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CHEMISTRY FOR 9TH CLASS (UNIT # 2)
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SHORT QUESTIONS
QUESTIONS
Define Atom
Define Subatomic particles
ANSWERS
It is the smallest particle of an element
which retains all properties of element.
An atom is composed of several
subatomic particles. Electron, Proton and
Neutron are very important. These are
also called fundamental particles.
He was a British physicist. He performed
many experiments using alphaparticles.
He proposed a planetary atomic model.
He was a Danish physicist. He proposed
an atomic model in 1913. His structure of
an atom nicely explains the observed ion
spectrum of the hydrogen atom.
Atoms having same atomic number but
different mass numbers called isotopes.
Protium (1H1)
Deuterium (1H2 or D)
Tritium (1H3 or T)
12
6C
13
6C
14
6C
35
17Cl
37
17Cl
234
92U
235
92U
238
92U
Electronic Configuration is the distribution
of electrons in different sub-shells
according to their increasing energy.
s sub shell = 2 electrons
p sub shell = 6 electrons
d sub shell = 10 electrons
f sub shell = 14 electrons
Because it contains equal number of
positively charged proton and negatively
charged electrons.
Yes. An atom can be identified by its
atomic number.
Radioactive material such as polonium
was used as a source.
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LONG QUESTIONS
Question: Describe Rutherfords experiment. Write his observations. Also
describe the defect of his model
Rutherfords Experiment:
Rutherford bombarded alpha particles on a 0.00004cm thick gold foil. He obtained
these alpha particles from a radioactive element polonium. These are actually
helium nuclei.
Observations: Most particles passed un-deflected.
Only few were slightly deflected.
1 out of 1 million particles was deflected at an angle greater than 900 .
Conclusions: Since most of the alpha particles passed un-deflected, therefore, most of the space
in atom is empty.
The deflection of a few particles proved that there is a center of heavy positive
charge in atom which causes repulsion. This heavy part is named as nucleus.
All the space outside the nucleus is occupied by the fast revolving electron. The
alpha particles are not deflected by these electrons.
The centrifugal force which is produced due to rotation of electrons balances the
electrostatic force of attraction between the nucleus and electron. This prevents
the electrons from falling into the nucleus.
Defects: According to classical physics, electrons being charged particle should emit energy
continuously. The orbit of electron should become smaller and smaller until it falls
into the nucleus. But this never happened.
If the electron emits energy continuously, atom should form continuous
spectrum while atoms give line spectrum.
Question: Why Bohrs Atomic Model is better than Rutherfords Model? Give
his postulates.
Rutherfords Model was defective and needs correction. To remove these defects,
Bohr gave his atomic theory in 1913. This theory clearly explained the line spectrum
obtained from hydrogen atom.
Postulates of Bohrs Atomic Theory:
i)
Electron revolves around the nucleus in fixed circular orbits called energy levels.
ii)
Higher the orbit, greater is its energy.
iii)
The electron can move only in orbits in which the angular momentum (mvr) of
electron is integral multiple of h/2.
iv)
As long as electron remains in a particular orbit, it does not radiate or absorb
energy. When an electron jumps from lower energy level to a higher energy
level it absorbs energy and when it jumps from higher energy level to a lower
energy orbit it radiates energy.
v)
This energy emitted is exactly equal to the difference between the two energy
levels.
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Question: Write down the main differences between Rutherfords and Bohr
atomic theories.
Rutherfords Atomic Theory
Bohrs Atomic Theory
It was based upon classical theory
It was based upon quantum theory
Electrons revolve around the nucleus
Electrons revolve around the nucleus in
orbits of fixed energy.
No idea about angular momentum was Orbits had angular momentum
introduced
Atoms
should
produce
continuous Atoms should produce line spectrum
spectrum
Atoms should collapse
Atoms should exist
Question: Describe the contribution that Rutherford made to the
development of the atomic theory.
Rutherford was the first scientist who proposed first atomic model of atom.
He performed a series of experiments in which he bombarded very thin foils of
different elements with alpha particles.
Based on observations from these experiments, he suggested that all the positive
charge and most of the mass of the atom is concentrated in the tiny nucleus.
The remaining volume of the atom is occupied by electrons that revolve around the
nucleus.
These suggestions remained unchanged.
But this model could not explain the stability and line spectrum for an atom.
Question: Discuss the application of isotopes in various fields of science and
technology.
Trace for Diagnosis and Medicine
Iodine-131 is used as a tracer in diagnosing thyroid problem.
Na-24 is used to trace the flow of blood and detect possible obstructions in the
circulatory system
Iodine-132 is used to image the brain
Cobalt-60 is sued to irradiate cancer cells
Chemical Reactions and structure determination
Radioactive isotopes are used to determine the molecular structure.
Radioactive isotopes are also used to study the mechanism of chemical reactions.
Carbon-14 is used to trace the path of carbon in photosynthesis.
Archaeological and geological uses
Carbon-14 is used for age determination of carbon containing substances (fossils)
Carbon-14 is incorporated into the tissues of all living things while they are alive.
On death no more C-14 is added.
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