Beruflich Dokumente
Kultur Dokumente
autnoma de Puebla
Facultad de Ingeniera Qumica
Colegio de Materiales
Fsicoqumica III
Luis Felipe Hernandez Rivera
Jos Cabrera Pelez
Primavera 2015
201318836
12.27
P
T
Cv
ds=
dT +
T
P
T
Cv
ds=
dT +
T
P
T
( RT ( vb )
a
)
T v2
RT ( vb )
a
T v2
ds= R ( vb )+
a
2 2
T v
()dV
RvRb+
s2
v2
ds=
s1
v1
a
dV
T 2 v2
RV2
a
S=
bRV 2
2
T V
b)
(V )
T
vT = dP
dH=CpdT +
(V )
T
v T = dP
dH=
x
y
y
z
z
x
V
T
T
P
P
V
V
T
T
P
P
V
V
T
P
T
P
V
P
V
RT ( vb )
a
T v2
P
T
RT ( vb )
T
a
T v2
P
V
P
T
vT
dH=
v T dP
dH=
v T dP
dH=
v T dP
dH=
T
T
2
( 2V )T 2 V 3 R+2 a
T V 3 ( 2V 2 R ( vb ) +a )
dP
vT
dH =
T
V ( 2V R ( vb ) +a )
( T ) (T 2 V 3 R+ 2a)
dP
v T
dH =
2
T
V ( 2V 2 R ( vb ) +a )
2
(T V R+ 2a)
v+ dP
dH =
T
V ( 2V R ( vb ) +a )
(T 2 V 3 R+ 2a)
v+ dP
P2
dH =
P
H2
H1
T
V ( 2V 2 R ( vb ) +a )
(T 2 V 3 R+ 2a)
v+ dP
P2
H =
P
T
V ( 2V R ( vb ) +a )
(T 2 V 3 R+ 2a)
v + P
H =
2
12.31
dH=C P dT 1
dP+VdP
( V
T )
P
PV
AP
=1+
RT
T
PV =1+
AP
( RT )
T
C P =B + CT
0
V=
RT APR
+
P
P
V=
RT
+ AR
P
dH= ( B+CT ) dT T
H= BT +
( RTP + AR )
T
dP+VdP
P
RT
RT
DP +
+ AR dP
P
P
dH= ( B+CT ) dT
T2
P2
CT
RT RT
+ 2+
+ ARP
2
2
P
P
P
T
P2
P1
C T 22
C T 21 RT RT RT
RT
H=B T 2+
B T 1
+ 2 2 2 + AR P2 + 2 AR P1
2
2
P2 P1 P 2
P1
H=B ( T 2T 1)
C 2
T 2T 21 ) + AR ( P2P1 )
(
2
T
CpCv=
14.67 x 103 m3
)(273.15 K )(174 x 106 K 1)2
mol
CpCv=
3.79 x 107 cm2 /N
(
CpCv=3.201 x 10
CpCv=
CpCv=
m
( K ) ( K 1)
Kmol
2
m
N
=(
m
1 N
)( )( 2 )
Kmol K m
mN
KJ
=
KmolK KmolK
CpCv=3.201 x 10(8 )
KJ
kmolK
b)
CpCv=3.201 x 10(8 )
28
KJ
kmolK
KJ
KJ
(8)
Cv=3.201 x 10
kmolK
kmolK
Cv=3.201 x 10
KJ
KJ
28
KmolK
kmolK
Cv=27.99999997
KJ
KmolK
Cv=27.99999997
KJ
KJ
=28
=Cp
KmolK
kmolK
12.42
CpCv=
T 2
CpCv=
CpCv=
1
ft
(R)( )
R lbmol
2
ft
lbf
) = ft 1 lbf
( lbmol )( R )( ft )
3
ft lbf
Btu
=
lbmolR lbmolF
Btu=778.169 lbf*ft
CpCv=3.055663358 x 1011
b)
Btu
lbmolF
6.69
Btu
Btu
Cv=3.055663358 x 1011
lbmolf
lbmolF
Cv=3.055663358 x 10 11
Btu
Btu
+6.69
lbmolF
lbmolF
11
Cv=
3.05566358 x 10 Btu
lbmolF
Cv=3.05566358 x 1011
Btu
Btu
=66.9
lbmolF
lbmolF
12.46
V
P
V
T
dV =
V
T
1
K=
V
V
T
V
T
dV =
k T =0.125 x 103 /v (P+2.740)
dV =
0.125 x 103
VdP
v ( P+2.740)
dV =
0.125 x 103
dP
(P+2.740)
V2
w= PdV
V1
P2
w= P
P1
0.125 x 103
dP
( P+ 2.740)
P2
3
w=0.125 x 10
( P+ 2.740) dP
P1
P2
(P+2.740) dP
P1
U=P
dv= ( P+2.740)
du=dP
v=ln
P+2.740
)
P+2.740
P. ln
)
P2
ln( P+ 2.740) dP
P1
U= P+2.740
du=dP
3
w=0.125 x 10
P+2.740
P. ln
)
P2
ln u du
P1
0.125 x 103
][P. ln ( P+2.740) -[( P+2.740 ln ( P+ 2.740 )( P+2.740 ) ]
w=
Evaluada de 1 a 600
[(600). ln (600+2.740) -[( 600+2.740 ln ( 600+2.740 ) ( 600+2.740 ) ][(1). ln (1+2.740) -[( 1+2.740 ln (1+2.740 ) ( 1+2.740 )
3
w=0.125 x 10
[[585.21]-[-7.354]]
w=[0.125 x 10 ] 592.56
W=-0.074 J
b)
De acuerdo a la primera ley de la termodinmica el calor transferido es igual al
trabajo
( TP )
M JT =
1 bar=102
( 330.79308.08
)
75
=11.355
2948.92
C
C
=1.135
MPa
(b)
417.80393.40
12.59
3097.5
=6.97
C
C
=0.697
MPa
Conversiones
1
10 2 kPa
C 103 MPa
6.97
MPa
1 kPa
1
10 2 kPa
C 103 MPa
6.97
MPa 1 KPa
, a12 y 80 C
C
1.01325
12 bar ( 1 atm ( 101.325 Kpa )( 1 Mpa ) = 1.2 Mpa
1 atm
1000 Kpa
MJT= ( p ) p ( P )
P=1.4
Mpa
KJ
Kg
temperatura
80
Y1
90
entalpia
308.34
311.39
319.37
9080
80=82.76
P=1 Mpa
MJT=
70
Y1
80
h
)
P
13.775Mpa
P=
8070
303.85
311.39
314.25
82.7677.25
)
KJ
1.41
311.39
Kg
1.01325
1atm
= 1.3775
1 Mpa
101.325 Kpa
1000 Kpa
1 atm
)(
=13.775 (
Mpa
a) el valor de Cp= ( t
)p
Cp= ( T
Cp=
) p ( T )
1429.81329.4
)
800600
100psia
BTU
= 0.502 ( Lbmol
b) MJT= ( p ) p ( P )
BTU
lbm
temperatura
600
Y1
700
P=80
psia
entalpia
1330.8
1379.5
1380.5
700600
P=120
psia
700
Y1
800
1378.4
1379.5
1380.5
800700
MJT= ( p ) p ( P )
=(
702.17697.98
= 0.10475
12080