiALH4/H2O
RCONH2
2011 D
Q7) Arrange the following compounds in an increasing order of their solubility
in
water C6H5NH2,(C2H5)2NH,C2H5NH2.
Q26) (a) Explain why an alkyl amine is more basic than ammonia?
(c) How would you convert
(i)
Aniline to nitro benzene
(ii)
Aniline to iodobenzene.
2011 F
Q7) Why is an alkyl amine more basic than ammonia
Q25) Illustrate the following reactions giving a chemical equation in each
case.
(i)
Gabriel phthalimide synthesis
(ii)
A coupling reaction
(iii) Hoffman bromamide reaction
2010 D COMPTT
Q9) Reasons: (i) ethyl amine is soluble in water whereas aniline is insoluble.
(ii ) The pKb of aniline is higher than that of methyl amine.
(iii ) methyl amine reacts with FeCl3 solution to precipitate
hydrated
Fe2O3.
(iv ) Aliphatic amines are stronger bases than aromatic amines.
Q10) Write the chemical reaction
(i)Carbyl amine reaction
(ii) Hoffman bromamide reaction
Q17) Write the reaction.
(i)
Coupling reaction
(ii)
Ammonolysis
Q12) Write the reaction.
(i)
Acetylation
(ii)
Gabriel phthalimide synthesis
2010 AI COMPTT
Q15) Reasons: (i) The pKb of aniline is higher than that of methyl amine.
(ii)Aniline does not undergo Friedel Craft reaction
(III) Gabriel phthalimide synthesis is preferred for
synthesizing
primary amines.
Q16) Distinguishing test:
(I)
Ethyl amine and aniline
(II)
Methyl amine and dimethyl amine.
Q26) (i) CH3CH2Cl ( NaCN) A (red.Ni/H2) B
(ii ) benzene diazonium chloride +H3PO2 + H2O
(iii ) RCONH2 (LAH/H2O)
2012 AI
Q16) describe the following giving the relevant chemical equation in each
case.
(i)
Carbylamines reaction
(ii)
Hofmanns bromamide reaction
Q17) complete the following reaction equation:
(i)
C6H5N2Cl + H3PO2 + H2O
(ii)
C6H5 NH2 + Br2 (aq)
2012 D
Equilibrium Mixture
(B)
1110
52.20
19.20
(i)
What are such isomers called?
(ii)
Can they be called enantiomers ? Justify your answer.
(iii) Draw the cyclic structure of isomer (A)
Q27)An optically active amino acid (A) can exist in 3 forms depending on the
pH of the medium.if the M.F. of (A) is C3H7NO2 write
(i)
Structure of compound (A) in aqueous medium. What are such
ions called?
(ii)In which medium will the cationic form of compound (A) exist?
(ii)
In alkaline medium, towards which electrode will the
compound (a) migrate in electric field?
2010 F
Q8) What happens when glucose is treated with Br2 water?
Q25) Explain the following:
(i)
Invert sugar (ii) poly peptides (iii) Denaturation of protein
Q25) Mention three such facts/ reactions about glucose which can not be
explained by its open chain structure .What is meant by pyranose structure
of glucose?
NEW SAMPLE PAPER I
Q25) (a) Give one reaction of D-glucose which can not be explained by its
open chain
structure.
(b) Give one example of each for essential and non essential amino acids.
( c) Differentiate between keratin and insulin.
NEW SAMPLE PAPER II
Q5) What type of linkage holds together the monomers of DNA?
Q21) (a) Write the zwitter ion structure of glycine.
(b) What is meant by inversion of sugar
( c ) Name the vitamin in each case whose deficiency causes (i)
Nightblindness
(ii)
Poor coagulation of blood
NEW SAMPLE PAPER III
Q8) What are the ultimate products of digestion of protein ?
Q21) (a) Give reasons: (i) glucose does not give 2,4-DNP test and Sciffs test
(ii) Amino acids have high m.p. and are soluble in water.
(b)What is meant by the secondary structure of protein.
2011 AI
Q17) Explain what is meant by the following:
(i)
Peptide linkage
(ii)
Pyranose structure of glucose
Q18) Write the main structural difference between DNA and RNA.Of the four
bases ,name those which are common to both DNA and RNA.
Q18) Write such facts/ reactions about glucose which can not be explained by
its open
chain structure .
2011D
Q16) What is essentially the difference between alpha form and beta form of
Glucose?
Q17) Describe what do you understand by primary and secondary structure
of
protein.
2011 F
Q16) Explain what is meant by
(i)
Peptide linkage
(ii)
Pyranose structure of glucose.
Q17)Name the products of hydrolysis of (i) sucrose (ii) lactose
Q17) Mention three such properties of glucose which can not be explained
by its
open chain structure.
2010 D COMPTT
class.
2008 F
Q8) What is the repeating structural unit in polythene polymer?
2008 comptt D
Q27) (b)Is (CH2CHC6H5)n-- a homopymer or copolymer? Why?
Q8) What is the difference two notations Nylon-6 & Nylon-6,6 ?
Q18) What is step growth polymerization? Explain the steps involved in the
process.
Q18)What is the difference between elastomers & fibres ? Give one example
of
each.
2009 AI
Q8) What does 6,6 indicate in the name Nylon -6,6 ?
Q18) Differentiate between molecular structure & behaviour of thermoplastic
&
thermosetting polymers.Give one example of each type.
Q8) What is the primary structural feature necessary for a molecule to make
it
useful in condensation polymerization reaction?
Q17) Differentite between condensation and addition polymerization.Give
one
example of each of the resulting polymers.
2009 D
Q7) Give an example of elastomers.
Q18) Draw monomers of Teflon & polythene.
Q18) What is the repeating unit in the condensation polymer obtained by
combing HOOC-CH2-CH2-COOH (succinic acid) & H2N-CH2-CH2-NH2
(ethylene diamine)
2009 F
Q27) Differentite between mode of formation of condensation &addition
polymerization.Give one example of each of these formation.
Q27) Draw molecular structure of monomers of (i) PVC (ii) Teflon(iii)
Neoprene
2009 D(COMPTT)
Q21) What are biodegradable polymers? Give an example of such polymer &
mention its uses
2010 - AI
Q8) What does the designation 6,6 mean in the name of nylon 6,6?
Q18) Draw molecular structure of monomers of (i) PVC (ii) Teflon
2010 - AI
Q8) What is meant by coplymerisation?
Q18) Draw molecular structure of monomers of (i) Bakelite (ii) Nylon -6
2010 D
Q26) Give one example of each (i) Addition polymers (ii) Condensation
polymers
(iii) Copolymers
Q25) Write the name and structure of monomers of each polymer
(i) Neoprene (ii) Buna-S (iii) Teflon
2010 F
Q26) Identify the four groups into which the polymers are classified on the
basis
of the magnitude of intermolecular forces present in them.To which
group
or groups do polythene and Bakelite belong?
Q27) Write the name and structure of monomers of each polymer
(i) Polyvinyl chloride (ii)Bakelite (iii) Teflon
Sample Paper - I-(New)
Q25) (a)Identify aliphatic biodegradable polyester which is used in packaging
and orthopedic devices.
(i) Write its full form
(ii)Give the structures of monomers from which it is formed.
(iii) Show the formation of polymer
(b)Write the name and structure of monomer of nylon-6
Sample Paper - II-(New)
Q20)(a)Write a reaction involved in the preparation of a biodegradable
polyester.
(b) Monomer unit of synthetic rubber (neoprene)
( c )One use of Nylon-6,6
Sample Paper - III-(New)
Q22) (a)Give an example of synthetic rubber and mention its one example.
( b) Write the structures of monomers of Dacron
( c ) Arrange the following in increasing order of their tensile strength.
Nylon 6 ,Buna-S ,Polythene
A I-2011
Q26)Draw the structures of monomers of (i) Polythene(ii) PVC(iii)Teflon
Q26) Write the name and structures of the following polymers:
(i)
Buna-S (ii)Dacron (iii) Neoprene
2011 D
Q8) What are biodegradable polymers?
Q18) Mention two important uses of each
(i)
Bakelite
(ii)
Nylon 6
Q8) In nylon 6,6 what does the designation 6,6 mean?
Q18) Name the subgroups into which polymers are classifiedon the basis of
magnitude of intermolecular forces.
2011 F
Q27) Mention two important uses of each
(i)
Bakelite
(ii)
Nylon-6,6
(iii) PVC
Q27) (a)What does the designation 6,6 mean in Nylon 6,6 polymer?
(b ) Which polymer is obtained when free radical polymerization of
chloroprene occurs? Write the structure of polymer thus obtained.
Q27) What are addition polymers? How are the two types of addition
polymers
different from each other? Give one example of each type.
2010 D COMPTT
Q21) What are biodegradable polymers? Give an example of such a polymer
and
mention its uses.
2010 AI COMPTT
Q26) Write the (i) structure and (ii) one use of each of the following polymers
(a) PVC
(b)Urea-formaldehyde resin
(c) Bakelite
2012AI
Q27) differentiate between thermoplastic and thermosetting polymers. Give
one
example of each type.
Q27) Explain the following terms giving example for each:
(i)
Elastomers
(ii)
Condensation polymers
(iii) addition polymers
2012 D
Q8) Define the term, homopolymerisation giving an example.
Q18) Draw the structure of monomers for each of the following polymers:
(i)
Nylon-6
(ii)
Polypropene.
2012 F
Q18) Draw the structure of monomers for each of the following polymers:
(i)
Nylon-6
(ii)
Teflon
(iii) Neoprene
2013 AI
Q8) Is (-CH2-CH)-n a homopolymer or a copolymer?
I
Cl
Q18) Define thermoplastic and thermosetting polymers. Give one example of
each.
Q18) What is a biodegradable polymer? Give an example of a biodegradable
aliphatic polyester.
Q8) Give one example of a condensation polymer.
Q6) Is (-CH2-CH)-n a homopolymer or a copolymer?
I
C6H5
Question Bank
(Chemistry in Everyday life)
3 marks
SamplePaper I (Old)
Q6) Give one example of artificial sweetener used by diabetic patients.
Q18) In order to wash clothes with water containing dissolved calcium
bicarbonate, which cleaning agent will you prefer & why, soap or
synthetic
detergent? Give one advantage of soap over synthetic detergent.
SamplePaper II (Old)
Q27) Reasons:
a)Aspirin drug helps in prevention of heart attack.
b) Diabetic patients are advised to take artificial sweetener instead of
natural
sweeteners.
c) Detergents are non biodegradable while soaps are biodegradable
SamplePaper III (Old)
Q27) Classify synthetic detergents giving an example in each case.
Q27) What are antihistamine? Give two examples. Explain how they act on
the
human body.
2008 - D
Q8) Name a substance that can be used as an antiseptic as well as
disinfectant
Q18) What are biodegradable & non biodegradable detergents? Give one
example of each class.
2008 AI
Q27) Mention one use of each:
a) Ranitidine b) Paracetamol c) Tincture of iodine
2008 F
Q27) a) What is the problem with hard water for washing with soap?
a) Explain (i) Broad spectrum antibiotics (ii) non ionic detergents
2008 D COMPTT
Q8) What is meant by Broad Spectrum Antibiotics?
Q18) Discuss the two ways in which drug prevent attachment of natural
substrate on active site of enzyme.
Q18) Explain with example:
a) cationic detergent
b) Tranqulizers
2008 AI COMPTT
Q27) (a) What are antihistamine? Give two examples. Explain how they act
on the
human body.Give an example.
(b)Name a substance that can be used as an antiseptic as well as
disinfectant
2008 AI COMPTT
Q19) What are antibiotics? Distinguish between narrow spectrum & broad
spectrum antibiotics.Classify the following into Bactericidal&
Bacteriostatic
antibiotics
Tetracycline , Penicillin.
2009- AI
c)
c)
2009 D
Q27) Explain with example: Analgesic ,Disinfectants, Antacid, Antiseptic.
Q27) How do antiseptics differ from disinfectants ? Give one example of each
2009 F
Q1)Write the name of an antacid which is often used as a medicine.
Q18) Reasons:
(i) Soap do not do the cleansing in hard water.
(ii) Synthetic detergents are preferred to soap in washing
machine.
Q8) What is meant by Broad Spectrum Antibiotics?
Q17) Explain with example:
a) Food preservatives b) cationic detergent
2009 D-COMPTT
Q22) What are anionic detergents ?How are they prepared ?Write their two
uses.
Q24) What are artificial sweetening agents ?Give two examples .Name the
sweetening agents used in the preparation of sweets for diabetic
patient.
Q20)(a) Define the term chemotherapy.
(b)While antacid & antiallergic drugs interfere with the function of
histamine ,why do these not interfere with the function of each
other.
2010- AI (I)
Q27)Explain the following with one example :
(i) Food Preservation (ii) Enzymes (iii) Detergents
2010 AI (II)
Q27) What are analgesic drugs?How are they classified and when are they
usually recommended for use?
2010 AI (III)
Q27)Explain the following with one example :
(i)
Antibiotics (ii) Antiseptics (iii) Analgesic
2010 D
Q27) What are analgesic medicines?How are they classified and when are
they
commonly recommended for use?
Q27) Explain with one suitable example
(i)
Cationic detergent
(ii)
Enzymes
(iii) Anti fertility drugs
2010 F
Q27) How do antiseptics differ from disinfectants? Name a substance that
can
be used as an antiseptic as well as disinfectant
Q26) What are biodegradable and non biodegradable detergents? Give one
Q22) What are anionic detergents? How are they prepared? Write their two
main
uses.
Q24) What are artificial sweetening agents? Give two examples. Name the
sweetening agent used in the preparation of sweets for a diabetic
patients.
Q20) (a) define the term chemotherapy.
(b ) While antacid and antiallergic drugs interfere with the function of
histamines,why do these not interfere with the function of each other?
2010 AI COMPTT.
Q27) Explain the following terms with suitable examples.
(d)Cationic detergent
(e) Broad spectrum antibiotics
(f) Tranquilizer
Q19) Explain the following terms:
(j) Anionic detergent
(k) Chemotherapy
(l) Analgesics
Q26) Explain the following terms with one suitable example.
(i) Non ionic detergent
(j) Antiseptic
(k) Antibiotic
2012AI
Q8) Differentiate between disinfectants and antiseptics.
Q18) what are food preservatives?Name two such substances.
Q17) explain the cleansing action of soap.why do soap not work in hard
water?
Q8) what is the cause of a feeling of depression in human beings?Name a
drug
which can be useful in treating this depression.
Q18) differentiate between disinfectants and antiseptics. give example of
each
group.
2012 D
Q27)What are the following substances? Give one example of each one of
them.
(i)
Tranqilizers
(ii)
Food preservatives
(iii) Synthetic detergent
Q27) Explain the following terms giving one example of each type:
(i)
antacid
(ii)
disinfectants
(iii) enzymes
2012 F
Q8) What is meant by narrow spectrum antibiotics ?
Q18) State a reason for each of the following statements:
(i)
soap does not work in hard water.
(ii)
The use of the sweetner aspartame is limited to cold foods
and drinks
Q18) What are biodegradable and non biodegradable detergents? Give one
example of each.
2013 AI
Q25) (i) What class of drug is Ranitidine?
(ii ) If water contains dissolved Ca2+ ions, out of soaps and synthetic
detergents,which will you use for cleaning clothes?
(iii ) Which of the following is an antiseptic?
0.2 % phenol , 1% phenol
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