Beruflich Dokumente
Kultur Dokumente
0 INTRODUCTION
Evaporation is a process of vaporization where the vapour from the boiling
point solution is removed which causes a more concentrated solution to remain.
An evaporator is a device used to turn the liquid form of a chemical into its gaseous
form. A climbing film evaporator (CFE) is a special type of evaporator which provides
a high heat transfer coefficient and a short residence time for the solution to be
evaporated. Multi tube CFEs are used to concentrate solutions such as fruit juices
that can be damaged by prolonged heat. It is designed to operate under vacuum,
which reduces the evaporation temperature and increases the heat flux by either
through batch or continuous process. In the application of CFE, it is normally used to
study the evaporation and concentration of sensitive products such as milk, fruit juice
and for desalination studies. There are also other types of evaporator which uses the
same application as climbing film evaporator such as rising film evaporator, thin film
evaporator, rotary evaporator and film on film evaporator.
2.0 OBJECTIVE
The objective of the experiment was to determine the concentration of product
concentrate of a once through experiment of grape juice (stimulated by KMnO4) and
water mixture. Besides that, there were also few other objectives for the experiment:
-
3.0 PROCEDURE
3.1 Effect of evaporator pressure
1. The valve for main cooling water supply is on. Subsequently, turn on cooling
water valve to allow flow into the condenser. Ensure that circulating cooling
water flow rate is 6 L/min.
2.
Before the experiment is started, ensure that V7, V9, V11, V12, V14 are
closed.
3. Open valve V2, V3, V5, and close V1, V4, V6. Turn on the feed pump and in
order to circulate the KMnO4 solution. Wait until the solution homogenous.
4. Collect a sample of feed from the feed tank by using V1. And measure its
corresponding refractive index. Record this value.
1
5. Now with the feed pump turned on, open V6 in order to set the level of
KMnO4 to 25 cm level.
6. Measure the volume of the KMnO4 solution inside the column by transferring
into volumetric cylinder by opening the valve V14.
7. Repeat the column filling process by opening valve V6 and set to the level 25
again.
8. Starting at atmospheric pressure [vacuum pump is not used] .
9. The steam supply is turn on. Open the steam condensate purge valve to allow
purging of condensate.
10. Before the steam is transferred, the purge valve is open, and main steam
valve and steam supply valve are closed. Very carefully [ensure that you have
put on your glove] open the main steam valve to 1/2 open. At the same time of
opening the main steam valve and closed steam purge valve, start the
stopwatch timing.
11. Observe the first bubble appearance and record the time taken.
12. Take the reading of steam flow rate and pressure
13. After 20 minutes, close steam supply valve, and open steam purge valve at
the same time. No need to close the main steam valve to obtain the same
steam flow rate and pressure for the next running.
14. Collect he samples of the Evaporator (via V14), concentrate and condensate
(via V12). Concentrate and condensate samples may be taken afterward. But,
the evaporator sample have to wait for a while ( 15 minutes).
15. The first sample taken is condensate. Easily, open V12. The second is
concentrate. Use vacuum pump to collect the sample. Close V12 and Open
V7 to let the liquid flow to the inlet transfer pump. Then close V7 and open V9.
Turn on the vacuum pump and the liquid will be transferred to the condensate
receiver tank 2. After all the liquid has been transferred, close V9 and easily,
open V12 to collect the concentrate sample. Redo the vacuuming if the liquid
is still remaining in the inlet transfer pump line.
16. Measure the volume and record the refractive index of all samples.
17. Return all the samples to the feed tank. (Before executing check with the
lecture and ensure that you are cleared by the lecture to conduct these
procedures).
18. Set the height of feed at 25 cm again.
19. Turn on the vacuum pump and set the at negative pressure 200 mmHg. (see
the pressure gauge)
20. At this pressure, repeat step i through r. And similarly for negative pressure
400 mmHg, 600 mmHg, and 700 mmHg. (Ask the technician to demonstrate
on how to relief the negative pressure in evaporator system)
100 cm.
4.0 RESULTS
Effect Of Vacuums Level On Evaporation Rates
No
.
Pressu
re
(mmH
g)
1
Level
of
KMnO
4
Time
(first
bubble
)
Time
(to
boil)
Evaporate
RI
Volume
Concentrate
RI
Volum
e
Condensate
RI
Volume
(ml)
(cm)
(min)
(ml)
(ml)
(min)
25
1.32
5.15
1.337
565
Atm
press
-200
25
0.59
1.26
1.339
400
-400
25
0.25
0.54
1.340
2
335
No
.
Pressu
re
Time
(first
bubble
)
(min)
25
1.32
5.15
(mmH
g)
Atm
press
-200
Level
of
KMnO
4
(cm)
25
0.59
1.26
-400
25
0.25
0.54
Time
(to
boil)
Evaporate
Conc Volume
entrat
ion
(ml)
(min)
(M)
0.057
0.098
7
0.123
7
565
400
335
1.340
8
1.337
9
1.337
9
65
3.4
177
1.340
7
1.339
172
1.336
122
Concentrate
Conce Volum
ntratio
e
n
(ml)
(M)
0.136
65
2
0.075
177
8
0.075
172
8
58
Condensate
Conc
Volume
entrat
ion
(ml)
(M)
0.134
2
0.098
7
0.036
2
3.4
58
122
Time(min)
2
1
0
-450-400-350-300-250-200-150-100 -50
Sample Calculation
Given RI = 1.337
Using this equation: y = 20.837x-27.802
Substitute RI into x, y = 20.837(1.337)-27.802
So, concentration = y = 0.0571 M
1
2
Pressu
re
(mmH
g)
Atm
press
Atm
press
Level
of
KMnO
4
Time
(first
bubble
)
Time
(to
boil)
Evaporate
RI
Volume
Concentrate
RI
Volum
e
Condensate
RI
Volume
(ml)
(cm)
50
(min)
0.48
(min)
1.54
75
0.44
2.22
1.338
2
1.338
5
(ml)
(ml)
165
540
1.338
630
1.3379 240
1.338
92
1.337
7
170
No
.
Pressu
re
Level
of
KMnO
4
(cm)
(mmH
g)
Atm
press
Atm
press
1
2
Time
(first
bubble
)
(min)
Time
(to
boil)
Evaporate
Conc Volume
entrat
ion
(ml)
540
Concentrate
Conce Volum
ntratio
e
n
(ml)
(M)
0.0779 165
630
0.0758 240
(min)
50
0.48
1.54
75
0.44
2.22
(M)
0.082
1
0.088
3
Condensate
Conc
Volume
entrat
ion
(ml)
(M)
0.077
9
0.071
7
92
170
Time (min)
2
1
0
20
30
40
50
60
70
80
Pressur
e
Level
of
KMnO
(mmHg
)
1
2
3
ATM
Press
ATM
Press
ATM
Press
Runnin
g time
(min)
Time
(first
bubble)
(min)
Time
(to
boil)
Evaporate
RI
(min)
(cm)
25
10
1.02
1.43
25
15
0.50
1.21
25
20
2.05
2.59
1.338
8
1.339
8
1.337
0
Concentrate
Volum
e
(ml)
570
RI
1.3385
Volum
e
(ml)
70
515
1.3392
125
565
1.3408
65
Condensate
RI
Volum
e
(ml)
20.5
1.338
4
1.338
6
1.340
7
40
3.4
N
o
Press
ure
Level
of
KMnO
(mm
Hg)
Runnin
g time
(min)
Time
(first
bubbl
e)
(min)
Time
(to
boil)
Evaporate
(min)
Concentrat
ion (M)
Volum
e
(ml)
Concentr
ation (M)
Volum
e
(ml)
Concentr
ation (M)
Volume
(ml)
(cm)
1
2
3
ATM
Press
ATM
Press
ATM
Press
Concentrate
Condensate
25
10
1.02
1.43
0.0946
570
0.0883
70
0.0862
20.5
25
15
0.50
1.21
0.1154
515
0.1029
125
0.0904
40
25
20
2.05
2.59
0.0570
565
0.1632
65
0.1342
3.4
Sample Calculation
Given RI = 1.337
Using this equation: y = 20.837x-27.802
Substitute RI into x, y = 20.837(1.337)-27.802
So, concentration = y = 0.0571 M
Runnin
g time
Time
(first
bubbl
e)
(min)
(min)
Concentra
tion (M)
10
1. 02
1.43
0.0946
15
0.50
1.21
0.1154
20
2.05
2.59
0.0570
(min)
Time
(to
boil)
Evaporate
Rate
(1st
bubbl
e)
0.092
7
0.230
8
0.027
8
Concentrate
Rate
(boiling)
Concentr
ation (M)
0.0662
0.0883
-0.0954
0.1029
0.0220
0.1632
Rate
(1st
bubbl
e)
0.086
6
0.205
8
0.079
6
Condensate
Rate
(boiling)
Concentr
ation (M)
Rate
(1st
bubble
)
0.0617
0.0862
0.0845
-0.0850
0.0904
0.1808
0.0630
0.1342
0.0655
Calculation :
Rate (1st bubble ) =
Concetration( M )
Time 1 st Bubble(min)
Rate (boiling ) =
Concetration(M )
Time boiling( min)
1st Bubble
1.5
Boiling Point
1
0.5
0
8
10
12
14
16
18
20
22
-0.1
-0.15
-0.2
-0.25
Running Time (min)
-0.1
-0.15
-0.2
-0.25
Running Time (min)
5 10 15 20 25
-0.1
-0.15
-0.2
Running Time (min)
5.0 DISCUSSION
not
the
the
the
While recording the time using the stopwatch, human error might occur where
there might be a time interval between the stopping time and the recorded
time.
While observing the bubbles with bare eyes, we might miss the first few
bubbles which were too small to be seen, causing longer bubble time being
recorded.
6.0 CONCLUSION
In this experiment, different parameters have been manipulated to study their
effect on evaporation rates. The manipulated variables are vacuum levels, feed flow
rate and evaporation time. In the first experiment, the value of vacuum levels inside
the evaporator is varied from atmospheric pressure to -400mmHg. From the result
obtained, it can be seen that as the pressure (vacuum level) decreases, the time for
first bubble and boiling point also decreases.
In the second experiment, the pressure is maintained at atmospheric pressure
while the level of the feed is varied from 25cm to 75cm. From the results, we can see
that as the level of feed increases, the evaporation time take place faster. This
shows that evaporation time is indirectly proportional to the feed level.
In the third experiment, the effect of evaporation time with time taken for feed
to boil is determined. The time for the first bubble to appear and the feed to boil is
recorded. From the result gained, we can see that as the running time increase, the
rate of evaporation decreases. In the graphs provided, the rate of reaction against
running time for evaporates, condensate, and concentrate is illustrated to show that
the relation between evaporation time on concentration of product left.
11
Therefore, we can conclude that all the parameters tested give influence to
the evaporation rates. All of these factors must be measured in order to attain
absolute evaporation rates.
7.0 REFERENCES
12