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1.
(d)
(d)
(d)
(a)
(c)
(b)
(b)
(c)
(c)
(b)
(a)
(a)
(a)
(c)
(a)
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
(b)
(b)
(a)
(d)
(a)
(c)
(c)
(d)
(d)
(c)
(b)
(b)
(c)
(a)
(c)
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
ANSWER KEY
(a)
46
(b)
47
(d)
48
(c)
49
(a)
50
(d)
51
(b)
52
(a)
53
(b)
54
(d)
55
(c)
56
(b)
57
(b)
58
(c)
59
(a)
60
2.
3.
(d)
-H+
conjugate base
Acid
-H+
(CH 3 ) 2 NH 2+ (CH 3 ) 2 NH
4.
5.
6.
7.
8.
(d)
(b)
(a)
(a)
(b)
(b)
(a)
(b)
(c)
(d)
(c)
(b)
(c)
(d)
(d)
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
(c)
(b)
(a)
(a)
(b)
(b)
(c)
(d)
(c)
(d)
(b)
(d)
(b)
(d)
(a)
Kw
Ka Kb
9.
CH3O CH 2Cl
(c) Esterification
CH 3 O CH 2
CH3 O = CH2
RCOOH + HOR
RCOOR + H 2 O
Alkyl-oxygen fission
6.4
6.4
=
= 58.18
=
sp.heat 0.11
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
(b) NH4 CN is a salt of weak acid and weak base and thus
for it.
Kh =
1
(a) H 2 (g) + O2 (g) H 2 O(g) H = 249
2
Let the bond enthalpy of O - H is x. Then
DH = SB.E. of reactant - S B.E.of product
1
249 = 433 + 492 - 2 x x = 464kJ mol-1.
2
(c) Approximate atomic wt. of the metal
(b)
(a)
(b)
(b)
(c)
(d)
(b)
(d)
(a)
(a)
(c)
(d)
(c)
(d)
(b)
or RCOOH + HOR
RCO.OR + H 2 O
Acyl-oxygen fission
10.
Na2S + 2Ag CN
AgCN + NaCN
Na[ Ag ( CN ) 2 ]
11.
(a)
M.P.
1
(HCl having more covalent character)
f
11
12.
19.
(d)
HOCl
CH 2 = CH 2 Cl.CH 2 .CH 2 OH
aq NaHCO
3 HO.CH CH OH
2
2
(soluble complex)
13.
K f w 1000
DTf W
20.
21.
22.
15.
(a)
T1 = 273 K, T2 = ?
Now, as d1T1 = d2T2
(B)
conc. H SO
- H 2O
2
4 C H O.C H
2C2 H5OH
2 5
2 5
16.
17.
32
gm/litres and, that
22.4
32
gm/litres, d2 = 16 gm/litres,
22.4
22.4
Here given, d1 =
Sod. ethoxide
(A)
1
.
2
2C 2 H 5 OH + 2 Na
2C 2 H 5 ONa + H 2
Ethanol
d1T1
32 273 22.4
=
K
d2
22.4 1
16
Therefore, T2 =
Diethyl ether
23.
A+
+
Ag + in solution. Remember Ksp = Ag [ Cl ] and
Cationic Vacancy
OH
NO2
Anionic Vacancy
OH
o
(d) Given : E Mg 2+ / Mg = -2.36V
Mg 2+(aq) + 2e - Mg (s)
+ conc. HNO3
18. (a)
Phenol
NO2
Picric acid
or
2, 4, 6-Trinitrophenol
Mg
2+
/ Mg
= Eo
Mg
2+
/ Mg
0.059
[Mg 2+ ]
log
2
[Mg]
0.059
log( 0.01) = -2.42V
2
12
25.
26.
37.
(b)
90 ahead
AgI ( s ) + Ag +
[ AgI ]Ag +
27.
28.
29.
90 behind
(b)
(c) Hydroxylamine and hydrazine, both do not have
carbon, hence NaCN will not be formed in Lassaignes
extract leading to negative test for nitrogen.
(a) Tollen's reagent also oxidises a-hydroxyketones, hence
positive result is observed in such case.
O OH
||
Ag ( NH ) +
||
||
H 2O
31.
32.
(b)
E=
Ag
39.
40.
displacement
total time
(c)
35.
(a)
36.
= 9 2 + 6 2 = 117 m/s
(d) Angular momentum J = mv R
It shows that angular momentum increases as the
perpendicular distance R increases along line BC.
1
9
1
q
4 p 0 r 2
r2E =
9 10
9 10 9
3
or qmax = 2 10 coulomb
(d) 4i 1 = 5i 2
Total R =
5 4 20
=
9
9
10 9 9
5
9
= i 2 + i 2 = i 2 = 2A
20
2
4
2
(c) We know that V = E IR or IR = E V
I=
41.
M' = m l' =
43.
2.5
= 12. 5 mA.
200
u 2 sin 2 q or H u 2
H=
2g
DH
Du
= 2.
= 2(+2%) = 4% increased
H
u
b
.
2a
5
i2
4
i1 = current through 4 W
i2 = current through Ammeter
distance covered
;
total time
Avg. Velocity =
a w 2 - bw + c
\ i1 =
or qmax =
33.
X=
\ 2aw - b = 0 w =
K1 + K 2
m
2p
=w=
K1 + K 2
T
m
s
or
0
(a)
p
and C lags behind by p /2
2
Silver mirror
38.
O O
3
2 R - C - C - R '+
R - C - C H - R '
30.
Hence, B leads by
l
2
ml M
=
= 40 unit
2
2
(b) As w 2 - w 20 = 2aq
2
60
0 2 - 2 p = 2 a (2p 10)
60
-a = p / 10 radian/ sec2
60 p
17 p
w = w 0 + at = 2 p - 3 =
rad / sec 2
60 10
10
13
44.
(c)
50sin30
l 2 = 4 10 -7 m, V2 = 0.82
50m/sec
30
f = 1.216 10 -19 J =
70m
48.
Sy = u y t +
1
a y t2
2
70 = 50 sin 30t
(a)
Q = KA
\Y =
1
L
200 - T1= 2T1 2T2 = 1.5 T2- 27,
Solving T1 = 116C and T2= 74C
v0
F' L (Vrg - V l g )L
=
Al w
Al w
which gives r =
49.
20 cm
u0
......(1)
......(2)
(200 - T1 )
(T - T )
= (2K)A 1 2
L
L
(b)
FL VrgL
=
Al a
Al a
1
(10)t2
2
=(1.5K) A (T2-18)
46.
(b) Let V be volume of the load, and let its relative density
be r then
Y=
70 = 25 t 5t2
5t2 25t 70 = 0 t2 5t 14 = 0
t2 7t + 2t 14 = 0 t = 7 sec
45.
hc
l 0 = 5451
l0
(b) Pitch =
la
la - l w
2mm
= 0.5 mm
4
Least count =
ue
Pitch
Number of division on circular scale
objective
Ve=25 cm
Eye piece
50.
1 1
1
+
for objective =
1 v0 u0
(a)
V=
\ v o = 20 - u e
1 hc
- f
el
Put l1 = 3 10 -7 m, V1 = 1.85 ,
51.
52.
53.
25 95
=
6
6
1
1
95 89
\
= 1= 1=
u0
v0
6 95
47.
T = 2p
1
1
1
1 1
1
=+
or +
=
fe
25 u e
5 25 u e
25
cm
6
u e = 20 -
0.05mm
= 0.01 mm
50
(c) For second's pendulum
T = 2s, g = 9.8 m/s2,
54.
95
\u0 =
89
gT
l
l=
= 0.99 m
g
4p2
v2 =
( m1 + m2 ) V = 3.88 m / sec
m1
14
55.
62.
(b) Let h( x ) =
56.
h (-x ) =
58.
59.
f
is an odd function
g
57.
f (- x )
f (x )
=
= -h (x )
g(- x ) - g (x )
\ h( x ) =
63.
f (x )
then
g(x )
(2g) 2 - 4 4 1 0 | g | 2
64. (a) If tan A, tan B, tan C are in A.P. then
2 tan A = tan A + tan C
3 tan B = tan A tan B tan C
Q tan B 0 tan A tan C = 3
3
= 5 2 sin 3pt +
cos3pt
2
p
p
3
3
p
= 10sin 3pt +
60.
61.
b
a-b
and p = 1 - q =
a
a
a2
a-b
So, np = a n
=
a
n
=
a -b
a
Thus,
a2
is a positive integer..
a -b
O
C
N D
Now, in DABC
OH is parallel to BC, so
OD = HN R cos A = 2R cos B cos C
- cos(B + C) = 2cos Bcos C
sin Bsin C = 3cos B cos C tan B tan C = 3
x +2
f (t)dt - f (t)dt =
f (t)dt
d
( g(x + 2) - g(x)) = f (x + 2) - f (x) = 0,
dx
as f is periodic of period 2.
15
g (x + 2) g (x) is a constant.
1
1
x 1 + 2 +
n
n 1
we get ,
6
n2
<
+ | a3 | | x | 3 + . + | an | | x | n
[12 x] + [2 2 x ] + .... + [ n 2 x] x
x
( 2) - 0 < Lt
3
6
n
n3
2 [| x | + | x |2 + .. + | x |n ] [Q an < 2]
lim
2| x|
2| x| 2 1
<
[1- | x |n ] <
=
1- | x |
1- | x | 3 1- | x |
1 3
. =1
3 2
[12 x ] + [2 2 x ] + ..... + [n 2 x ]
69.
67.
(a) Since, e
\ log e
i.e.,
p
2
p
2
<q<
(d) Sp = coeff. of xp =
p+qC
and Sq = coeff. of xq =
p
2
71.
p
p
p
< log q < log < 1 <
2
2
2
Cq = (p + q)! , \ Sp = Sq
q!p!
10!
and further they can be given
2!.3!.5!
72.
(x, y)
(0, 3)
G
(1, 4)
i.e., log (cos q) < 0. Hence, cos (log q) > log ( cos q)
(b) Since 12 x 1 < [12 x] 12 . x
22 x 1 < [22 x] 22 x
32 x 1 < [32 x] 32 x
n2 x 1 < [n 2 x] n2 x
Adding all terms, we get,
x n 2 - n < {[12 x] + [22 x] + [32 x] +
+ [ n2 x]} x n 2
10!
3!
2!3!5!
p
p
< log q <
\ cos (log q) > 0
2
2
p+ q
(p + q)!
p!q!
p=
p
< log q < log
2
p
p
p
Q 2 < e \ log 2 < log e = 1 and 1 < 2
x
3
\ 10 3r = 1 3r =9 r = 3
n3
Let n , we get,
1
1
x1 + 2 +
n
n
[12 x ] + [2 2 x] + ..... + [ n 2 x]
\0=
-3 =
73.
-1 + 5 + x
x = -4
3
4+2+y
y = -15, \ pt. is ( 4 ,15)
3
(5, 2)
a
b
=
sin A sin B
2
3
=
sin B = 1 B = 90
2 sin B
3
16
74.
77.
x + 1+ w + w
we get, x + 1 + w + w
x + 1+ w + w
x+w
=0
x+w
h +1
k+2
=5,
=5
2
2
w2
x x + w2
x
1
= 0 [Q 1 + w + w2 = 0]
1
x+w
78.
\ h = 9, k = 8
2
x 1 x+w
1
1
75.
C1C2 =
w2
=0x=0
1
x+w
l =0
l+m+n m
l+m+n n
l+m+n
n
l =0
79.
(4 - 1) 2 + ( -1 - 3) 2 = 9 + 16 = 5
80.
3p
- a = cos 4 a,
2
(b) sin 4
(C1 C1 + C 2 + C3 )
sin 4 ( 3p + a) = sin4 a,
p
2
\ given quantity
= 3[cos4a + sin4 a] 2 [cos6 a + sin6 a]
= 3 [1 2sin 2 a cos2a] 2 [1 3 sin2 a cos2a] = 1
l =0
m
(l + m + n )(mn + nl + lm - l 2 - m 2 - n 2 ) = 0
81.
82.
3 4 2
5 8 2 =
y 2
x -5 y -8 0
= 2 (2y 16 4x + 20 ) = 2 (2y 4x + 4 )
\ given determinant = 0 2y 4x + 4 = 0
2x y 2 = 0 which represents st. line.
p
x
4
p p
p
p
= np + (1)n x = np + (1)n +
4 4
4
4
r r r r r r
[A - B B - C C - A]
\ l2 + m2 + n2 = lm +mn + nl
(c)
p
4
l + m + n = 0 ; l 2 + m 2 + n 2 - lm - mn - nl = 0
76.
(c)
r r
r r
r r
= [(A - B) (B - C)]. (C - A)
r r r r r r r r r
= [A B - A C - 0 + B C].(C - A)
r r r r r r
= [A B].C - [B C].A
r rr
r rr
= [A BC] - [A BC] = 0 (Q [ABC] = [BCA])
17
83.
r
r
B = 4i + 3j + 4k
(d) Vector A = i + j + k,
r
And C = i + aj + bk are linearly independent, if
1
4
1
3
1
4 =0
1 a b
87.
\ x1 = 1 and x2 = 1 y1 = 2 and y2 = 2 ;
\ OP = i + 2j; OQ = - i - 2j
Hence, a = 1 , b = 1
Lt [f (x ) + g ( x ) + h (x )]
\ 2OP + 3OQ = 2i + 4 j - 3i - 6 j = -i - 2 j ;
x 3
2(2 x + 1)
2
x -3
= Lt
+
x 3 x - 3 x + 4 x 2 + x - 12
2 x + 8 + x 2 - 6x + 9 - 4 x - 2
= Lt
x 3
x 2 + x - 12
x 2 - 8x + 15
x 3
85.
86.
x + x - 12
1
. Let i be unit vector along x-axis and
x
uuur
Since, OP i = 1 and OQ.i = 1 and OQ.i = -1
\ a2 = 1 a = 1
= Lt
1
ab (s r) [ rs s r + 1 ]
2
uuur
uuur
OP = x1i + y1j, OQ = x 2i + y 2j
1 + a2 + b2 = 3 1 + a2 + 1 = 3
x 3
r
Again, | C | = 1 + a 2 + b 2 = 3
= Lt
1
ab [ rs (s r ) + (r 2 s2) + (s r )]
2
= x+
(b1)=0b=1
(c)
1
ab (s r ) (s 1) (r 1 )
2
(d) Let P ( x1, y1 ), Q ( x2,y2 ) be two points on the curve y
we get, 4 -1
0 =0
1 a -1 b -1
84.
1
[abrs2 abr2s+abr2 abs2 + abs bar ]
2
\ A is (16, 4)
Reqd. area = Area of rect. OMAC Area OMA
(x - 3)( x - 5)
x 3 ( x + 4)( x - 3)
= Lt
x -5 3-5
2
=
=x + 4 3+ 4
7
2 and
d = bs, f =
16
16
= 4 16 x dx = 64 -
3
2
.
0
bs2
= 64 -
a b 1
1
c d 1
Then area of triangle, A =
2
e f 1
3/ 2
1
[(cf ed ) + (be af ) + (ad ac )]
2
89.
(d)
2
128 64
=
(4) 3 = 64 sq.units
3
3
3
3p / 2
5p / 6
p/2
p/2
5p / 6
7p / 6
3p / 2
7p / 6
18
5p / 6
7p /6
3p / 2
p/2
5p / 6
7p / 6
1 dx + 0 dx + (-1) dx +
(-2) dx
7 p 7 p 3p
p
5p p
= - + 0 + p - + 2 - = 6
6 2
6
2
2
90.
(a) L f (1)
f ( x ) - f (1)
ax 2 + b - a - b
= Lt
x -1
x -1
x 1
x 1
= Lt
a ( x 2 - 1)
= Lt a ( x + 1) = 2a
x 1 x - 1
x 1
= Lt
Rf (1)
f ( x ) - f (1)
bx 2 + ax + c - a - b
= Lt
x -1
x -1
x 1
x 1
= Lt
= Lt [b ( x + 1) + a ] +
x 1
= 2b + a +
c
x -1
c
= 2b + a if c = 0
x -1
Since, f is diff. at x = 1\ 2 a = 2 b + a
a = 2 b. Thus, result holds if a = 2 b, c = 0.